Exotic Behavior Research Articles

Structural determination and exotic resistive behaviour of α-RuI3 under high-pressure

Structural determination and exotic resistive behaviour of α-RuI3 under high-pressure

Intrinsic Out-Of-Plane and In-Plane Ferroelectricity in 2D AgCrS2 with High Curie Temperature.

2D ferroelectric materials have attracted extensive research interest due to potential applications in nonvolatile memory, nanoelectronics and optoelectronics. However, the available 2D ferroelectric materials are scarce and most of them are limited by the uncontrollable preparation. Herein, a novel 2D ferroelectric material AgCrS2 is reported that are controllably synthesized in large-scale via salt-assist chemical vapor deposition growth. By tuning the growth temperature from 800 to 900°C, the thickness of AgCrS2 nanosheets can be precisely modulated from 2.1 to 40nm. Structural and nonlinear optical characterizations demonstrate that AgCrS2 nanosheet crystallizes in a non-centrosymmetric structure with high crystallinity and remarkable air stability. As a result, AgCrS2 of various thicknesses display robust ferroelectric polarization in both in-plane (IP) and out-of-plane (OOP)directions with strong intercorrelation and high ferroelectric phase transition temperature (682 K). Theoretical calculations suggest that the ferroelectricity in AgCrS2 originates from the displacement of Ag atoms in AgS4 tetrahedrons, which changes the dipole moment alignment. Moreover, ferroelectric switching is demonstrated in both lateral and vertical AgCrS2 devices, which exhibit exotic nonvolatile memory behavior with distinct high and low resistance states. This study expands the scope of 2D ferroelectric materials and facilitates the ferroelectric-based nonvolatile memory applications.

Quantum logarithmic multifractality

Through a combination of rigorous analytical derivations and extensive numerical simulations, this work reports an exotic multifractal behavior, dubbed “logarithmic multifractality,” in effectively infinite-dimensional systems undergoing the Anderson transition. In contrast to conventional multifractality observed in finite dimensions, logarithmic multifractality at infinite dimension introduces an algebraic behavior with respect to the logarithm of system size or time. We demonstrate this phenomenon across eigenstate statistics, spatial correlations, and wave packet dynamics. Our findings offer crucial insights into strong finite-size effects and slow dynamics in complex systems undergoing the Anderson transition, such as the many-body localization transition. Published by the American Physical Society 2024

Thermoelectric Response in Nodal‐Point Semimetals

AbstractIn this review, the thermoelectric properties in nodal‐point semimetals with two bands are discussed. For the two‐dimensional (2D) cases, it is shown that the expressions of the thermoelectric coefficients take different values depending on the nature of the scattering mechanism responsible for transport, by considering examples of short‐ranged disorder potential and screened charged impurities. An anisotropy in the energy dispersion spectrum invariably affects the thermopower quite significantly, as illustrated by the results for a node of semi‐Dirac semimetal and a single valley of graphene. The scenario when a magnetic field of magnitude is applied perpendicular to the plane of the 2D semimetal is also considered. The computations for the three‐dimensional (3D) cases necessarily involve the inclusion of nontrivial Berry phase effects. In addition to demonstrating the expressions for the response tensors, the exotic behavior observed in planar Hall and planar thermal Hall set‐ups is discussed.

Superlubric Sliding of Graphene Auto-Kirigami with Interfaces Containing Self-Assembled Stripe-Pattern Adsorbates.

Van der Waals heterostructures formed by stacked 2D materials show exceptional electronic, mechanical, and optical properties. Superlubricity, a condition where atomically flat, incommensurate planes of atoms result in ultra-low friction, is a prime example enabling, for example, self-assembly of optically visible graphene nanostructures in air via a sliding auto-kirigami process. Here, it is demonstrated that a subtle but ubiquitous adsorbate stripe structure found on graphene and graphitic surfaces in ambient conditions remains stable within the interface between twisted graphene layers as they slide over each other. Despite this contamination, the interface retains an exceptional superlubricious state with an estimated upper bound frictional shear strength of 10kPa, indicating that direct atomic incommensurate contact is not required to achieve ambient superlubricity for 2D materials. The results suggest that any phenomena depending on 2D heterostructure interfaces such as exotic electronic behavior may need to consider the presence of stripe adsorbate structures that remain intercalated.

Superfine Nanodomain Engineering Unleashing Ferroelectricity in Incipient Ferroelectrics.

Incipient ferroelectrics have emerged as an attractive class of functional materials owing to their potential to be engineered for exotic ferroelectric behavior, holding great promise for expanding the ferroelectric family. However, thus far, their artificially engineered ferroelectricity has fallen far short of rivaling classic ferroelectrics. In this study, we address this challenge by developing a superfine nanodomain engineering strategy. By applying this approach to representative incipient ferroelectric of SrTiO3-based films, we achieve unprecedentedly strong ferroelectricity, not only surpassing previous records for incipient ferroelectrics but also being comparable to classic ferroelectrics. The remanent polarization of the thin film reaches up to 17.0 μC cm-2 with an ultrahigh Curie temperature of 973 K. Atomic-scale investigations elucidate the origin of this robust ferroelectricity in the emergent high-density superfine nanodomains spanning merely 3-10 unit cells. Combining experimental results with theoretical assessments, we unveil the underlying mechanism, where the intentionally introduced diluted foreign Fe element creates a deeper Landau energy well and promotes a short-range ordering of polarization. Our developed strategy significantly streamlines the design of unconventional ferroelectrics, providing a versatile pathway for exploring new and superior ferroelectric materials.

INSPIRED: Inelastic neutron scattering prediction for instantaneous results and experimental design

Inelastic neutron scattering (INS) has unique advantages in probing how atoms vibrate and how the vibrations propagate and interact. Such dynamic information is crucial in understanding various material properties, from heat capacity, thermal conductivity, phase transitions, and chemical reactions to more exotic quantum behavior. The analysis and interpretation of the INS spectra often start from a model structure of the sample, followed by a series of calculations to obtain the simulated spectra to compare with experiments. The conventional way to perform such calculations usually requires significant time, computing resources, and specialized expertise. Here, we present a new program named INSPIRED (Inelastic Neutron Scattering Prediction for Instantaneous Results and Experimental Design), which enables users to perform rapid INS simulations in several different ways on their personal computers in just a few clicks, with the crystal structure as the only input file. Specifically, the users can choose a pre-trained symmetry-aware neural network (coupled with an autoencoder) to predict the phonon density of states (DOS), 1D S(E) and 2D S(|Q|,E) spectra for any given structure. One can also choose an existing density functional theory (DFT) calculation from a database (containing over 12,000 crystals), and quickly obtain the simulated INS spectra for single crystals and powders. It is also possible to use pre-trained universal machine learning force fields to relax a given crystal structure, calculate the phonon dispersion and DOS, and, subsequently, the INS spectra. All these functions are implemented with a PyQt graphic user interface. We expect these new tools will benefit broad user communities and significantly improve the efficiency of experiment design, execution, and data analysis for INS. Program summaryProgram Title: INSPIREDCPC Library link to program files:https://doi.org/10.17632/8g3s8f9n2p.1Developer's repository link:https://github.com/cyqjh/inspired (software), https://doi.org/10.5281/zenodo.11478889 (database, models files, and virtual machine appliance file)Licensing provisions: MITProgramming language: PythonNature of problem: How to easily and quickly assess the expected INS spectra for a given crystal structure has been a major challenge in the INS user community. It is a main bottleneck affecting almost every stage of the workflow, from experimental design and steering to data analysis and interpretation. The widely used approach involving DFT calculations is time-consuming, requires advanced computing resources, and has a steep learning curve. With the growing power of neutron sources and more high-throughput INS experiments, there is a pressing need to address this problem, preferably by taking advantage of the recent developments in machine learning and artificial intelligence.Solution method: We take a data-driven approach to tackle the problem. A symmetry-aware neural network is trained to make direct predictions from the crystal structure to either 1D spectra or latent space vectors, which can be decoded to reconstruct 2D spectra. The database used for the training contains over ten thousand crystals, which can also be used to calculate INS spectra for single crystals and powders. The recently emerging universal machine learning force fields provide another venue to accelerate the simulation significantly. All these solutions are implemented in a graphic user interface so that a user with no modeling/programming background or access to powerful computers can still easily run the workflow.

Period Three Cycles of the Logistic Map

The logistic map is famous for its simple definition yet exotic behavior. Among its many fascinating features are its cycles, that is, iterations of the map that return to their starting points. We use a new algebraic approach to identify the value of the growth parameter of the logistic map at which cycles of period three first appear.

Manipulation of band gap in 1T-TiSe2 via rubidium deposition

Abstract The 1T-TiSe2 is a two-dimensional charge-density-wave (CDW) material that attracts great interest. A small band gap locates at the Fermi level separating the Ti d-bands and Se p-bands, which makes 1T-TiSe2 a promising candidate for realizing excitonic condensation. Here, we studied the band gap in 1T-TiSe2 using angle-resolved photoemission spectroscopy (ARPES). Instead of only focusing on the in-plane band dispersions, we obtained the detailed band dispersions of both conduction and valance bands along the out-of-plane direction. We found that the conduction and valance bands split into multiple sub-bands in the CDW state due to band folding. As a result, the band gap between the Ti d-bands and Se p-bands reduces to ∼25 meV and becomes a direct gap in the CDW state. More intriguingly, such band gap can be further reduced by the rubidium deposition. The band structure becomes semimetallic in the rubidium-doped sample. Meanwhile, exotic gapless behaviors were observed at the p–d band crossing. Our result characterized the band gap of 1T-TiSe2 in three-dimensional Brillouin zone with unpreceded precision. It also suggests a closing of band gap or a potential band inversion in 1T-TiSe2 driven by rubidium deposition.

Momentum-exchange interactions in a Bragg atom interferometer suppress Doppler dephasing.

Large ensembles of laser-cooled atoms interacting through infinite-range photon-mediated interactions are powerful platforms for quantum simulation and sensing. Here we realize momentum-exchange interactions in which pairs of atoms exchange their momentum states by collective emission and absorption of photons from a common cavity mode, a process equivalent to a spin-exchange or XX collective Heisenberg interaction. The momentum-exchange interaction leads to an observed all-to-all Ising-like interaction in a matter-wave interferometer. A many-body energy gap also emerges, effectively binding interferometer matter-wave packets together to suppress Doppler dephasing in analogy to Mössbauer spectroscopy. The tunable momentum-exchange interaction expands the capabilities of quantum interaction-enhanced matter-wave interferometry and may enable the realization of exotic behaviors, including simulations of superconductors and dynamical gauge fields.

Observation of the nonanalytic behavior of optical phonons in monolayer hexagonal boron nitride

Phonon splitting of the longitudinal and transverse optical modes (LO-TO splitting), a ubiquitous phenomenon in three-dimensional polar materials, will break down in two-dimensional (2D) polar systems. Theoretical predictions propose that the LO phonon in 2D polar monolayers becomes degenerate with the TO phonon, displaying a distinctive “V-shaped” nonanalytic behavior near the center of the Brillouin zone. However, the full experimental verification of these nonanalytic behaviors has been lacking. Here, using monolayer hexagonal boron nitride (h-BN) as a prototypical example, we report the comprehensive and direct experimental verification of the nonanalytic behavior of LO phonons by inelastic electron scattering spectroscopy. Interestingly, the slope of the LO phonon in our measurements is lower than the theoretically predicted value for a freestanding monolayer due to the screening of the Cu foil substrate. This enables the phonon polaritons in monolayer h-BN/Cu foil to exhibit ultra-slow group velocity (~5 × 10−6c, c is the speed of light) and ultra-high confinement (~ 4000 times smaller wavelength than that of light). These exotic behaviors of the optical phonons in h-BN presents promising prospects for future optoelectronic applications.

The 2022 Outburst of IGR J17091–3624: Connecting the Exotic GRS 1915+105 to Standard Black Hole X-Ray Binaries

While the standard X-ray variability of black hole X-ray binaries (BHXBs) is stochastic and noisy, there are two known BHXBs that exhibit exotic “heartbeat”-like variability in their lightcurves: GRS 1915+105 and IGR J17091–3624. In 2022, IGR J17091–3624 went into outburst for the first time in the NICER/NuSTAR era. These exquisite data allow us to simultaneously track the exotic variability and the corresponding spectral features with unprecedented detail. We find that as in typical BHXBs, the outburst began in the hard state, then continued in the intermediate state, but then transitioned to an exotic soft state, where we identify two types of heartbeat-like variability (Class V and a new Class X). The flux energy spectra show a broad iron emission line due to relativistic reflection when there is no exotic variability, and absorption features from highly ionized iron when the source exhibits exotic variability. Whether absorption lines from highly ionized iron are detected in IGR J17091–3624 is not determined by the spectral state alone, but rather is determined by the presence of exotic variability; in a soft spectral state, absorption lines are only detected along with exotic variability. Our finding indicates that IGR J17091–3624 can be seen as a bridge between the most peculiar BHXB GRS 1915+105 and “normal” BHXBs, because it alternates between the conventional and exotic behaviors of BHXBs. We discuss the physical nature of the absorbing material and exotic variability in light of this new legacy data set.

Temperature dependence of photoluminescence in twisted heterobilayers of transition-metal dichalcogenides

Two-dimensional (2D) van der Waals transition metal dichalcogenides (TMDCs) are highly attractive due to their novel phenomena and potential device applications. Especially, twisted heterojunction of different 2D TMDC monolayers for various twist angles (θ) is one of the hot issues in the area of 2D TMDCs because they exhibit exotic quantum behaviors. Here, we report the effect of temperature (T) on the θ-dependent variation of photoluminescence (PL) spectra of MoS2/WS2 heterobilayers. The PL peak-vs-T variations are divided into three θ regions. Near θ = 0 and 60°, the PL peak energies show almost monotonically-decreasing behaviors with increasing T, caused by stronger electron-phonon interactions at higher T. However, in the intermediate θ range, the PL peaks show similar red shifts over almost full T range except anomalous blue shifts in a short T range near ∼150 K. We discuss this anomalous PL behaviors based on hybridization of interlayer and intralayer excitons, resulting in the formation of hybridized excitons, correlated with structural transition.

Mediation of collisionless turbulent dissipation through cyclotron resonance

The dissipation of turbulence in astrophysical systems is fundamental to energy transfer and heating in environments ranging from the solar wind and corona to accretion disks and the intracluster medium. Although turbulent dissipation is relatively well understood in fluid dynamics, astrophysical plasmas often exhibit exotic behaviour, arising from the lack of interparticle collisions, which complicates turbulent dissipation and heating in these systems. Recent observations by NASA’s Parker Solar Probe mission in the inner heliosphere have shed new light on the role of ion cyclotron resonance as a potential candidate for turbulent dissipation and plasma heating. Here, using in situ observations of turbulence and wave populations, we show that ion cyclotron waves provide a major pathway for dissipation and plasma heating in the solar wind. Our results support recent theoretical predictions of turbulence in the inner heliosphere, known as the helicity barrier, that suggest a role of cyclotron resonance in ion-scale dissipation. Taken together, these results provide important constraints for turbulent dissipation and acceleration efficiency in astrophysical plasmas.

Odd Response-Induced Phase Separation of Active Spinners.

Due to the breaking of time-reversal and parity symmetries and the presence of non-conservative microscopic interactions, active spinner fluids and solids respectively exhibit nondissipative odd viscosity and nonstorage odd elasticity, engendering phenomena unattainable in traditional passive or active systems. Here, we study the effects of odd viscosity and elasticity on phase behaviors of active spinner systems. We find the spinner fluid under a simple shear experiences an anisotropic gas-liquid phase separation driven by the odd-viscosity stress. This phase separation exhibits equilibrium-like behavior, with both binodal-like and spinodal curves and critical point. However, the formed dense liquid phase is unstable, since the odd elasticity instantly takes over the odd viscosity to condense the liquid into a solid-like phase. The unusual phase behavior essentially arises from the competition between thermal fluctuations and the odd response-induced effective attraction. Our results demonstrate that the cooperation of odd viscosity and elasticity can lead to exotic phase behavior, revealing their fundamental roles in phase transition.

Nonsaturating Linear Magnetoresistance Manifesting Two-Dimensional Transport in Wet-Chemical Patternable Bi2O2Te Thin Films.

Two-dimensional (2D) materials with exotic transport behaviors have attracted extensive interest in microelectronics and condensed matter physics, while scaled-up 2D thin films compatible with the efficient wet-chemical etching process represent realistic advancement toward new-generation integrated functional devices. Here, thickness-controllable growth and chemical patterning of high-quality Bi2O2Te continuous films are demonstrated. Noticeably, except for an ultrahigh mobility (∼45074 cm2 V-1 s-1 at 2 K) and obvious Shubnikov-de Hass quantum oscillations, a 2D transport channel and large linear magnetoresistance are revealed in the patterned Bi2O2Te films. Investigation implies that the linear magnetoresistance correlates with the inhomogeneity described by P. B. Littlewood's theory and EMT-RRN theory developed recently. These results not only reveal the nonsaturating linear magnetoresistance in high-quality Bi2O2Te but shed light on understanding the corresponding physical origin of linear magnetoresistance in 2D high-mobility semiconductors and providing a pathway for the potential application in multifunctional electronic devices.

Polaronic Nonlinear Optical Response and All-Optical Switching Based on an Ionic Metal Oxide.

It has been well-established that light-matter interactions, as manifested by diverse linear and nonlinear optical (NLO) processes, are mediated by real and virtual particles, such as electrons, phonons, and excitons. Polarons, often regarded as electrons dressed by phonons, are known to contribute to exotic behaviors of solids, from superconductivity to photocatalysis, while their role in materials' NLO response remains largely unexplored. Here, the NLO response mediated by polarons supported by a model ionic metal oxide, TiO2, is examined. It is observed that the formation of polaronic states within the bandgap results in a dramatic enhancement of NLO absorption coefficient by over 130 times for photon energies in the sub-bandgap regions, characterized by a 100fs scale ultrafast response that is typical for thermalized electrons in metals. The ultrafast polaronic NLO response is then exploited for the development of all-optical switches for ultrafast pulse generation in near-infrared (NIR) fiber lasers and modulation of optical signal in the telecommunication band based on evanescent interaction on a planar waveguide chip. These results suggest that the polarons supported by dielectric ionic oxides can fill the gaps left by dielectric and metallic materials and serve as a novel platform for nonlinear photonic applications.

Origin of the Anomalous Electrical Transports in Quasi-One-Dimensional Ta2NiSe7.

Exploration of exotic transport behavior is of great interest and importance for revealing the properties of the CDW phase of quasi-one-dimensional Ta2NiSe7. We report the anisotropic electrical transport properties of Ta2NiSe7 single crystals in the CDW phase. The anisotropic constant (γ = ρb/ρc) increased rapidly at TCDW = 60 K upon cooling. The results of the Hall resistivity show that both the concentrations and mobilities of carriers change abruptly at TCDW. The out-of-plane AMR exhibits C2 and C4 symmetry components while the in-plane AMR exhibits C2, C4, and C6 at the CDW state. The planar Hall effect is observed in Ta2NiSe7 at low temperature, which is suggested to originate from the anisotropic orbital magnetoresistance. The calculated results show that the Fermi surface of Ta2NiSe7 was slightly reconstructed due to the CDW transition. This work highlights the enhancement of Fermi surface anisotropy during CDW formation and provides a novel approach to study the CDW materials.

The exotic behavior of the wave evolution in Lévy crystals within a fractional medium

We investigate a traveling Gaussian wave packet transport through a rectangular quantum barrier of lévy crystals in fractional quantum mechanics formalism. We study both standard and fractional Schrödinger equations in linear and nonlinear regimes by using a split-step finite difference (SSFD) method. We evaluate the reflection, trapping, and transmission coefficients of the wave packet and the wave packet spreading by using time-dependent inverse participation ratio (IPR) and second moment. By simultaneously adjusting the fractional and nonlinear terms, we create sharp pulses, which is an essential issue in optoelectronic devices. We illustrate that the effects of barrier height and width on the transmission coefficient are strangely different for the standard and fractional Schrödinger equations. We observe fortunately soliton-like localized wave packets in the fractional regime. Thus, we can effectively control the behavior of the wave evolution by adjusting the available parameters, which can excite new ideas in optics.

Conduction Mechanism Switching from Coulomb Blockade to Classical Critical Percolation Behavior in Disordered Nanoparticle Array

AbstractLarge, open‐gate transistors made from metal nanoparticle arrays offer possibilities to build new electronic devices, such as sensors. A nanoparticle necklace network (N3) of Au particles from 300 K to cryogenic temperatures exhibit a nonohmic I–Vd behavior, I ≈ (Vd–VT)ζ, where VT is a conduction gap and ζ is a constant critical exponent. The conduction gap in N3, made from disordered networks of 1D chains of 10 nm diameter Au particles exhibits room temperature (RT) gating. Although the I–Vd behavior at RT is identical to Coulomb blockade, the conduction is modulated by field‐assisted tunneling exhibiting classical critical behavior. In this study, based on three results, invariance of VT on gating, invariance of VT on temperature, and zero–bias conductance, a sharp transition temperature at ≈140 K is discovered where the conduction mechanism switches from Coulomb blockade to classical critical percolation behavior. The N3 architecture allows the reconciliation of the Coulomb blockade versus activation process as a sharp thermal transition to serve as a model system to study the exotic behavior in nanogranular‐metallic materials. The novel global critical behavior to local Coulomb blockade governed transition in these N3 architectures may potentially lead to novel sensors and biosensors.