Exchange Interactions In Dimers Research Articles

Engineering of Magnetic Coupling in Nanographene.

Nanographenes with sublattice imbalance host a net spin according to Lieb's theorem for bipartite lattices. Here, we report the on-surface synthesis of atomically precise nanographenes and their atomic-scale characterization on a gold substrate by using low-temperature noncontact atomic force microscopy and scanning tunneling spectroscopy. Our results clearly confirm individual nanographenes host a single spin of S=1/2 via the Kondo effect. In covalently linked nanographene dimers, two spins are antiferromagnetically coupled with each other as revealed by inelastic spin-flip excitation spectroscopy. The magnetic exchange interaction in dimers can be well engineered by tuning the local spin density distribution near the connection region, consistent with mean-field Hubbard model calculations. Our work clearly reveals the emergence of magnetism in nanographenes and provides an efficient way to further explore the carbon-based magnetism.

Mn doped BiNbO4 ceramics: Thermal stability, phase transitions, magnetic properties, NEXAFS and ESR spectroscopy

Thermal stability, magnetic properties, ESR (Electron Spin Resonance) and NEXAFS (Near-Edge X-ray Absorption Fine Structure) spectra of the orthorhombic and triclinic modifications of solid solutions BiNb1-xMnxO4-δ have been studied. X-ray diffraction determined the reversibility of the phase transition from the high-temperature triclinic modification to the orthorhombic modification at 950 °C in the BiNb1-xMnxO4-δ solid solutions. The ESR spectra of the triclinic BiNb1-xMnxO4-δ revealed the sextet structure of Mn(II) ions with 8.4 mT splitting and some features at g = 3.80 and 1.47, and a broad diffuse band with g ∼ 2.2 having a sextet with 8–9 mT splitting and g = 2.0 against its background. The measurements of magnetic susceptibility allowed us to calculate the parameters of exchange interactions in dimers and the distribution of manganese atoms (II), (III) and (IV) in dependence on concentrations of the solid solutions in the orthorhombic and triclinic modifications. It was established that in the manganese-doped solid solutions of triclinic modification, the degree of aggregation and the nuclearity of the clusters were higher than in the solid solutions of orthorhombic modification. The clusters were presented in the forms of dimers and trimers of Mn(II), Mn(III) and Mn(IV) atoms with different valence atoms with antiferro- and ferromagnetic types of exchange.The solid solutions BiNb1-xMnxO4-δ as well as manganese oxides MnO, Mn2O3 and MnO2 were studied by the NEXAFS spectroscopy in order to determine the degrees of oxidation of manganese atoms. The DSC (Differential Scanning Calorimetry) curves of the samples BiNb1-xMnxO4-δ revealed the endothermic effects associated with the phase transition from the orthorhombic modification to the triclinic one at 1050 °C (x = 0.03) and 1048 °C (x = 0.06). The melting peaks were observed at 1231 °C (x = 0.03) and 1220 °C (x = 0.06), respectively. The differences in the magnetic characteristics and in the results of ESR and NEXAFs spectroscopy of the BiNb1-xMnxO4-δ of orthorhombic and triclinic modifications were due to the relative content of Mn(II), Mn(III), Mn(IV) ions and the degree of distortion of their local surroundings, composition and nature of exchange interactions in the clusters of manganese atoms.

Exchange interactions between dimers of chromium(III). A cluster approach

Exchange interactions in dimers, tetramers and octamers of chromium(III) are treated with an effective Hamiltonian of the Heisenberg-Dirac-vanVleck (HDvV) type. Energies and wave functions of the cluster states are computed. The results of interdimer interactions are: (i) energy splittings and (ii) a contamination of the cluster ground state with excited configurations. The results are used for a qualitative rationalisation of the observed low-temperature properties of Cs3Cr2Cl9.