Exceptional High Density Research Articles

Oxygen solutes induced anomalous hardening, toughening and embrittlement in body-centered cubic vanadium

Vanadium (V) is sensitive to minute quantity of oxygen interstitials, which induce pronounced hardening and embrittlement. Here, we utilize oxygen to synthesize V solid solutions in order to reveal the mechanism of oxygen solutes induced hardening. With increasing of oxygen solute concentrations, the fracture modes of V samples transform from dimple, to a mixture of dimple and cleavage, and to a fully transgranular cleavage. High density of dislocations and dislocation debris are produced in strained samples. The mobility of screw dislocations is reduced and the dislocation cross-slip events are promoted by oxygen solutes. In addition to oxygen solution hardening, the generation of high density of oxygen-vacancy complexes plays a dominant role in the strengthening. High quantity of loop-shaped dislocation debris are direct evidence for the formation of oxygen-vacancy complexes. Profuse oxygen-vacancy complexes trap dislocations, promote cross-slips and assist dislocation storage, thus give rise to a superior combination of strengthening, strain hardening, and ductility in V with 1.0 at% of oxygen. Once beyond a critical oxygen concentration (>1.6 at%), V shows catastrophic brittle failure due to the exceptional high density of oxygen-vacancy complexes. These findings provide insight to design high performance refractory metals utilizing oxygen solutes.

Magnetic fabrics in the Western Central-Pyrenees: An overview

In the Western Central-Pyrenees numerous investigations during the past years have yielded an exceptional high density of localities (more than 700 sites) where the AMS and rock magnetic properties have been determined. This unique AMS dataset helps in understanding the orogenic evolution of the Pyrenees and its foreland basins. Processes related to AMS development in different structural units permit to identify: (i) an early recording of strain related to the transtensional or transpressional stages during the Early Triassic and Early Cretaceous, (ii) a moderate shortening related to the fold-and-thrust belt and foreland basin evolution during the Cretaceous–Tertiary orogenic stage, and (iii) a relatively strong deformation that produced cleavage related to the emplacement of basement thrusts in the Axial Zone during the Middle–Late Eocene. The main achievement of this contribution is the integration in cross-section and map-view of magnetic fabrics (orientation and parameters) in the western Central-Pyrenees, which allow constraining the processes affecting magnetic fabrics at the orogen scale. AMS results indicate: (i) a dominant bedding-controlled foliation, very sensitive to subtle layer parallel shortening (LPS) processes, especially in the foreland basins; (ii) magnetic lineations parallel to fold axes or strike of thrusts outside the cleavage front that can be deflected by vertical-axis rotations in particular areas; and (iii) an overall decrease of the definition of AMS fabrics (magnetic lineation or the anisotropy of the ellipsoid) associated with incipient cleavage and intersection lineation fabrics in the internal zones of the orogen. Therefore, AMS is a sensitive indicator to delineate the strain patterns at the orogen-scale, in particular, in those areas undergoing a modest degree of deformation.

Interior Evolution of Mercury

The interior evolution of Mercury—the innermost planet in the solar system, with its exceptional high density—is poorly known. Our current knowledge of Mercury is based on observations from Mariner 10’s three flybys. That knowledge includes the important discoveries of a weak, active magnetic field and a system of lobate scarps that suggests limited radial contraction of the planet during the last 4 billion years. We review existing models of Mercury’s interior evolution and further present new 2D and 3D convection models that consider both a strongly temperature-dependent viscosity and core cooling. These studies provide a framework for understanding the basic characteristics of the planet’s internal evolution as well as the role of the amount and distribution of radiogenic heat production, mantle viscosity, and sulfur content of the core have had on the history of Mercury’s interior.