Evolution Of Spectral Properties Research Articles

Relationship between anaerobic digestion of biodegradable solid waste and spectral characteristics of the derived liquid digestate

The evolution of spectral properties during anaerobic digestion (AD) of 29 types of biodegradable solid waste was investigated to determine if spectral characteristics could be used for assessment of biological stabilization during AD. Biochemical methane potential tests were conducted and spectral indicators (including the ratio of ultraviolet-visible absorbance at 254nm to dissolved organic carbon concentration (SUVA254), the ratio of ultraviolet-visible absorbance measured at 465nm and 665nm (E4/E6), and the abundance of fluorescence peaks) were measured at different AD phases. Inter-relationship between organic degradation and spectral indicators were analyzed by principle component analysis. The results shows that from methane production phase to the end of methane production phase, SUVA254 increased by 0.16-10.93 times, the abundance of fulvic acid-like compounds fluorescence peak increased by 0.01-0.54 times, the abundance of tyrosine fluorescence peak decreased by 0.03-0.64 times. Therefore, these indicators were useful to judge the course of mixed waste digestion.

Dimers of Quadrupolar Chromophores in Solution: Electrostatic Interactions and Optical Spectra

Two dimers of a heteroaromatic quadrupolar (acceptor-donor-acceptor) chromophore have been synthesized with different interchromophoric distances. Optical spectra of dimers in solution show a red shift of the linear absorption band upon decreasing the interchromophore distance, while fluorescence and two-photon absorption spectra are only marginally affected by the interactions. A bottom up approach is adopted to describe the spectra: via a detailed spectroscopic analysis of the monomeric species in solution, we define an essential-state model for the isolated chromophore and use this information to set up a model for the dimers also accounting for interchromophore electrostatic interactions. To discriminate between static screening governed by the static dielectric constant and dynamical screening at optical frequencies, we first solve the problem in the mean-field approximation and then define the excitonic Hamiltonian on the resulting best excitonic basis. Along this line, the evolution of spectral properties with the interchromophore distance is properly rationalized.

Towards a general model of space weathering of S-complex asteroids and ordinary chondrites

Context.The effect of the space weathering on the spectral properties of the S-complex asteroids has been widely discussed in recent times, and a systematic reddening due to the exposure to the various influxes has been found. The evolution of spectral properties is also affected by other processes, such as close encounters with planetary bodies.

Evolution of spectral properties along the O(6)-U(5) transition in the interacting boson model. I. Level dynamics

We investigate the evolution of quantal spectra and the corresponding wave functions along the [O(6)-U(5)]$\supset$O(5) transition of the interacting boson model. The model is integrable in this regime and its ground state passes through a second-order structural phase transition. We show that the whole spectrum as a function of the Hamiltonian control parameter, as well as structures of all excited states, exhibit rather organized and correlated behaviors, that provide deeper insight into the nature of this transitional path.

Evolution of spectral properties along the O(6)-U(5) transition in the interacting boson model. II. Classical trajectories

This article continues our previous study of level dynamics in the [O(6)-U(5)]$\supset$O(5) transition of the interacting boson model [nucl-th/0504016] using the semiclassical theory of spectral fluctuations. We find classical monodromy, related to a singular bundle of orbits with infinite period at energy E=0, and bifurcations of numerous periodic orbits for E>0. The spectrum of allowed ratios of periods associated with beta- and gamma-vibrations exhibits an abrupt change around zero energy. These findings explain anomalous bunching of quantum states in the E$\approx$0 region, which is responsible for the redistribution of levels between O(6) and U(5) multiplets.