Evolution Of Precipitation Research Articles

Peering into Cloud Physics Using Ultra-Fine-Resolution Radar and Lidar Systems

Abstract Cloud microphysical processes, such as droplet activation, condensational growth, and collisional growth, play a central role in the evolution of clouds and precipitation. Accurate representations of these processes in numerical models are challenging partially due to incomplete understanding of them at the process level arising from limited systematic observations. Most surface-based active remote sensors, including today’s operational cloud radars and lidars, have a resolution on the order of tens of meters. This resolution is insufficient to resolve cloud microphysical processes that manifest at finer (meter and submeter) scales. A new set of ultra-high-resolution ground-based radar and lidar systems have been developed to address this observational gap. The newly developed 94-GHz cloud radar has a range resolution down to 2.8 m, or a factor of 10 finer than typical radars, using a large bandwidth and quadratic phase coding techniques. The lidar has a range resolution down to 10 cm, or a factor of 100 finer than typical lidars, using a time-gated time-correlated single-photon-counting technique. Such high-resolution observations were previously only achievable through in situ aircraft measurements. Even then, aircraft measurements do not permit continuous long-term cloud observation as is possible with ground-based remote sensing instruments. In this study, the first-light cloud observations from the new radar and lidar systems are shown to reveal detailed cloud structures that conventional sensors could only perceive in a bulk sense, thus providing new avenues to investigate cloud microphysical processes and their impact on weather and climate.

Direct observation of the evolution behavior of micro to nanoscale precipitates in austenitic heat-resistant steel via electron channeling contrast imaging

Precipitation directly determines the high-temperature properties of the austenitic heat-resistant steels. The precipitations of MX, Z-phase, M23C6 and σ-phase, ranging from micrometers to nanometers, are commonly characterized using the scanning electron microscopy (SEM) and transmission electron microscopy (TEM). However, details of their evolution behavior are still unclear due to the limited SEM resolution using the traditional sampling method and the limited spatial resolution of TEM. In this work, field emission SEM-based electron channel contrast imaging (ECCI) techniques with flexible sampling routes were introduced to observe the precipitation evolution behavior of HR3C steel after aging at 700 °C for 8095 h. We showed that the coarse primary-MX and Z-phase in the as-received steel are relatively stable during aging. The coarse M23C6 and tiny secondary Z-phase dispersions were rapidly formed along the grain/twin boundaries and within dislocation arrays inside the grain interior, respectively. We further found that the M23C6 at grain boundaries would change from continuous to semi-continuous due to the formation of σ-phases, while in twin boundaries, it would become continuous over aging. Moreover, we showed that the σ-phases were in-situ transformed from M23C6 at the grain boundaries via its dissolution, facilitating the nucleation of tiny Z-phase inside the σ-phase grains, and this phenomenon has not been reported so far. We have demonstrated that ECCI with an electrolytic-polishing-based sampling route is effective in revealing multi-scale precipitation with high-throughput efficiency, and it allows the direct observation of the complex behavior of precipitates down to the nanoscale using a bulk sample. This method can be used as an efficient way for the quantitative microstructure study.

Quantification of precipitate evolution in cast Al–Li alloys containing Cu and Mg additions using small-angle X-ray scattering

Quantification of precipitate evolution in cast Al–Li alloys containing Cu and Mg additions using small-angle X-ray scattering

Investigating the Role of TiC Precipitation in Dynamic Recrystallization Behavior of a Novel Ship Steel

This study examines the single‐pass thermal compression behavior of Ti‐bearing ship plate steel across a temperature range of 850–1150 °C and strain rates from 0.01 to 7 s−1, employing the Gleeble‐2000D thermomechanical simulator. It delves into the evolution of TiC precipitation and dynamic recrystallization (DRX), along with the austenite decomposition transformation during hot compression and subsequent cooling. Active dynamic recrystallization commences at deformation temperatures above 1050 °C, facilitated by the diminished pinning pressure of TiC carbides. This leads to the development of fine DRX austenite grains, influenced by an increase in strain rates and a decrease in temperature. Simultaneously, the fraction of TiC dispersions decreases as the deformation temperature increases, yet they maintain a consistent size of 5–10 nm. The refined particle size is attributed to their low interfacial energy with the austenite matrix, determined by the first principle to be 0.21 J m−2. Due to the severe deformation and numerous dispersions, specimens subjected to a thermal deformation regime at 850 °C and a strain rate of 7 s−1 present a peak in hardness, reaching a maximum of 324 HV. The Ti microalloying approach offers pivotal insights into improving the rollability and mechanical characteristics of ship plate steel.

Residual Stress and Precipitation Evolution of Bulk Nickel-Based Superalloy During Heat Treatment

Residual Stress and Precipitation Evolution of Bulk Nickel-Based Superalloy During Heat Treatment

A non-melting additive approach to structural repair of aluminum aircraft fastener holes

The damage to fastener holes in aerospace aluminum structures presents significant challenges for aircraft durability, and conventional bushing methods for repairing oversized holes often fall short due to the lack of metallurgical bonding and limited edge distance availability. This study investigates additive friction stir deposition, a non-melting additive process, as a viable alternative for the structural repair of aerospace fastener holes. The repair process, demonstrated on AA7050 (Al-Zn-Mg-Cu-Zr) hole structures, involves filling oversized holes with new material and machining to restore the original hole size. The repaired hole coupons are defect-free and exhibit good fatigue performance under fully reversed tension-compression loading (R = -1). At a nominal stress amplitude of 123.5 MPa, the average number of cycles to failure is 12,666 for unrepaired baseline coupons and 17,372 for effectively repaired coupons. Restoring complex geometries without compromising fatigue performance has been difficult in aerospace applications; this study marks the first demonstration of additive repair that consistently outperforms the unrepaired baseline coupons. Notably, the result is achieved through a low-energy, cost-effective solution without the need for post-repair heat treatment. Except for a few outliers, the post-repair fatigue performance generally remains inferior to that of undamaged, pristine coupons, likely due to precipitate evolution in AA7050 caused by the thermomechanical processing nature of additive friction stir deposition. This evolution weakens the repair region and the adjacent base material, leading to faster crack initiation and growth compared to the properly aged base material, AA7050-T7451.

Evolution of precipitate and its effect on the degradation of impact toughness in a carbon and nitrogen-controlled 316 stainless steel during thermal aging at 650 °C

Impact toughness degradation and microstructure evolution of a carbon and nitrogen-controlled 316 stainless steel during long-term aging at 650 °C for up to 8800 h were investigated. The degradation of impact toughness during aging can be divided into three stages: a rapid decrease during stage I (the first 400 h), a slow decrease during stage II (from 400 to 3200 h), and the stable stage during stage III (up to 8800 h). P enrichment at the M23C6/γ interface is induced by the rejection of P during the formation of M23C6 carbide, and the M23C6/γ interface is preferred location for crack initiation. An increase in the amount of grain boundary M23C6 carbides increases the crack initiation sites, resulting in a rapid decrease of impact toughness during stage I. The ongoing rejection of Ni and Si during the coarsening of M23C6 carbide is beneficial for the nucleation of M6C carbide. The micro-crack initiation at the M23C6/M6C and M6C/γ interfaces is introduced, and a semi-continuous network of M23C6 carbide along grain boundary promotes the crack propagation, leading to a further decrease of impact toughness during stage II. The nearly continuous precipitate morphology is induced through continued growth of grain boundary M23C6 and M6C carbides. The propagation of micro-cracks along the M6C/γ, M23C6/γ, and M23C6/M6C interfaces leads to the mostly intergranular fracture, thus the impact energy tends to be stable during stage III.

Influence of Mn Addition on the Evolution of Precipitates in Al-Cu Alloys

Influence of Mn Addition on the Evolution of Precipitates in Al-Cu Alloys

Investigating reactive transport and precipitation patterns of calcium carbonate in fractured porous media

HypothesisUnderstanding calcium carbonate (CaCO3) precipitation in various polymorphs from nanoparticle size (amorphous calcium carbonate) to microparticle size (vaterite, aragonite, dendrite, calcite) is important for practical applications, including carbon geo-storage (e.g., basalt formations), hydrogen storage, groundwater management, and soil stabilization. Our hypothesis suggests that the interplay of Péclet numbers (Pe), Damköhler numbers (Da), and Supersaturation Index (SI) significantly impacts the evolution of CaCO3 precipitation in fractured porous media in terms of mixing patterns, spatiotemporal evolution, crystal morphology, crystal size, and clogging behavior. ExperimentsThis study takes a novel approach to explore the colloidal formation and precipitation dynamics of CaCO3 within a fractured microfluidic system. Here, calcium chloride (CaCl2) and sodium bicarbonate (NaHCO3) solutions were injected and reacted under varied Pe (0–11), Da (0–1), and SI (2–5). FindingsOur analysis revealed distinct precipitation patterns and mixing types, such as transverse, longitudinal, and incomplete mixing, providing insights into the behavior in fractured porous media. We systematically analyzed the temporal and spatial evolution of precipitation, demonstrating how Pe, Da, and SI dictate precipitation rates and spatial distribution. Additionally, the study uncovered a range of CaCO3 polymorphic forms, illustrating their evolution and coexistence. Morphological changes and crystal sizes were examined to decode nucleation and growth processes. Significantly, our findings highlight the relationship between precipitation and clogging in the fractured medium, offering a deeper understanding of reactive transport in complex porous environments. These insights are crucial for enhancing carbon containment security and storage efficiency in underground formations, improving groundwater remediation techniques, and developing novel construction materials through controlled precipitation processes.

Solute and phase heterogeneous distribution at different scales and its effect on ageing physical phenomena in a laser powder bed fusion produced maraging steel

The Laser Powder Bed Fusion process involves complex thermodynamic and heat transfer mechanisms which results in a complicated understanding of the material’s microstructure and phase transformation processes. In the case of additive manufacturing maraging steels, these present heterogeneous structures which mainly consist of Body-Centred Tetragonal (BCT) martensite and retained austenite (Face-Centred Cubic (FCC) phase structure), unlike conventionally processed material. Research has already been done on the competitive or collaborative nature of austenite growth/reversion and precipitation in these materials. However, for Laser Powder Bed Fusion maraging steels, studies have focused on either the effect of the heterogeneous structures on austenite reversion kinetics or the formation, evolution and behaviour of precipitation. Still, no comprehensive research exists that covers in detail the relation between solute heterogeneity from the meso- to the nanoscale and its influence on both phase distribution and ageing physical phenomena. To do so, multiscale chemical analyses and microstructural characterisation techniques were used to investigate a maraging steel M300 in different transformed conditions: as-built, aged at 480 and 540 °C. The results showed that competing mechanisms during printing caused segregation at the mesoscale, which remains in aged samples. Vaporisation led to Cr segregation, while melt convections caused Ni and Ti depletion at melt pool boundaries. Retained austenite location was found at melt pool boundaries and away from them on the as-built structure. Its preferential location remains unclear. Dissimilarities from conventional material were identified in nanosized clustering and precipitates on aged samples.

Additive manufacturing of sustainable and heat-resistant Al-Fe-Mo-Si-Zr alloys

Improving the sustainability of metals and alloys is essential for slowing down global warming. The reason is that their extraction and production stand for about 40% of all greenhouse gas emissions in the industrial sector. This motivates new alloy design and processing criteria such as the (1) preferred use of abundant and sustainable alloying elements and (2) improved material tolerance against impurity intrusion from recycling. In this context, additive manufacturing (AM) is attractive, through rapid solidification, capable of quenching impurities into a solid solution state, avoiding formation of large intermetallics and introduction of metastable phases. Here, by using this approach we show how iron, an important scrap-related contaminant in aluminum alloys, can be turned from a harmful into a valuable ingredient. Specifically, the addition of Mo and Si facilitates the formation of beneficial metastable body-centred cubic (BCC) Al12(Fe, Mo)3Si phase, instead of more stable but detrimental intermetallic variants commonly observed in Al-Fe alloys. The as-built microstructures have excellent thermal stability, tested up to 200hours at 300 °C, because of low diffusivity of Fe and the formation of Zr shell. We find that for such supersaturated alloys, two issues are important, namely (a) the heterogeneous microstructures in the as-built condition, (b) the evolution of metastable precipitates during heating. We suggest that this type of approach help to guide sustainable alloy design via AM and other rapid solidification processes.

Effect of precipitate evolution on galvanic corrosion behavior of friction stir welded AA6061-T6 joint after post-weld aging

The microstructural transformation of FSW AA6061-T6 joint after post-weld T6 and its effects on the mechanical properties and corrosion behavior was investigated through electrochemical tests, immersion experiments and transmission electron microscopy (TEM) observation. The research results show that the joint efficiency and strength can be enhanced by post-welding aging. The hardness of SZ is recovered to a level close to that of matrix due to the sufficient precipitation of the effective strengthening phase β''. The main β' precipitate in over-aged HAZ coarsens during post-weld aging and cannot effectively restore strength, resulting in the lowest hardness in HAZ and limited tensile strength of the joint. The presence of macro-galvanic effects in the whole joint was confirmed. In SZ, the highest level of aging characteristics is caused by the highest aging drive due to fully solidified atoms, and is confirmed by the continuous grain boundary precipitates (GBPs) and dense matrix precipitates, which lead to the most positive potentials. Whereas, in HAZ, discrete GBPs and coarsened matrix precipitates indicate over-aged features, which lead to the most negative potentials. The potential difference between SZ and HAZ results in a macro-galvanic effect in the joint, where SZ is protected as the cathode and HAZ is corroded faster as the anode.

Initiation and evolution of urban-induced precipitation under different background wind speeds: Roles of urban breeze circulation and cold pool

Urban-enhanced precipitation is often observed far downwind of cities, suggesting important roles of background wind. This study examines the impacts of background wind on the initiation and evolution of urban-induced precipitation through idealized ensemble large-eddy simulations with different initial background wind speeds of 0, 1, 2, 3, 4, and 5 m s−1. Without background wind, a strong urban breeze circulation (UBC) initiates a relatively large number of cumulus clouds in the urban area, which exhibit greater cloud top heights than those in the rural area. The early-initiated clouds do not produce precipitation but moisten the middle troposphere, assisting later-initiated clouds to develop into deep convective clouds and produce concentrated precipitation in the urban area. As the background wind speed increases, the UBC weakens. Also, the high-humidity area generated by early-initiated clouds is continuously advected away from the urban area. Consequently, the precipitation initiation is delayed as the background wind speed increases. Precipitating clouds are advected downwind and generate a cold pool, and updrafts are repeatedly produced at the downwind boundary of the cold pool. The downwind-advected clouds are fed by the newly produced updrafts, being a long-lived organized precipitation system that produces a considerable amount of precipitation in the downwind area. This feeding effect is most prominent for a moderate background wind (3 m s−1), causing the precipitation amount and duration to be maximized. For stronger background winds, precipitation is initiated by the mechanical lifting of the warm air of the urban boundary layer over the cool rural boundary layer around sunset.

Evolution mechanism of Mo-rich, B2-NiAl, and Cu-rich particles under aging and its influence on strength and elongation in a maraging hot work steel SDH88

A novel maraging hot work steel, SDH88, is developed to achieve a balance between ultimate tensile strength (UTS), yield strength (YS), and elongation by combining nanometer-scale precipitates of B2-NiAl, Cu-rich, and M2C carbide. The peak-aging sample demonstrates a YS of ∼1281.8 MPa, a UTS of ∼1665.9 MPa, and an elongation (EL) of ∼17.5 % at room temperature. The microstructure and precipitation changes from peak aging (8h) to over-aging (48h) were examined using different techniques. Under peak aging condition, the precipitates consist of four nanoparticles: 9R-Cu, B2-NiAl, Cu-NiAl, and M2C carbides. However, at over-aging condition, the type of particles changes and consist of B2-NiAl, M6C, Laves phases and FCC-Cu. This study systematically investigates the precipitation evolution of Mo-rich, B2-NiAl, and Cu-rich particles from peak-aging to over-aging conditions. The high YS at peak aging condition is attributed to high precipitation strengthening of ∼553.3 MPa and dislocation strengthening of about 430.8 MPa. The number densities of NiAl (<3.8 nm) particles are more than that of Cu particles which indicates that the NiAl nanoparticles are the dominant strengthening phase. Finally, this work clearly demonstrates that the new alloy composition design allows the application of aging steels in die casting steels with great advantages and potential for obtaining balanced mechanical properties through the systematic study of the aging process and mechanism of precipitation evolution. Proposing a new approach for designing hot work die steel without quenching treatment during mold processing.

Study on the evolution of multistage and multiscale Ti-bearing precipitation and microstructure in ultrahigh-strength titanium microalloyed weathering steels

In this study, 900 MPa ultrahigh-strength weathering steels were successfully developed through thermomechanical controlled processing (TMCP). Advanced microstructure characterization, combined with precipitation thermodynamics and kinetics models, elucidated the evolution of Ti-bearing precipitation and microstructure. The results showed that coiling temperature (CT) significantly impacts phase fractions, grain boundary density, and misorientation angles, while both CT and finishing rolling temperature (FRT) influence grain sizes in acicular ferrite (AF) and granular bainite. The lower coiling temperature resulted in a higher dislocation density of the test steel, which provided more nucleation sites for AF and TiC, favoring a higher number of TiC particles and a higher proportion of AF. Above 1050 °C, the addition of nitrogen changed the shape of the precipitation kinetics curve, reduced the nucleation energy barrier of TiC, decreased the critical nucleation size, and improved the nucleation rate. Meanwhile, the addition of nitrogen accelerated the precipitation transformation of TiC, which promoted the formation of Ti(C, N). Furthermore, increasing the deformation stored energy (DSE) further accelerated the precipitation of Ti(C, N) and significantly increased the nucleation rate. The formation mechanism of large-size Ti(C, N) and the transformation mechanism of Ti(C, N) to TiC are revealed by precipitation thermodynamics and kinetics. The completion time of TiC precipitation on dislocations is shorter than that on grain boundaries, which results in the TiC on dislocations being prone to coarsening during prolonged coiling. These findings provide crucial insights for optimizing the industrial production of ultrahigh-strength titanium microalloyed weathering steels.

Complex precipitation behavior in a Co-free high entropy alloy during aging

High entropy alloys (HEAs) demonstrate high strength, thermal stability, and irradiation resistance, making them desirable for applications in nuclear reactors and other harsh environments. Many existing HEAs contain cobalt (Co), which makes them unsuitable for nuclear applications due to the long-term activation of Co. A previously studied Co-free alloy, (Fe0.3Ni0.3Mn0.3Cr0.1)88Ti4Al8, exhibits high strength but compromised ductility due to its network of brittle precipitates upon aging. This work investigates the formation mechanism and evolution of the precipitates, including L12 (Ni3Ti type, ordered face-centered cubic structure), B2 (NiAl type, ordered body-centered cubic structure), and Chi (FeCr-rich ordered α-Mn structure), in this alloy at 650 °C, the aging temperature that yields the alloy’s peak strength after 120 hours. Using ex-situ scanning electron microscopy, transmission electron microscopy, and atom probe tomography, the precipitates were characterized in terms of their composition, morphology, and crystal structure at various aging times. In addition, synchrotron-based, in-situ X-ray diffraction was used to probe the evolution of precipitates in the bulk during key phases of in-situ aging. The L12 precipitates exhibit complex growth and coarsening behavior – their coarsening starts after just 24 hours, and competition between the L12 and B2 phases arises after 72 hours leading to a decrease in L12 volume fraction. Conversely, B2 and Chi precipitates exhibit delayed nucleation and growth, and do not form in observable quantities until after 24 hours. Once formed, however, these precipitates quickly dominate the microstructure, with >50 % volume fraction after 120 hours, leading to the previously observed mechanical properties. This study provides a foundational understanding of the evolution of multi-precipitate structures in HEAs and guides future alloy development and optimization by tailoring the precipitates.

Microstructural Evolution and Quantitative Evaluation of Precipitates during Long-term Creep of KA-SUS304J1HTB

Microstructural Evolution and Quantitative Evaluation of Precipitates during Long-term Creep of KA-SUS304J1HTB

Exploring the influence of urban agglomeration on extreme precipitation: Evidence from the middle reaches of the Yangtze River, China

Study regionThe urban agglomeration in the middle reaches of the Yangtze River (MRUA) consisting of 31 cities is a pillar of the Yangtze River Economic Belt and the largest urban agglomeration in China, densely populated, and rapidly urbanizing. Study focusExtreme precipitation events are affected by rapidly urbanized regions with uneven levels of urbanization. Hence, it is important to explore the spatiotemporal evolution of extreme precipitation in urban agglomerations and the influence of the spatially uneven development of urban areas under rapid large-scale urbanization. New hydrological insights for the regionExtreme precipitation indices (Pmax1d, R20, and PF95) exhibited significant positive trends during 1979–2018 in the MRUA, increasing by 0.43 mm/year, 0.11 day/year, and 2.46 mm/year, respectively. Regression models based on raster urbanization data were constructed, and the impervious area ratio (IA) and landscape shape index (SI) were shown to be the dominant urbanization factors affecting regional extreme precipitation, with a particularly positive spatial correlation with PF95 and Pmax1d at all stages of urbanization. Moreover, the urban-rural comparison results revealed that the difference in SI of each city was positively correlated with the urban heat island intensity. In the three provincial capitals, Pmax1d and R50 were greater in urban centres than in rural areas. This study contributes to a comprehensive understanding in the variability of extreme precipitation events under the influence of large-scale urbanization.

Evolution of Precipitates in a Mechanical Vibration-Assisted Metal Inert Gas Welded Joint of 6082-T6 Aluminum Alloy Made with an ER5356 Filler Wire

Evolution of Precipitates in a Mechanical Vibration-Assisted Metal Inert Gas Welded Joint of 6082-T6 Aluminum Alloy Made with an ER5356 Filler Wire

A full-field approach for precipitation in metallic alloys. Comparison with a mean-field model

Modeling precipitation in metallic alloys is a topic of great importance in physical metallurgy as the resulting strengthening strongly depends on the precipitate microstructure. We propose here a numerical full-field model for precipitation that describes precipitates with shape functions, thereby allowing to bridge scales between phase-field approaches - that accurately describe the precipitate evolution but require a fine discretization grid - and mean-field approaches - that are computationally very efficient but rely on strong assumptions. Our results demonstrate the capability of the full-field approach to model the different stages of precipitation during isothermal treatments. The comparison with mean-field results allow to discuss the influence of solutal impingement and precipitate coagulations on the evolution of the precipitate microstructure.