Evolution Of Mantle Research Articles

Lead isotope evolution of the Central European upper mantle: Constraints from the Bohemian Massif

The Pb isotope composition of the upper mantle beneath Central Europe is heterogeneous due to the subduction of regionally contrasting material during the Variscan and Alpine orogenies. Late Variscan to Cenozoic mantle-derived melts allow mapping this heterogeneity on a regional scale for the last ca. 340 Myr. Late Cretaceous and Cenozoic anorogenic magmatic rocks of the Bohemian Massif (lamprophyres, volcanic rocks of basanite/tephrite and trachyte/phonolite series) concentrate mostly in the Eger Rift. Cretaceous ultramafic lamprophyres yielded the most radiogenic Pb isotope signatures reflecting a maximum contribution from metasomatised lithospheric mantle, whereas Tertiary alkaline lamprophyres originated from mantle with less radiogenic 206Pb/204Pb ratios suggesting a more substantial modification of lithospheric source by interaction with asthenospheric-derived melts. Cenozoic volcanic rocks of the basanite/tephrite and trachyte/phonolite series define a linear mixing trend between these components, indicating dilution of the initial lithospheric mantle signature by upwelling asthenosphere during rifting. The Pb isotope composition of Late Cretaceous and Cenozoic magmatic rocks of the Bohemian Massif follows the same Pb growth curve as Variscan orogenic lamprophyres and lamproites that formed during the collision between Laurussia, Gondwana, and associated terranes. This implies that the crustal Pb signature in the post-Variscan mantle is repeatedly sampled by younger anorogenic melts. Most Cenozoic mantle-derived rocks of Central Europe show similar Pb isotope ranges as the Bohemian Massif.

Pore-scale permeability prediction for Newtonian and non-Newtonian fluids

Abstract. The flow of fluids through porous media such as groundwater flow or magma migration is a key process in geological sciences. Flow is controlled by the permeability of the rock; thus, an accurate determination and prediction of its value is of crucial importance. For this reason, permeability has been measured across different scales. As laboratory measurements exhibit a range of limitations, the numerical prediction of permeability at conditions where laboratory experiments struggle has become an important method to complement laboratory approaches. At high resolutions, this prediction becomes computationally very expensive, which makes it crucial to develop methods that maximize accuracy. In recent years, the flow of non-Newtonian fluids through porous media has gained additional importance due to, e.g., the use of nanofluids for enhanced oil recovery. Numerical methods to predict fluid flow in these cases are therefore required. Here, we employ the open-source finite difference solver LaMEM (Lithosphere and Mantle Evolution Model) to numerically predict the permeability of porous media at low Reynolds numbers for both Newtonian and non-Newtonian fluids. We employ a stencil rescaling method to better describe the solid–fluid interface. The accuracy of the code is verified by comparing numerical solutions to analytical ones for a set of simplified model setups. Results show that stencil rescaling significantly increases the accuracy at no additional computational cost. Finally, we use our modeling framework to predict the permeability of a Fontainebleau sandstone and demonstrate numerical convergence. Results show very good agreement with experimental estimates as well as with previous studies. We also demonstrate the ability of the code to simulate the flow of power-law fluids through porous media. As in the Newtonian case, results show good agreement with analytical solutions.

Where does subduction initiate and cease? A global scale perspective

The thermo-mechanical evolution of the Earth's mantle is largely controlled by the dynamics of subduction zones, which connect the surface tectonic plates with the interior. However, little is known about the systematics of where subduction initiates and ceases within the framework of global plate motions and evolving continental configurations. Here, we investigate where new subduction zones preferentially form, and where they endure and cease using statistical analysis of large-scale simulations of mantle convection that feature self-consistent plate–like lithospheric behaviour and continental drift in the spherical annulus geometry. We juxtapose the results of numerical modelling with subduction histories retrieved from plate tectonic reconstruction models and from seismic tomography. Numerical models show that subduction initiation is largely controlled by the strength of the lithosphere and by the length of continental margins (for 2D models, the number of continental margins). Strong lithosphere favours subduction inception in the vicinity of the continents while for weak lithosphere the distribution of subduction initiation follows a random process distribution. Reconstructions suggest that subduction initiation and cessation on Earth is also not randomly distributed within the oceans, and more subduction zones cease in the vicinity of continental margins compared to subduction initiation. Our model results also suggest that intra-oceanic subduction initiation is more prevalent during times of supercontinent assembly (e.g. Pangea) compared to more recent continental dispersal, consistent with recent interpretations of relict slabs in seismic tomography.

Early Paleozoic mantle evolution of East Kunlun Orogenic Belt in Qinghai, NW China: evidence from the geochemistry and geochronology of the Late Ordovician to Late Silurian mafic-ultramafic rocks in the Qimantag region

ABSTRACT Subduction-related basaltic rocks in active continental margins should record information about the lithospheric mantle. Mafic rocks from the Qimantag region of the East Kunlun Orogenic Belt (EKOB), NW China, can be used to constrain the evolution of mantle sources. The Heishan basalts (445 Ma) and Xiarihamu gabbros (427 Ma) display distinct geochemical and isotopic features, with basalts yielding relatively lower Na2O+K2O (1.48–4.16 wt.%) and Mg# (0.50–0.57) than gabbros (Na2O+K2O = 2.96–4.07 wt.%, Mg# = 0.65–0.81). Although the basalts and gabbros show similar enrichment of LILE and depletion of HFSE, the gabbros have higher Th/Y and lower Sm/Th and Nb/U ratios than the basalts, indicative of derivation from a more enriched mantle source. The Heishan basalts have relatively positive εNd(t) values (+4.7 to +5.8) whereas the Xiarihamu gabbros have negative εNd(t) values ranging from −5.5 to −3.8. Crustal contamination played an insignificant role in the formation of the basalts and gabbros. Our data suggest that the basalts originated from a depleted mantle source, slightly enriched by subduction-related fluids, whereas the gabbros originated from an enriched mantle source. These findings support a subduction-related progressive lithospheric mantle enrichment model over ~20 Ma beneath the Qimantag region in the Early Palaeozoic.

Two billion years of mantle evolution in sync with global tectonic cycles

The continental crust and sub-continental lithospheric mantle (SCLM) are co-dependent reservoirs in terms of their geochemistry, tectonics, and long-term evolution. Obtaining insight into the mechanisms of lithosphere formation and differentiation requires robust constraint on the complex petrological history of mantle rocks. This has proven difficult as samples from the deep mantle are rare and, although many may have formed in the Archean, no such age has been obtained directly from mantle-derived silicate minerals. Lutetium-hafnium geochronology of garnet has the potential of overcoming this limitation. In this study, this technique was applied on fragments of the SCLM exposed in the Norwegian Caledonides. The chronologic record of these rocks is rich and extensive, yet it is difficult to interpret and is, in part, inconsistent. Our Lu–Hf results from supersilicic pyrope in dunite provide the first Archean internal isochron ages for mantle rocks. These ages are consistent with a period of juvenile crust formation worldwide and provide a record of deeply sourced mantle upwellings from >350 km depth. Results from fertile rock types indicate that melting and isotope re-equilibration occurred in sync with two Proterozoic supercontinent break-up events that are recorded in the Laurentian and Baltic lithospheres. Together, the results indicate that since its extraction during a period of rapid Archean crustal growth, the SCLM appears to have largely been at petro-physical and chemical stasis, with the exception of major episodes of continental break-up. The evolution of the SCLM is thus, highly punctuated and ultimately controlled by the Wilson cycle.

Geochemistry of arc-related mantle peridotites and gabbros from the Chaldoran ophiolite, NW Iran

ABSTRACT The Neo-Tethys-related Chaldoran ophiolite peridotites in NW Iran are remnants of mantle lithosphere, exhumed tectonically during the Late Cretaceous. Harzburgite is the predominant peridotite type, associated with oceanic lower crust cumulate gabbros occasionally. The ophiolite rocks are unconformably overlain by Late Cretaceous-Paleocene sediments. New whole-rock geochemistry of the variably serpentinized harzburgites shows a depleted nature, exemplified by low Al2O3, CaO, TiO2, V and Y and high Ni, Cr and Mg and also low rare earth element (REE) contents. The harzburgites present LREE enrichment. Positive correlations between some LREEs and high field strength elements (HFSE) suggest enrichment of LREEs by melt re-fertilization processes. Cr-spinels have Cr number of [Cr# = Cr/(Cr + Al) = 0.53–0.67], showing medium to high degree of partial melting (F = ~17-20%). Both whole-rock and mineral chemistry data show a supra-subduction zone setting and progressive depletion along with increase in spinel Cr# (MOR to fore arc). The cumulate gabbros have high MgO and SiO2, low TiO2 and Ti/V < 10 and also low chondrite normalized Dy (<8.5). The gabbro samples show enriched LREEs and LILEs and depleted HREEs and HFSEs with respect to MORBs. Subduction initiation (SI) model in a fore-arc/proto-fore-arc environment is suggested for the upper mantle evolution of the Chaldoran ophiolite. The rocks have experienced depletion in a second melting process at the later stages of SI and compositions were probably modified by extraction of island arc tholeiitic (IAT) and possibly boninitic (BON) melts. The chemostratigraphic progression for ‘subduction initiation rule (SIR)’ is likely traceable in Chaldoran mafic-ultramafic sequence, which corresponds to the most Neo-Tethyan ophiolites and is similar to MOR to supra-subduction zone (SSZ) evolution of most Iranian ‘Inner’ and ‘Outer Zagros’ ophiolitic peridotites.

Osmium isotope compositions and highly siderophile element abundances in abyssal peridotites from the Southwest Indian Ridge: Implications for evolution of the oceanic upper mantle

Abyssal peridotites are extensively exposed on the seafloor of amagmatic segments at the ultraslow spreading Southwest Indian Ridge (SWIR). This study presents abundances of highly siderophile elements (HSEs; Os, Ir, Ru, Pt, Pd and Re) and Re–Os isotope compositions as well as major and trace element concentrations of nine spinel-facies peridotites from the Dragon Bone amagmatic segment (~53°E) and the easternmost part (~63.5°E and 69.5°E) of the SWIR. These peridotites have experienced intense serpentinization and seafloor weathering in addition to variable degrees of melt depletion (bulk rock Al2O3 = 0.74–2.73 wt%). Low-temperature alterations, however, have a negligible effect on Os isotope compositions and concentrations of platinum-group elements. The 63.5°E peridotites displayed sub-chondritic Os/Ir and chondritic Pt/Ir ratios and slightly variable Re/Ir and Pd/Ir ratios. The observed positive covariance between 187Re/188Os ratios and γOs, Re and Pd abundances can be explained most likely by interaction of mantle residues with radiogenic basaltic melts, which is consistent with the petrographic observations indicative of melt infiltration. The 53°E peridotites, on the other hand, displayed larger variations in Os isotopes and relative HSE abundances, indicating a more complex evolutionary history. High Re abundances and 187Os/188Os ratios in some 53°E samples attest to Re and radiogenic Os addition, probably through reaction with S-undersaturated hydrous melts. Specifically, sample 21V-S9-D5‐2 exhibited a high 187Os/188Os ratio (0.148) and enrichment of Cu and Pt abundances, implying interaction with an oxidizing agent. Although the Re–Os isotopes of SWIR peridotites were superimposed by variable metasomatic processes, they preserve the ancient Os isotope signature (~1Ga) and record the melting episode at ~0.7 Ga during the closure of the Mozambique Ocean. We infer that ancient depleted and hence buoyant mantle exists beneath the SWIR, which probably supports the weakly magmatic rifted Marion Rise.

Shaping of intraplate mountain patterns: The Cantabrian orocline legacy in Alpine Iberia

AbstractThe present-day topography in Iberia is related to geodynamic processes dealing with lithospheric-scale deformation. However, little attention has been paid to the role of inherited crustal- or lithospheric-scale structures involved in the recent observed large-scale topographic patterns. Whereas the analysis of brittle structures focuses on the evolution of Mesozoic sedimentary basins and their subsequent response to tectonic inversion, their contribution to mountain building has been underestimated. Large numbers of structures, from ductile to brittle, which affected the whole lithosphere, were developed during the evolution of the Cantabrian orocline (ca. 310–300 Ma). The contribution of these Paleozoic post-Variscan structures, together with lithospheric mantle evolution and replacement during orocline development in the Mesozoic and Cenozoic geological evolution of Iberia, remains unexplored. To explore the role of these inherited structures on the final configuration of topography during N-S Pyrenean shortening, we carried out a series of analogue experiments complemented by surface velocity field analyses. Our experiments indicate that strain was concentrated along preexisting crustal- to lithospheric-scale discontinuities, and they show several reactivation events marked by differences in the velocity vector field. Differences in fault displacement were also observed in the models depending upon preexisting fault trends. The obtained results may explain the different amount of displacement observed during the reactivation of some of the post-orocline structures in Iberia during the Cenozoic, indicating the key role of unveiled structures, which probably have accommodated most of the Alpine shortening.

Metasomatic Processes in the Lithospheric Mantle Beneath the No. 30 Kimberlite (Wafangdian Region, North China Craton)

AbstractThis paper presents the first major and trace element compositions of mantle-derived garnet xenocrysts from the diamondiferous No. 30 kimberlite pipe in the Wafangdian region, and these are used to constrain the nature and evolution of mantle metasomatism beneath the North China Craton (NCC). The major element data were acquired using an electron probe micro-analyzer and the trace element data were obtained using laser ablation inductively coupled plasma-mass spectrometry. Based on Ni-in-garnet thermometry, equilibrium temperatures of 1107–1365 °C were estimated for peridotitic garnets xenocrysts from the No. 30 kimberlite, with an average temperature of 1258 °C, and pressures calculated to be between 5.0 and 7.4 GPa. In a CaO versus Cr2O3 diagram, 52% of the garnets fall in the lherzolite field and 28% in the harzburgite field; a few of the garnets are eclogitic. Based on rare earth element patterns, the lherzolitic garnets are further divided into three groups. The compositional variations in garnet xenocrysts reflect two stages of metasomatism: early carbonatite melt/fluid metasomatism and late kimberlite metasomatism. The carbonatite melt/fluids are effective at introducing Sr and the light rare earth elements, but ineffective at transporting much Zr, Ti, Y, or heavy rare earth elements. The kimberlite metasomatic agent is highly effective at element transport, introducing, e.g., Ti, Zr, Y, and the rare earth elements. Combined with compositional data for garnet inclusions in diamonds and megacrysts from the Mengyin and Wafangdian kimberlites, we suggest that these signatures reflect a two-stage evolution of the sub-continental lithospheric mantle (SCLM) beneath the NCC: (1) early-stage carbonatite melt/fluid metasomatism resulting in metasomatic modification of the SCLM and likely associated with diamond crystallization; (2) late-stage kimberlite metasomatism related to the eruption of the 465 Ma kimberlite.

Nature and evolution of the lithospheric mantle revealed by water contents and He-Ar isotopes of peridotite xenoliths from Changbaishan and Longgang basalts in Northeast China

The nature and evolution of the lithospheric mantle underlying Northeast (NE) China were investigated by assessing the mineral chemistry, water contents, and noble gas (He-Ar) isotopes of peridotite xenoliths captured by Cenozoic basalts from the Changbaishan and Longgang regions. The xenoliths, which have 863–1141 °C equilibration temperatures, primarily comprise spinel lherzolites and rare spinel harzburgites. The Mg# (Fo) values of olivine in the peridotite xenoliths vary from 86.9 to 91.3. The clinopyroxenes have high Ti/Eu and low (La/Yb)N, and their chondrite-normalized rare earth elements (REEs) exhibit light REE-depletion to -enrichment patterns, indicating that the mantle underneath the investigated region was predominantly subjected to partial melting (1%–10%) and was metasomatized by silicate melts. The measured 3He/4He ratios of the Changbaishan xenoliths have a narrow range from 5.8 Ra to 8.4 Ra with an average of 7.4 Ra. The 3He/4He isotopic ratios of the Longgang xenoliths varied from 4.7 Ra to 8.1 Ra with an average of 5.9 Ra; slightly lower than the Changbaishan xenoliths. The whole-rock H2O contents of the studied peridotite ranged from 9 to 132 ppm. The high H2O contents in excess of 50 ppm (up to 132 ppm) might represent newly accreted and cooled asthenospheric materials, while those with H2O contents lower than 50 ppm (as little as 9 ppm) may represent thinned, relic, ancient lithospheric mantle. These geochemical evidences, in combination with published data, indicated that the lithospheric mantle beneath the Changbaishan and Longgang in NE China is dominated by the younger and more fertile lithospheric mantle with a minor ancient and refractory keel. In addition, the lithospheric mantle of this area was metasomatized by melts related to the recent subduction event (e.g., Pacific oceanic plate). Therefore, the westward-dipping Pacific oceanic plate subduction had an important contribution to the transformation of the lithospheric mantle beneath NE China.

Constraining Mantle Heterogeneity beneath the South China Sea: A New Perspective on Magma Water Content

The nature of upper mantle is important to understand the evolution of the South China Sea (SCS); thus, we need better constrains on its mantle heterogeneity. Magma water concentration is a good indicator, but few data have been reported. However, the rarity of glass and melt inclusions and the special genesis for phenocrysts in SCS basalts present challenges to analyzing magmatic water content. Therefore, it is possible to estimate the water variations through the characteristics of partial melting and magma crystallization. We evaluated variations in Fe depletion, degree of melt fractions, and mantle source composition along the fossil spreading ridge (FSR) using SCS basalt data from published papers. We found that lava from the FSR 116.2° E, FSR 117.7° E, and non-FSR regions can be considered normal lava with normal water content; in contrast, lava from the FSR 117° E-carbonatite and 114.9–115.0° E basalts have higher water content and show evidence of strong Fe depletion during the fractional crystallization after elimination of the effects of plagioclase oversaturation. The enriched water in the 117° E-carbonatite basalts is contained in carbonated silicate melts, and that in the 114.9–115.0° E basalts results from mantle contamination with the lower continental crust. The lava from the 117° E-normal basalt has much lower water content because of the lesser influence of the Hainan plume. Therefore, there must be a mantle source compositional transition area between the southwestern and eastern sub-basins of the SCS, which have different mantle evolution histories. The mantle in the west is more affected by contamination with continental materials, while that in the east is more affected by the Hainan mantle plume.

The evolution of the Kaapvaal craton: A multi-isotopic perspective from lithospheric peridotites from Finsch diamond mine

Accurately dating the formation and modification of Earth’s sub-cratonic mantle still faces many challenges, primarily due to the long and complex history of depletion and subsequent metasomatism of this reservoir. In an attempt to improve this, we carried out the first study on peridotites from the Kaapvaal craton (Finsch Mine) that integrates results from Re-Os, Lu-Hf, Sm-Nd and Sr-isotope systems together with analyses of major-, trace- and platinum-group elements. The Finsch peridotites are well-suited for such a study because certain compositional features reflect they were highly depleted residues of shallow melting (1.5 GPa) at ambient Archean mantle temperatures. Yet, many of them have overabundant orthopyroxene, garnet and clinopyroxene compared to expected modal amounts for residues from partial melting. Finsch peridotites exhibit a wide range of rhenium depletion ages (TRD) from present day to 2.7 Ga, with a prominent mode at 2.5 Ga. This age overlaps well with a Lu-Hf isochron of 2.64 Ga (εHf (t) = +26) which records silico-carbonatitic metasomatism of the refractory residues. This late Archean metasomatism is manifested by positive correlations of Pt/Ir and Pd/Ir with 187Os/188Os ratios and good correlations of modal amounts of silicates, especially garnet, with Os isotope ratios. These correlations suggest that the Highly Siderophile Elements (HSE) and incompatible element reenrichment and modal metasomatism result from one single major metasomatic event at late Archean.Our detailed study of Finsch peridotites highlights the importance of using multiple isotopic systems, to constrain the ages of events defining the evolution of lithospheric mantle. The Re-Os isotope system is very effective in documenting the presence of Archean lithosphere, but only the oldest TRD ages may accurately date or closely approach the age of the last major partial melting event. For a meaningful interpretation of the Re-Os isotope systematics the data must be combined with HSE patterns, trace-element compositions and ideally other isotopic systems, e.g. Lu-Hf. This is highlighted by the widespread evidence in Finsch peridotites of Pt, Pd and Re enrichment through significant Base Metal Sulfide (BMS) addition (mainly in the range of 0.002–0.08 wt%) that systematically shifts the mode of TRD model ages to younger ages.

The age and evolution of the lithospheric mantle in the East Antarctic Craton: osmium isotope composition and the distribution of the platinum group elements in spinel lherzolite nodules

The mantle xenoliths of lherzolite composition from Mesozoic alkaline-ultrabasic diatremes of the Jetty Oasis were studied. The studied xenoliths represent the mantle section of the East Antarctic Craton down to depths of 60-80 km. The osmium isotope composition of these nodules testifies to the beginning of the formation of the lithospheric mantle in the considered region at about 2400 Ma. The absence of any signs of Early Archean lithosphere points either to partial destruction of the lithosphere at the convergent boundary of the plates in the Late Archean or to thermal erosion of the Archean lithosphere under the deep-seated plume impact at the Mesozoic time during rift propagation.

Diamond-forming media through time – Trace element and noble gas systematics of diamonds formed over 3 billion years of Earth’s history

Ten individual gem-quality monocrystalline diamonds of known peridotite/eclogite paragenesis from Southern Africa (Koffiefontein, Letlhakane, Orapa) were studied for trace element concentrations and He and Ar abundances and isotopic compositions. In addition, two samples, consisting of pooled fragments of gem-quality peridotitic diamonds from Finsch and DeBeers Pool respectively, were analysed for noble gases. Previous studies (Richardson et al., 1984; Pearson et al., 1998; Gress et al., 2017; Timmerman et al., 2017) provided age constraints of 0.09, 1.0–1.1, 1.7, 2.3, and 3.2–3.4 Ga on mineral inclusions in the studied diamonds, allowing us to study trace elements and noble gases over 3 Gyr of geological time. Concentrations of trace elements in the diamonds are very low – a few hundred ppt to several tens of ppbs – and are likely dependent on the amount of sub-micron inclusions present. Trace element patterns and trace element/3He ratios of the studied monocrystalline diamonds are similar to those in fibrous diamonds, suggesting that trace elements and stable noble gas isotopes reside within the same locations in diamond and track the same processes that are reflected in the trace element patterns. We cannot discern any temporal differences in these geochemical tracers, suggesting that the processes generating them have been occurring over at least the past 2.3 Ga. 3He/4He ratios decrease and 4He and 40Ar* contents increase with increasing age of peridotitic and some eclogitic diamonds, showing the importance of in-situ radiogenic 4He and 40Ar ingrowth by the decay of U-Th-Sm and K respectively. For most gem-quality monocrystalline diamonds, uncertainties in the 3He/4He evolution of the continental lithospheric mantle combined with large analytical uncertainties and possible spatial variability in U-Th-Sm concentrations limit our ability to provide estimates of diamond formation ages using 4He ingrowth. However, the limited observed 4He ingrowth (low U + Th/3He) together with a R/Ra value of 5.3 for peridotitic diamond K306 is comparable to the present-day sub-continental lithospheric mantle value and supports the young diamond formation age found by Re-Os dating of sulphides in the same diamond by Pearson et al. (1998). After correction for in-situ radiogenic 4He produced since diamond formation a large variation in 3He/4He remains in ∼1 Ga old eclogitic diamonds that is suggested to result from the variable influence of subducted altered oceanic crust that has low 3He/4He. Hence, the 3He/4He isotope tracer supports an origin of the diamond-forming fluids from recycled oceanic crust for eclogitic diamonds, as indicated by other geochemical proxies.

The subduction of the west Pacific plate and the destruction of the North China Craton

While a general concensus has recently been reached as to the causal relationship between the subduction of the west Pacific plate and the destruction of the North China Craton, a number of important questions remain to answer, including the initial subduction of west Pacific plate beneath the eastern Asian continent, the position of west Pacific subduction zone during the peak period of decratonization (i.e., Early Cretaceous), the formation age of the big mantle wedge under eastern Asia, and the fate of the subducted Pacific slab. Integration of available data suggests that the subduction of the western Pacific plate was initiated as early as Early Jurrasic and the subduction zone was situated to 2,200 km west of the present-day trench in the Early Creataceous, as a result of eastward migration of the Asian continent over a distance of ca. 900 km since the Early Cretaceous. The retreat of the subducting west Pacific plate started ∼145 Ma ago, corresponding to the initial formation of the big mantle wedge system in the Early Cretaceous. The subduction of the Pacific slab excerted severe influence on the North China Craton most likely through material and energy echange between the big mantle wedge and overlying cratonic lithosphere. The evolution history of the west Pacific plate was reconstructed based on tectonic events. This allows to propose that the causes of phases A and B for the Yanshanian orogeny were respectively related to rapid low-angle subduction and to lowering subduction angle of the west Pacific plate. At ca. 130–120 Ma, the subduction of the west Pacific plate was characterized by increasing subducting angle, slab rollback and rapid trench retreat, leading to the final stagnation of the subducting slab within the mantle transition zone. This process may have significantly affected the physical property and viscosity of the mantle wedge above the stagnant slab, resulting in non-steady mantle flows. The ingression of slab-released melts/fluids would significantly lower the viscosity of the mantle wedge and overlying lithosphere, inducing decratonization. This study yields important bearings on the relationship between the subduction of the west Pacific plate and the evolution of the lithospheric mantle beneath the North China Craton.

Diamond-Bearing Root Beneath the Northern East European Platform (Arkhangelsk Region, Russia): Evidence from Cr-Pyrope Trace-Element Geochemistry

In this study, we reconstruct the composition and metasomatic evolution of the lithospheric mantle beneath the poorly-studied southern Arkhangelsk region, based on the geochemistry of 145 Cr-pyrope grains recovered from samples of modern rivers and stream sediments, to evaluate the diamond exploration potential of these territories. Based on the concentrations of Cr2O3, CaO, TiO2, and rare earth elements (REEs), the garnets are divided into four groups: (1) low-chromium lherzolitic pyropes with fractionated heavy REE patterns; (2) low- to medium-chromium pyropes of lherzolitic and megacryst associations with flat heavy REE patterns; (3) high-chromium lherzolitic pyropes with “humped” REE patterns; and (4) high-chromium and low-chromium lherzolitic and harzburgitic pyropes with sinusoidal REE patterns. The pyrope geochemistry suggests a multi-stage model for the evolution of the lithospheric mantle, including partial melting to different degrees and further metasomatic overprints by silicate and carbonatite melts. The results confirm that the lithospheric mantle beneath the study area is suitable for the formation and preservation of diamonds. The significant percentage of diamond-associated pyropes (15%) emphasizes the likelihood of high diamond contents in kimberlites to be discovered within the study area.

Geodynamic history and mantle evolution recorded in Cenozoic lavas of Sardinia

Two Cenozoic magmatic cycles occurred in Sardinia separated by a 5 myr gap: Oligo-Miocene subduction-related calc-alkaline magmatism associated with Sardinia migrating from the European continental margin to its current location, and Plio-Pleistocene intraplate alkaline magmatism associated with the opening of the southern Tyrrhenian basin. Based on an integration of new and published geochemical data on the Cenozoic volcanic rocks of Sardinia, and regional tectonics, we propose that a northward propagating slab tear formed south of Sardinia at the end of the Oligo-Miocene cycle. This was responsible for the transition from subduction-controlled calc-alkaline to extension-controlled mildly alkaline to peralkaline magmatism in the Sulcis area (SW Sardinia), and for the end of the Oligo-Miocene magmatism. The inflow of hotter material from the European Asthenospheric Reservoir (EAR) through the slab window could have produced the minor EAR-type alkaline lavas that erupted at the end of the Oligo-Miocene cycle and at the beginning of the Plio-Pleistocene cycle. The dominant younger Plio-Pleistocene lavas with EMI-type compositions probably formed from decompression melting of a shallower lithospheric mantle with little influence from the EAR-forming event. Supplementary material: A summary of Sulcis rocks petrography, representative whole-rock analysis of Sulcis rocks, Sr, Nd and Pb isotope analytical methods and results, a list of sources of whole-rock geochemical data from the literature and complementary diagrams are available at https://doi.org/10.6084/m9.figshare.c.4447802

Extended Deep Earth Water Model for predicting major element mantle metasomatism

Abstract Fluids in the deep crust and upper mantle appear to have played roles in the long-term evolution of the subcratonic lithospheric mantle and the stabilities of the continents, in the geochemical cycles of the elements from subduction zones to Earth’s surface environment, and in the formation of diamonds. Much evidence of the chemistry of deep fluids has accumulated from studies of fluid inclusions in diamonds and xenoliths. But the origins of the fluids and their behavior are still unclear. In part, this is due to the lack of a comprehensive theoretical model of aqueous, high-pressure fluids. Traditional models have used a C-O-H-type of model, which contains no major rock-forming elements or aqueous ions or metal-complexes. In the present study, we use experimentally measured solubility data for multicomponent K-free eclogite, K-free peridotite and K-bearing peridotite rocks at upper mantle conditions from the literature to construct aqueous speciation solubility models that enabled calibration of the thermodynamic properties of ions and metal-complex species involving the elements Na, K, Mg, Ca, Fe, Al, Si, and C in an extended Deep Earth Water (DEW) model. New equilibrium constants were retrieved for the aqueous bisilicate anion, a silica trimer, silicate complexes of Ca, Fe, and Al, a silicate complex of Mg and bicarbonate, and formate complexes of Fe and Ca. The aqueous speciation and solubility model also took account of decreases in the activity of water and aqueous activity coefficients of neutral dissolved gases and included consideration of H 2 CO 3 0 . Based on the temperature and pressure dependences of the equilibrium constants, and supporting data covering a wide range of conditions, we then developed aqueous equation of state characterizations of the ions and metal-complex species. Overall, the results form a basis for modeling fluid-rock interactions under upper mantle conditions consistent with experimental solubility measurements.

The Age and Evolution of the Lithospheric Mantle in the East Antarctic Craton: Osmium Isotope Composition and the Distribution of Platinum Group Elements in Spinel Lherzolite Nodules

The mantle xenoliths of lherzolite composition from Mesozoic alkaline–ultrabasic diatremes of Jetty Oasis were studied. The treated xenoliths represent the mantle section of the East Antarctic Craton down to depths of 60–80 km. The osmium isotope composition of these nodules testifies to the beginning of the formation of the lithospheric mantle in the considered region of the craton 2400 Ma ago. The absence of any signs of Early Archeozoic lithosphere points either to partial destruction of the lithosphere at the convergent boundary of the plates in the Late Archean or to thermal erosion of the Archean lithosphere under the effect of a deep-seated plume in the Mesozoic during rift formation.

Slab Control on the Northeastern Edge of the Mid‐Pacific LLSVP Near Hawaii

AbstractAt the core‐mantle boundary, most observed ultralow velocity zones (ULVZs) cluster along the edges of the large low shear velocity provinces (LLSVPs) and provide key information on the composition, dynamics, and evolution of the lower mantle. However, their detailed structure near slab‐like structures beneath the mid‐Pacific remains particularly challenging because of the lack of station coverage. While most studies of ULVZs concentrate on SKS‐complexity, here we report on the multipathing of ScS, which expands the sampling for ULVZs. We find the strongest multipathing along a ULVZ patch located just south of Hawaii and the far northeastern edge of the LLSVP, in a zone ~200 km in width and extending 600 km southward. The anomalous ScS travel times and distorted Sdiff waveforms further reveal patches interrupted by observed enhanced D″ indicative of slab‐debris influence on the complexity of the northeastern boundary of the mid‐Pacific LLSVP.