Evaluation Of Material Degradation Research Articles

Biphasic bone substitutes coated with PLGA incorporating therapeutic ions Sr2+ and Mg2+: cytotoxicity cascade and in vivo response of immune and bone regeneration.

The incorporation of bioactive ions into biomaterials has gained significant attention as a strategy to enhance bone tissue regeneration on the molecular level. However, little knowledge exists about the effects of the addition of these ions on the immune response and especially on the most important cellular regulators, the macrophages. Thus, this study aimed to investigate the in vitro cytocompatibility and in vivo regulation of bone remodeling and material-related immune responses of a biphasic bone substitute (BBS) coated with metal ions (Sr2+/Mg2+) and PLGA, using the pure BBS as control group. Initially, two cytocompatible modified material variants were identified according to the in vitro results obtained following the DIN EN ISO 10993-5 protocol. The surface structure and ion release of both materials were characterized using SEM-EDX and ICP-OES. The materials were then implanted into Wistar rats for 10, 30, and 90days using a cranial defect model. Histopathological and histomorphometrical analyses were applied to evaluate material degradation, bone regeneration, osteoconductivity, and immune response. The findings revealed that in all study groups comparable new bone formation were found. However, during the early implantation period, the BBS_Sr2+ group exhibited significantly faster regeneration compared to the other two groups. Additionally, all materials induced comparable tissue and immune responses involving high numbers of both pro-inflammatory macrophages and multinucleated giant cells (MNGCs). In conclusion, this study delved into the repercussions of therapeutic ion doping on bone regeneration patterns and inflammatory responses, offering insights for the advancement of a new generation of biphasic calcium phosphate materials with potential clinical applicability.

Evaluation of heat transfer in porous scaffolds under cryogenic treatment: a numerical study.

The present work had evaluated the effect of cryogenic treatment (233K) on the degradation of polymeric biomaterial using a numerical model. The study on effect of cryogenic temperature on mechanical properties of cell-seeded biomaterials is very limited. However, no study had reported material degradation evaluation. Different structures of silk-fibroin-poly-electrolyte complex (SFPEC) scaffolds had been designed by varying hole distance and hole diameter, with reference to existing literature. The size of scaffolds were maintained at 5 [Formula: see text] 5 mm2. Current study evaluates the effect of cryogenic temperature on mechanical properties (corelated to degradation) of scaffold. Six parameters related to scaffold degradation: heat transfer, deformation gradient, stress, strain, strain tensor, and displacement gradient were analyzed for three different cooling rates (- 5K/min, - 2K/min, and - 1K/min). Scaffold degradation had been evaluated in the presence of water and four different concentrations of cryoprotectant solution. Heat distribution at various points (points_base, point_wall and point_core) on the region of interest (ROI) was found similar for different cooling rates of the system. Thermal stress was found developing proportional to cooling rate, which leads to minimal variation in thermal stress over time. Strain tensor was found gradually decreasing due to attenuating response of deformation gradient. In addition to that, dipping down of cryogenic temperature had prohibited the movement of molecules in the crystalline structure which had restricting the displacement gradient. It was found that uniform distribution of desired heat at different cooling rates has the ability to minimize the responses of other scaffold degradation parameters. It was found that the rates of change in stress, strain, and strain tensor were minimal at different concentrations of cryoprotectant. The present study had predicted the degradation behavior of PEC scaffold under cryogenic temperature on the basis of explicit mechanical properties.

Non-Destructive Electromagnetic Evaluation of Material Degradation Due to Steel Cutting in a Fully Stacked Electrical Machine

Although it is well known that the magnetic properties of electrical steel can be deeply affected by the cutting process, it is still not clear how to accurately evaluate these effects on a prototyped machine on its final shape, especially at a high frequency or a high power rating. This research provides a more practical method for accurate measurement of magnetic losses in electrical steel with consideration of material degradation effects due to the cutting process. Unlike other similar studies, these investigations are conducted not only on a few laminations but also on a complete electrical machine core. For a fair comparison between both cases, backlack bonding is used for lamination stacking since it is the most non-damaging joining technique. Two different test setups are used to measure the steel performance at a wide range of frequency and input power. Furthermore, a full axial length stator of a switched reluctance machine (SRM) is used as a case study to identify the magnetic properties of NO20 electrical steel. Additionally, by comparing the results obtained from the individual laminations and the assembled stator, the extra losses due to the cutting process and material degradation are extracted accurately.

In situ elastic constant determination of unidirectional CFRP composites via backwall reflected multi-mode ultrasonic bulk waves using a linear array probe

The determination of elastic constants of a transversely isotropic carbon fiber reinforced plastic (CFRP) composite is the prerequisite of mechanical strength calculation, material degradation evaluation, ultrasonic non-destructive testing for main load-bearing CFRP structures both after manufacturing and in service. Conventional ultrasonic methods request extra sample preparation, water immersion condition or special designed goniometric devices to rotate the test structures, making the elastic constants measurement expensive, inconvenient and not in situ. In this paper, a novel ultrasonic method that enables in situ determination of elastic constants via backwall reflection method (BRM) using a linear array probe is proposed. The BRM can achieve single sided measurement of ultrasonic travel times in various directions including the fiber direction using different pairs of transmitter and receiver array elements. Both quasi longitudinal and quasi shear waves are captured via the mode conversions from the multiple surface reflections. All elastic constants are determined through the particle swarm optimization by minimizing the sum of the squared deviations between the BRM measured and theoretically calculated multi-mode bulk wave travel times in the fiber orthogonal and parallel planes. This method is experimentally verified on a 4.45 mm thick unidirectional T700 carbon fiber/epoxy CFRP composite. The BRM measured Young's modulus in the fiber direction agrees well with that measured by tensile test, with a small deviation of −4.58%. This work proves that the proposed method is single sided, easy to operate, without the necessity of sample preparation, water immersion and extra rotation device, and can determine all elastic constants with high precision, which is therefore promising for in situ applications.

Durability Control of Brickwork's Material Including Operation Parameters of the Building Enclosure

This paper aims to develop a method to determine material durability based on physicochemical laws that describe chemical corrosion in building enclosures. The subject of this research is studying the chemical corrosion in the material in building constructions. The object of this research is the material of building ceramics. Methods that the authors used for reaching this goal include developing a multi-staged process of material degradation of building ceramics, conduction of thermodynamic calculations, and conducting laboratory research on process kinetics. The results of kinetic researches are generalized based on a developed mathematical model. This comprehensive approach to solving the goal task allowed obtaining the following results: research methods of chemical processes in brick material and its plaster on humidification were developed. A mathematical model for evaluating material degradation in time with the changing climatic influence on enclosure was developed.

Evaluation of material degradation using phased array ultrasonic technique with full matrix capture

This paper presents a new approach based on phased array ultrasonic technique (PAUT) with full matrix capture (FMC) to effectively measure acoustic properties such as ultrasonic wave velocity and attenuation coefficient and to evaluate material degradation. This paper also proposes the use of PAUT with FMC, to simultaneously generate and detect ultrasonic waves such as longitudinal, shear, and Rayleigh waves in the material. A theoretical model is developed to derive the analytical solution of ultrasonic waves induced in the material by an ultrasonic phased array probe. Based on the theoretical prediction, experiments are carried out on AISI 316L stainless steel specimen of 3 mm thickness, and a 2D finite element model is built to verify the generation and detection of these waves. Furthermore, measurements of acoustic properties are carried out on the specimen using the proposed approach as well as the conventional ultrasonic testing (CUT) technique and their sensitivities are compared. The measurements of time-of-flight and back-wall echo amplitude are more accurate with the proposed approach than the CUT technique, which makes the former technique better than the latter for the evaluation of material degradation. Finally, experiments are performed on AISI 316L specimen degraded with different levels of tensile stress to verify the capability of PAUT with FMC. The results show that the velocities and attenuation coefficient increase with an increase in tensile stress until material fracture. This phenomenon is interpreted as resulting from microstructural changes such as dislocations during material degradation. From the experimental results, it is proposed that PAUT with FMC can potentially be used to evaluate early-stage materials degradation.

UAV photogrammetry, infrared thermography and GPR for enhancing structural and material degradation evaluation of the Roman masonry bridge of Ponte Lucano in Italy

This paper presents a case study regarding the cooperative use of non-destructive contactless diagnostic investigations as a tool to aid and assist the degradation evaluation of an iconic Roman masonry bridge: Ponte Lucano in Tivoli, Italy. Specifically, unmanned aerial photogrammetric surveys are considered to perform detailed visual inspections and obtain a geometrical 3D model; infrared thermography analyses are carried out to characterize the thermal surface map of the structure detecting anomalies related to material degradation, such as the presence of humidity; ground penetrating radar investigations are performed to improve knowledge of the bridge subsurface structure. The results of the analyses demonstrate that the integration of mentioned diagnostic tools provides information regarding the degradation state of the stones and its causes, as well as regarding the evolution of the structure from its construction up to the present configurations.

Evaluation of yield strength by ultrasonic reconstruction of quadratic nonlinear Stress–Strain curve

The ultrasonic nonlinearity parameter β defined by the ratio of the second-order harmonic amplitude to the square of fundamental frequency amplitude, has been considered as a potential index to evaluate material degradation. However, the yield strength obtained from destructive tensile testing is still widely adopted for this purpose since it is a more intuitive concept to the field engineer than the parameter β. Therefore, this study proposes a nondestructive method to evaluate the yield strength directly from the ultrasonic measurements. In this regard, the tensile stress–strain curve is represented in the form of a quadratic nonlinear stress–strain equation within the elastic range, which includes the linear elastic modulus and the second-order nonlinearity parameter βt. The linear elastic modulus is obtained by measuring the propagation velocity of longitudinal and transverse waves using a traditional ultrasonic pulse-echo method, and the second-order nonlinearity parameter is obtained by measuring the Murnaghan constants using acoustoelastic effects. Then, the tensile stress–strain curve is reconstructed to estimate the 0.01% offset yield strength. To demonstrate the application of the proposed algorithm, the experiments were performed for heat-treated SA508 specimens. The results indicate that the 0.01% offset yield strength obtained using the proposed algorithm exhibit a good agreement with that obtained via destructive tensile testing.

Ultrasonic nonlinearity parameter in uniaxial stress condition

The ultrasonic nonlinearity parameter derived for one-dimensional propagation of a longitudinal wave in an isotropic material has been considered useful in the evaluation of material degradation. To demonstrate this, many researchers have reported on the correlation with the yield strength obtained from a tensile test. However, there is an essential issue with this procedure – which is that the ultrasonic nonlinearity parameter is derived in a state where the lateral strain is restrained, whereas the tensile test to measure the yield strength is carried out under uniaxial stress conditions, where lateral deformation is free. In this study, to address this issue, the authors have defined the ultrasonic nonlinearity parameter under uniaxial stress conditions which were the same as the tensile test, and showed that the correlation with the yield strength was higher than the currently used ultrasonic nonlinearity parameter. To verify the validity of the proposed ultrasonic nonlinearity parameter, experiments were carried out for Al6061-T6 alloy specimens heat-treated with different aging times. Results showed that the proposed ultrasonic nonlinearity parameter exhibited a much higher correlation with yield strength than the currently used nonlinearity parameter.

Neural network utilization for evaluation of the steel material properties

The aim of this work is to develop and test a new method for identification of material properties of the steel. This work deals with application of the small punch test for evaluation of material degradation of power station in the CEZ company (main Czech energetic company) within the project TE01020068 “Centre of research and experimental development of reliable energy production, work package 8: Research and development of new testing methods for evaluation of material properties”. The main effort is here an improvement of empirical correlation of selected steel materials used in power industry for manufacturing of the critical components (rotors, steam-pipes, etc.). The effort here is on the utilization of the finite element method (FEM) and the neural network (NN) for evaluation of mechanical properties (Young modulus of elasticity, yield stress, tensile strength) of the selected material, based on SPT results only.

Correlation between Ultrasonic Nonlinearity and Elastic Nonlinearity in Heat-Treated Aluminum Alloy

The nonlinear ultrasonic technique is a potential nondestructive method to evaluate material degradation, in which the ultrasonic nonlinearity parameter is usually measured. The ultrasonic nonlinearity parameter is defined by the elastic nonlinearity coefficients of the nonlinear Hooke's equation. Therefore, even though the ultrasonic nonlinearity parameter is not equal to the elastic nonlinearity parameter, they have a close relationship. However, there has been no experimental verification of the relationship between the ultrasonic and elastic nonlinearity parameters. In this study, the relationship is experimentally verified for a heat-treated aluminum alloy. Specimens of the aluminum alloy were heat-treated at <TEX>$300^{\circ}C$</TEX> for different periods of time (0, 1, 2, 5, 10, 20, and 50 h). The relative ultrasonic nonlinearity parameter of each specimen was then measured, and the elastic nonlinearity parameter was determined by fitting the stress-strain curve obtained from a tensile test to the 5th-order-polynomial nonlinear Hooke's equation. The results showed that the variations in these parameters were in good agreement with each other.

Assessment of thermal degradation by cumulative variation of ultrasonic nonlinear parameter

The ultrasonic nonlinear parameter β has been studied for the evaluation of material degradation. However, there is a limit to the assessment of degradation induced by thermal aging in aluminum alloy because the nonlinear parameter may fluctuate with the aging time and thus it has not one-to-one correspondence with the thermal degradation. In order to overcome such limitation, we propose a cumulative nonlinear parameter βc defined by the accumulation of variation in the nonlinear parameter over the aging time. For verifying the usefulness of the proposed parameter, two kinds of aluminum alloy specimens heat-treated with different aging temperatures and aging times were tested. After the ultrasonic test has been completed, the tensile test was conducted for all specimens to measure the yield strength as a quantitative index of material degradation. Results showed that the nonlinear parameter β fluctuated in directions of both increase and decrease, while the strength decreased one-sidedly with the increase of aging time. On the other hand, the proposed parameter βc was one-sidedly increased, which showed strong exponential negative correlation with the yield strength. These tendencies were similar in different material and different aging temperature.

Quantitative evaluation of strength degradation by using linear-nonlinear ultrasonic techniques

The ultrasonic nonlinear parameter, β, has been known as effective for the evaluation of material degradation, and its correlation with material degradations such as thermal aging, fatigue, creep, and plastic deformation has been reported. However, most studies were limited to the relative measurements that is effective only for the relative comparison and not able to evaluate the degradation in quantitative. To overcome this limit, this study proposes a new algorithm which is able to evaluate the quantitative strength degradation. The proposed method mainly consists of four steps: 1) Measure the linear elastic modulus (E) from the longitudinal and shear wave velocities by using pulse echo method. 2) Measure the absolute ultrasonic nonlinear parameter, β, by using piezoelectric detection method. 3) Construct the stress-strain curve by substituting the measured linear elastic modulus (E) and absolute ultrasonic nonlinear parameter β to the nonlinear stress-strain equation. 4) Estimate the 0.01% offset yield strain and yield strength. The yield strengths estimated by the proposed technique in the heat-treated Al6061-T6 and SA508 showed good agreement with the yield strength obtained by tensile test. Consequently, the proposed method makes the quantitative evaluation of strength degradation using ultrasonic measurement possible. [This research was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (NRF-2013M2A2A9043241).]

ICOPE-15-1118 Evaluation of material degradation in sea-water for development of ocean current power generation system

ICOPE-15-1118 Evaluation of material degradation in sea-water for development of ocean current power generation system

『材料劣化評価・寿命余寿命評価』の特集にあたって

『材料劣化評価・寿命余寿命評価』の特集にあたって

Degradation mechanism of rock under impact loadings by integrated investigation on crack and damage development

Failure of rock under impact loadings involves complex micro-fracturing and progressive damage. Strength increase and splitting failure have been observed during dynamic tests of rock materials. However, the failure mechanism still remains unclear. In this work, based on laboratory tests, numerical simulations with the particle flow code (PFC) were carried out to reproduce the micro-fracturing process of granite specimens. Shear and tensile cracks were both recorded to investigate the failure mode of rocks under different loading conditions. At the same time, a dynamic damage model based on the Weibull distribution was established to predict the deformation and degradation behavior of specimens. It is found that micro-cracks play important roles in controlling the dynamic deformation and failure process of rock under impact loadings. The sharp increase in the number of cracks may be the reason for the strength increase of rock under high strain rates. Tensile cracks tend to be the key reason for splitting failure of specimens. Numerical simulation of crack propagation by PFC can give vivid description of the failure process. However, it is not enough for evaluation of material degradation. The dynamic damage model is able to predict the stress-strain relationship of specimens reasonably well, and can be used to explain the degradation of specimens under impact loadings at macro-scale. Crack and damage can describe material degradation at different scales and can be used together to reveal the failure mechanism of rocks.

In vivo degradation of 14C-labeled porcine dermis biologic scaffold

Biologic scaffold materials are used for repair and reconstruction of injured or missing tissues. Such materials are often composed of allogeneic or xenogeneic extracellular matrix (ECM) manufactured by decellularization of source tissue, such as dermis. Dermal ECM (D-ECM) has been observed to degrade and remodel in vivo more slowly than other biologic scaffold materials, such as small intestinal submucosa (SIS-ECM). Histologic examination is a common method for evaluating material degradation, but it lacks sensitivity and is subject to observer bias. Utilization of 14C-proline labeled ECM is a quantitative alternative for measuring degradation of ECM scaffolds. Using both methods, the amount of degradation of D-ECM and SIS-ECM was determined at 2, 4, and 24 weeks post-implantation in a rodent model. Results utilizing 14C liquid scintillation counting (LSC) analysis showed distinct differences in degradation at the three time points. D-ECM material in situ stayed the same at 76% remaining from 2 to 4 weeks post-implantation, and then decreased to 44% remaining at 24 weeks. In the same time period, implanted SIS-ECM material decreased from 72% to 13% to 0%. Visual examination of device degradation by histology overestimated degradation at 2 weeks and underestimated device degradation at 24 weeks, compared to the 14C method.

인공시효된 Al6061-T6의 초음파 비선형 특성 평가

Abstract Generally, the nonlinearity of ultrasonic waves is measured using a nonlinear parameter  , which is defined as the ratio of the second harmonic’s magnitude to the power of the fundamental frequency component after the ultrasonic wave propagates through a material. Nonlinear parameter  is recognized as an effective parameter for evaluating material degradation. In this paper, we evaluated the nonlinear parameter of Al6061-T6 which had been subjected to an artificial aging heat treatment. The measurement was using the transmitted signal obtained from contact-type transducers. After the ultrasonic test, a micro Vickers hardness test was conducted. From the result of the ultrasonic nonlinear parameter, the microstructural changes resulting from the heat treatment were estimated and the hardness test proved that these estimates were reasonable. Experimental results showed a correlation between the ultrasonic nonlinear parameter and microstructural changes produced by precipitation behavior in the material. These results suggest that the evaluation of mechanical properties using ultrasonic nonlinear parameter

Evaluating the Effect of Hardness on Erosion Characteristics of Aluminum and Steels

In this paper, the erosion behavior of commonly used stainless steels (AISI 310S, AISI 316), carbon steel (AISI 1020), and Aluminum 6060 were experimentally investigated. The effect of hardness on erosion rates and on the morphologies of eroded surfaces has been evaluated. The experiments were carried out using an air jet erosion tester and utilizing angular alumina as erodent with 50 lm particle size. The samples were tested at six different impact angles (15 ,3 0 ,4 5 ,6 0 ,7 5, and 90) using three different impact velocities (30, 60, and 100 m/s). The eroded surfaces were analyzed using a scanning electron microscope (SEM) for the evaluation of material degradation. The erosion rates were found to increase with the increase of the alloy bulk hardness and Aluminum 6060 showed maximum erosion resistance. For all specimens, the erosion rates were found to increase with the increase of impact velocity and the maximum erosion rate was found to occur between 15 and 30 impact angles. The obtained results were found to correlate very well with Oka et al. (Wear, 259:95–101, 2005) erosion model.

Nondestructive evaluation of material degradation and sub-millimeter sized defect detection in steel using magnetic measurements

This paper investigates the possibility of simultaneous nondestructive evaluation of material degradation and detection of sub-millimeter sized defects using magnetic methods. We confirmed by FEM simulation that assessment of both degradation and small defects in steel is possible using a single-yoke probe. This was also verified experimentally. The hysteresis loop measurements were sensitive to degradation in the material, and the scanning flux distribution could be effectively used for detecting sub-millimeter sized defects. The degradation and small defects can also be evaluated separately with this single measurement configuration.