We report for the first time the detection of thermal free–free emission from post-flare loops at 34 GHz in images from the Nobeyama Radioheliograph. We studied eight loops, seven of which were from regions with an extremely strong coronal magnetic field reported by Fedenev et al. Loop emission was observed in a wide range of wavelength bands, up to soft X-rays, confirming their multitemperature structure and was associated with noise storm emission in metric λ. The comparison of the 17 GHz emission with that at 34 GHz, after a calibration correction of the latter, showed that the emission was optically thin at both frequencies. We describe the structure and evolution of the loops and we computed their density, obtaining values for the top of the loops between 1 and 6 × 1010 cm−3, noticeably varying from one loop to another and in the course of the evolution of the same loop system; these values have only a weak dependence on the assumed temperature, 2 × 106 K in our case, as we are in the optically thin regime. Our density values are above those reported from EUV observations, which go up to about 1010 cm−3. This difference could be due to the fact that different emitting regions are sampled in the two domains and/or due to the more accurate diagnostics in the radio range, which do not suffer from inherent uncertainties arising from abundances and non-LTE excitation/ionization equilibria. We also estimated the magnetic field in the loop tops to be in the range of 10–30 G.