Ether Ketone Research Articles

Nanoscale Poly(Dopamine)‐Modified ZIF‐8 Particle Hybrid Solvent‐Resistant Thin Film Nanocomposite (TFN) Membranes via Interfacial Polymerization on a Robust Polyether Ether Ketone (PEEK) Substrate

ABSTRACTThis study introduces an innovative approach to fabricating a poly ether ketone (PEEK)‐based thin‐film nanocomposite (TFN) nanofiltration membrane. Ultrafine polydopamine (PDA) modified zeolitic imidazolate framework‐8 (ZIF‐8) nanoparticles were integrated into the polyamide (PA) layer through a process of interfacial polymerization. The impacts of PDA@ZIF‐8 nanoparticle loading on composite membranes were examined, and their separation performances with different solvents and small molecular organics with various molecular weights and charges were evaluated. The PDA modification is credited with inducing a thinner, less crosslinked PA layer, culminating in the formation of a selective barrier that is both loose and ultra‐thin, improving the separation capabilities of membranes. The TFN‐3 membrane, with a 0.01 wt% loading of PDA@ZIF‐8 nanoparticles, emerged as a standout, demonstrating notably enhanced hydrophilicity. The pure water and organic solvent permeances through the TFN‐3 membrane were remarkably enhanced, with recorded values of 6.19 ± 0.26 L h−1 m−2 bar−1 for pure water and 3.44 ± 0.21 L h−1 m−2 bar−1 for methanol. Furthermore, the TFN‐3 membrane showcased impressive molecular retention in ethanol solutions for compounds with a molecular weight cut‐off (MWCO) of 464 g/mol. The PEEK‐based TFN‐3 membrane also exhibited exceptional creep resistance, ensuring consistent performance during long‐term testing. In a 5‐day ethanol separation test, the TFN‐3 membrane maintained a Rose Bengal (RB) retention rate exceeding 99%, underscoring its stability and reliability. The newly developed PEEK‐based TFN membrane not only promises robust solvent resistance and stability but also delivers efficient separation and purification capabilities. It holds great potential for offering effective and sustainable solutions across a spectrum of industries, particularly in pharmaceutical production and chemical processing, where the separation, recovery, and purification of solvents are paramount.

Interfacial crystallization behavior and properties of T1100-grade carbon fiber reinforced PEEK composites

As a semi-crystalline resin, the crystallization behavior of Polyether ether ketone at the interface between carbon fiber and resin matrix profoundly affects the interfacial properties of carbon fiber-reinforced PEEK composite. Therefore, the research on the interfacial crystallization behavior of CF/PEEK composite is of great significance. Aiming at Chinese-made T1100-grade carbon fiber and PEEK resin matrix, the effects of cooling rate and sizing agent on the interfacial crystallization behavior of T1100-grade carbon fiber/PEEK were studied by POM and DSC, and the IFSS was tested by microdebond. The experimental results show that the increase of the cooling rate and the removal of the sizing agent can improve the nucleation ability of PEEK and promote the interfacial crystallization of PEEK. PEEK starts to form transcrystallization, when the nucleus density is increased to about 0.07/μm. The interfacial crystallization behavior has an effect on the interfacial properties. The IFSS increases with increasing cooling rate and removal of sizing agent.

Design of High-Performance Electrospun Membranes for Protective Clothing Applications.

The integration of nanomaterials into the textile industry has significantly advanced the development of high-performance fabrics, offering enhanced properties such as UV blocking, fire resistance, breathability, hydrophobicity, antimicrobial activity, and dust rejection. In this context, our research explores the development and characterization of electrospun membranes composed of polyether ether ketone (PEEK) and various polyimides (PIs (1-6)), focusing on their application in protective clothing. The combination of phosphorus-containing polyimides and PEEK, along with the electrospinning process, enhances the distinctive properties of both PEEK and polyimides, leading to composite membranes that stand out according to key parameters essential for maintaining physiological balance. The structural and morphological characteristics of these membranes have been evaluated using Fourier transform infrared spectroscopy (FTIR) to identify the functional groups and scanning electron microscopy (SEM) to examine their morphology. These analyses provide critical insights into these materials' properties, which influence key performance parameters such as moisture management, breathability, and barrier functions. The membranes' breathability and impermeability were assessed through the water vapor transmission rate (WVTR), contact angle measurements, water and air permeability, and flame resistance tests. The results obtained indicate that PEEK/polyimide composite membranes meet the complex requirements of modern protective textiles, ensuring both safety and comfort for users through their optimized structural properties and enhanced functional capabilities.

Mechanism and performance of thermal radiation recycling for in-space 3D printed continuous carbon fibre-reinforced PEEK composites

ABSTRACT The benefits of space recycling lie in reducing launch mass and achieving self-sufficiency. For 3D printed continuous fibre-reinforced composites (CFRCs), a reverse melt recycling technology was proposed, involving heating resin opposite to the 3D printing path and continuously peeling-off the fibres from the melt. An infrared radiation heating recycling device suitable for a vacuum environment was designed and the temperature distributions were optimised, achieving recycling of continuous carbon fibre-reinforced polyether ether ketone (CF/PEEK) thin-walled rotational structures. The recycled filaments with diameters of 0.7 and 0.8 mm could achieve good surface quality and low pore defects. The porosity decreased from 11.2% of original samples to 5.7% of remanufactured samples, leading to improvements in mechanical properties with flexural strength and modulus increased by 4.8% and 50.8% respectively. Overall, the recycling technology emphasised a non-degradation recycling solution for 3D-printed CFRCs in space to form a full lifecycle application model for space composites.

Application of fumed silica supported copper catalysts in the dehydrogenation of sec-butanol to methyl ethyl ketone

Application of fumed silica supported copper catalysts in the dehydrogenation of sec-butanol to methyl ethyl ketone

Using Layer-by-layer Assembled Clay Composite Junctions to Enhance the Water Dissociation in Bipolar Membranes.

Bipolar membranes (BPMs) with a layer-by-layer (LbL) assembled montmorillonite (K30 MMT) clay-polyelectrolyte (PE) composite junction coated onto a sulfonated poly(ether ether ketone (SPEEK)) electrospun support are prepared, characterized and their water dissociation performance is analyzed. In particular, the focus is on the effect of the presence of the K30 MMT clay as a catalyst for water dissociation, the bilayer number (three, six, and nine), and the PE strength (poly(ethylenimine) (PEI) as a weak PE and poly(diallyl dimethylammonium chloride) (PDADMAC) as a strong PE) on the BPM performance. The BPMs are prepared by electrospinning and hot pressing SPEEK and the Fumion FAA-3 polymer. Adding the composite multilayers in the BPM junction decreases the membrane area resistance in reverse bias from 560 to 21 Ohms cm2 for the best-performing modified BPM. The bilayer number has limited influence on the overall membrane resistance, while the PDADMAC BPMs outperform the PEI BPMs due to the higher and more stable PE and clay adsorptions. Electrochemical impedance spectroscopy shows that the depletion layer thickness decreases exponentially with the number of bilayers as the water dissociation reaction becomes less dependent on the junction electric field. Furthermore, the higher Donnan exclusion at the modified junctions improves the BPM permselectivity 3-fold compared to the BPM containing no catalyst. Altogether, these improvements lead to 6.7 times less energy being used in BPM electrodialysis for the production of acid and base when a BPM with composite LBL junction is used compared to a BPM without catalyst. Thus, adding MMT clay composite LbL catalyst to BPM junctions is a promising method to improve the efficiency and reduce the energy consumption of electrochemical processes that rely on BPMs.

Interfacial adhesion enhancement in high‐modulus carbon fiber/poly (ether ether ketone) composites: through the flexible macromolecule‐grafted‐carbon nanotubes sizing treatment

AbstractIn this study, a flexible macromolecule‐grafted‐carbon nanotube (t‐CTN‐SPEEK) is developed and utilized as bridge to enhance the interfacial properties of high‐modulus carbon fiber (HM‐CF) reinforced poly (ether ether ketone) (PEEK) composites. With t‐CTN‐SPEEK sizing, the wettability of HM‐CF is enhanced, thereby promoting better resin wetting. The increased roughness induced by the t‐CTNs‐SPEEK on the surface of the HM‐CF affords improved mechanical interlocking among interface. Additionally, SPEEK enhances the interfacial compatibility of the composites. Thus, after the t‐CTN‐SPEEK sizing treatment, the composite exhibits the best interfacial shear strength (IFSS), as evaluated using the interfacial strength evaluation instrument. This paper also discusses in detail the interfacial strengthening mechanism after sizing and presents a promising approach to enhancing the interfacial properties of HM‐CF composites.

Efficient separation of methyl ethyl ketone and water azeotrope using hydrophobic amino acid ester ionic liquids

BackgroundMethyl ethyl ketone (MEK), an essential organic solvent, is commonly produced via the n-butene method, where water emerges as the principal impurity. The conventional distillation processes, which are necessitated by the azeotropic behavior between MEK and water, result in a substantial expenditure of energy. As a result, liquid-liquid extraction represents a promising alternative for energy-efficient separation. MethodsIn this work, three hydrophobic amino acid ester ionic liquids L-phenylalanine ethyl ester bis(trifluoromethylsulfonyl) imide ([Phe][NTf2]), L-leucine ethyl ester bis(trifluoromethylsulfonyl) imide ([Leu][NTf2]) and L-valine ethyl ester bis(trifluoromethylsulfonyl) imide ([Val][NTf2]) were utilized as extractants for separation of the binary azeotrope methyl ethyl ketone and water. The effects of extraction time, extraction temperature, mass ratio of MEK-water mixture to ionic liquid and initial concentration of MEK on extraction efficiency were investigated. Significant findingsThe results demonstrate that the ionic liquid [Phe][NTf2] exhibits superior extraction ability for the separation of the azeotrope methyl ethyl ketone and water. The maximum extraction yield of 99.86 % was achieved with the optimum extraction conditions of extraction time, 10 min, extraction temperature, 293.15 K, mass ratio of mixture to ionic liquid, 1:1 and initial concentration of MEK, 20 %. In addition, the relationship between the structure of ionic liquids and their extraction performance was revealed by quantum chemical calculations of ionic liquids with MEK and water. These ionic liquids were positioned as promising environmentally friendly alternatives to traditional organic solvents for the recovery of MEK from aqueous solutions, providing valuable insights for industrial applications.

Assessments and investigation of process parameter impacts on surface roughness, microstructure, tensile strength, and porosity of 3D printed polyetherether ketone (PEEK) materials

Additive manufacturing (AM) is emerging as a competitive technology with promising applications across various sectors, including biomedical, automotive, construction, and dental implants. This study investigates the influence of key process parameters on the surface roughness, microstructure, tensile strength, and porosity of Polyether Ether Ketone (PEEK), a high-performance thermoplastic used in dental prosthetics. Traditionally, metals and ceramics have been the standard for dental restorations, but advancements in computer-aided design (CAD) and computer-aided manufacturing (CAM) have improved accuracy, particularly for implant-supported prostheses. However, conventional methods like CAD-milling face challenges such as material waste and tool wear. AM techniques, such as fused deposition modeling (FDM), offer a solution by constructing objects layer by layer, minimizing waste. This research explores the effects of nozzle temperature on the mechanical properties of 3D-printed PEEK, emphasizing its role in optimizing performance and minimizing issues like porosity. Key factors like surface roughness and microstructure are highlighted as critical to the biocompatibility and longevity of dental restorations. The study identifies the optimal nozzle temperature range for PEEK 380–440 °C, noting that deviations from this range lead to compromised mechanical properties. Overall, the findings provide valuable insights into optimizing the AM process for PEEK in dental applications and suggest that further biological and chemical studies are necessary to fully realize the material's potential in replacing traditional dental restoration materials.

Effects of various laser applications on surface roughness and bond strength to veneering composites of polyether ether ketone (PEEK) and polyether ketone ketone (PEKK) materials.

The aim of this study was to investigate the bond strength between PEEK/PEKK and composite resins after various laser treatments and to compare the effectiveness of lasers on these polymers. 130 disc-shaped PEEK and PEKK blocks were obtained (10mm diameter-4mm height). One sample from each group (10 in total) was selected for scanning electron microscopy (SEM) analysis. The samples were randomly divided into 5 different surface treatment groups for each material (PEEK and PEKK): Er: YAG laser, Nd: YAG laser, diode laser, femtosecond laser and control (no surface treatment) (n = 12). Baseline and post-treatment surface roughness measurements were performed using a profilometer. The composite resin was bonded and SBS was measured. Comparisons among the groups were conducted via Kruskal-Wallis, one-way ANOVA; Tukey and Dunn tests were used as a post hoc test (p ≤ 0.05). All lasers significantly increased the roughness values of the PEEK and PEKK samples. In terms of shear bond strength; the Er: YAG and femtosecond laser groups had the highest values and the Nd: YAG, diode and control groups had the lowest values of the PEEK samples (p ≤ 0.05). The control group had the highest bond strength values and the femtosecond group had the lowest values for PEKK samples (p ≤ 0.05). All laser treatments increased the surface roughness of the PEEK and PEKK. Lasers increased the bond strength of PEEK to the veneering composite resin and decreased the bond strength values of PEKK. This shows that lasers behave differently in PEEK and PEKK materials.

“Janus” PEEK implant with sandwich Mg-containing coating for infected tissue repair

Having good antibacterial properties and promoting soft and hard tissue repair are the keys to successful implantation of intraosseous transcutaneous. Polyether ether ketone (PEEK) is a class of FDA-approved polymer implants. However, the surface of PEEK is bioinert, which is easy to cause postoperative infection and poor tissue integration. In this study, polypyrrole (Ppy) was polymerized on sulfonated PEEK, Mg3(PO4)2 nanosheets were grown in situ on one side, and polycaprolactone (PCL) was then spun on the surface to form a Janus-like surface on PEEK. The Ppy/Mg3(PO4)2/PCL composite coating could inhibit bacterial adhesion, and the excellent photothermal properties of Ppy/Mg3(PO4)2/PCL and Ppy coatings further promote the removal of bacteria due to the accumulated heat. After the infection was eliminated, the Janus-like surface of modified PEEK switched macrophages to anti-proinflammatory response and promoted both soft and hard tissue repair. The Ppy modified sulfonated PEEK could promote collagen secretion in the soft tissue, while the PCL films on Ppy/Mg3(PO4)2/PCL was densified by temperature response under near-infrared light treatment to close the exposed interface of Mg3(PO4)2 nanosheets that was more conducive to bone repair. In summary, PEEK with Janus-like surface consisting of Ppy/Mg3(PO4)2/PCL and Ppy has multiple biological functions of sequential antibacterial and soft and hard tissue repair, and is a promising candidate material for intraosseous transcutaneous implants.

Optimization of high performance hybrid composite under ballistic test and performance of the hybrid composite under IED blast

Abstract In this investigation a novel material has been developed comprising of Silicon Carbide (ceramic), Aluminium honeycomb (metal) and Poly Ether Ketone (PEK)—Poly Phynelene Benzobisoxaole (PBO) fiber based blast proof composite. The experimental results proved that this polymeric composite is highly suitable for 9 mm pistol bullet with 430 m s−1 at distance of 5 m as well as for improvised explosive devices blast to absorb the sharpnels/splinters. This investigation also highlights an efficient back layer for a blast-proof sandwich composite. Layer optimization was carried out by finite element method (FEM) analysis of blast effect on the multi-layer polymer composite panel by ANSYS Explicit Dynamics (LS DYNA Solver). The resultant optimal layers of PEK-PBO composites then tested to validate results of FEM analysis. Experimentally it is proved that polymeric composite with 10 layers of PBO fabric when test fired under 9 mm pistol bullet with 430 m s–1 at distance of 5 m, the bullet penetrates, however, when the polymeric composite is made with a total of 20 layers of PEK-PBO fabric, all the test fired bullets are stopped. Therefore, under SNANAG 4569 blast test, the polymeric composite was essentially made with 20 layers of PBO fabric and it is experimentally proved that PEK-PBO composite is highly efficient as the back layer of hybrid composite and all the sharpnels of IED blast are completely absorbed.

Vapor–Liquid Equilibrium Phase Behavior for Binary Mixtures Isopropyl Alcohol and Methyl Ethyl Ketone with Dimethyl Sulfoxide

Vapor–Liquid Equilibrium Phase Behavior for Binary Mixtures Isopropyl Alcohol and Methyl Ethyl Ketone with Dimethyl Sulfoxide

The Influence of Carbon Fiber on Crystallization and Morphology of Poly(Ether Ketone Ketone) Composites Towards High Rate Thermoplastic Manufacturing Processes

Recent interest in thermoplastic composites for aerospace applications is driven by the need for high-volume manufacturing of materials that display excellent mechanical, thermal, and solvent resistive properties. Specifically, a large component of the composite properties of thermoplastic composites are highly dependent on the crystalline fraction of the semi-crystalline polymer matrix of the reinforced system. This work investigates the melting behavior of poly (ether ketone ketone) (PEKK) and the influence of temperature and fiber on crystallization kinetics and morphology of (PEKK) composites utilizing, differential scanning calorimetry, Velaris-Sefaris modelling, and polarized optical microscopy (POM). Annealing temperatures of 380°C and above were required to fully erase crystalline ordering in the PEKK matrix. Furthermore, carbon fibers accelerated crystallization kinetics in PEKK at a range of temperatures observed via DSC, and Velaris-Sefaris modelling implied a shift from bulk to surface induced nucleation by the addition carbon fiber to the PEKK matrix, reducing activation energy of crystallization events. This nucleation behavior was visually confirmed through POM with observation of transcrystalline domains nucleated from the surface of a single carbon fiber.

Electrospun Sulfonated Poly(ether ether ketone) and Chitosan/Poly(vinyl alcohol) Bifunctional Nanofibers to Accelerate Proton Conduction at Subzero Temperature.

Multilayered microstructures can accelerate the proton conduction process in proton exchange membranes (PEMs). Herein, we design and construct PEMs with microstructures based on bifunctional nanofibers and sulfonated poly(ether ether ketone) (SPEEK) nanofibers. Specifically, the bifunctional nanofibers composed of poly(vinyl alcohol) and chitosan are prepared and then combined with the electrospun SPEEK nanofibers. The stable microstructure is derived from the compatible interfacial property of nanofibers and the formed hydrogen bonds. The multilayered microstructure consisting of nanofibers accelerates the proton conduction even at subzero temperature because of regulating the proton conduction pathways. Specifically, the (SKNF/CPNF/SKNF)/PA membrane exhibits the proton conductivities of (0.951 ± 0.138) × 10-2 S/cm at -30 °C and (7.32 ± 0.37) × 10-2 S/cm at 160 °C. Additionally, the fine proton conductivity stability is demonstrated by the proton conductivity in the long-term test and the cooling/heating cycle test, such as 1.67 × 10-2 S/cm at -30 °C (after 1000 h), 4.52 × 10-2 S/cm at 30 °C (after 810 h), 1.12 × 10-2 S/cm at -30 °C, and 1.01 × 10-1 S/cm at 30 °C in the cooling/heating process (5 cycles). The single fuel cell possesses an open-circuit voltage of 0.886 V and a peak power density of 0.508 W/cm2 at 130 °C.

The Influence of Carbon Fiber on Crystallization and Morphology of Poly(Ether Ketone Ketone) Composites Towards High Rate Thermoplastic Manufacturing Processes

Recent interest in thermoplastic composites for aerospace applications is driven by the need for high-volume manufacturing of materials that display excellent mechanical, thermal, and solvent resistive properties. Specifically, a large component of the composite properties of thermoplastic composites are highly dependent on the crystalline fraction of the semi-crystalline polymer matrix of the reinforced system. This work investigates the melting behavior of poly (ether ketone ketone) (PEKK) and the influence of temperature and fiber on crystallization kinetics and morphology of (PEKK) composites utilizing, differential scanning calorimetry, Velaris-Sefaris modelling, and polarized optical microscopy (POM). Annealing temperatures of 380°C and above were required to fully erase crystalline ordering in the PEKK matrix. Furthermore, carbon fibers accelerated crystallization kinetics in PEKK at a range of temperatures observed via DSC, and Velaris-Sefaris modelling implied a shift from bulk to surface induced nucleation by the addition carbon fiber to the PEKK matrix, reducing activation energy of crystallization events. This nucleation behavior was visually confirmed through POM with observation of transcrystalline domains nucleated from the surface of a single carbon fiber.

Ultra-high Prussian blue loading in SPEEK matrix fabricated by one-step electrostatic spraying as proton exchange membranes for fuel cell

Mixed matrix proton exchange membrane is promising for fuel cell application, but maximizing nanofiller loading to enhance performance is significant challenge. This study developed a one-step electrostatic spraying strategy to prepare ultra-high Prussian blue loading (up to 66.7 wt%) in sulfonated poly(ether ether ketone) matrix (PB@SPEEK). By coupling the electrostatic spraying and in situ solvent evaporation densification, SPEEK fills the voids between PB nanoparticles, forming a bicontinuous microstructure in the membrane. The ultra-high PB content of 66.7 wt% enable a fully utilization of its intrinsic properties, resulting in extremely low swelling ratio of 3.4% at 80°C, excellent flexibility of freely folding, and nearly 100% mass retention after 12-hour immersion in Fenton reagent at 60°C. In single-cell tests, the PB@SPEEK mixed matrix membrane shows stable internal resistance due to easily water hydration, therefore achieving excellent low-temperature peak power (1973.9 mW/cm2 at 40 °C and 2078.0 mW/cm2 at 60°C). The strategy developed in this study enables the one-step preparation of large-area, ultra-thin and ultra-high capacity of inorganic nanofiller mixed matrix proton exchange membranes for high-performance fuel cell.

Novel heart valve leaflet designs with stiff polymeric materials and biomimetic kinematics

Despite continuous efforts to improve the robustness of cardiac valve implants, neither bioprosthetic nor mechanical valves fulfill both hemodynamic and durability requirements. This study discussed novel flexible leaflet designs, focusing on polymeric materials with proven hemocompatibility, such as polyether ether ketone, of much higher stiffness than native tissue, aiming at optimal valve implants. A biomimetic valve with a single-curvature belly-curve (B-C) was used as a reference for new design variants with a double-curvature B-C with varying radii. Soft (13.2 MPa) and stiff (2.4 GPa) leaflet materials and different thicknesses were studied using lean simulations and in vitro experiments under physiologic hemodynamic conditions. The performance was assessed using opening pressure (OP) and orifice area (OA). The latter was determined by a newly developed automatized image processing tool. Experimental trends are in agreement with simulations and demonstrated that a buckling-inspired double-curvature leaflet design significantly enhances the trileaflet valve opening behavior, which is particularly advantageous for stiffer leaflet materials. Compared to the reference, the best-performing variant showed an OP improvement of 47% and 44% based on simulations and experiments, respectively. In contrast, the achieved mean pressure differential was directly comparable to state-of-the-art bioprosthetic valves. The OA was slightly reduced for new variants but still in the satisfying range.Graphic abstract

Additively manufactured plastic plasma spectrometer.

We report results in the development and testing of a low resource tophat electrostatic analyzer (ESA) for space plasma measurements. This device has been additively manufactured (3D-printed) using fused deposition modeling. The classic tophat design is composed of four plastic pieces, without any surface coatings. The three conducting electrodes are printed from carbon nanotube infused polyether ether ketone (CNT-PEEK). The fourth piece, an insulating electrode support, uses pure PEEK. This ESA is designed to detect electrons in space from 10eV up to 30keV. We demonstrate that the printed CNT-PEEK is sufficiently electrically conductive to support the fast high voltage slewing often required for high time resolution measurements. The plastic ESA has been successfully vibrated beyond standard pre-flight levels, tested under keV electron beam illumination over a wide range of temperatures, and tested under UV illumination, simulating the solar Ly-α flux. In comparison with an identical machined aluminum ESA, our CNT-PEEK ESA provides nominal energy/angle bandpasses, closely matching simulation. These bandpasses imply minimal impact from surface charging at beam energies of 2-3keV, although more investigation is needed. We also find that the CNT-PEEK ESA provides far superior out-of-band electron rejection and UV photon rejection compared to the machined aluminum ESA. We do not detect any problems with trapped gases or outgassing. This development offers the potential for significant mass savings, implementation of otherwise unattainable geometric configurations, and dramatic simplification in manufacturing and assembly processes required for the development of space plasma instruments.

Peroxidation of methyl ethyl ketone catalyzed by UiO-66 and the thermal stability analysis

The synthesis of methyl ethyl ketone peroxide (MEKP) generally belongs to the homogeneous strong acid catalysed process. Acid is corrosive to the equipment, cannot be reused and thus has a large amount of wastewater to be post-treated and needs high treatment cost. The heterogeneous catalytic synthesis of organic peroxides is gaining more and more attention. In this study, methyl ethyl ketone peroxide was prepared from butanone oxidized by hydrogen peroxide and in the presence of UiO-66 as the catalyst. Under the conditions that the molar ratio of H2O2 to methyl ethyl ketone (MEK) is 2, the mass ratio of UiO-66 to MEK is 0.045, the reaction temperature is 30 °C, and the reaction time is 70 min, the active oxygen content of the product reaches 10.81 %, and the main products are methyl ethyl ketone peroxide and its oligomers. The thermal decomposition heat and activated energy are 748 J·g−1 and 101 kJ·mol−1 based on the thermogravimetric-differential scanning calorimetry (TG-DSC) determination. Finally, after four cycles, uio-66 still had 70.2 % yield, and XRD and FTIR after the cycles proved the good stability of the catalyst. The study provides a new way for the production of methyl ethyl ketone peroxide by heterogeneous catalytic oxidation.