With the continued advancement of spaceborne hyperspectral sensors, hyperspectral remote sensing is evolving as an increasingly pivotal tool for high-precision global monitoring applications. Novel image spectroscopy data, e.g., the PRecursore IperSpettrale della Missione Applicativa (PRISMA) and Environmental Mapping and Analysis Program (EnMAP), can rapidly and non-invasively capture subtle spectral information of terrestrial vegetation, facilitating the precise retrieval of the required vegetation parameters. As critical vegetation traits, Leaf Mass per Area (LMA) and Equivalent Water Thickness (EWT) hold significant importance for comprehending ecosystem functionality and the physiological status of plants. To address the demand for high-precision vegetation parameter datasets, a hybrid modeling approach was proposed in this study, integrating the radiative transfer model PROSAIL and neural network models to retrieve LMA and EWT from PRISMA and EnMAP images. To achieve this objective, canopy reflectance was simulated via PROSAIL, and the optimal band combinations for LMA and EWT were selected as inputs to train neural networks. The evaluation of the hybrid inversion models over field measurements showed that the RMSE values for the LMA and EWT were 4.11 mg·cm−2 and 9.08 mg·cm−2, respectively. The hybrid models were applied to PRISMA and EnMAP images, resulting in LMA and EWT maps displaying adequate spatial consistency, along with cross-validation results showing high accuracy (RMSELMA = 5.78 mg·cm−2, RMSEEWT = 6.84 mg·cm−2). The results demonstrated the hybrid inversion model’s universality and applicability, enabling the retrieval of vegetation parameters from image spectroscopy data and offering a valuable contribution to hyperspectral remote sensing for vegetation monitoring, though the availability of field measurement data remained a significant challenge.
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