Equiatomic Alloy Research Articles

Bayesian Optimization of 7-component (AlVCrFeCoNiMo) single crystal alloy’s compositional space to optimize elasto-plastic properties from Molecular Dynamics Simulations

Abstract Exploring the vast compositional space of high-entropy alloys promises materials with superior mechanical properties much needed in industrial applications. We demonstrate on the 7-component alloy AlVCrFeCoNiMo system with randomly ordered atoms that this exploration of the compositional space can be accelerated by combining molecular dynamics simulations with Bayesian optimization. Our algorithm is tested on maximizing the shear modulus, resulting in pure Mo, an unsurprising result based on Mo’s large density. Maximizing the yield stress results in Co-, Cr- and Ni-based alloys with the optimal composition varying depending on the presence of defects within the crystal. Finally, we optimize the plastic behaviour by aiming for high stresses while minimizing the deformation fluctuations, and find that a predominantly NiMo alloy’s high lattice distortions ensure a smooth stress response. The results suggest that mechanical properties of 2- to 4-component alloys with optimized composition may be superior to those of equiatomic high-entropy alloys without short-range order.

Ordering-facilitated lower hydrogen embrittlement sensitivity in a prototype high-entropy alloy

The ageing treatment (450 °C/60 h) led to the spinodal decomposition at grain boundaries (GBs) and the development of chemical short-range orders (CSROs) in the alloy matrix, increasing the strength and effectively reducing the HE sensitivity of the equiatomic FeMnNiCoCr alloy. Firstly, the emergence of NiMn- and Cr-rich orders at GB regions reduces hydrogen diffusion rates along GBs and limits hydrogen enrichment at these sites. Secondly, CSROs promote hydrogen accumulation within the grain interior and impede hydrogen penetration, resulting in a shallower hydrogen-affected depth in the aged sample. Moreover, the modulation of hydrogen distribution by microstructure initiates transgranular cracking in the aged sample.

Microstructural Stability and High-Temperature Oxidation Behavior of Al0.25CoCrCuFeNi High Entropy Alloy

Al0.25CoCrCuFeNi is a high-entropy alloy composed of transition metals, specifically designed for high-temperature applications owing to its favorable mechanical properties, high melting point, and excellent high-temperature resistance. This alloy has been identified as a promising material for space exploration, particularly in the fabrication of combustion chambers and rocket nozzles by the National Aeronautics and Space Agency. Ongoing alloy development involves modifying the elemental composition. This study reduced aluminum content in the equiatomic AlCoCrCuFeNi alloy to Al0.25CoCrCuFeNi, followed by isothermal oxidation treatments at 800, 900, and 1000℃. A series of experiments were conducted to investigate the microstructure stability and oxidation behavior of the Al0.25CoCrCuFeNi alloy. The alloying elements were melted using a single DC electric arc furnace, followed by homogenization at 1100°C for 10 hours in an inert atmosphere. Subsequently, samples were cut into coupons for isothermal oxidation testing at the desired temperatures for 2, 16, 40, and 168 hours. The oxidized samples were characterized using XRD (x-ray diffraction), SEM (scanning electron microscopy) equipped with EDS (energy-dispersive X-ray spectroscopy), optical microscopy, and Vickers hardness testing. The as-homogenized alloy consisted of two constituent phases: an FCC (face-centered cubic) phase in the dendritic region and a copper-rich FCC phase in the inter-dendritic region. The oxides formed during the oxidation process included Al2O3, Cr2O3, Fe3O4, CoO, CuO, NiO, and spinel oxides (Co,Ni,Cu)(Al,Cr,Fe)2O4), with distinct formation mechanisms at each temperature.

Thermodynamic Investigation of Propagating Behavior in SHS for Equiatomic and Non-Equiatomic NiTi Alloys Using Factsage Software

Thermodynamic Investigation of Propagating Behavior in SHS for Equiatomic and Non-Equiatomic NiTi Alloys Using Factsage Software

Towards quantifying (meta-)stability of multi-principal element alloys: From configurational entropy to characteristic temperatures

Understanding and hence predicting the stability and metastability of multi-principal-element alloys (MPEAs) is crucial for their design and applications, but it remains a complex and time-consuming task. Descriptors based on the configurational entropy alone are often insufficient in determining the relative stability of MPEA solid solutions, since they predict, against experimental evidence, that alloys containing a large number of elements will be eventually stable. Here we introduce two characteristic temperatures, derived from the temperature dependence of the configurational entropy, which effectively act as (meta-)stability indicators. These can be further combined in a dimensionless quantity, Td0, which enables us to rank alloys according to their compositional and structural (meta-)stability across a broad composition range. In particular, we are able to map equiatomic and non-equiatomic alloys, and even regions covered by conventional alloys. Our proposed descriptors are validated against a large body of experimental results and compared to other (meta-)stability descriptors. Furthermore, they allow us to revise the alloys classification scheme into high-entropy, medium-entropy and low-entropy. Our work sheds new light into the thermodynamic origin of alloying metastability, it provides a potential tool to correlate metastability thermodynamics and kinetics, and ultimately may help in alloys design and discovery.

Grain boundary diffusion in additively manufactured CoCrFeMnNi high-entropy alloys: Impact of non-equilibrium state, temperature and relaxation

Grain boundary diffusion of Ni in the equiatomic CoCrFeMnNi high-entropy alloy, produced by additive manufacturing, is measured using a radiotracer technique in an extended temperature interval of 350 to 703 K. A strongly non-monotonic temperature dependence of the Ni grain boundary diffusion coefficients (with a spectacular intermittent retardation of the diffusion rates with increasing temperature) is seen and explained by relaxation of a non-equilibrium state induced by rapid solidification during fabrication. The grain boundary excess energy of the non-equilibrium state of these grain boundaries, as estimated from the diffusion data, is found to be larger than 0.3 J/m2. This corresponds to an increase of about 30% of the interface energy compared to relaxed general high-angle grain boundaries. The temperature-induced evolution of the grain boundary state is analyzed in terms of the concomitant structure evolution, segregation, phase stability and precipitation in the multi-component alloy.

Plasticity and strength of an equiatomic and a non-equiatomic HfNbTaTiZr high entropy alloy during uniaxial loading : a molecular dynamics simulation study

Abstract Understanding plasticity and strength of high entropy alloys of HfNbTaTiZr is extremely significant in building nuclear reactors, gas turbines, aerospace devices etc. Here we study an equiatomic (Hf0.20-Nb0.20-Ta0.20-Ti0.2-Zr0.20) and a non-equiatomic (Hf0.35-Nb0.20-Ta0.15-Ti0.15-Zr0.15) mixture of two alloys under uniaxial tensile loading from molecular dynamics simulations. Modified Embedded atom potential is used to model both these bcc alloys and all simulations are performed at 300 K with three different tensile strain rates–0.0002, 0.0005 and 0.001 ps−1. Radial distribution functions, bond-orientational parameters and OVITO are used to analyse the MD trajectories. At 0.001 ps−1 strain, both these alloys deform similarly, but differences are observed at 0.0005 and 0.0002 ps−1 strains. At these rates, both alloys deform elastically till 3%, thereafter they deform plastically till 15%–20% strain. Yield strengths are comparable in the elastic limit but in the plastic limit non-equiatomic alloy have higher strength. In equiatomic alloy, bcc phase transforms to fcc whereas in non-equiatomic alloy bcc phase transforms to both fcc and hcp. Formation of hcp atoms (50%) decrease the plasticity of the non-equiatomic alloy but increases its strength. We also observe that in both these alloys and at all strain rates, bcc atoms transform to fcc/hcp atoms through an intermediate amorphous like state. Local coordination and orientation of all atoms change similarly in equiatomic mixture. But in non-equiatomic mixture local orientation in Hf, Ti and Zr changes differently compared to Nb and Ta.

Investigation of the failure behaviour of equiatomic AlCrCuNiFe based high entropy alloy TIG weld cladding

The present research focuses on the development of an equiatomic AlCrCuNiFe high entropy alloy (HEA) cladding using the TIG welding process. The influence and contribution of TIG cladding process parameters (welding current, welding speed, and SOD) on the microhardness and flexural stress have been investigated using the response surface methodology (RSM) and analysis of variance (ANOVA), respectively. The indentation fracture toughness test has been conducted over the claddings exhibiting minimum, maximum, and optimum microhardness values. The result revealed that welding current has the highest effect on the mechanical performance of the HEA cladding. The FE-SEM, optical microscopy, XRD and EDS analysis were performed to characterize the claddings. The cladding deposited at the S12 test run offered the least flexural resistance, microhardness, and indentation fracture toughness which was about 812 MPa, 494.97 HV0.3, and 1.29 ± 0.04 MPa.m1/2, respectively. In contrast, the optimized S5 cladding specimen exhibited good flexural resistance, appreciable microhardness and indentation fracture toughness of about 1543.92 MPa, 712 HV0.3, and 1.63 ± 0.03 MPa.m1/2 respectively. The optimum cladding exhibited flexural stress, microhardness, and fracture toughness enhancement of 46.77 %, 30 %, and 26.35 % compared to the least resistance cladding (S12) due to the high-retained alloying elements leading to enhanced solid solution strengthening. The three-point bend-tested cladding specimens’ optical microscopy images revealed that the cladding failure was primarily due to cohesive failure, crack progression, and delamination.

Phase analysis of near equiatomic bulk FeRh alloys: X-ray versus neutron diffraction and magnetization measurements

The information obtained by X-ray diffraction (XRD) by impinging the X-ray beam onto the flat surface of bulk Fe–Rh alloys is contrasted with that provided by the thermomagnetic analysis curves measured under a magnetic field of 5 mT and 2 T, and the neutron diffraction (ND) patterns. The experiments were performed on slices cut from bulk Fe50Rh50 and Fe49Rh51 alloys prepared by induction melting followed by 48 h of thermal annealing at 1273 K. Whereas ND patterns and magnetization curves, directly and indirectly point out that the samples are single-phase with a CsCl-type crystal structure undergoing a magnetoelastic transition that changes the magnetic structure from antiferromagnetic to ferromagnetic on heating, multiple phases are identified in the XRD patterns, which modify upon polishing or etching the surface with a mixture of hydrochloric (HCl) and nitric acid (HNO3) at a volume ratio of 90:10 from 30 to 210 min. The limitation of XRD for accurately characterizing the phase constitution within the bulk of Fe–Rh alloys is underlined.

Efficient alloy design strategy for fast searching for high-entropy alloys with desired mechanical properties

The exponentially large compositional space of high entropy alloys (HEAs) offers more possibilities for designing alloys with desired properties. However, it also poses challenges to using the traditional “trial and error” approach in alloy design. In this work, an XGBoost model for predicting the elastic properties of the NbTiVZr family across the entire compositional space was established by combining density-functional theory (DFT) calculation results as the dataset with machine learning (ML) algorithms. Furthermore, considerations of charge transfer were incorporated into the solid solution hardening (SSH) model, and the model was further modified. Through comparing plasticity evaluation indices, the parameter D (γSurf/γGSFE) was determined to be suitable for predicting the plasticity of NbTiVZr alloys. A full compositional space model for yield strength and plasticity has been constructed based on the modified SSH model and the parameter D, respectively. Ultimately, an alloy design system combining the full compositional space models for yield strength and plasticity was established, achieving good consistency with experimental results. And a non-equiatomic alloy with a yield strength exceeding that of equiatomic alloys by 32.2 % (1409 MPa), while maintaining 29.27 % compressive strain was discovered. In conclusion, this work provides an efficient design strategy for alloys with desired properties.

Comparative study of microstructure and mechanical properties of cold rolled and annealed CoCrFeNi-MEA and CoCrFeNiMn-HEA fabricated by laser energy deposition

Equi-atomic quaternary CoCrFeNi Medium-entropy alloy (MEA) and quinary CoCrFeNiMn high-entropy alloy (HEA) are fabricated by laser energy deposition, followed by 5-pass cold rolling to total reduction of 70 % and annealing at temperatures of 600–1000 °C for 1 h. CoCrFeNi-MEA is severely cracked while CoCrFeNiMn- HEA is slightly cracked after cold rolling. Hardness of as deposited and fully recrystallized (heat treating temperature at 800–1000 °C) CoCrFeNi-MEAs are slightly higher than those of CoCrFeNiMn- HEAs, due to the larger atomic size misfit and lattice strain in CoCrFeNi-MEA than in CoCrFeNiMn-HEA. However, the higher microhardness of CoCrFeNiMn-HEAas-rolled than CoCrFeNi-MEAas-rolled is associated with the higher strain state in CoCrFeNiMn-HEAas-rolled than in CoCrFeNi-MEAas-rolled. With the increase of heat-treating temperature, microhardness of CoCrFeNi-MEA increases first and then decreases due to the precipitation hardening effect of Cr-rich (B2) particles in CoCrFeNi-MEAR-600. Microhardness of CoCrFeNiMn-HEA decreases with the increase of annealing temperature because of the weaker precipitation hardening effect of MnNi phase (L10) and Cr-rich particles (BCC) after annealing at 600 ℃ and higher temperatures. CoCrFeNi-MEAR-700 is much harder than CoCrFeNiMn-HEAR-700 because CoCrFeNi-MEAR-700 is partially recrystallized and CoCrFeNiMn-HEAR-700 is fully recrystallized. Strength behavior of the two alloys is consistent with microhardness behavior. {100}<110> texture component is acquired in both CoCrFeNi-MEAas-rolled and CoCrFeNiMn-HEAas-rolled. <111>//ND texture is observed in both alloys after annealing at 600 ℃. Orientation of recrystallized grains is random in both alloys. Size of recrystallized grains in CoCrFeNiMn-HEA is slightly larger than those in CoCrFeNi-MEA since homologous temperature (T/Tm) of CoCrFeNiMn-HEA is slightly higher than that of CoCrFeNi-MEA.

An assessment of the mechanically alloyed equiatomic FeCoNiMnSi high entropy amorphous alloy for non-isothermal crystallization kinetics and magnetocaloric refrigeration application

We studied an equiatomic FeCoNiMnSi high entropy amorphous alloy successfully processed via mechanical alloying technique. The structural, magnetic, and magnetocaloric characteristics of the resulting materials were examined using X-ray diffraction, field emission scanning electron microscopy, high-resolution transmission electron microscopy, and a vibrating sample magnetometer. The structural analysis showed a prominent amorphous phase formation as the milling time increases from t = 0–35h of mechanical alloying. The differential scanning calorimetry was employed to investigate the non-isothermal crystallization kinetics of the 35-h milled sample. The results revealed that the milled powder consists of a single exothermic peak with its apparent activation energy (Eg, Ex, Ep) being determined using the Kissinger, Ozawa, and Augis-Bennett equations. The findings exhibit Ex > Ep > Eg, representing that nucleation is more complicated than the growth mechanism during the crystallization process. Meanwhile, under non-isothermal conditions, the Kissinger-Akahira-Sunose, Friedman, and Flynn-Wall-Ozawa models were calculated using the local activation energies that agree with the apparent activation energy. Furthermore, the Johson-Mehl-Avrami-Kolmogorov exponent (n) and Avrami-Ozawa combined [F(T)] models exhibit high-dimensional nucleation and growth with an increasing nucleation rate enabled by lowering the local activation energies as a function of degree of conversion with respect to temperature. In magnetic measurements, a feasible mathematical model was proposed as a novel strategy for predicting the value of saturation magnetization as a milling time function. The model has an exceptional predictive capability, confirmed by fitting other research outcomes. Finally, the proposed system also delivers the best magnetocaloric properties with a maximum magnetic entropy change of 3.70 Jkg−1 K−1 at 150 K curie temperature and a refrigeration capacity of 252.86 J/kg with 1000 Oe applied magnetic field.

Weak strain-rate sensitivity of hardness in the VCoNi equi-atomic medium entropy alloy

In this study, high strain rate nanoindentation was utilized to elucidate the dynamic behavior and the underlying deformation mechanisms of the equi-atomic vanadium-cobalt-nickel (VCoNi) medium entropy alloy. The hardness at high strain rate (average indentation strain rate: ∼11,000 s−1) exceeded that at low strain rate (constant indentation strain rate: 0.01 s−1) by only ∼3.5 %. Planar slip was identified as the predominant deformation mechanism at both strain rates, with no evidence of deformation twinning or phase transformation. The low strain rate sensitivity of VCoNi can be attributed to its lower lattice friction relative to that of conventional BCC metals and limited dislocation-dislocation interaction compared to that in typical FCC metals. The low strain rate sensitivity observed in VCoNi may also extend to other intermediate stacking fault energy alloy systems in which planar slip is prevalent.

Flow Behavior and Microstructure of Hot‐Worked TiNbTaVW Refractory High‐Entropy Alloy

The high‐temperature deformation behavior of an equiatomic TiNbTaVW refractory high entropy alloy (RHEA) was studied at temperatures of 950, 1000, and 1050 °C and a strain rate of 10−3 s−1. The flow stress, high‐temperature strength, and softening mechanisms were analyzed and compared with the IN718 nickel‐based superalloy. The results indicate that the flow stress of both TiNbTaVW and IN718 is sensitive to deformation temperature, with high temperatures resulting in reduced flow stress. Globular grains and elongated grains were observed at 950 and 1000 °C for TiNbTaVW, signifying both dynamic recovery and dynamic globularization as the softening mechanisms. Globular grains were only observed at 1050 °C for TiNbTaVW, signifying dynamic globularization as the softening mechanism. The TiNbTaVW RHEA has a higher temperature strength of 910, 870, and 658 MPa compared to the IN718 alloy with 72, 87, and 61 MPa at 950–1000 °C/10−3 s−1. By demonstrating comparable or superior performance in specific aspects, RHEAs can be considered in the near future for potential applications traditionally dominated by nickel‐based superalloys.

Design, Synthesis, and Characterization of Al‐Containing Multicomponent Alloys for Hydrogen Storage and Compression

AbstractIn this paper, compositions within the TiZrAlCrMn, TiZrAlCrFe, and TiZrAlMnFe alloy systems that form the C14 Laves phase are investigated. The design, synthesis, structural, and hydrogen storage characterizations for an equiatomic and a non‐equiatomic composition for each alloy system are presented. Additionally, the further development of a thermodynamic method for the calculation of pressure‐composition‐isotherms (PCIs) is presented of C14 Laves phase alloys that absorb hydrogen by solid solution. Overall, the results shown in this paper indicate that Al‐containing multicomponent alloys can present promising hydrogen storage performance under high pressures. Nonetheless, high concentrations of aluminum in highly concentrated (equiatomic) alloys can have a negative impact on the hydrogenation properties. The Ti0.29Zr0.05Al0.05Cr0.26Mn0.35 composition showed promising hydrogenation/dehydrogenation properties. The gravimetric capacity of this alloy is ≈1.76 wt.% H2 and the PCIs measured indicate that this material has potential for high‐pressure hydrogen storage and compression applications. The use of the presented thermodynamic model for the design of multicomponent alloys is suggested.

Additive Manufacturing of Interstitial Nitrogen‐Strengthened CoCrNi Medium Entropy Alloy

Equiatomic CoCrNi medium entropy alloy (MEA) is known for its excellent mechanical properties, oxidation resistance, and hydrogen embrittlement resistance. Interstitial elements like carbon and nitrogen further enhance these properties. However, there is limited research on interstitial solid solution‐strengthened alloys produced via powder bed fusion‐laser beam (PBF‐LB). This study investigates the role of nitrogen as an interstitial alloying element in CoCrNi MEA using PBF‐LB. Two alloy variants, one without nitrogen and one prealloyed with nitrogen, are analyzed through thermodynamic calculations and experimental validations. A minor nitrogen loss occurs in as‐printed samples compared to prealloyed powders, but the remaining nitrogen stays as an interstitial solid solution without forming detrimental secondary phases. This leads to improved mechanical properties, with yield and ultimate tensile strengths increasing from about 690 and 900 MPa in nitrogen‐free samples to over 750 and 1000 MPa in nitrogen‐containing samples while maintaining the high ductility of the nitrogen‐free counterpart in the as‐printed materials. Additionally, the nitrogen‐containing CoCrNi‐N MEA exhibits ≈35HV higher hardness than the nitrogen‐free variant in both as‐printed and heat‐treated states. These findings highlight the benefits of nitrogen addition in enhancing the mechanical properties of CoCrNi MEA produced by PBF‐LB.

Improving the Mechanical and Magnetic Properties of Equiatomic FeCo-2V Alloy Through Mild Magnetic Field Annealing

Improving the Mechanical and Magnetic Properties of Equiatomic FeCo-2V Alloy Through Mild Magnetic Field Annealing

Carbon reduction of 3D-ink-extruded oxide powders for synthesis of equiatomic CoCuFeNi microlattices

Equiatomic CoCuFeNi high-entropy alloy microlattices are created by 3D-extrusion printing with an ink containing a blend of binary oxides (Co3O4+CuO+Fe2O3+NiO) and graphite (C) powders. After printing, the green parts are subjected to a series of heat treatments under Ar leading to (i) the carbon reduction of the oxides to form metallic particles, (ii) the interdiffusion of these metallic particles to create an alloy, and (iii) sintering to remove porosity. The phase evolution in individual extruded filaments (similar to struts in the microlattices) is observed by in-situ X-ray diffraction, showing that intermediate suboxide phases (Cu2O, CoO, Fe3O4, CuFeO2, and FeO) form as the original oxides are reduced by carbon, before the final metallic alloy is formed. At 830 °C, the extruded filaments comprise a face-centered cubic CoCuNi(+Fe) alloy with unreduced FeO inclusions. After reduction and sintering at 1100 °C, homogeneous, densified, equiatomic CoCuFeNi microlattices are achieved, containing small amounts of a Cu-rich phase. At room temperature, the compressive strength of these CoCuFeNi microlattices increases as the strut diameter decreases from ~260 to ~130µm, as expected from an observed drop in strut porosity resulting from more complete sintering. This is consistent with the easier escape of CO+CO2 gas created during carbothermic oxide reduction from the thinner struts undergoing reduction and sintering.

Functional Medium Entropy Alloys for Joint Replacement: An Atomistic Perspective of Material Deformation and a Correlation to Wear, Corrosion, and Biocompatibility

The present study adopts a muti-facet approach to design bio inspired concentrated alloys for potential application as articulating surfaces in joint replacements. A series of equiatomic, Nb rich and Ti rich TiMoNbZr based medium entropy alloys (MEAs) were processed via arc melting and their mechanical, in-vitro corrosion, wear, and in vitro and in vivo biocompatibility were investigated. Equiatomic MEA had primarily bcc with minor hcp phases where the single bcc was achieved with the addition of Nb. The single bcc Nb rich alloy resulted in 13% elongation, much higher than equiatomic or Ti rich alloy. All the MEAs showed comparatively higher yield strength due to the climb of edge dislocations which is the main rate limiting mechanism at 300 K, as evident molecular dynamics (MD) simulation. The locally fluctuating energy landscape promotes kinks on edge dislocation, and at local minima nanoscale segments gets pinned. Upon yielding the entangled kink leaves a trail of vacancies/interstitials and escapes via climb motion to render high yield strength. The higher corrosion and pitting resistance of Nb enriched alloys can be attributed to the stable ZrO2, Nb2O5, TiO2, and MoO3 oxides, high polarization resistance (106-105 Ωcm−2), and low defect densities (1016-1018). In vitro cell-materials interaction using MC3T3-E1 showed bioinert but cytocompatible nature of the MEAs. The wear rate of the MEAs was in the range of 7-9×10−5 mm3N−1m−1. The wear debris did not show any tissue necrosis when implanted in rabbit femur rather new bone regeneration can be seen around the particles. Statement of SignificanceIn the present work, a noble Nb enriched MEAs with superior mechanical, in vitro wear, corrosion and cytocompatibility properties was designed for articulating surfaces in joint replacement.•Single bcc in Nb enriched MEAs resulted in 13 % elongation with high hardness and yield strength.•Climb of entangled edge segment is the rate limiting mechanism in controlling high yield strength of MEAs at 300 K.•High polarization resistance (106-105 Ωcm−2), and low defect densities (1016-1018) attributes to ZrO2, Nb2O5, TiO2, and MoO3 oxides enriched passive film.•Wet sliding wear rate ranged in order 7-9×10−5 mm3N−1m−1. In-situ generated wear debris when implanted in rabbit femur did not show any tissue necrosis rather new bone regeneration was observed around debris.

A Study on the Structural, Wear, and Corrosion Properties of CoCuFeNiMo High-Entropy Alloy

This study investigates the structural properties, wear resistance and corrosion behavior of a CoCuFeNiMo equiatomic high-entropy alloy. The alloy was prepared using a vacuum arc melting device, and its structural properties were analyzed through X-ray diffraction (XRD) and scanning electron microscopy (SEM). Wear tests were conducted using a pin-on-disc machine against 4140 stainless steel at different loads. Corrosion behavior was evaluated through potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in a 3.5wt% NaCl solution. The results indicated the presence of a major face-centered cubic (FCC) phase and a minor (µ) phase. The alloy exhibited segregation of Cu, attributed to positive mixing enthalpy. The coefficient of friction exhibited stability under lower loads but fluctuated under higher loads, possibly due to inhomogeneity in the microstructure caused by Cu segregation. Wear rates increased linearly with applied loads, indicating a direct relationship between load and wear properties. The worn surfaces displayed characteristics of mild abrasive wear, with delaminations, ploughing, and abrasive wear tracks. Pitting corrosion was observed, and the corrosion process was explained as the attack of Cl- ions leading to galvanic corrosion between different phases. In the corrosion analysis, the Ecorr value was -0.616V, and the icorr value was found to be 2.22 × 10-5 A/cm2.