Environmental Compatibility Research Articles

A “performance-inheritance” strategy for achieving hydrophilic/hydrophobic fluorescent biomass-derived carbon dots through simple solvothermal treatments

It remains a challenge to obtain hydrophilic/hydrophobic materials with promising biocompatibility and environmental compatibility by simple methods. Herein, we designed a “performance-inheritance” strategy and for the first time constructed hydrophilic/hydrophobic fluorescent spirulina-derived carbon dots (CDs) through simple solvothermal treatments. The contact angle of hydrophobic CDs with near-infrared (NIR) fluorescence is 110°, while hydrophilic CDs with blue fluorescence is 19°. We further revealed that the NIR luminescence is derived from the chlorophyll structure, while blue fluorescence is from the surface states. Based on the hydrophilicity/hydrophobicity of CDs, a ratiometric sensor was constructed to detect water content in organic solutions. In addition, CDs with NIR emission have low toxicity and good biocompatibility, making them efficient probes for bioimaging. This strategy provides a simple method for the high value-added conversion of algae and a new perspective for the “design-preparation-application” of biomass-derived CDs with specific properties.

A Sustainable and Eco-Friendly Membrane for PEM Fuel Cells Using Bacterial Cellulose

Bacterial cellulose (BC) is an advantageous polymer due to its renewable nature, low cost, environmental compatibility, biocompatibility, biodegradability, chemical stability, and ease of modification. With these advantages, BC is an interesting candidate for the development of novel eco-friendly materials for proton-exchange membrane (PEM) applications. However, its practical applications have been limited by its relatively high dispersion in water, which usually occurs during the operation of proton-exchange membrane fuel cells (PEMFCs). In addition, the proton conductivity of bacterial cellulose is poor. In this study, functionalized BC modified with 3-aminopropyltriethoxysilane (APTES) was prepared using a solvent casting method to enhance its performance. The results showed that the water stability of the modified BC membrane was significantly improved, with the contact angle increasing from 54.9° to 103.3°. Furthermore, the optimum ratio of BC and APTES was used to prepare a proton-exchange membrane with a maximum proton conductivity of 62.2 mS/cm, which exhibited a power generation performance of 4.85 mW/cm2 in PEMFCs. It is worth mentioning that modified BC membranes obtained by combining an alkaline proton carrier (-NH2) with BC have rarely been reported. As fully bio-based conductive membranes for PEMFCs, they have the potential to be a low-cost, eco-friendly, and degradable alternative to expensive, ecologically problematic fluoric ionomers in short-term or disposable applications, such as biodegradable electronics and portable power supplies.

Environmental and economic assessment of energy projects.

The energy industry has a significant impact on the scarce fossil hydrocarbon resources and on the environment. The burning of natural energy carriers by traditional energy facilities is one of the factors increasing the content of greenhouse gases in the atmosphere that entails serious climate changes. Evaluating the efficiency of energy enterprises and the implementation of energy projects requires an integrated approach that considers not only technical and economic aspects, but also the environmental impact. Such approach is especially important in the context of the energy transition and the implementation of circular economy principles. Despite the attention of scientists to the tasks of scientific, methodological, and practical determination of the economic efficiency and environmental consequences of energy projects, the issue of environmental and economic assessment remains relevant, in particular considering resource and environmental efficiency. The purpose of this study is to improve the methodological tools of environmental and economic assessment of energy projects. The authors propose an approach to the assessment of energy projects using an integral indicator. This indicator is calculated based on a system of specific indicators of the natural resource capacity and the environmental compatibility of energy production at the energy facility, considering the regional environmental conditions. The formed approach can be used for environmental and economic assessment and comparison of energy projects, fast-acting measures, and projects for the development of energy enterprises.

Impacts of a marine engineering project on hydrodynamics and diffusion characteristics of fluvial pollutants in Laizhou Bay, China

IntroductionThe rapid advances in marine engineering projects are exacerbating environmental pressures on bay ecosystems. This study utilized the MIKE 21 model to evaluate the impacts of such projects in Laizhou Bay (LZB) on hydrodynamic conditions and the spread of dissolved inorganic nitrogen (DIN) from riverine inputs.ResultsThe results indicated an expansion of 80.77 km2 in areas with DIN concentrations surpassing 0.5 mg/L 2 months after input from the Yellow River, with increased levels in the southern Yellow River Delta. Decreased flow velocities adjacent to the wave barriers at the Xiaoqing River estuary impeded lateral DIN dispersion, resulting in a 0.93 mg/L increase in DIN concentrations at the river mouth. After the construction of marine engineering projects (2020), significant alterations in the coastline of LZB have markedly modified hydrodynamic characteristics near marine structures, altering DIN dispersion patterns.ConclusionThis study provides crucial information for the management of pollutants at estuaries, understanding dispersion mechanisms, and evaluating the feasibility and environmental compatibility of marine engineering projects.

Nanomaterial-mediated strategies for enhancing bioremediation of polycyclic aromatic hydrocarbons: A systematic review

Polycyclic aromatic hydrocarbons (PAHs) are pervasive organic pollutants in the environment that are formed as an outcome of partial combustion of organic matter. PAHs pose a significant threat to ecological systems and human health due to their cytotoxic and genotoxic effects. Therefore, an immediate need for effective PAH remediation methods is crucial. Although nanomaterials are effective for remediation of PAHs, concerns regarding environmental compatibility and sustainability remains. Therefore, this study emphasizes integration of nanomaterials with bioremediation methods, which might offer a more sustainable and ecofriendly approach to PAHs remediation. A systematic search was conducted through scholarly databases from 2013 to 2023. A total of 360 articles were scrutinized, among which 26 articles were selected that resonated with the application of nano-bioremediation. These literatures comprise both comparative analysis of bioremediation only as well as nano-bioremediation. There is an elevation of 18.9 % in PAHs removal of liquid-phase samples, when comparing bioremediation (52.2 %) with nano-bioremediation (71.1 %). A consistent trend was observed in soil samples, with bioremediation and nano-bioremediation that successfully remove PAHs, with 60.8 % and 75.1 % respectively, indicating a 14.3 % improvement. Furthermore, the review elaborated on the various features of nanomaterials that led to their efficiency in the bioremediation of PAH. The review also discussed the strategies of nano-bioremediation namely nanomaterial-assisted microbial degradation, nanomaterial-assisted enzyme-enhanced microbial activity, nanomaterial-immobilized microbial cells, nanomaterial-facilitated electron transfer, and even some eco-green approaches to remediate PAHs, like biogenic nanomaterial for PAHs.

Evaluating Microgrid Investments: Introducing the MPIR Index for Economic and Environmental Synergy

In view of the increasing environmental challenges and the growing demand for sustainable energy solutions, the optimization of microgrid systems with regard to economic efficiency and environmental compatibility is becoming ever more important. This paper presents the Microgrid Performance and Investment Rating (MPIR) index, a novel assessment framework developed to link economic and environmental objectives within microgrid configurations. The MPIR index evaluates microgrid configurations based on five critical dimensions: financial viability, sustainability, regional renewable integration readiness, energy demand, and community engagement, facilitating comprehensive and balanced decision making. The current cases focus on the area of Greece; however, the model can have a wider application. Developed using a two-target optimization model, this index integrates various energy sources—including photovoltaics, micro-wind turbines, and different types of batteries—with advanced energy management strategies to assess and improve microgrid performance. This paper presents case studies in which the MPIR index is applied to different microgrid scenarios. It demonstrates its effectiveness in identifying optimal configurations that reduce the carbon footprint while maximizing economic returns. The MPIR index provides a quantifiable, scalable tool for stakeholders, not only advancing the field of microgrid optimization, but also aligning with global sustainability goals and promoting the transition to a more resilient and sustainable energy future.

Synergistic corrosion inhibition of 4-hydroxypyridine and halogen ions: Insights from interfacial nonlinear spectroscopy.

4-Hydroxypiridine (4-HPy) is a green chemistry corrosion inhibitor for low-carbon steel, valued for its environmental compatibility and low toxicity. Despite lower initial effectiveness than 4-mercapto/4-aminopyridine, 4-HPy's performance is markedly enhanced by halogen ions. By employing second harmonic generation (SHG) spectroscopy combined with electrochemical methods, Raman spectroscopy, atomic force microscopy, x-ray photoelectron spectroscopy, and in situ UV spectroscopy, this study elucidates the synergistic enhancement mechanism of 4-HPy with Cl-, Br-, and I- in 0.5 mol/L HCl solution. Time-dependent SHG measurements showed a two-step process of rapid adsorption and subsequent orientation change, with a proposed mechanism to interpret the temporal changes in SHG intensity. Deducing the adsorption kinetic equations and their application to the experimental data yields the adsorption rate (kad) and orientation change rate (Kre). Halogens reduce the orientation angle of 4-HPy, facilitating its adsorption on the substrate surface and effectively inhibiting corrosion via distinct mechanisms. Cl- and Br- ions primarily adsorb onto the metal surface, forming an adsorption film that not only enhances the subsequent adsorption of 4-HPy but also provides a protective effect for the metal surface. Conversely, I- forms mainly complexes with 4-HPy in solution, co-adsorbs onto the metal surface, and demonstrates a significant synergistic effect. This study revealed the synergistic efficacy hierarchy among halogen ions, with the order 4HPy + NaCl < 4HPy + NaBr < 4HPy + NaI. This study enhances our molecular-level understanding of the synergistic mechanism between halogen ions and corrosion inhibitors and provides valuable insights for designing and developing effective corrosion inhibitors.

Water-Rewritable Structural Color Textiles with Fast Response Speed and Antispreading Capability.

The stimuli-responsive textiles, especially water-responsive textiles, have garnered attention owing to their environmental compatibility. Inspired by the hydrochromic behavior of Diphylleia grayi, water-rewritable structural color (WRSC) textiles exhibiting fast response speed and antispreading capability were fabricated by spraying hollow SiO2 (H-SiO2) microspheres and poly(trifluoroethyl methacrylate-butyl acrylate) [P(TFEMA-BA)]. The water-written textiles exhibited structural color changes in 0.6 s via an increase in the refractive index, driven by water penetrating the gaps between H-SiO2 microspheres. The structural color was restored to the initial state after the water evaporated, allowing multiple cycles of the write-erase-write mode. The hydrophobic P(TFEMA-BA) adhesive was used to construct a stable chromogenic array and endow WRSC textiles with antispreading properties, thereby improving structural stability and achieving clear writing patterns. The prepared WRSC textiles demonstrated high flexibility, structural stability, and water-rewritable properties, providing advanced bionic inspiration and valuable design ideas for rewritable materials and smart textiles.

Relevance of noise control for the development of acoustics in 20th century

Driven by progress and requirements of the advancing machine age, Acoustics of the 20th century has run through a tremendous development. Starting from a profound understanding and formulation of its theoretical physical framework by Hermann von Helmholtz and Lord Rayleigh at the end of the 19th century, Acoustics and its many sub-disciplines developed to an important technical and engineering discipline which, at the beginning of the 21st century, had become a basic design tool for environmental compatibility and comfort features of most technical products and utilities. In Europe, this development has strongly been driven by urgent requirements of fast after-war reconstruction and growing needs of noise control which enforced particular interactive efforts of research institutes and companies to cope with the challenges of the time. Based on recent widespread contributions to the history of European Acoustics presented at Forum Acusticum 2023 in Torino, the relevance of noise control for the development of Acoustics in the last century will be highlighted and appreciated. With reference to some typical examples, it will be shown how the disciplines of engineering acoustics and noise control essentially contributed to renew and strengthen acoustics as an indispensable interdisciplinary field of science and technology.

Innovations in Wind Turbine Blade Engineering: Exploring Materials, Sustainability, and Market Dynamics

This manuscript delves into the transformative advancements in wind turbine blade technology, emphasizing the integration of innovative materials, dynamic aerodynamic designs, and sustainable manufacturing practices. Through an exploration of the evolution from traditional materials to cutting-edge composites, the paper highlights how these developments significantly enhance the efficiency, durability, and environmental compatibility of wind turbines. Detailed case studies of notable global projects, such as the Hornsea Project One, the Gansu Wind Farm, and the Block Island Wind Farm, illustrate the practical applications of these technologies and their impact on energy production and sustainability. Additionally, the manuscript examines the critical role of regulatory frameworks and industry standards in fostering these technological advancements, ensuring safety, and promoting global adoption. By analyzing the current trends and future directions, this study underscores the potential of modern turbine technologies to meet the increasing global demand for renewable energy and contribute to sustainable development goals. The findings advocate for continued innovation and policy alignment to fully harness the potential of wind energy in the renewable energy landscape.

Interstitial N-Doped TiO2 for Photocatalytic Methylene Blue Degradation under Visible Light Irradiation

Photocatalysis is a promising method for methylene blue (MB) degradation due to its effectiveness and environmental compatibility. Among the photocatalysts, titanium dioxide (TiO2) has been widely used for MB degradation due to its exceptional photocatalytic activity. However, the wide bandgap limits the degradation efficiency of TiO2 under visible light. Here, an interstitial nitrogen-doped TiO2 (5%NT/TiO2) used thiourea as the N source was fabricated for visible light-derived MB degradation. The 5%NT/TiO2 exhibited an extended absorption range of visible light. Moreover, photoelectrochemical measurements showed an improvement in the photocurrent response and charge transfer behavior on N/TiO2. Thus, 5%NT/TiO2 had enhanced photocatalytic activity compared with pristine TiO2 and substitutive N-doped TiO2 (5%NAB/TiO2). The accelerated photocatalytic MB degradation process on N/TiO2 could be mainly attributed to the interstitial N doping, which caused the appearance of new energy states and extended optical properties. Through comparing the impact of interstitial and substitutive in TiO2 activity, our work proposes a suitable form of element doping to enhance the optical properties and photocatalytic activity of TiO2 and even other semiconductors, providing guidance for future work.

Development of a thermal diagnostic system for the SPARC tokamak.

The SPARC tokamak will have scrape-off layer parallel heat fluxes on the order of GW/m2. Managing power exhaust of this magnitude will be mandatory for a reactor-scale device. To enable this mission, a thermal diagnostic suite will be deployed to measure the in-vessel structural temperatures to ensure they do not exceed their design limits and to determine the spatial distribution and magnitude of energy deposited onto the first wall. Thermocouples and fiber Bragg gratings have been selected for their environmental compatibility and proven useful on other fusion devices. High-density thermocouple arrays in the divertor will have two spring-loaded thermocouples per divertor target tile, which are being used as calorimeters, and will look to resolve the temperature distribution within the tile due to a swept or static strike point. All systems will need to survive the vacuum vessel bake, set at a minimum plasma facing surface temperature of 350 °C, which presents a particularly challenging environment for the fiber-based subsystem. Along with this temperature design requirement, all the materials in the primary vacuum need to be ultra-high vacuum compatible, able to handle the expected neutron and gamma radiation, as well as tritium exposure, all of which restrict material options. Finally, due to the expected activated environment in SPARC, there will be little chance to replace defective sensors, so system resilience is ensured through toroidal redundancy, probe material selection, and mitigating the impact of common-mode failures. Initial testing of sensors show that intershot structural measurements are sufficiently captured with the raw output, but intrashot measurements of the plasma facing material requires model-based interpretive tools.

Fabrication of Ti3CN quasi-MXene based poly glycidyl methacrylate and poly (3,4-ethylene dioxythiophene): Poly (styrene sulfonate) conducting polymer coated materials for photocatalytic eradicator of organic pollutants

MXene, a two-dimensional (2D) transition metal carbide or nitride, has gained significant attention due to its exceptional properties and wide-ranging applications. MXenes exhibit distinctive physical and chemical characteristics, making them suitable for electrocatalysis, supercapacitors, semiconductors, batteries, sensors, biomedicine, water splitting, and photocatalysis. In environmental photocatalysis, efforts have been made to improve conductivity, structural stability, and morphology. This study synthesized a photocatalyst by coating or doping a conducting polymer onto a quasi-MXene (Ti3CN) substrate. Initially, Ti3AlCN was exfoliated using HF to form 2D Ti3CN quasi-MXene, which was then doped with GMA and PEDOT: PSS conducting polymers for photocatalytic dye degradation. The broad heterogeneous interfaces in this network significantly enhance photocatalytic performance and pollutant removal capacity. The Ti3CN@GMA/PEDOT: PSS photocatalyst was characterized through SEM, FTIR, XPS, XRD, BET, and EDX techniques and tested for the degradation of various pollutants in wastewater under visible light. The degradation rates achieved were 94.1 % for Rose Bengal, 91.6 % for Rhodamine B, and 90.6 % for Methylene Blue, with corresponding rate constants of 0.0366 min−1, 0.0400 min−1, and 0.0388 min−1 over 60 min. The photocatalyst demonstrated excellent performance, highlighting several advantages, including low energy consumption, cost-effectiveness, non-toxic properties, and environmental compatibility, making it a promising solution for wastewater treatment applications.

Enhancing soil nitrogen measurement via visible-near infrared spectroscopy: Integrating soil particle size distribution with long short-term memory models

Good quality of soil nitrogen data, which is essential for the advancement of both enhanced agricultural management and ecological environment, traditionally depends on labor intensive chemical procedures. Visible near-infrared (Vis-NIR) spectroscopy, acknowledged for its efficiency, environmental compatibility and rapidity, merges as a promising alternative. However, the effectiveness of Vis-NIR measurement models are significantly compromised by soil particle size distribution (PSD), presenting a substantial challenge in improving the measurement accuracy and reliability. Here an innovative deep learning methodology that integrates PSD with Vis-NIR spectroscopy was proposed for the measurement of nitrogen content in soil samples. By leveraging the LUCAS dataset, different strategies for integrating PSD with Vis-NIR spectral data in deep learning models were explored, revealing that our proposed InSGraL framework, which incorporated mixed features of PSD and spectra as LSTM inputs achieves superior performance. Compared to models utilizing solely Vis-NIR data, InSGraL exhibits a 39.47 % reduction in RMSE and a 42.55 % decrease in MAE, and demonstrates robust performance across various land cover types, achieving an R2 of 0.94 on grassland samples. Moreover, Shapley Additive exPlanations (SHAP) analysis revealed that incorporating PSD modifies the spectral input importance distribution, effectively mitigating spectral interference from particle size while highlighting critical wavelengths previously obscured. This study provides an innovative modeling strategy to mitigate the influence of PSD by integrating it within deep learning framework using Vis-NIR, contributing a deeper understanding of the relationship between PSD and Vis-NIR spectra for the measurement of nitrogen content and offering an effective means to attain soil nitrogen data.

Novel magnetic metal ferrite-mango starch composite for the removal of dyes in single and ternary dye mixtures from aqueous solutions: kinetic and thermodynamic studies

ABSTRACT Magnetic metal ferrites attached to biowastes are proven to be promising adsorbents for the removal of dyes from water. Magnetic composites with biopolymers are gaining interest in the field of treatment of wastewater because of their selective nature, recyclability, low cost and environmental compatibility. In this work, Zinc ferrite composite with starch, extracted from mango seed kernel (ZFNMS) was synthesised. Characterisation techniques, such as FTIR, XRD, FESEM, BET, TGA and pHzpc, were used for the structural analysis of ZFNMS. ZFNMS was used to remove Methylene blue, Crystal violet and Brilliant green dyes in single and multiple (ternary) dye systems. The kinetics of adsorption by ZFNMS revealed that pseudo-second-order of kinetics was most appropriate for this study. Maximum adsorption capacities using ZFNMS for CV, BG and MB dyes were 142.9, 101.2 and 105.8 mg/g, respectively. The values of adsorption energies using ZFNMS were 200.5, 494.3 and 183.6 KJ/mol for CV, BG and MB dyes, respectively. Thermodynamic data revealed the spontaneous nature of the adsorption of dyes by ZFNMS and it was found that chemical adsorption was taking place in the present study. Regeneration of the adsorbent was done for successive five cycles and showed significant results. Thus ZFNMS is an ideal adsorbent for cationic dyes removal from water.

Which Publicly Financed Green Technology R&amp;D Option Most Effectively Drives Carbon Productivity? Instances of Energy Efficiency, Renewables, Nuclear, Hydrogen, and Energy Storage

ABSTRACTAs a strategy, countries seek ways to improve national income and, at the same time, keep carbon emissions minimal. Such a scenario is captured by the respective economies' carbon productivity (CP) scores. Remarkably, it is expected that technological advancements could be harnessed to achieve CP. Hence, many countries have publicly invested in green technologies R&amp;D, including energy efficiency, renewables, nuclear, hydrogen, and energy storage. However, existing studies did not verify the specific contributions of these technological advances to CP, leaving a notable void in the literature. Hence, the current research verified various green technology R&amp;D contributions to CP. Based on panel data from 2003 to 2022, this study implemented the novel instrumental variable quantile regression technique for updated insights. The study uncovers the heterogeneous contributions of each energy innovation variant to the quantile distributions of CP. The heterogeneous effects underscore each country's changing economic structures and varied energy innovation implementation paths. Hence, policy consistency is key to driving CP and ensuring environmental compatibility. R&amp;D on renewable, nuclear, and energy efficiency technologies contributed most significantly to CP across the distributions. R&amp;D on hydrogen and energy storage technologies contributed the least to CP. Therefore, allocating more funds to all R&amp;Ds that boost energy‐enhancing technologies for overall environmental sustainability is expedient. Such proactive and integrative policies consistent with SDGs 7 and 13 would reduce carbon emissions while escalating national income. Meanwhile, isolated and inconsistent funding should be discouraged for overall environmental progress. A robustness evaluation based on SIVQR produced corroborative evidence.

Efficient degradation of ciprofloxacin by innovative VUV/BN system: Kinetics, mechanism and toxicity assessment

Given the increasing emergence of widespread fluoroquinolones (FQs) in natural water environments and the limitations of traditional vacuum ultraviolet (VUV) systems for water decontamination, an innovative VUV/BN system was developed for the degradation and detoxification of ciprofloxacin (CIP) in this work. Unlike the VUV system, which primarily relies on hydroxyl radicals (·OH), the VUV/BN system significantly enhances the concentration of singlet molecular oxygen (1O2) to target the piperazine ring of CIP, achieving a defluorination efficiency of 98.88 % within 60 min. The degradation rate constant for CIP was found to be 2.76 times greater than that of the traditional VUV system. Additionally, varying concentrations of reactive species (RSs) in the VUV and VUV/BN systems resulted in distinct CIP degradation pathways. Due to the high selective oxidation capacity and environmental compatibility of 1O2, the VUV/BN system demonstrated excellent adaptability to environmental factors, maintaining stable operation in complex water matrices. Furthermore, the system exhibited high degradation capacity for CIP even in the fifth cycle, confirming its exceptional stability and reusability. The economic feasibility of the VUV/BN system was confirmed by its low electrical energy per order (EEO). This study underscores the potential of VUV/BN systems and enhances the understanding of CIP photodegradation.

High-capacity and long-life Fe2O3/MOFs composite anodes: Preparation, characterization, morphology regulation and electrochemical performance

Among the various transition metal oxides used in lithium-ion battery anodes, iron oxide (Fe2O3) has received extensive attention due to its low cost, good environmental compatibility and high theoretical capacity. However, the volume expansion and structural collapse during the charging-discharging cycling process significantly limited the practical application of Fe2O3. Herein, we demonstrate enhanced electrochemical properties and stability of Fe2O3 by anchoring it on metal-organic frameworks (MOFs). Through adjusting the MOF ligands and introducing humic acid (HA), we reached rational control of the morphology for the Fe2O3/MOF composites. The optimized sample, namely Fe2O3@HA-Fe-ATA, shows 3D cauliflower-like structure with abundant pores, which are beneficial to the active sites exposure, electrolyte penetration, as well as the tolerance toward volume expansion. Consequently, high reversible capacity of 1442.7 mAh g−1 (at 0.1 A g−1), excellent rate performance (<11 % capacity decrease when current density increases from 0.1 A g−1 to 1 A g−1), and satisfactory cycle stability (91 % capacity retention after 500 cycles at 1 A g−1) are obtained. This work demonstrates that the rational design of MOF by introduction of appropriate ligand is a very efficient approach to optimize the electrochemical properties of the resultant electrode material.

Cu(II) Coordination Polymers for the Selective Oxidation of Biomass-Derived Veratryl Alcohol in Green Solvents: A Sustainable Catalytic Approach.

Four air-stable one-dimensional copper(II) coordination polymers (CP1-CP4) with azide linkers were synthesized using tridentate NNS and NNN ligands. Single-crystal X-ray diffraction (XRD) analysis confirmed the molecular structures of CP1, CP3, and CP4. In the presence of TEMPO, all four coordination polymers demonstrated effective catalytic activity for the selective aerobic oxidation of veratryl alcohol, a biomass model compound, under base-free conditions. CP4 exhibited the best catalytic efficiency. Oxidations were conducted at ambient temperature (40 °C) utilizing air as a sustainable oxidant. Selective oxidation of veratryl alcohol to veratraldehyde was also conducted in the presence of a catalytic amount of base (5 mol %), and enhanced reactivity was observed. The green solvents, acetone, and water, were used to maximize sustainability. The optimized reaction conditions were applied to broaden the substrate scope of various lignin model alcohols and substituted benzylic alcohols with wide electronic variability. CP4 exhibited high recyclability, consistently providing quantitative yields even after ten consecutive runs. The catalytic protocol demonstrated sustainability and environmental compatibility, as evidenced by a low E-factor (4.29) and a high Eco-scale score (90). Based on experimental evidence and theoretical calculations, a plausible catalytic cycle was proposed. Finally, the sustainability credentials of the different optimized reaction protocols were evaluated using the CHEM21 green metrics toolkit.

Environment-compatible heavy metal risk prediction method created with multilevel ensemble learning

Accurate health risk prediction (HRP) is an effective means of reducing the hazards of heavy metal (HM) exposure. It can address the drawbacks of lag and passivity faced by health risk assessment. This study innovatively proposed an HRP method, MEL-HR, based on multilevel ensemble learning (MEL) technology and environment compatibility. We conducted point and interval prediction experiments on health risks using 490 sets of data covering 17 environment factors. The point prediction results indicated that when the model predicts HI and TCR, the R2 values were 0.707 and 0.619, respectively. For P5, P50, and P95 in interval prediction, the R2 values of the model were 0.706, 0.703, and 0.672 for HI, and that for TCR were 0.620, 0.607, and 0.616, respectively. The analysis of feature importance indicated that, in addition to HM factors, longitude, mining area coefficient, and soil organic matter were key environmental factors affecting the MEL-HR model. Comparative experiments showed that compared to soil HMs-based MEL-HR, environment compatibility-based MEL-HR has improved the accuracy for HI and TCR by 19.83 % and 40.36 % for the point prediction and 22.06 % and 40.01 % for interval prediction. This study can provide technical support for targeted and resilient prevention and control of health risks.