Enrichment In Incompatible Trace Elements Research Articles

The oxygen fugacity of intermediate shergottite NWA 11043: implications for Martian mantle evolution

Shergottite meteorites, classified as depleted, intermediate, or enriched based on incompatible trace elements and specific radiogenic isotope compositions (Sr, Nd, and Hf isotope ratios), point to multiple Martian mantle source regions. The oxygen fugacity (fO2) of these mantle regions, determined from early crystallizing minerals using the olivine-pyroxene-spinel oxybarometer, appears to correlate with incompatible trace element enrichment and isotope compositions. However, values derived from the vanadium-in-olivine oxybarometer challenge this correlation, hinting at potential biases in oxybarometry or complexities in the redox conditions of the Martian mantle. By analyzing the intermediate shergottite Northwest Africa (NWA) 11043 with various oxybarometers, this study deduced its origin from a reduced mantle source, with an average fO2 value of −0.77 ± 0.35 relative to the iron-wüstite (IW) buffer. Notably, these values coincide with those of depleted shergottites, which represent the depleted Martian mantle region. This redox similarity between intermediate and depleted shergottites contrasts with earlier notions that postulated intermediate shergottites as a mix of depleted and enriched mantle derivatives. Moreover, intermediate shergottites such as NWA 11043, Elephant Moraine (EETA) 79001A, and Allan Hills (ALH) 77005 display 176Hf/177Hf values akin to those of depleted shergottites, suggesting that intermediate mantle components can be separated from the depleted mantle source at approximately 2.2 Ga based on model age calculations. Therefore, there presents a consistent redox state between mantle magma sources of both intermediate and depleted shergottites since the Hesperian period, while enriched shergottites lean toward more oxidized conditions past source formation.This study prompts a reassessment of conventional theories, emphasizing the nuanced redox evolution of the Martian mantle across distinct mantle source regions and underscoring the complexity of the redox evolution of the Martian mantle. The emergence of chemically diverse mantle reservoirs might predominantly arise from early magma ocean differentiation processes, albeit with inherent oxidation nuances. The differences in fO2 observed between intermediate and depleted shergottites underscore the need for more in-depth studies to decipher Martian mantle differentiation and evolution.

Pliocene-to-Holocene volcano-tectonic activity on Mohéli Island (Comoros archipelago) constrained by new K[sbnd]Ar ages

The volcanism of the Comoros archipelago (from west to east: Grande Comore, Mohéli, Anjouan, and Mayotte islands) has been under renewed scientific scrutiny since the eruption of a new submarine volcanic edifice (Fani Maoré) which begun in May 2018 east of Mayotte. West of Mayotte, Mohéli island has received little attention from the geoscience community, despite its largely uneroded volcanic landscapes suggesting a recent activity that has not been dated. Here we address this gap in knowledge by applying KAr geochronology on groundmass and major-trace element analyses to subaerial and submarine rocks, in an attempt to reconstruct the volcano-tectonic and geochemical evolution of Mohéli. Our results show that Mohéli's volcano-tectonic evolution proceeded in two constructional stages, including a primary edification along a N070°E axis from before ca. 3.8 Ma to ca. 3 Ma (Stage 1), and a second construction along a N110°E ridge shaping the present-day island since ca. 2 Ma (Stage 2). The two stages were separated by an increased subsidence (≥0.2 mm/yr) that drowned a large part of the N070°E primary edifice. The two identified volcano-tectonic stages are reflected also in the geochemical evolution of emitted magmas, which were moderately silica-undersaturated in Stage 1 and moderately to highly silica-undersaturated in Stage 2. Silica undersaturation increases with time up to the olivine melilitite field, together with enrichments in Ca, P, and incompatible trace elements, suggesting the increasing contribution of a metasomatized mantle in melts. The coeval changes of construction orientations and magmas compositions of Mohéli suggest a modification in the tectonics of the Comoros related to magmatism at about 2 Ma. The most recent volcanic morphology investigated is an olivine nephelinite lava flow on the north coast of the island dated at 8 ± 2 ka. This finding of Holocene volcanism on Mohéli implies that the entire Comoros archipelago should be considered as an active zone in any volcanic hazard assessment. The melilite-bearing rocks of Mohéli share geochemical similarities with those of Mayotte and of the Cenozoic volcanic provinces of Madagascar, further pointing to similar melting sources and magmatic processes over the Mozambique channel.

Assessing global trends in Mars magma compositions using ground truth

AbstractGlobal magmatic trends inferred from gamma‐ray, visible/near‐infrared, and thermal infrared spectrometers on Mars‐orbiting spacecraft have been used to constrain planetary petrogenetic processes and global thermal evolution models. Inferred magmatic trends include temporal variations in the relative proportions of low‐Ca and high‐Ca pyroxenes, and in the abundances of potassium (and total alkalis), silica, FeO* (total iron expressed as FeO), and thorium. These patterns are evaluated for consistency with the compositions of surface igneous rocks of different ages analyzed by Mars rovers and of martian meteorites. Trends of decreasing low‐Ca pyroxene/total pyroxene ratios and of decreasing potassium (and total alkalis), with time are generally supported by surface rock analyses. However, significant differences in the GRS‐measured silica in Amazonian volcanoes and in martian meteorites of equivalent age result from contamination by silica‐rich dust and are problematic for a silica trend. Comparison of FeO* in Noachian and Amazonian surface data shows no decrease. An inferred temporal trend in thorium is in conflict with the complex enrichment and depletion patterns of incompatible trace elements in martian meteorites of various ages. A dearth of analyses of Hesperian‐age surface rocks precludes a firm evaluation of inferred Noachian‐Hesperian trends and Hesperian‐Amazonian trends, but abundant Noachian rocks and a few Hesperian rocks at rover sites, and Amazonian martian meteorites, collectively representing at least 16 surface locations, afford useful comparisons with orbital remote‐sensing data.

A Tentative Model for the Origin of A-Type Granitoids

A-type granites are typically formed in stable intra-plate, back-arc or postcollisional settings and are characterized by highly ferroan and potassic major element compositions, and by strong enrichment in incompatible trace elements. Unlike I-, S- and M-type granites, where the letters denote the dominant source material (igneous, sedimentary or mantle derived), there is no consensus on the source and processes giving rise to A-type magmas. In this contribution, a conceptual model for the origin of A-type granitoids, using the Bornholm A-type granitoid complex in southern Fennoscandia as an example, is presented. In this model, underplated mantle-derived basaltic magma may develop into intermediate and siliceous A-type magma, which is ferroan, potassic and highly enriched in incompatible trace elements, through a combination of fractional crystallization leading to cumulate formation, and partial melting and crustal assimilation, in a process akin to zone refining in metallurgy. The key factor is a relatively stable tectonic environment (postcollisional, anorogenic, or extensional), where there is little or no replenishment of more primitive basaltic magma to the system, allowing it to attain more evolved, enriched and extreme compositions. The A-type granitoids may then be viewed as a more evolved counterpart of subduction-related I-type granitoids.

Middle Miocene forearc alkaline magmatism in Amami-Oshima Island, central Ryukyu Arc: implications for paleoreconstruction of Shikoku Basin

During the middle Miocene, forearc alkaline magmatism occurred in the Outer Zone of Southwest Japan and the northern Ryukyu Arc, resulting in the formation of forearc alkaline basaltic rocks with ocean island basalt (OIB)-like chemical signatures. In contrast, subduction-related magmatism was present in the central Ryukyu Arc. However, the southwestern margin of the forearc alkaline magmatism was poorly constrained in the Ryukyu Arc. We examined two basaltic dikes in the Chichibu accretionary complex of Amami-Oshima Island, the central Ryukyu Arc. The dikes cut massive basalt, reddish chert, varicolored shale, and grey chert. The chemical compositions of basaltic dikes are characterized by the enrichment of incompatible trace elements, possibly representing a low degree of partial melting from a deep mantle source. 40Ar/39Ar dating analyses indicate that the basaltic dikes yield ages of 16.37 ± 0.14 Ma and 16.51 ± 0.10 Ma. The paleomagnetic analyses on stepwise thermal demagnetizations allowed extracting the direction of stable magnetizations with unblocking temperatures of 450–575 °C for the two dikes [(Dec, Inc) = (138.1°, − 13.3°), (124.0°, − 24.9°)]. The magnetization could be primary, acquired either as part of a secular variation or a geomagnetic excursion during reversed polarity chron/subchron. The 40Ar/39Ar ages and paleomagnetic directions within the error range imply that they intruded almost simultaneously during C5Cn.2r (16.532–16.434 Ma). The age and trace element patterns of the basaltic dikes are comparable to those of Miocene alkaline basaltic rocks, which resulted from forearc alkaline magmatism during the initial subduction of the young and warm Shikoku Basin. The discovery of alkaline basaltic dikes on Amami-Oshima Island suggests that the distribution of middle Miocene forearc alkaline magmatism may extend to the central Ryukyu Arc. Hence, the northern end of the Kyushu-Palau Ridge (i.e., southern end of Shikoku Basin) could have been located south of Amami-Oshima Island around 16.5–16.4 Ma, then moved eastward to the current location.Graphical

Geochronological and geochemical constraints on the petrogenesis of alkali granites from the Makrohar Granulite Belt: Evidence for Mesoproterozoic extensional regime in the eastern Central Indian Shield

The Chotanagpur Gneissic Complex (CGC) is characterized by the Makrohar Granulite Belt (MGB) at its north‐western margin parallel to Son‐Narmada lineaments. The MGB exhibits a typical association of mantle‐derived mafic tholeiitic and alkaline rocks along with the felsic units. The zircon U–Pb data on the intrusive granite gneiss from this association define a crystallization age of 1,498 ± 38 Ma, representing a widespread Mesoproterozoic within‐plate magmatic event in CGC synchronous with the breakup of the Columbia Supercontinent. These granite gneisses have an alkaline affinity and are metaluminous in character. They exhibit many of the geochemical characteristics of anorogenic (A‐type) magmas, including enrichment of incompatible trace elements, like Zr, Hf, Nb, Y, Ga, and rare earth elements (REE), but low in Ba and Sr as well as high FeOt/(FeOt + MgO) (~0.98) values and Ga/Al (~3.92) ratios. They show less fractionated REE patterns, characterized by relatively enriched LREE and flat HREE with negative Eu anomaly, and have high Zr‐saturation temperatures (~955°C). Considering their field characteristics and all the geochemical and isotopic features, we conclude that they were derived from melting the lower crust metasomatized by mantle‐derived alkali‐rich fluids due to asthenospheric upwelling.

Early Precambrian Granitoid Magmatism of the Kitoy Block and Stages of Collisional Events in the Southwestern Siberian Craton

Abstract —The paper presents the zircon U–Pb age and geochemical and isotopic characteristics of granitoids from the Kitoy block (Sharyzhalgai uplift, southwestern Siberian craton). The studied granitoids compose vein bodies of different scales. According to structural relations of rocks and their zircon U–Pb ages, early Precambrian granite formation proceeded in three stages: at ~2.99, 2.54, and 1.88 Ga. The Neoarchean and Paleoproterozoic granites contain inherited zircons of ~3.00–2.97 Ga, which are close in age to magmatic zircons from the Mesoarchean granite-gneiss. The Kitoy granitoids of different ages share similar enrichment in SiO2, K2O, and incompatible trace elements. In terms of trace-element composition and crystallization temperatures, the Mesoarchean granite-gneisses are similar to the A-type granite, while the Neoarchean and Paleoproterozoic granitoids are close to the I-type one. Inherited ~3.00–2.97 Ga zircons and the narrow range of model Nd ages (TNd(DM) = 3.3–3.0 Ga) indicate that Neoarchean and Paleoproterozoic granitoids formed through recycling of the Mesoarchean crust. The Neoarchean (~2.54 Ga) and Paleoproterozoic (~1.88 Ga) stages of granite emplacement in the northwest of the Kitoy block correlate with formation of granitoids and high-temperature metamorphism in the Irkut block and the border zone between two blocks. Coeval granite formation and metamorphism at ~2.54 Ga are strong evidence that the amalgamation of the Kitoy and Irkut blocks resulted from collisional orogeny in the terminal Neoarchean.

Petrogenesis of the Mesoarchean (~3.05 Ga) mafic volcanics from the western Iron Ore Group volcano-sedimentary succession, Singhbhum craton, eastern India: Constraints from geochemical modelling and Sm-Nd geochronology

Cratonic Mesoarchean volcano-sedimentary successions preserve compositionally diverse volcanic rocks which give insight into Archean mantle characteristics and crustal evolution. The late Archean western Iron Ore Group (W-IOG) succession in the Singhbhum craton represents deposition during this time period. As the W-IOG depositional age has remained poorly constrained, to between Paleo- and Mesoarchean, petogenesis and chronology of the interbedded volcanics would be an important geological constraint. Mafic volcanics, interlayered with BIF and Fe-Mn-rich phyllite/shale, were sampled from Kalta and Ongarbira, and petrogenetic modelling of their mantle source and Sm-Nd geochronology were conducted. The Ongarbira basalts show tholeiitic affinity, are depleted in LILE, LREE, Zr and Th and an absence of Nb-Ta-Ti anomalies that imply a depleted MORB-type mantle source. Tholeiitic basalts yield an isochron age of 3050 ± 71 Ma (2SD) with Ndi = 0.50885 ± 0.00010, MSWD = 0.17 (n = 10) and εNd(T) = +3.3 ± 1.6. Geochemical modelling indicates the most primitive tholeiitic basalt (Mg# = 61) formed by ~14% partial melting of depleted mantle whereas the most enriched variant formed by its subsequent assimilation-fractional crystallization (AFC) (~15% with r = 0.2 being the ratio between assimilation rate and fractional crystallization rate). In contrast, the Kalta basaltic andesite have calc-alkaline affinity, are enriched in LILE, LREE, Zr and Th with pronounced negative Nb-Ta-Ti anomalies indicating incompatible trace element enrichment in their petrogenesis. The basaltic andesite yield an isochron age of 3041 ± 94 Ma (2SD) with Ndi = 0.50875 ± 0.00009, MSWD = 0.62 (n = 10) and εNd(T) = +1.1 ± 1.6. Geochemical modelling indicates that their compositions were generated by 20–40% AFC (r = 0.2) of ~14% partial melt of depleted mantle. The source magma to the Ongarbira basalt is interpreted to have formed during lithospheric extension of the Singhbhum craton, by partial melting of depleted mantle followed by minor AFC, whereas the Kalta basaltic andesite represents higher extents of AFC of the Ongarbira-type tholeiitic magma.

First Evidence of the Post-Variscan Magmatic Pulse on the Western Edge of East European Craton: U-Pb Geochronology and Geochemistry of the Dolerite in the Lublin Podlasie Basin, Eastern Poland

The U–Pb measurements of youngest, coherent group of zircons from the Mielnik IG1 dolerite at the Teisseyre-Tornquist margin (TTZ) of East European Craton (EEC) in Poland yielded age of 300 ± 4 Ma. Zircon dated an evolved portion of magma at the late stage crystallization. It is shown that this isolated dyke from the northern margin of the Lublin Podlasie basin (Podlasie Depression) and regional dyke swarms of close ages from the Swedish Scania, Bornholm and Rügen islands, Oslo rift, Norway, and the Great Whine Sill in northeastern England, were coeval. They have been controlled by the same prominent tectonic event. The Mielnik IG1 dolerite is mafic rock with Mg-number between 52 and 50 composed of the clinopyroxene, olivine-pseudomorph, plagioclase, titanite, magnetite mineral assemblage, indicating relatively evolved melt. This hypabyssal rock has been affected by postmagmatic alteration. The subalkaline basalt composition, enrichment in incompatible trace elements, progressive crustal contamination, including abundance of zircon xenocrysts determines individual characteristics of the Mielnik IG1 dolerite. The revised age of dolerite, emplaced in vicinity of TTZ provides more evidences documenting the reach of the Permo-Carboniferous extension and rifting accompanied by magmatic pulses, that were widespread across Europe including the margin of the EEC incorporated that time into the broad foreland of the Variscan orogen.

Footprints and conditions of multistep alkali enrichment in basaltic melts at Piton de la Fournaise (La Réunion Island, Indian Ocean)

Deciphering magma evolution below ocean basaltic volcanoes is all the more challenging because magma mixing is a common process tending to modify the pristine geochemical diversity during magma ascent. On the western flank of the Piton de la Fournaise volcano, transitional basalts have compositions that testify to origins down to the upper mantle and display a widespread geochemical diversity ranging from a tholeiitic affinity to an alkaline one. There, we show that evolved melt inclusions and matrix glasses (MgO < 9 wt%) record an alkali enrichment coupled with a Ca/Al ratio decrease, which tracks the effect of clinopyroxene crystallization at the depth of the mantle-crust underplating layer. At this depth and shallower, reverse zoning of olivine crystals, clinopyroxene dissolution, and hybrid melt compositions testify to extensive mixing processes leading to a homogenization of the pristine geochemical footprint of melts upon ascent. Enrichment in incompatible trace elements in some evolved melt inclusions suggests that magma ponding at the depth of the mantle-crust underplating layer favours also assimilation of melts originating from low degrees of partial melting of cumulates (wehrlites, dunites). Conversely, the most primitive melt inclusions documented so far at La Reunion Island (MgO up to 11.2 wt%) better preserve a pristine geochemical variability related to partial melting of a slightly heterogeneous mantle source. We suggest that these slightly distinct source components may mirror the compositions of recent melts from the two closely located Piton de la Fournaise and Piton des Neiges volcanoes.

Petrogenesis of Mediterranean lamproites and associated rocks: The role of overprinted metasomatic events in the post-collisional lithospheric upper mantle

AbstractHigh-MgO lamproite and lamproite-like (i.e. lamprophyric) ultrapotassic rocks are recurrent in the Mediterranean and surrounding regions. They are associated in space and time with ultrapotassic shoshonites and high-K calc-alkaline rocks. This magmatism is linked with the geodynamic evolution of the westernmost sector of the Alpine–Himalayan collisional margin, which followed the closure of the Tethys Ocean. Subduction-related lamproites, lamprophyres, shoshonites and high-K calc-alkaline suites were emplaced in the Mediterranean region in the form of shallow level intrusions (e.g. plugs, dykes and laccoliths) and small volume lava flows, with very subordinate pyroclastic rocks, starting from the Oligocene, in the Western Alps (northern Italy), through the Late Miocene in Corsica (southern France) and in Murcia-Almeria (southeastern Spain), to the Plio-Pleistocene in Southern Tuscany and Northern Latium (central Italy), in the Balkan peninsula (Serbia and Macedonia) and in the Western Anatolia (Turkey). The ultrapotassic rocks are mostly lamprophyric, but olivine latitic lavas with a clear lamproitic affinity are also found, as well as dacitic to trachytic differentiated products. Lamproite-like rocks range from slightly silica under-saturated to silica over-saturated composition, have relatively low Al2O3, CaO and Na2O contents, resulting in plagioclase-free parageneses, and consist of abundant K-feldspar, phlogopite, diopsidic clinopyroxene and highly forsteritic olivine. Leucite is generally absent, and it is rarely found only in the groundmasses of Spanish lamproites. Mediterranean lamproites and associated rocks share an extreme enrichment in many incompatible trace elements and depletion in High Field Strength Elements and high, and positively correlated Th/La and Sm/La ratios. They have radiogenic Sr and unradiogenic Nd isotope compositions, high 207Pb over 206Pb and high time-integrated 232Th/238U. Their composition requires an originally depleted lithospheric mantle source metasomatized by at least two different agents: (1) a high Th/La and Sm/La (i.e. SALATHO) component deriving from lawsonite-bearing, ancient crustal domains likely hosted in mélanges formed during the diachronous collision of the northward drifting continental slivers from Gondwana; (2) a K-rich component derived from a recent subduction and recycling of siliciclastic sediments. These metasomatic melts produced a lithospheric mantle source characterized by network of felsic and phlogopite-rich veins, respectively. Geothermal readjustment during post-collisional events induced progressive melting of the different types of veins and the surrounding peridotite generating the entire compositional spectrum of the observed magmas. In this complex scenario, orogenic Mediterranean lamproites represent rocks that characterize areas that were affected by multiple Wilson cycles, as observed in the Alpine–Himalayan Realm.

Uniform oxygen fugacity of shergottite mantle sources and an oxidized martian lithosphere

Martian meteorites are the only available samples that can be directly measured to constrain the geological evolution of Mars. It has been suggested that the oxygen fugacity (fO2) of martian shergottite meteorites, which have low (∼7 wt.%) to high-MgO (∼30 wt.%) compositions, correlates with incompatible trace element enrichment (i.e., La/Yb), and 87Sr/86Sr, 143Nd/144Nd, 187Os/188Os and 176Hf/177Hf at the time of crystallization. These relationships have been interpreted to result from early magmatic processes segregating enriched and more oxidized from depleted and more reduced reservoirs in Mars. Here we use the V-in-olivine oxybarometer to constrain the fO2 of shergottites and the dunitic chassignites. These data, utilizing early crystallizing silicate phases, constrain the shergottite fO2 range to between −3.72 ± 0.07 and −0.21 ± 0.55 ΔFMQ (log units relative to the fayalite-magnetite-quartz buffer), with no correlation with trace element enrichment or Nd isotope systematics. Previously employed oxybarometers that use later-formed or multiple mineral phases, and that show such correlations, likely differ from the V-in-olivine oxybarometer in that they record effects from late-stage magmatic processes. In contrast to shergottites, chassignites are relatively oxidized, at +2.1 ± 0.4 to +2.2 ± 0.5 ΔFMQ. The chassignites, along with the nakhlites, have been proposed to be sourced from metasomatized lithospheric mantle, and their high fO2 strengthens this model. The new data implies that the martian mantle sources of shergottites have fO2 of −2.1 ± 1.8 ΔFMQ. This estimate indicates that the mantle and core of Mars are not in redox equilibrium and therefore that oxidation of the martian mantle following core formation is required.

Constraints from geochemistry, zircon U-Pb geochronology and Hf-Nd isotopic compositions on the origin of Cenozoic volcanic rocks from central Urumieh-Dokhtar magmatic arc, Iran

Considerable debate persists regarding the petrogenesis of high-alumina basalts (HAB) which are purported to occur exclusively in subduction zones. Major and trace element, mineral chemistry, whole-rock Sr-Nd-Hf-isotopes and zircon U-Pb age data are reported for the Cenozoic Eshtehard HABs, in order to constrain the nature of mantle beneath the central Urumieh-Dokhtar magmatic arc, and further investigate the mechanism of HABs generation. Eshtehard HABs, chemically akin to those from continental arcs, include basaltic, basaltic andesite, andesitic and dacitic rocks. U-Pb geochronology of zircon yield ages of 47.2 ± 0.6 Ma, 43.9 ± 0.3, and 40.9 ± 0.5 to 39.4 ± 0.9 for basaltic, andesitic and dacitic samples, respectively. Basaltic andesitic dikes intruded into dacitic hosts yield age of ca. 20–18 Ma. εHf(t) values for Eocene zircons display a range variable from −6.4 to +6.5. Miocene zircons have higher εHf(t), ranging between −1.8 and +10.7. The studied rocks are characterized by enrichment in incompatible trace elements and have relatively homogeneous Sr-Nd isotopes. Integrated studies indicate that Eshtehard HABs were derived from the hydrated, dominantly depleted shallow asthenospheric mantle wedge (and possibly also in the lower lithosphere) overlying subducted oceanic lithosphere. Traversing lithospheric mantle and Cadomian crust, and assimilating crustal material while fractionating plagioclase, high-Ca pyroxene, magnetite, and amphibole, the primary melt formed Eshtehard high-alumina, low-Mg# basalts. We hypothesize that ponding of hydrous magma at the base of the crust allowed for further crustal assimilation and fractionation of Ca-pyroxene and magnetite without plagioclase and zircon nucleation; then, ascending magmas through the crust led to crystallization of plagioclase and eventually zircon. We suggest comparatively high water content (rather than high crystallization pressure), up to 4% sediment melt and less than 10% of continental crust materials were involved, as subordinate components, in the petrogenesis of Eshtehard HABs.

Episodic Melt Percolating and Chromite Mineralization in Yushigou Peridotite, North Qilian Suture Zone

AbstractHarzburgite‐dunite associations are the dominant type of ultramafic heterogeneities in the exhumed peridotites. Although the dunite network are usually small in volume of exposed mantle rocks, their mineral structures and chemical variations are widely observed in various tectonic environments and record complex mantle evolution. The Yushigou peridotite complex displays a 25 km2 mantle section belonging to a partly dismembered ophiolite in North Qilian suture zone, northwest China. It is mostly composed of depleted spinel harzburgite re‐equilibrated at temperatures of 900 °C, contain dunite veins and minor podiform chromite at its Moho level.Here we report the petrological observations and mineral chemical analyses of harzburgite‐dunite associations in the Yushigou peridotite complex. Based on the data we classified high Cr # (51–74) and low Cr# (19–34) dunite veins in this Yushigou complex. The podiform chromite are mainly high Cr# affinity and are production of melt‐harzburgite interaction. There are three main microstructures recorded the episodic melt‐rock interaction process: (1) complex spinel mineral inclusions both in harzburgite and two kind of dunite record widespread melt percolating. The observed primary inclusions (not related to later low temperature fluid activities) including hydrous and anhydrous silicates and minor sulphides, such as PGE and Fe‐Cu‐Ni related sulfidies, olivine, orthopyroxene, clinopyroxene, amphibole and phlogopite. (2) In all dunite samples, clinopyroxene dominated sieve‐textured rims around spinel are more abundant and more thicken than the harzburgite; implying stained/pulsated melt supply after the chromite crystallization. (3) Millimeter scale veined reaction patches in some dunite samples consist of clinopyroxene, amphibole, phlogopite, Fe‐Ni sulfidies and carbonates. Such metasomatic minerals assemblages may response for the later fluid infiltration after chromite mineralization. All these petrological observations and mineral chemical compositions (major and trace element contents) thus provide a wealth of information on the pathways of migrating melts in the mantle wedge, and provide constrain on nature and evolution of the uprising magma. Strong enrichment of incompatible trace elements in dunite clinopyroxene (LREE/HREE &gt;10) possible reflect a slab origin of the percolating melt which is not observed elsewhere participating in chromite forming.

Trace element composition of amphibole and petrogenesis of hornblendites and plutonic suites of Cretaceous magmatic arcs developed in the Fuegian Andes, southernmost South America

The evolution of continental crust in convergent margins can be explored in southernmost South America (54-56°S). Plutonic rocks of the Fuegian Batholith and the rear-arc satellite Ushuaia Pluton were emplaced within the magmatic arc and the Fuegian fold-and-thrust belt, respectively. They record subduction zone processes in two distinct tectonic settings during the evolution of the Rocas Verdes Basin. We report new U-Pb zircon geochronology, bulk rock chemistry, Sr-Nd isotope data, and EPMA and in-situ LA-ICP-MS analyses of amphibole from ‘hornblendites’ and gabbroic-granitoid suites in order to evaluate the origin and evolution of the magmatic plumbing systems in the upper plate of the subduction zone. Textural relationships and amphibole compositions in hornblendite indicate crystallization at lower crustal depths with pressures of 7-8 kbar in the Fuegian Batholith and of 5-6 kbar in the Ushuaia Pluton. Lower Cretaceous suites of hornblendite and calc-alkaline hornblende-gabbro, diorite and tonalite in the Fuegian Batholith have εNdt values ranging between +2 and +4. They were emplaced within an island arc coeval with mid-oceanic type spreading in the Rocas Verdes back-arc basin. Isotope ratios and amphibole compositions in hornblendite indicate crystallization from primitive and hydrous sub-alkaline basaltic melts with relatively low LREE/HREE and low alkali contents. The Late Cretaceous plutons in the fold-and-thrust belt were emplaced after the tectonic juxtaposition of Rocas Verdes ophiolitic complexes. The Ushuaia Pluton, consisting of clinopyroxene-hornblende cumulates, hornblende-gabbro, diorite and monzodiorite, was emplaced during the waning stage of Late Cretaceous magmatism. In this case hornblendite amphiboles show high contents of alkalis, LREE and incompatible elements with a strong crustal affinity (Th, Ba, Rb). The enriched incompatible trace element patterns indicate their derivation from K-rich transitional magmas formed in supra-subduction settings. Chemical variations in amphibole from hornblendites and spatially related plutonic rocks are evaluated in terms of fluid flux from the subducted slab and partial melting of the sub-arc mantle, ultimately controlled by the thermal state of the subducted slab and convergence rates.

Imprints of ancient recycled oceanic lithosphere in heterogeneous Indian Ocean mantle: Evidence from petrogenesis of Carlsberg ridge basalts from Northwest Indian Ocean

This paper reports new petrological, geochemical and isotopic data for Carlsberg Ridge Basalts (CRB) of northwest Indian Ocean and evaluates their petrogenetic aspects in the context of the geochemical and tectonic evolution of the Indian Ocean mantle. The CRB samples exhibit tholeiitic to transitional composition of precursor melts derived by high degree, shallow level partial melting of a spinel peridotite mantle source. CRB reflects distinct E-MORB affinity with selective enrichment in incompatible trace elements. Higher values of Zr/Hf (33.8–47.3) and Zr/Sm (24.9–36.4) in conjunction with lower Nb/Ta (1.7–7.3) ratio corroborate their origin from an enriched mantle source. Negative Nb anomalies with lower Nb/Y (0.04–0.11) and Zr/Y (2.5–3.5) conform to a non-plume origin of these basalts. Higher Zr/Nb (25.5–71.5) and Th/Nb (0.6–0.42) compared to OIB substantiate contributions from recycled subduction-processed components in the source mantle. Lower Nb/U (6.2–37.9) values with higher Ba/Nb (6.1–21.9), Ba/Th (27.7–147.5), Zr/Nb (25.5–71.5) and Th/Nb (0.6–0.42) compared to OIB and N-MORB attest to role of a metasomatized oceanic lithosphere that recycled into the depleted upper mantle attributing to the source heterogeneity. Sr-Nd isotopic signatures (87Sr/86Sr: 0.702668 to 0.702841 and 143Nd/144Nd: 0.512972 to 0.513068) of CRB suggest a HIMU source component preserved in the northwest Indian Ocean Ridge mantle. The compositional diversity of the Indian Ocean mantle can be translated in terms of periodic refertilization of depleted N-MORB type mantle through delamination and recycling of oceanic (HIMU component) and continental lithosphere (EM I component) concurrent with Neoproterozoic-Palaeozoic amalgamation and Jurassic dispersal of Gondwana Supercontinent respectively. This study complies with the derivation of CRB from a geochemically heterogeneous Indian Ocean mantle that experienced a protracted residence beneath the Gondwana Supercontinent prior to the opening of Indian Ocean and trapped recycled metasomatized oceanic lithosphere genetically linked with multiple stages of paleo-ocean closure and continental convergence during Gondwana assembly.

Iron-nickel metallic components bearing silicate-melts and coesite from Ramgarh impact structure, west-central India: Possible identification of the impactor

The Ramgarh structure (rim-to-rim diameter ~2.4 km) in the Vindhyan Supergroup of sedimentary rocks (including sandstone, shale and minor limestone) of the Mesoproterozoic age in the west-central India, is India’s third confirmed asteroid impact crater. This eroded structure is roughly rectangular in shape and resembles to the Barringer Crater, USA. The presence of central peak and its current crater diameter/depth ratio of ~12 well corroborate the range (10–20) of terrestrial complex asteroid impact craters. The mm-sized, iron-rich (FeO ~50 wt.% in average), spherule-like particles, recovered from the alluvium inside the Ramgarh structure, have internal morphology similar to those of the accretionary lapilli described in known impact craters. The in-situ LA-ICP-MS analyses also suggested high Co–Ni (up to 13,000 and 2500 ppm, respectively)-rich areas locally within these spherules/lapilli. A few non-in-situ, mm-sized particles, recovered from the rim of the structure show the presence of coesite, one of the diagnostic indicators of shock metamorphism. A few fragments of iron-rich, Ca–Al–silicate glasses recovered from the soil inside the structure and outside of the western crater rim include the presence of dendritic magnetite with occasional inclusions of relict native iron. Our microprobe analyses confirm that these metallic irons contain high proportions of Co (~350–3000 ppm), Ni (~200–4000 ppm) and Cu (~2200–7000 ppm) and possibly could be the relict component of a Cu-rich iron meteorite impactor. The field observation and relative enrichment of compatible and incompatible trace elements in the spherule-like substance (recovered from the alluvium inside the Ramgarh structure) as compared to target rocks suggests that hydrothermal activity played an important role in the evolution of the crater.

Petrogenesis of hirna mafic lavas, in southeastern Ethiopia volcanic province: Assessments from major and trace elements

We have conducted measurements of a new whole rock major and trace elements for Hirna mafic lavas (MgO > 4.5 wt %) in southeastern Ethiopia plateau to assess the petrogenesis of the lavas in the area. The mafic rock of the area exhibit two types of lava series regarding major and trace element compositions: 1) Silica saturated basalt and 2) silica under-saturated melanephelinite lavas. The silica saturated basaltic lavas show tholeiitic character with SiO2 and Na2O + K2O ranges between 45.5 and 49.04 wt% and 3.3–4.07 wt% respectively. Melanephelinite lavas exhibits alkaline nature and characterized by SiO2 (34.89–35.02 wt%), Na2O + K2O (4.14–4.18 wt%) and high Fe2O3 (17.34–17.54 wt%), this lava is enriched in incompatible trace elements (e.g Sr = 806–1198.5 ppm; Zr = 323–423 ppm, Nb = 111–142.5 ppm and light rare earth elements (LREE)). The basalt lavas have relatively restricted highly incompatible trace element composition (e.g. Sr = 594–721 ppm; Zr = 145–172 ppm; Nb = 17–19.5 ppm and LREEs). Major and compatible trace element variation suggests that primary magmas for both lavas have undergone fractional crystallization involving olivine, pyroxene, and iron/titanium oxide ± plagioclase. The basalt samples in the area have moderate fractionated light rare earth element to heavy rare earth element ratio (LREE/HREE) (e.g. La/Yb = 9.6–10.56; La/Lu = 65–72.7) and middle rare earth element to heavy rare earth element ratio (MREE/HREE) (Sm/Yb = 3.47–3.79) whereas melanephelinite lavas show strong fractionated LREE/HREE (e.g. La/Lu = 322.5–3236) and MREE/HREE (e.g. Sm/Yb = 6.3–6.5). The trace element data of both lavas suggests their derivation from amphibole bearing garnet peredotite lithospheric mantle. Variation of the two lavas in the level of high incompatible trace element most likely suggests their derivation from a mantle source with a different source region enrichment history. Melanephelinite lavas exhibit very high enrichment of high field strength element (HFSE) (Zr, Nb, Hf, Ta and LREEs) and have elevated Zr/Hf ratio (44–45) (and overall high incompatible trace element enrichment) suggests that, this lava series might have originated from a more metasomatized mantle region.

Re-interpretation of volcanic units from San Ambrosio Island and Gonzalez Islet, Southeast Pacific, Chile: Using new textural and geochemical data

The San Felix - San Ambrosio Oceanic Volcanic Complex (SSOVOC), located in the Southeast Pacific, 940 km offshore northern continental Chile, corresponds to a case of intraplate volcanism in the Nazca Plate. The complex is comprised of San Felix, San Ambrosio and González islands, which are mainly composed of alkaline lavas and hyaloclastic sequences. San Ambrosio Island (2.86–2.93 Ma) would be made up mainly, in its subaerial section, of two eruptive shield-type events called Carpa Group and Fardelas Group, the latter event being slightly more alkaline than the Carpa Group. The González Islet (1 Ma?) is made up of a Hyaloclastic Unit, submarine and subaerial basanitic lava flows and the Punta Bari Group, the latter described previously on San Felix Island. The Hyaloclastic Unit and basanitic lava flows have textures associated with an underwater deposition environment and a subsequent transition to a subaerial environment.Geochemical data indicate an increase in alkalinity between San Ambrosio Island and González Islet and different degrees of partial melting based on Th/Nd vs Th and Rb/Nd vs Rb data and enrichment in incompatible trace elements suggest a decrease in partial melting between the generating event of San Ambrosio Island and González Islet. The isotopic mixing model of Sr and Nd indicates that this volcanic complex represents a mixing of 35%–45% between DM and EM-I members, although from the San Ambrosio Island to González-San Félix Islands there is an independent trend between both islands towards EM-I, which suggests a cortical contamination of the same volcanic edifice of which the three islands of the complex are part.

Petrogenesis of an alkaline lamprophyre (camptonite) with ocean island basalt (OIB)-affinity at the NW margin of the Cuddapah basin, eastern Dharwar craton, southern India

We report petrology and geochemistry (including Sr and Nd isotopes) of a fresh lamprophyre at Ankiraopalli area at the north-western margin of Paleo-Mesoproterozoic Cuddapah basin, eastern Dharwar craton, southern India. Ankiraopalli samples possess a typical lamprophyre porphyritic-panidiomorphic texture with phenocrysts of kaersutite and diopside set in a plagioclase dominant groundmass. Combined mineralogy and geochemistry classify it as alkaline lampro- phyre in general and camptonite in particular. Contrary to the calc-alkaline and/or shoshonitic orogenic nature portrayed by lamprophyres occurring towards the western margin of the Cuddapah basin, the Ankiraopalli samples display trace element composition revealing striking similarity with those of ocean island basalts, Italian alkaline lamprophyres and highlights an anorogenic character. However, the87 Sr/86 Srinitial (0.710316 to 0.720016) and εNdinitial (– 9.54 to – 9.61) of the Ankiraopalli lamprophyre show derivation from an 'enriched' mantle source showing long term enrichment of incompatible trace elements and contrast from those of (i) OIB, and (ii) nearby Mahbubnagar alkaline mafic dykes of OIB affinity. Combining results of this study and recent advances made, multiple mantle domains are identified in the Eastern Dharwar craton which generated distinct Mesoproterozoic lamprophyre varieties. These include (i) Domain I, involving sub-continental lithospheric mantle source essentially metasomatized by subduction-derived melts/fluids (represented by orogenic calcalkaline and/or shoshonitic lamprophyres at the Mudigubba, the Udiripikonda and the Kadiri); (ii) Domain II, comprising a mixed sub-continental lithospheric and asthenospheric source (represented by orogenic-anorogenic, alkaline to calc-alkaline transitional lamprophyres at the Korakkodu), and (iii) Domain III, representing a sub-continental lithospheric source with a dominant overprint of an asthenospheric (plume) component (represented by essentially alkaline lamprophyres at the Ankiraopalli). Our study highlights the varied mantle source heterogeneities and complexity of geodynamic processes involved in the Neoarchean-Paleo/Mesoproterozoic evolution of the Eastern Dharwar craton.