Enhancement Of S-process Elements Research Articles

Searching for Barium Stars from the LAMOST Spectra Using the Machine-learning Method: I

Barium stars are chemically peculiar stars that exhibit enhancement of s-process elements. Chemical abundance analysis of barium stars can provide crucial clues for the study of the chemical evolution of the Galaxy. The Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST) has released more than 6 million low-resolution spectra of FGK-type stars by Data Release 9, which can significantly increase the sample size of barium stars. In this paper, we used machine-learning algorithms to search for barium stars from low-resolution spectra of LAMOST. We have applied the Light Gradient Boosting Machine (LGBM) algorithm to build classifiers of barium stars based on different features, and build predictors for determining [Ba/Fe] and [Sr/Fe] of barium candidates. The classification with features in the whole spectrum performs best: for the sample with strontium enhancement, Precision = 97.81% and Recall = 96.05%; for the sample with barium enhancement, Precision = 96.03% and Recall = 97.70%. In prediction, [Ba/Fe] estimated from Ba ii line at 4554 Å has smaller dispersion than that from Ba ii line at 4934 Å: MAE4554 Å = 0.07, σ 4554 Å = 0.12. [Sr/Fe] estimated from Sr ii line at 4077 Å performs better than that from Sr ii line at 4215 Å: MAE4077 Å = 0.09, σ 4077 Å = 0.16. A comparison of the LGBM and other popular algorithms shows that LGBM is accurate and efficient in classifying barium stars. This work demonstrated that machine learning can be used as an effective means to identify chemically peculiar stars and determine their elemental abundance.

R Coronae Borealis Star Evolution: Simulating 3D Merger Events to 1D Stellar Evolution Including Large-scale Nucleosynthesis

Abstract R Coronae Borealis (RCB) stars are rare hydrogen-deficient carbon-rich variable supergiants thought to be the result of dynamically unstable white dwarf mergers. We attempt to model RCB stars through all the relevant timescales by simulating a merger event in Octo-tiger, a 3D adaptive mesh refinement (AMR) hydrodynamics code, and mapping the post-merger object into MESA, a 1D stellar evolution code. We then post-process the nucleosynthesis on a much larger nuclear reaction network to study the enhancement of s-process elements. We present models that match observations or previous studies in most surface abundances, isotopic ratios, early evolution, and lifetimes. We also observe similar mixing behavior to previous modeling attempts that result in the partial He-burning products visible on the surface in observations. However, we do note that our subsolar models lack any enhancement in s-process elements, which we attribute to a lack of hydrogen in the envelope. We also find that the 16O/18O isotopic ratio is very sensitive to initial hydrogen abundance and increases outside of the acceptable range with a hydrogen mass fraction greater than 10−4.

Three new barium dwarfs with white dwarf companions: BD+68°1027, RE J0702+129 and BD+80°670

We report three new barium (Ba) dwarfs lying in Sirius-like systems, which provides direct evidence that Ba dwarfs are companions to white dwarfs (WDs). Atmospheric parameters, stellar masses, and chemical abundances of 25 elements, including light, $\alpha$, Fe-peak and s-process elements, are derived from high resolution and high S/N spectra. Enhancement of s-process elements with [s/Fe] ratios between 0.4 and 0.6 confirm them as mild barium stars. The estimated metallicities ($-$0.31, $-$0.06, 0.13) of BD+68$^\circ$1027, RE~J0702+129 and BD+80$^\circ$670 are in the range of known Ba dwarfs and giants. As expected, observed indices of [hs/ls], [s/Fe] and [C/Fe] show anticorrelation with metallicity. AGB progenitor masses are estimated for the WD companions of RE~J0702+129 (1.47 $M_{\odot}$) and BD+80$^\circ$670 (3.59 $M_{\odot}$), which confirms the predicted range of progenitor AGB masses (1.5 $\sim$ 4 $M_{\odot}$) for unseen WDs around Ba dwarfs. Surface abundances of s-process elements in RE~J0702+129 and BD+80$^\circ$670 are compared with AGB models and they are in close agreement, within predicted accretion efficiencies and pollution factors for Ba stars. These results support that the origin of s-process overabundances in Ba dwarfs is similar to Ba giants via McClure hypothesis in which Ba stars accumulate s-process elements through mass transfer from their host companions during AGB phase.

Abundances of carbon-enhanced metal-poor stars as constraints on their formation

An increasing fraction of carbon-enhanced metal-poor (CEMP) stars is found as their iron abundance, [Fe/H], decreases below [Fe/H] = -2.0. The CEMP-s stars have the highest absolute carbon abundances, [C/H], and are thought to owe their enrichment in carbon and the slow neutron-capture (s-process) elements to mass transfer from a former asymptotic giant-branch (AGB) binary companion. The most Fe-poor CEMP stars are normally single, exhibit somewhat lower [C/H] than CEMP-s stars, but show no s-process element enhancement (CEMP-no stars). CNO abundance determinations offer clues to their formation sites. C, N, Sr, and Ba abundances (or limits) and 12C/13C ratios where possible are derived for a sample of 27 faint metal-poor stars for which the X-shooter spectra have sufficient S/N ratios. These moderate resolution, low S/N (~10-40) spectra prove sufficient to perform limited chemical tagging and enable assignment of these stars into the CEMP sub-classes (CEMP-s and CEMP-no). According to the derived abundances, 17 of our sample stars are CEMP-s and three are CEMP-no, while the remaining seven are carbon-normal. For four CEMP stars, the sub-classification remains uncertain, and two of them may be pulsating AGB stars. The derived stellar abundances trace the formation processes and sites of our sample stars. The [C/N] abundance ratio is useful to identify stars with chemical compositions unaffected by internal mixing, and the [Sr/Ba] abundance ratio allows us to distinguish between CEMP-s stars with AGB progenitors and the CEMP-no stars. Suggested formation sites for the latter include faint supernovae with mixing and fallback and/or primordial, rapidly-rotating, massive stars (spinstars). X-shooter spectra have thus proved to be valuable tools in the continued search for their origin. Abridged.

HIP 10725: The first solar twin/analogue field blue straggler

[Context]. Blue stragglers are easy to identify in globular clusters, but are much harder to identify in the field. Here we present the serendipitous discovery of one field blue straggler, HIP 10725, that closely matches the Sun in mass and age, but with a metallicity slightly lower than the Sun's. [Methods]. We employ high resolution (R $\sim 10^5$) high S/N (330) VLT/UVES spectra to perform a differential abundance analysis of the solar analogue HIP 10725. Radial velocities obtained by other instruments were also used to check for binarity. We also study its chromospheric activity, age and rotational velocity. [Results]. We find that HIP 10725 is severely depleted in beryllium ([Be/H] <= -1.2 dex) for its stellar parameters and age. The abundances relative to solar of the elements with Z <= 30 show a correlation with condensation temperature and the neutron capture elements produced by the s-process are greatly enhanced, while the r-process elements seem normal. We found its projected rotational velocity (v sin i = 3.3+/-0.1 km/s) to be significantly larger than solar, and incompatible with its isochrone-derived age. Radial velocity monitoring shows that the star has a binary companion. [Conclusions]. Based on the high s-process element enhancements and low beryllium abundance, we suggest that HIP 10725 has been polluted by mass-transfer from an AGB star, probably with initial mass of about 2 M_Sun. The radial velocity variations suggest the presence of an unseen binary companion, probably the remnant of a former AGB star. Isochrones predict a solar-age star, but this is in disagreement with the high projected rotational velocity and high chromospheric activity. We conclude that HIP 10725 is a field blue straggler, rejuvenated by the mass transfer process of its former AGB companion.

On the Optical Spectrum of 89 Her

AbstractThe high resolution spectra of a post-AGB candidate, binary system 89 Her, were analysed for the chemical composition. The star was found to be metal deficient with [Fe/H] = -0.50±0.20. No enhancement of s-process elements was found. The refractory elements are depleted but this is not the reason of metal deficiency. More than 320 narrow and weak emission lines from low levels of neutral metals were identified. Radial velocities of these lines coincide with the systemic velocity. We propose that the circum-binary dusty disk is observed face-on.

A search for s-process elements in extremely metal-poor halo planetary nebulae

AbstractWe have performed deep high-dispersion spectroscopy to examine enhancement of s-process elements in the exremely metal-poor ([Ar/H]~−2.1) halo planetary nebulae H4-1 and BoBn1 using the 8.2-m Subaru telescope/High-Dispersion Spectrograph (HDS). We have detected several emission lines of s-process elements in H4-1 and BoBn1, and we have found that the enhancement of heavy s-process elements in these objects is comparable with that in s-process enhanced CEMP stars with [Fe/H]&gt;−2.5. The C- and N-rich abundances of H4-1 and BoBn1 might be explained by binary evolution models. We have detected 5 fluorine lines in BoBn1. The re-estimated F abundance using these lines is [F/H]=+1.4±0.1.

EARLY-AGE EVOLUTION OF THE MILKY WAY RELATED BY EXTREMELY METAL-POOR STARS

We exploit the recent observations of extremely metal-poor (EMP) stars in the Galactic halo and investigate the constraints on the IMF of the stellar population that left these low-mass survivors of [Fe/H]<-2.5 and the chemical evolution that they took part in. A high-mass IMF with the typical mass~10Msun and the overwhelming contribution of low-mass members of binaries to the EMP survivors are derived from the statistics of carbon-enriched EMP stars with and without the enhancement of s-process elements (Komiya et al. 2007). We first examine the analysis to confirm their results for various assumptions on the mass-ratio distribution function. As compared with the uniform distribution, the increase or decrease function of the mass ratio gives a higher- or lower-mass IMF, and a lower-mass IMF results for the independent distribution with the both members in the same IMF, but the derived ranges of typical mass differ less than by a factor of two and overlap for the extreme cases. Furthermore, we prove that the same constraints are placed on the IMF from the surface density of EMP stars estimated from the surveys and the chemical evolution consistent with the metal yields of theoretical supernova models. We then apply the derived high-mass IMF with the binary contribution to show that the observed MDF of EMP stars can be reproduced not only for the shape but also for the number of EMP stars. In particular, the scarcity of stars below [Fe/H]<-4 is naturally explained in terms of the hierarchical structure formation, and there is no indication of significant changes in the IMF for the EMP Population. The present study indicates that 3 HMP stars of [Fe/H]<-4 are the primordial stars that were born as the low-mass members of binaries before the host clouds were polluted by their own supernovae.

ELEMENT ENHANCEMENTS ALONG THE ENTIRE ASYMPTOTIC GIANT BRANCH PHASE

The results of a study of the AGB phase of stellar evolution are presented. Abundances have been determined for Fe, C, O, the light s-process elements, Y and Zr, the heavy s-process elements, La and Nd, and the r-process element, Eu. The expected relationship between enhanced C, increasing C/O ratio and enhanced s-process elements has been quantified. Results are presented to provide observational data with which to compare theoretical predictions. The results in this paper confirm previously suggested relationships between C, C/O and s-process element enhancements. It is seen that AGB stars show C/O ratios from C/O around 0.4 to 1.0, while C enhancements lie between [C/Fe]=0.1 to 0.9 dex. Enhancements of s-process elements are as much as [s/Fe] around 1.0 dex for the stars in which C is also greatly enhanced.

Chemical Abundances of the S Star GZ Peg

AbstractThe chemical compositions of stars from the Asymptotic Giant Branch are still poorly known due to the low temperatures of their atmospheres and therefore the presence of many molecular transitions hampering the analysis of atomic lines. One way to overcome this difficulty is by the study of lines in regions free from molecular contamination. We have chosen some of those regions to study the chemical abundance of the S-type star GZ Peg. Stellar parameters are derived from spectroscopic analysis and a metallicity of –0.77 dex is found. Chemical abundances of 9 elements are reported and an enhancement of s-process elements is inferred, typical to that of an S-type star.

A SPECTROSCOPIC AND PHOTOMETRIC STUDY OF THE METAL-POOR, PULSATING, POST-ASYMPTOTIC GIANT BRANCH BINARY HD 46703

The metal-poor post-asymptotic giant branch (AGB) star HD 46703 is shown to be a single-line spectroscopic binary with a period of 600 days, a high velocity of –94 km s–1, and an orbital eccentricity of 0.3. Light-curve studies show that it also pulsates with a period of 29 days. High-resolution, high signal-to-noise spectra were used for a new abundance study. The atmospheric model determined is T eff = 6250 K, log g = 1.0, Vt = 3.0 km s–1, and a metal abundance of [M/H] = –1.5. A low carbon abundance and a lack of s-process element enhancement indicate that the star has not experienced a third dredge-up on the AGB. The sulfur and zinc abundances are high compared with iron, and the chemical abundances show a clear anti-correlation with condensation temperature. The abundance depletion pattern is similar to that seen in other post-AGB binaries, and, like them, is attributed to the chemical fractionation of refractory elements onto dust stored in a circumbinary disk and the re-accretion of volatiles in the stellar atmosphere. The infrared excess is small but the excess energy distribution is very similar to what can be expected from a disk. HD 46703 joins the growing list of depleted, post-AGB stars which are likely surrounded by a dusty and stable circumbinary disk.

LIGHT ELEMENT ABUNDANCES IN TWO CHEMICALLY PECULIAR STARS: HD 104340 AND HD 206983

We derive carbon, nitrogen, oxygen, and lithium abundances as well as 12C/13C isotopic ratios in two chemically peculiar red giant stars: HD 104340 and HD 206983. The abundances were determined via spectrum synthesis of optical high-resolution spectra containing C2, CH, CN, [O I], and Li I lines. Our results indicate that HD 206983 is a barium star, while HD 104340, although showing enhancements of s-process elements, should not be considered as a classical barium star: its barium star nature can be explained by internal nucleosynthesis. The low metallicity giant HD 104340 can experience deeper convective mixing and, consequently, a larger dredge-up of CNO-cycle products compared to normal red giants. The light element abundance pattern of HD 104340 resembles anomalies resulting from the appearance on the stellar surface of material enriched by triple-α and CNO cycling.

S‐Process Abundances in Planetary Nebulae

The s-process should occur in all but the lower mass progenitor stars of planetary nebulae, and this should be reflected in the chemical composition of the gas which is expelled to create the current planetary nebula shell. Weak forbidden emission lines are expected from several s-process elements in these shells, and have been searched for and in some cases detected in previous investigations. Here we extend these studies by combining very high signal-to-noise echelle spectra of a sample of PNe with a critical analysis of the identification of the emission lines of Z>30 ions. Emission lines of Br, Kr, Xe, Rb, Ba, and Pb are detected with a reasonable degree of certainty in at least some of the objects studied here, and we also tentatively identify lines from Te and I, each in one object. The strengths of these lines indicate enhancement of s-process elements in the central star progenitors, and we determine the abundances of Br, Kr, and Xe, elements for which atomic data relevant for abundance determination have recently become available. As representative elements of the ``light'' and ``heavy'' s-process peaks Kr and Xe exhibit similar enhancements over solar values, suggesting that PNe progenitors experience substantial neutron exposure.

The Origin of Carbon Enhancement and the Initial Mass Function of Extremely Metal‐poor Stars in the Galactic Halo

It is known that the carbon-enhanced, extremely metal-poor (CEMP) stars constitute a substantial proportion in the extremely metal-poor (EMP) stars of the Galactic Halo, by far larger than CH stars in Population II stars. We investigate their origin with taking into account an additional evolutionary path to the surface carbon-enrichment, triggered by hydrogen engulfment by the helium flash convection, in EMP stars of $[Fe/H] \lesssim -2.5$. This process is distinct from the third dredge-up operating in more metal-rich stars and also in EMP stars. In binary systems of EMP stars, the secondary stars become CEMP stars through mass transfer from the primary stars of low and intermediate masses, which have developed the surface carbon-enhancement. Our binary scenario can predict the variations in the abundances not only for carbon but also for nitrogen and s-process elements and reasonably explain the observed properties such as the stellar distributions with respect to the carbon abundances, the binary periods, and the evolutionary stages. Furthermore, from the observed frequencies of CEMP stars with and without s-process element enhancement, we demonstrate that the initial mass function of EMP stars need to give the mean mass $~10\msun$ under the reasonable assumptions on the distributions of orbital separations and mass ratio of binary components. This also indicates that the currently observed EMP stars were exclusively born as the secondary members of binaries, making up $\sim 10%$ remnants of EMP binary systems of mass $~10^8\msun$ in total; in addition to CEMP stars with white dwarf companions, a significant fraction of them have experienced supernova explosions of their companions. We discuss the implications of the present results in relation to the formation of Galactic halo.

CNO and Li abundances in Barium-enriched stars

AbstractCNO and Li abundances and 12C/13C isotopic ratios have been derived for two metal-poor Ba giants, HD 104340 and HD 206983, and two CH subgiants, HD 50264 and HD 87080. High resolution spectra obtained with the 1.52 m telescope and the FEROS echelle spectrograph at ESO, La Silla, Chile, were used in this study. CNO and Li abundances so as 12C/13C isotopic ratios were determined by applying the synthetic spectrum method to the lines of C2, CH, CN, [O I’ and Li I. Our analysis showed that the giant stars studied here have quite different natures: HD 206983 is a metal-poor barium star while HD 104340, although showing enhancement of s-process elements, should not be considered as a classical barium star: its barium syndrome can be explained by internal nucleosynthesis. The low metallicity giant HD 104340 can experience deeper convective mixing and, consequently, a larger dredge-up of CNO-cycle products compared to normal red giants. Light element abundance pattern of HD 104340 resembles anomalies resulting from the appearance on the stellar surface of material enriched in triple-α and CNO cycling.

Enrichment of Very Metal Poor Stars with Bothr‐Process ands‐Process Elements from 8–10M⊙Stars

Recent spectroscopic studies have revealed the presence of numerous carbon-enhanced, metal-poor stars with [Fe/H] < -2.0 that exhibit strong enhancements of s-process elements. These stars are believed to be the result of a binary mass transfer episode from a former asymptotic giant branch (AGB) companion that underwent s-process nucleosynthesis. However, several such stars exhibit significantly lower Ba/Eu ratios than solar s-process values. This might be explained if there were an additional contribution from the r-process, thereby diluting the Ba/Eu ratio by extra production of Eu. We propose a model in which the double enhancements of r-process and s-process elements originate from a former 8-10 M☉ companion in a wide binary system, which may undergo s-processing during an AGB phase, followed by r-processing during its subsequent supernova explosion. The mass of Eu (as representative of r-process elements) captured by the secondary through the wind from the supernova is estimated and is assumed to be proportional to the geometric fraction of the secondary (low-mass, main-sequence) star with respect to the primary (exploding) star. We find that the estimated mass is in good agreement with a constraint on the Eu yield per supernova event obtained from a Galactic chemical evolution study, when the initial orbital separation is taken to be ~1 yr. If one assumes an orbital period on the order of 5 yr, the efficiency of wind pollution from the supernova must be enhanced by a factor of ~10. This may, in fact, be realized if the expansion velocity of the supernova's innermost ejecta, in which the r-process has taken place, is significantly slow, resulting in an enhancement of accretion efficiency by gravitational focusing.

The Unusual Abundance of Copper in the Sagittarius Dwarf Spheroidal Galaxy and Implications for the Origin of ω Centauri

We present copper abundances for 14 red giant stars in the Sagittarius dwarf spheroidal galaxy (Sgr dSph), showing that [Cu/Fe] is deficient by ~0.5 dex, relative to the Galactic trend. This is most easily understood as due to an enhanced contribution of iron peak nucleosynthesis products from Type Ia supernovae (SNe Ia). The deficient [Cu/Fe] ratios might also be the result of a metallicity-dependent yield from SNe Ia, similar to previous conclusions for Mn, although SN Ia nucleosynthesis predictions suggest a negligible Cu yield. The enhanced SN Ia products, suggested by our low [Cu/Fe] ratios, fit a leaky box chemical evolution scenario for the Sgr dSph, where ejecta from the old, metal-poor, population overwhelmed nucleosynthesis products from younger generations, resulting in young stars with uncharacteristic compositions. The only other system known to have unusually low [Cu/Fe] is the Galactic globular cluster ω Cen, which, like the Sagittarius dwarf galaxy, has strong enhancements of s-process elements. Thus, our copper abundances lend support to the idea that ω Cen is the remaining nucleus of an accreted dwarf galaxy.

Abundance Analysis of HE 2148−1247, A Star with Extremely Enhanced Neutron Capture Elements

Abundances for 27 elements in the very metal-poor dwarf star HE 2148-1247 are presented, including many of the neutron capture elements. We establish that HE 2148-1247 is a very highly s-process-enhanced star with anomalously high Eu as well, Eu/H ~ half-solar, demonstrating the large addition of heavy nuclei at [Fe/H] = -2.3 dex. Ba and La are enhanced by a somewhat larger factor and reach the solar abundance, while Pb significantly exceeds it, thus demonstrating the addition of substantial s-process material. Ba/Eu is 10 times the solar r-process ratio but much less than that of the s-process, indicating a substantial r-process addition as well. C and N are also very highly enhanced. We have found that HE 2148-1247 is a radial velocity variable; it is probably a small-amplitude long-period binary. The C, N, and the s-process element enhancements were thus presumably produced through mass transfer from a former asymptotic giant branch (AGB) binary companion. The large enhancement of heavy r-nuclides also requires an additional source as this is far above any inventory in the interstellar medium at such low [Fe/H]. We consider that the s-process material was added by mass transfer of a more massive companion during its thermally pulsating AGB phase and ending up as a white dwarf. We further hypothesize that accretion onto the white dwarf from the envelope of the star caused accretion-induced collapse of the white dwarf, forming a neutron star, which then produced heavy r-nuclides and again contaminated its companion. This mechanism in a binary system can thus enhance the envelope of the lower mass star in s- and r-process material sequentially. Through analysis of the neutron capture element abundances taken from the literature for a large sample of very metal-poor stars, we demonstrate, as exemplified by HE 2148-1247, that mass transfer in a suitable binary can be very efficient in enhancing the heavy elements in a star; it appears to be capable of enhancing the s-process elements in very metal-poor stars to near the solar abundance but not substantially above it. The yield of Pb relative to Ba appears to vary among very metal-poor stars.

Detection of Lead in the Carbon-rich, Very Metal-poor Star LP 625-44: A Strong Constraint on s-Process Nucleosynthesis at Low Metallicity.

We report the detection of the Pb i lambda4057.8 line in the very metal-poor (&sqbl0;Fe&solm0;H&sqbr0;=-2.7), carbon-rich star, LP 625-44. We determine the abundance of Pb (&sqbl0;Pb&solm0;Fe&sqbr0;=2.65) and 15 other neutron-capture elements. The abundance pattern between Ba and Pb agrees well with a scaled solar system s-process component, while the lighter elements (Sr-Zr) are less abundant than Ba. The enhancement of s-process elements is interpreted as a result of mass transfer in a binary system from a previous asymptotic giant branch (AGB) companion, an interpretation strongly supported by radial velocity variations of this system. The detection of Pb makes it possible, for the first time, to compare model predictions of s-process nucleosynthesis in AGB stars with observations of elements between Sr and Pb. The Pb abundance is significantly lower than the prediction of recent models (e.g., Gallino et al.), which succeeded in explaining the metallicity dependence of the abundance ratios of light s-elements (Sr-Zr) to heavy ones (Ba-Dy) found in previously observed s-process-enhanced stars. This suggests that one should either (1) reconsider the underlying assumptions concerning the (13)C-rich s-processing site ((13)C pocket) in the present models or (2) investigate alternative sites of s-process nucleosynthesis in very metal-poor AGB stars.

A STUDY OF THE UV-BRIGHT STARS IN OMEGA CEN AND THE TYPE II CEPHEID ST PUP

ABSTRACT Photometric and spectroscopic observations of UV-bright stars were acquired and analyzed in the framework of recent theories concerning post-horizontal branch stellar evolution. Photometric CCD B and V observations of V1, V9, V43, V48, and V92 in omega Cen and of the field cepheid, ST Pup, with a period of about 19 days, are used to calculate their masses, temperatures, and surface gravities. The resultant masses range from 0.51 to 0.67 solar masses and are consistent with theoretical expectations. The new observations are also combined with historical data to derive more accurate (and precise) period derivatives. The most luminous cepheids are found to experience large and sudden period changes, while the fainter ones exhibit constant period derivatives. The abundances of 26 elements were calculated for 5 UV-bright stars in omega Cen and ST Pup from high resolution CCD spectra. Compared to the giants, the most luminous UV-bright stars in omega Cen display significant enhancements of the CNO and s-process elements. The CNO enhancements correlate with s-process enhancemenets in general in omega Cen, implying that these two sets of elements are mixed with the atmosphere together. The UV-bright stars also show an apparent deficiency of Al; the most likely cause of this is mass loss combined with a small NLTE effect. An analysis of the s-process element abundances demonstrates that the average time integrated neutron flux, t0, for the most luminous UV-bright stars in omega Cen, V1, and ROA 24, is about 0.6 mbarn-1. The observed s-process abundance patterns are also consistent with theoretical AGB models. The amount of s-process element enhancement observed in V1 and ROA 24 requires that about 0.1% of their atmopheres be composed of material mixed to the surface from the s-processed region. The abundance patterns of ST Pup are significantly different from those in any star in omega Cen. While it displays enhanced CNO abundances, its s-process abundances are much less than those of the omega Cen stars. It most closely resembles the field CH stars.