The composites with the nominal composition of (1 − x)La 2/3Ca 1/3MnO 3 (LCMO)/ xSb 2O 5 were fabricated, and their electrical transport and magnetoresistance (MR) behavior were investigated. Experimental results show that the metal–insulator transition temperature ( T MI) and resitivity ( ρ) of the composites are largely dependent on Sb 2O 5 addition level x. T MI shifts downwards and ρ increases with the increase of x at the range of x ≤ 3%, but T MI shifts upwards and ρ decreases with further increasing of x ≥ 3%. The high temperature ( T > T MI) semi-conducting part of the ρ data follow a small polaron hopping (SPH) conduction mechanism, and the metallic behavior of the samples ( T < T MI) fits the model in terms of electron–magnon scattering of the carriers. Furthermore, the MR effect can be largely enhanced over a wide temperature range in the composites compared with pure LCMO. At 3 T field, the MR rises from a base value ∼46%, for pure LCMO, to a maximum value of ∼86.7% for the case of x = 3%. It is argued that the enhancement of MR effect is attributed to the enhanced spin-polarized tunneling, which is manipulated by magnetic disorder especially at LCMO grain boundaries caused by Sb 2O 5 addition.
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