Intensity Enhancement Factor Research Articles

An Evaluation of Moderate-Refractive-Index Nanoantennas for Enhancing the Photoluminescence Signal of Quantum Dots.

The use of nanostructures to enhance the emission of single-photon sources has attracted some attention in the last decade due to the development of quantum technologies. In particular, the use of metallic and high-refractive-index dielectric materials has been proposed. However, the utility of moderate-refractive-index dielectric nanostructures to achieve more efficient single-photon sources remains unexplored. Here, a systematic comparison of various metallic, high-refractive-index and moderate-refractive-index dielectric nanostructures was performed to optimize the excitation and emission of a CdSe/ZnS single quantum dot in the visible spectral region. Several geometries were evaluated in terms of electric field enhancement and Purcell factor, considering the combination of metallic, high-refractive-index and moderate-refractive-index dielectric materials conforming to homogeneous and hybrid nanoparticle dimers. Our results demonstrate that moderate-refractive-index dielectric nanoparticles can enhance the photoluminescence signal of quantum emitters due to their broader electric and magnetic dipolar resonances compared to high-refractive-index dielectric nanoparticles. However, hybrid combinations of metallic and high-refractive-index dielectric nanostructures offer the largest intensity enhancement and Purcell factors at the excitation and emission wavelengths of the quantum emitter, respectively. The results of this work may find applications in the development of single-photon sources.

Towards understanding hybrid influencing mechanisms of substrate microstructure on SERS effect

Micro/nano hierarchical structures have been investigated as a manner to improve the enhancement factor of surface enhanced Raman scattering (SERS). However, the exploration of influencing mechanisms of substrate microstructure on SERS effect is relatively lacking at present. In this study, finite element analysis (FEA) and molecular dynamics (MD) simulations were conducted, aiming to reveal the intrinsic relationships between microstructure characterization and Raman signal intensity. The distributions of near field and far field, as well as the energy density on substrate surfaces with various microstructures were obtained, and their influencing mechanisms on electromagnetic enhancement (EM) and chemical enhancement (CM) were analyzed. Meanwhile, the adsorption capacity of probe molecule on different substrate was expounded from the perspectives of superficial area, interaction energy and surface profile characteristics. Results demonstrated that the characterization parameter S/d × h, of which S, d and h are respectively the superficial area, interval space of adjacent micro-cavities and peak-valley height of surface microstructure, significantly determines the electric enhancement factor of electric field intensity and the energy density at the same time. The substrate surface with larger superficial areas can generate higher interaction energy thereby more probe molecules can be caught successfully. In addition, the molecular clusters are easier to form near convexities compared with the concaves on the same substrate. What was studied in this work is expected to provide a theoretical reference for the structural optimization of SERS substrate with high performances.

Gold-Deposited Graphene Nanosheets for Self-Cleaning Graphene Surface-Enhanced Raman Spectroscopy with Superior Charge-Transfer Contribution.

The interaction of graphene with metals initiates charge-transfer interaction-induced chemical enhancements, which critically depend on the doping effect from deposited metallic configurations. In this paper, we have explored the gold nanoparticle-decorated monolayer graphene nanosheets for the large graphene-induced Raman enhancement of adsorbed analytes, indicating the surface-enhanced Raman spectroscopy (SERS) capabilities of metal-doped graphene (G-SERS). Here, the systematically sputtered Au thickness optimization procedure revealed noticeable modifications in the graphene Raman spectra and photoluminescence (PL) background quenching, which indicated favorable charge transfer through n-type doping of chemical vapor deposition-grown graphene nanosheets. The highly consistent, individually distributed morphology of the gold nanoislands over graphene nanosheets depicted a reproducibly uniform G-SERS signal with excellent relative standard deviation values (<5%), resulting in the strongest Raman intensity enhancement factors of ∼108 (MB) (methylene blue) and 107 (DPA) (2,6-pyridinedicarboxylic acid) composed of the weakest PL background. The combined charge-transfer-induced chemical enhancement and electromagnetic enhancement from individual Au nanoislands result in a lowering of detectability down to 10-16 M (MB) and 10-11 M (DPA) concentrations with efficient time-dependent signal stability. Additionally, the GAu demonstrated its effective (∼94.4%) photocatalytic degradation capabilities by decomposing MB dye molecules from a concentration of 1 μM to 2.52 fM within 60 min. Therefore, the prominent charge-transfer contribution through controlled Au decoration over graphene nanosheets provides a potential strategy for fabricating superior SERS sensors and photocatalysts exhibiting adequate signal consistency, stability, and photodegradation efficiency through overcoming the limitations of the traditional sensing platforms.

Enhancement of dual zero phonon line emissions in nanodiamonds using quasiperiodic photonic structures.

Color centers in nanodiamonds (NDs) have been largely explored by coupling to a photonic structured matrix (PSM) to amplify visible range emission features, enhancing their use in quantum technologies. Here, we study the emission enhancement of dual near-infrared zero phonon line (ZPL) emission from silicon-boron (SiB) and silicon-vacancy (SiV-) centers in NDs using a spontaneously emerged low index-contrast quasiperiodic PSM, having micron-scale air pores. An intensity enhancement factor of 6.15 for SiV- and 7.8 for SiB ZPLs is attained for the PSM sample compared to a control sample. We find Purcell enhancement of 2.77 times for the PSM sample using spatial-dependent decay rate measurements, supported by localized field intensity confinement in the sample. Such cavity-like emission enhancement and lifetime reduction are enabled by an in-plane order-disorder scattering in the PSM sample substantiated by pump-dependent emission measurements. The results put forward a facile approach to tailor the near-infrared dual ZPL emission from NDs using nanophotonic structures.

The effect of heavy atoms on the deactivation of electronic excited states of dye molecules near the surface of metal nanoparticles.

The influence of a heavy atom and the plasmon field on the efficiency of populating the lowest triplet state (T1) and on the phosphorescence intensity has been studied for fluorescein, 2Br-fluorescein, eosin and erythrosine, which have an increasing number of substituted heavy atoms. We show that the heavy atoms affect not only the rate constant of intersystem crossing (kISC) but also the rate constant of internal conversion (kIC). The calculations show that the C-H bonds in the meso position are the primary acceptors of the excitation energy of the lowest excited electronic singlet state (S1). Substitution of the meso hydrogen atoms with I or Br leads to a smaller kIC rate constant of 1 × 108 s-1 for fluorescein to 8 × 106 s-1 for eosin. Substitution with heavy atoms also leads to a larger ISC rate constant (kISC) between the T2 and S1 states because the spin-orbit coupling matrix element 〈S1|HSO|T2〉 increases by two orders of magnitude from 0.36 cm-1 for fluorescein to 35.0 cm-1 for erythrosine. The phosphorescence rate constant increases by three orders of magnitude from 4.8 × 10 s-1 for fluorescein to 3.3 × 104 s-1 for erythrosine, which is supported by experimental data. The plasmon effect increases the intensity of the xanthene dye emissions. The intensity and the quantum yield of fluorescence increase in the series fluorescein < 2Br-fluorescein < eosin < erythrosine. The intensity of the delayed fluorescence and phosphorescence grows in the same way. The enhancement factor of the phosphorescence intensity increases from 1.8 to 5.6 in the series from fluorescein to erythrosine. The differences in the plasmon effect originate from intensity borrowing to the radiative triplet-singlet transition (T1 → S0) from the singlet-singlet transitions (Sn → S0), which is more efficient when molecules have heavy atoms in the meso position.

Plasmon mediated SERS and photocatalysis enhancement in Au nanoparticle decorated 2D-TiSe2

The combination of 2D materials and noble metallic nanostructure is becoming an attractive research domain for label-free, highly sensitive surface-enhanced Raman spectroscopy (SERS) applications. This study demonstrated photocatalysis degradation and SERS enhancements of organic fluorophore (Rhodamine 6G) on two-dimensional (2D) TiSe2 using Raman spectroscopy. The Au nanoparticles (NPs) were decorated on TiSe2 thin films by thermal annealing at variable temperatures. The selective deposition of Au NPs on the hexagonal TiSe2 nanocrystals increases surface roughness, creating a larger surface area for molecule adsorption. It has been observed that the Au decoration at 250 °C on TiSe2 exhibits efficient detection capabilities for R6G with the Raman intensity enhancement factors of the order of ≈105 along with the significantly improved visible light-induced photodegradation efficiency. The optimized Au NP size creates large electromagnetic hot spots produced by strong plasmon coupling that assists in the charge transfer mechanism among TiSe2, Au NPs, and R6G for enhanced SERS and photocatalysis activities. It has been observed that the intensity of Raman scattering decreases as the Au NP size increases on the TiSe2 material. A possible charge transfer mechanism is proposed with an energy band diagram. The simultaneous measurement of SERS and photocatalytic dye degradation in Au decorated TiSe2 can be used as a sensitive technique for water pollution treatment and biodegradable organic contaminants for the environmental ecosystem.

High-aspect-ratio dielectric pillar with nanocavity backed by metal substrate in the infrared range.

We investigated absorption and field enhancements of shallow nanocavities on top of high-aspect-ratio dielectric pillars in the infrared range. The structure includes a high-aspect-ratio nanopillar array of high refractive index, with nano-cavities on top of the pillars, and a metal plane at the bottom. The enhancement factor of electric field intensity reaches 3180 in the nanocavities and peak absorption reaches 99%. We also investigated the finite-size effect of the presented structure to simulate real experiments. Due to its narrow absorption bandwidth 3.5 nm, it can work as a refractive index sensor with sensitivity 297.5 nm/RIU and figure of merit 85. This paves the way to directly control light field at the nanoscales in the infrared light range. The investigated nanostructure will find applications in multifunctional photonics devices such as chips for culturing cells, refractive index sensors, biosensors of single molecule detection and nonlinear sensors.

Wide tuning of epsilon-near-zero plasmon resonance in pulsed laser deposited ITO thin films

Oxygen vacancies in indium tin oxide (ITO) thin films provide a direct route to effectively tune the free electron density and thereby, controlling the epsilon-near-zero (ENZ) cut-off wavelength, the wavelength at which the real part of permittivity crosses zero of the permittivity axis. In this report, oxygen vacancies in pulsed laser deposited ITO thin films are systematically tuned using different background gases (O2, N2, Ar, and He). ENZ cut-offs are observed for the films deposited under He and Ar gases. In contrast, no such cut-offs are observed in the case of other two gases. An ITO thin film deposited under He gas exhibits deeper resonance signal than the one deposited under Ar gas. As expected, no such dip in the resonance spectra is observed for the films deposited under O2 and N2 gases. This observation is directly correlated to the change in the number of oxygen vacancies under different ambient gases. A modified transfer matrix method which incorporates surface roughness as an effective medium layer is developed to describe the experimentally observed resonance spectra numerically. Angular invariancy of ENZ plasmon resonance and the difference in absorption values for ITO films deposited under different gases is understood in terms of local field intensity enhancement factor. The study presented here will certainly be very useful in understanding the ENZ plasmon resonance phenomena as a whole. Additionally, ITO films deposited under an inert gas environment could be excellent material platforms for realizing several exotic ENZ applications.

Tailoring Near-Infrared-IIb Fluorescence of Thulium(III) by Nanocrystal Structure Engineering.

Currently, mainstream lanthanide probes with fluorescence located in the second near-infrared subwindow of 1500-1700 nm (NIR-IIb) are predominantly Er(III)-based nanoparticles (NPs). Here we report a newly developed NIR-IIb fluorescent nanoprobe, α-Tm NP (cubic-phase NaYF4@NaYF4:Tm@NaYF4), with an emission at 1630 nm. We activate the 1630 nm emission of Tm(III) in α-Tm NP through the large spread of the Stark split sublevels induced by the crystal-field effect of the α-NaYF4 host. Further, we systematically investigated the effect of crystalline structure of the host NaYF4 NP (cubic phase (α) or hexagonal phase (β)), the type and concentrations of dopants (Yb(III), Tm(III), and Ca(II) ions) in the α-phase host, and the thicknesses of the interlayer and inert shell on the NIR-IIb fluorescence of Tm(III). The ultimate nanostructure presents a significant enhancement factor of the NIR-IIb photoluminescence intensity of Tm(III) up to ∼315. With this bright NIR-IIb fluorescent nanoprobe, we demonstrate high-spatial-resolution time-coursing imaging of breast cancer bone metastasis.

Investigations of Dynamic Mechanical Performance of Rubber Concrete under Freeze-Thaw Cycle Damage

In order to study the effect of the freeze-thaw cycle on the integrity and dynamic mechanical performance of rubber concrete, the wave speed of rubber concrete specimens with 10% rubber volume was measured by a nonmetallic ultrasonic detector. The impact tests were also performed on rubber concrete specimens with different numbers of freeze-thaw cycles (0, 25, 50, 75, 100, and 125) at different impact air pressures (0.3, 0.4, 0.5, and 0.6 MPa) using a 74 mm diameter split Hopkinson pressure bar (SHPB) device, peak stress, ultimate strain dynamic intensity enhancement factor (DIF), and energy absorption effect. The results show that with the increase of freeze-thaw cycles, the wave speed decreases, and the freeze-thaw action will damage the rubber concrete and reduce the longitudinal wave velocity. Under the same freeze-thaw cycles, with the rise of strain rate, the peak stress, limit strain, DIF, and absorbed energy increase, and there is an obvious strain rate effect; under the pressure of 0.6 MPa, the peak stress of 25, 50, 75, 100, and 125 freeze-thaw cycles decreases by 25.1%, 37.1%, 46%, 52.5%, and 54.8%. With the increase of the freeze-thaw cycles, the peak stress of the specimen decreases, and the decrease gradually decreases. After the number of cycles exceeds 100, the stress decrease of the specimen is no longer obvious, the limit strain increases, and the absorbed energy decreases. The freeze-thaw environment significantly reduces the strength and integrity of rubber concrete specimens.

Tightly focused linearly and radially polarized beam effect on the LSPR peak with varying particle size

Interactions of gold and silver spherical nanoparticles (NPs) of a wide range of radius size with tightly focused beams are investigated for a wide range of wavelengths. The scattering of tightly focused beams with a single NP of varying size is examined using a generalized Mie theory and average intensity enhancement in the near-field due to localized surface plasmons is examined for different tightly focused beams. A multipole expansion approach is used to observe the contribution of modes in shaping the scattered light intensity. Influence of particle size and tightly focused beam on intensity enhancement factor is investigated and a shift in localized surface plasmon resonance (LSPR) peak towards higher wavelength is observed with increasing particle size. Maximum intensity enhancement factor due to scattering of different incident beams by a metallic NP is theoretically examined and reported. Gold and silver NP having radius size ranging from 30–60 nm and 1–15 nm respectively showed a maximum intensity enhancement factor in different media. A significant enhancement for the tightly focused radially polarized beam is observed for gold and silver NPs of radius size between 50 nm and 100 nm. Variation towards higher wavelength in LSPR peak due to involvement of higher order of multipoles, and the surrounding medium are also examined in detail.

Enhancing Up-Conversion Luminescence Using Dielectric Metasurfaces: Role of the Quality Factor of Resonance at a Pumping Wavelength.

Photonic applications of up-conversion luminescence (UCL) suffer from poor external quantum yield owing to a low absorption cross-section of UCL nanoparticles (UCNPs) doped with lanthanide ions. In this regard, plasmonic nanostructures have been proposed for enhancing UCL intensity through strong electromagnetic local-field enhancement; however, their intrinsic ohmic loss opens additional nonradiative decay channels. Herein, we demonstrate that dielectric metasurfaces can overcome this disadvantage. A periodic array of amorphous-silicon nanodisks serves as a metasurface on which a layer of UCNPs is self-assembled. Sharp resonances supported by the metasurface overlap the absorption wavelength (λ = 980 nm) of UCNPs to excite them, resulting in the enhancement of UCL intensity. We further sharpen the resonances through rapid thermal annealing (RTA) of the metasurface, crystallizing silicon to reduce intrinsic optical losses. By optimizing the RTA condition (at 1000 °C for 20 min in N2/H2 (3 vol %) atmosphere), the resonance quality factor improves from 17.2 to 32.9, accompanied by an increase in the enhancement factor of the UCL intensity from 86- to over 600-fold. Moreover, a reduction in the intrinsic optical losses mitigates the UCL thermal quenching under a high excitation density. These findings provide a strategy for increasing light-matter interactions in nanophotonic composite systems and promote UCNP applications.

Energy-distributable waterborne acoustic launcher for directional sensing

Highly directional launch and intensity adjustment of underwater acoustic signals are crucial in many areas such as abyssal navigation, underwater signal communication, and detection for marine biology. Inspired by the phenomenon that aquatic animals like dolphins detect and track prey with high resolution, we propose an energy-distributable directional sensing strategy which can achieve parallel needle-like transmitting sound beams with adjustable energy based on out-coupling valley-polarized edge states. The acoustic spin angular momentum and energy flow distribution at different interfaces inside the phononic crystal are provided and they show tight coupling. Furthermore, a sound beam with a width of 20° and an acoustic intensity enhancement factor ≈ 6.6 are observed in the far field. As an application, we show that this device can be used as an acoustic energy distributor. This communication pattern with excellent functionalities and performance provides a desirable idea for high-energy-level directional collimated underwater sensing and underwater acoustic energy distribution.

High performance SPR biosensor using Cu-Pt bimetallic layers and 2D materials

In this present paper, we propose a surface plasmon resonance(SPR)sensor having better performance parameters based on Kretschmann configuration. The proposed SPR sensor is a modified Kretschmann configuration comprised of BK7 prism-Cu-Pt-Graphene/BP/WS2. The bimetallic layer provides consistent enhancement of sensitivity over other SPR structures. Extensive numerical analysis based on transfer matrix theory has been performed to characterize the sensor response considering sensitivity, full width at half maxima (FWHM), detection accuracy(DA), quality factor(QF) with other conventional reported SPR sensor. We have also analyzed the electric field intensity enhancement factor(EFIEF) for the proposed SPR sensor. We have found that maximum sensitivity of 309deg/RIU corresponds to the four layer of BP configuration. We believe that this proposed SPR sensor could find the new platform for the chemical examination, medical diagnosis, gas detection and biological detection.

Microwave-enhanced laser-induced breakdown spectroscopy of Zirconium metal

A microwave-enhanced laser-induced breakdown spectrometer (MWE-LIBS) was developed to produce high emission intensities and a high signal-to-noise ratio for spectrochemical and analytical applications inside the Fukushima Daiichi Nuclear Power Station. MWE-LIBS potentially solves the problem of signal attenuation in fiber-coupled laser-induced breakdown spectroscopy (LIBS), which may be experienced in an intense radiation environment. Zirconium (Zr) metal was used as the target material in this study. The variations of the emission intensity enhancement factor and SNR with increasing the microwave power were investigated. The results revealed that the SNR for the atomic Zr I and ionic Zr II emissions was increased to several hundred times higher than that under standard LIBS. The interaction of the microwave and plasma enhanced the excitation and recombination cycles of Zr I and released stronger emissions for analysis. Consequently, ionization and the molecular formation of ZrO were enhanced and sustained for extended periods. The lifetime of the emissions lasted longer than the microwave duration of 1000 µs. The microwaves also enlarged the plasma by twenty times the initial volume.

Spontaneous emission enhancement and directional emission by an optical nanonatenna array on a metallic mirror

Optical nanoantennas support surface plasmon polariton (SPP) with a confinement of light breaking through the diffraction limit, and thereby achieving an enhancement and regulation of electromagnetic field on a deep-subwavelength scale. In this paper, a periodic array of optical nanoantennas on a metallic mirror is proposed, where the antennas are gold nanocubes forming a two-dimensional periodic array, and a single point emission source is located in the nanogap between the antenna of gold nanocube and the gold mirror. The nanogap between the antenna and mirror can support gap surface plasmon, which results in an enhanced spontaneous emission rate. Meanwhile, the periodic array of nanoantennas can support the surface lattice resonance (SLR), which can achieve directional far-field radiation perpendicular to the substrate or in a specified direction by properly designing the array period. To design the antenna that can simultaneously achieve an enhancement of spontaneous emission rate and a directional radiation of far field, the calculation of the radiation field of a single point source in a periodic structure is transformed into the calculation of the radiation fields of a set of pseudoperiodic point-source arrays by combining the array scanning method (ASM) and full-wave rigorous numerical method, thus giving the spontaneous emission rate of the emitter and the near-field distribution of the antenna. Concerning the calculation of the angular distribution of far-field radiation intensity, we start from the Maxwell’s equations and provide a rigorous formulation and proof of the reciprocity-theorem method. This proof is different from those reported in existing literature and has a more rigorous applicability for infinite-extent periodic structures or has a lower amount of computational work. Based on the reciprocity-theorem method, the antenna parameters are designed so that the enhancement factor of far-field radiation intensity reaches a maximum value of 2756 in the direction perpendicular to the substrate, and simultaneously, the enhancement factors of total spontaneous emission rate and far-field spontaneous emission rate of the point source reach 1097 and 55.50, respectively. The proposed antenna has a simple structure that is easy to design and fabricate, and the proposed design method is intuitive and easy to implement, which can be used to guide the design of high-speed, high-brightness and directional-radiation light sources.

Reflection-enhanced laser-induced fluorescence spectroscopy to improve the analytical sensitivity in liquids

The current work demonstrates a novel approach to enhancing the analytical sensitivity of the laser-induced fluorescence (LIF) technique in liquids. An increase in the fluorescence spectral band intensity of about sixfold compared to the conventional LIF has been achieved. Such betterment has been accomplished by having the fluorophore liquid in a cuvette having a reflecting mirror-like side facing the exciting incident laser beam. The silvered or aluminized reflecting side of the cuvette was tested. The pilot test of the proposed cuvette was performed using an excitation laser light of 405 nm wavelength and five mW average power on chlorophyll-a (Chl-a) samples of different concentrations. As a result, a pronounced improvement in the Chl-a fluorescence spectral band intensity is achieved. Such a novel approach, the reflection-enhanced laser-induced fluorescence (RELIF), has been used to analyze six Egyptian brands of extra virgin olive oil (EVOO). Compared to the LIF measurement results on the same EVOO, the RELIF was superior in terms of the fluorescence-spectrum intensity enhancement factor. Both Ag and Al coatings of the cuvette revealed similar results. Statistical analysis of the measured fluorescence spectra via the partial least square regression (PLSR) method for LIF and RELIF revealed a higher coefficient of determination R2 for both RELIF measurements (with silver and aluminum coating) than for LIF. The proposed novel RELIF approach can be utilized for other fluorophore liquids at higher analytical sensitivity than conventional LIF. On the other hand, the RELIF technique is straightforward, cost-effective, and does not complicate the traditional LIF setup.

Enhancement of spectral line intensity and lifetime of femtosecond laser-induced Cu plasma in a cylindrical cavity

The spatial confinement effects in the femtosecond laser-induced Cu plasma contained within a cylindrical cavity are studied by optical emission spectroscopy. The Cu atomic emission intensity and spectral line lifetime are enhanced significantly when a cylindrical cavity with an inner diameter of 6 mm confined the femtosecond laser-induced Cu plasma. The enhancement factor of the emission intensity under the spatial confinement depends on the upper level energy of the spectral line, and the maximum enhancement factors is about 2.48 for the Cu I 529.3 nm spectral line. The spatial confinement can effectively prolong the lifetime of the femtosecond-induced Cu and the persistence time of the plasma is near to 7 μs. The enhancements of the spectral line intensity and lifetime are attributed to the increased electron temperature and density owing to the spatial confinement, and the mechanism for the enhancement effects with the cylindrical cavity are discussed in terms of the shockwave interactions.

Highly sensitive MXene-immobilized long range SPR sensor for biomolecule detection

In this article, a long-range surface plasmon resonance (LRSPR) sensor is proposed using the dielectric (Teflon)-metal (Silver)-Ti3C2Tx (MXene) layer for imaging sensitivity enhancement. MXene shows excellent properties, such as larger surface area, hydrophilic nature, high metallic conductivity, chemical stability, and strong biocompatibility for detection of biomolecules. The MXene layer is used here to improve imaging sensitivity and prevent unwanted silver oxidation. The proposed sensor takes advantage of the high adsorption efficiency of MXene for biomolecules and high resolution due to the LRSPR technique. Long-range SPPs are used to improve the imaging sensitivity, detection accuracy (DA), figure of merit (FoM) and penetration depth (PD) up to 4998/RIU, 12.5/°, 199.1/RIU and 546.65 nm, respectively, which are much higher than the present state of the art. The field intensity enhancement factor at the interface of the constituent layer of the proposed sensor and the conventional surface plasmon resonance (cSPR) sensor is also verified. The penetration depth (PD) of the field into the sensing layer for the LRSPR sensor is 2.5 times greater than that of the cSPR sensor. Thus, the proposed sensor offers potential benefits for sensing of large-sized biomolecules in the area of medical diagnostics.

Quartz Tube Enhanced Raman Scattering Spectroscopy

Raman spectroscopy is widely used in many fields with the advantages of simultaneous species detection and molecular fingerprint characteristics, but the low detection sensitivity limits its further development, especially for highly scattering or turbid mediums. In this consideration, a new method called quartz tube enhanced Raman scattering spectroscopy was proposed for the first time in this paper. A quartz tube was inserted into the powder sample to improve the coupling of light into the medium and increase the interaction volume of the laser with the sample (“volume-excitation”), multiple scattering of the light within the turbid medium resulted in an increased Raman signal. In this paper, the effect of different sizes of quartz tubes on the sensitivity enhancement was studied. The results show that the enhancement factor of the signal intensity was nearly 5.37 (the Raman signal of HCO3−) compared to traditional Raman spectroscopy technology. Furthermore, the method was successfully applied to improve the Raman signal intensity of the mixed sample (1:5, m (PO43−):m (HCO3−)) and detect the baking soda powder buried under a 6 mm thick layer of potassium dihydrogen phosphate powder. The results show that the technology will open a new way for the quantitative analysis and detection of powder samples.