Enhanced Moisture Resistance Research Articles

Sustainable innovations: Mechanical and thermal stability in palm fiber-reinforced boron carbide epoxy composites

This study reports the development of a sustainable composite material by integrating boron carbide (B4C) nanoparticles into palm fruit fiber (PFF)-reinforced epoxy matrices. The mechanical and thermal properties of these composites were thoroughly assessed, yielding promising results across key performance metrics. Tensile strength increased to 41.73 MPa with 4 % B4C, while flexural strength reached 43.29 MPa at the same concentration. Impact energy also saw an improvement, peaking at 5.6 kJ/m² with 4 % B4C. Similarly, hardness values showed an upward trend, with a Shore D value of 73. Additionally, water absorption was reduced from 7.2 % to 5.3 %, indicating enhanced moisture resistance. Thermal analysis confirmed the superior thermal stability of the composite, as shown by Thermogravimetric Analysis (TGA) and Differential Thermogravimetry (DTG) curves, with the maximum mass loss occurring at a higher temperature for the 4 % B4C composite. Fatigue stress testing also demonstrated improved durability, with the 4 % and 5 % composites exhibiting higher fatigue resistance over multiple cycles. The findings suggest that a 4 % concentration of boron carbide achieves an optimal balance of improved mechanical strength, durability, and thermal stability, making these composites suitable for high-performance applications while promoting environmental sustainability.

Reconstructing the Surface of K2SiF6:Mn4+ Phosphors toward Enhanced Moisture Resistance for White LED Applications.

The K2SiF6:Mn4+ (KSFM) phosphor featuring efficient ultranarrow red emissions is an outstanding candidate for white light-emitting diode (WLED) applications. However, poor moisture resistance seriously affects its application performance. In this study, a two-step surface reconstruction strategy is proposed to dramatically enhance the moisture resistance of commercially available KSFM phosphors, involving treatment with H2NbF7 and subsequent hydrothermal treatment. The modified KSFM phosphor exhibits a high internal quantum efficiency (IQE) of 98.9% after the two-step surface treatment. Meanwhile, nearly 100% of the initial emission intensity is retained for the modified KSFM phosphor even after aging in high temperature (85 °C) and high relative humidity (85% RH) environments for 6 days, in sharp contrast to only 18.6% retention for the original KSFM phosphor. The relative emission intensity of the modified KSFM remains at 98.9% even after being immersed in water for 6 h. Additionally, the phosphor-converted LED fabricated with the modified KSFM phosphor demonstrated excellent long-term stability, retaining up to 97.9% of initial luminous efficacy after aging under 85 °C and 85% RH conditions for 500 h. The moisture-resistance mechanism is elucidated on the basis of spectroscopic analysis as well as structural and compositional characterization of the phosphor surface layer, which can be attributed to the formation of a robust Mn4+-rare shell with high crystalline quality following this two-step surface treatment. The findings contribute to the performance improvements of KSFM phosphors for industrial applications.

Mechanism of the G/M ratio and zein in enhancing the mechanical and hydrophobic properties of sodium alginate films

This study developed an edible film based on calcium-crosslinked sodium alginate (SA) using the casting method. The investigation assessed how the α-L-guluronic acid/β-D-mannuronic acid (G/M ratio) and zein addition influence the film's physicochemical properties. Fourier transform infrared spectroscopy and scanning electron microscopy findings suggest that the G/M ratio modulates the film's physicochemical characteristics by altering SA molecular cross-linking strength and the film's network structure density. At a G/M ratio of 0.85, the film exhibits a more uniform network structure, enhanced moisture resistance, hydrophobicity, and mechanical properties. Zein, evenly dispersed within the film matrix, establishes strong hydrogen bonds and electrostatic interactions with SA, enhancing the film's network structure and boosting its thermophysical, mechanical, and moisture resistance characteristics. The study demonstrates that modifying the G/M ratio and incorporating zein enhances the film's mechanical and hydrophobic properties, broadening its potential applications in food packaging.

Enhancing waste asphalt durability through cold recycling and additive integration

The longevity of waste asphalt can be considerably improved through cold recycling techniques combined with various additives. This research investigates the cold regeneration of aged asphalt concrete using Reclaimed Asphalt Pavement (RAP), Portland cement, cationic bitumen emulsion, and additional aggregates. The primary goal is to evaluate the performance enhancements in terms of average density, compressive strength, water resistance, and swelling across different mix compositions. Three distinct mixtures were formulated and assessed. Mix No. 1, composed solely of RAP, showed the lowest average density and highest swelling, indicating poor performance due to the lack of binding agents. Mix No. 2, which incorporated RAP, Portland cement, and water, exhibited the highest density and compressive strength, highlighting the crucial role of Portland cement in improving structural integrity. Mix No. 3, a more complex mixture including RAP, aggregates, Portland cement, water, and bitumen emulsion, displayed balanced properties with enhanced moisture resistance and reduced swelling. The experimental findings emphasize the effectiveness of adding Portland cement and bitumen emulsion to improve the mechanical and durability characteristics of recycled asphalt mixtures. Specifically, Mix No. 2 and Mix No. 3 demonstrated significant performance improvements, making them suitable for road maintenance applications. This study advocates for the widespread use of cold recycling methods with additive integration to achieve sustainable and cost-effective pavement restoration solutions.

Flexible, Breathable and Hydrophobic SnO2–SnS2–SiO2/SiO2 All‐Inorganic Self‐Supporting Nanofiber Membrane for Ultralow‐Concentration NO2 Sensing Under High Humidity

AbstractInorganic semiconductor gas sensors, being widely utilized in gas‐sensing applications, face significant challenges in attaining mechanical flexibility and humidity resistance in wearable sensing fields. Herein, a highly flexible, breathable, and hydrophobic all‐inorganic self‐supporting nanofiber (NF) gas sensor is developed using electrospinning combined with thermal sulfidation approach. This innovative sensor features a bilayer configuration, with an amorphous SiO2 nanofiber substrate layer and an interwoven SiO2 and SnO2–SnS2 nanofiber active layer. The relatively low elastic modulus of the amorphous SiO2 nanofibers, combined with the three‐dimensional network interwoven structure, endow the SnO2–SnS2–SiO2/SiO2 sensor with superior mechanical flexibility. The sensor exhibits excellent sensitivity, selectivity, moisture resistance, and cycling stability (>10 000 cycles at 140° bending) to both high and low concentration NO2. Notably, an excellent flexible detecting capability of the sensor to NO2, an asthma‐related biomarker, is demonstrated at ultralow concentrations (≈25 ppb) in simulated exhaled breath environments. The enhanced moisture resistance is attributed to the effective inhibition of hydrogen bond formation from H2O molecules by the Sn─S bonds formed through sulfidation of SnO2 nanofibers. This work represents a substantial advancement in the universal fabrication of flexible, breathable and moisture‐resistant inorganic semiconductor sensors for wearable breath sensing applications.

Fluorinated metal-organic framework aerogels with enhanced moisture resistance and efficient gas diffusion for CO2 capture

Escalating CO2 levels in confined spaces threatens human well-being and safety, underscoring the urgent need for effective CO2 mitigation strategies. Metal-organic frameworks (MOFs), with their large surface areas and capacious pores, represent a promising avenue for CO2 capture. However, their application is often limited by susceptibility to moisture and lack of uniformity in mesopore distribution. Here, we present a novel approach involving ligand fluorination modification and pore reconstruction to fabricate ultralight, highly moisture resistant, and hierarchically porous UiO-66-NH2-F4 aerogels. This design ingenuity promotes the formation of an efficient gas transport network and generates an abundance of micropores decorated with hydrophobic units, effectively shielding CO2 adsorption from the interference of water molecules. The UiO-66-NH2-F4 aerogels exhibit an impressive CO2 adsorption capacity of 5.18 mmol/g (dry) and 4.48 mmol/g (70 % RH) at 298 K, a remarkable CO2/N2 selectivity of 29, and exceptional cyclability. Density functional theory (DFT) calculations further elucidate the robust binding interactions of these CO2-selective UiO-66-NH2-F4 aerogels, attributing them to the tailed pore environment created by fluorinated hydrophobic groups and the accessibility of adsorption sites. This work charts a promising course for developing moisture-resistant and hierarchically porous MOF aerogels, which are poised to revolutionize CO2 adsorption practices in confined environments.

Controlling Water for Enhanced Homogeneities in Perovskite Solar Cells with Remarkable Reproducibility

AbstractTwo‐step sequential deposition of perovskite films is proven efficient and compatible with large‐scale production. Nevertheless, its critically regulated environmental humidity often remains a burden, hindering its applications in reproducible fabrication of perovskite solar cells (PSCs). Herein, by introducing a water ethyl acetate (W‐EA) solution treatment before annealing, improved perovskite crystallinity and homogeneity in FA0.95‐xMAxCs0.05PbI3 films without additional composition regulation is achieved. In situ Grazing‐incidence Wide‐angle X‐ray Scattering experiments highlighted accelerated crystallization kinetics in W‐EA‐treated films, leading to high‐quality perovskite formation. PSCs based on this method reached an optimal power conversion efficiency of 25.01% and demonstrated enhanced moisture resistance, retaining 88% efficiency after 1000 h in ambient conditions. This W‐EA treatment simplifies the fabrication process, greatly reducing the need for controlled humidity, and offers insights into the role of water in perovskite film crystallization, with significant implications to produce high‐performance PSCs.

Sustainable Asphalt Mixtures with Enhanced Water Resistance for Flood-Prone Regions Using Recycled LDPE and Carnauba-Soybean Oil Additive.

This manuscript presents a comprehensive study on the sustainable optimization of asphalt mixtures tailored for regions prone to flooding. The research addresses the challenges associated with water damage to asphalt pavements by incorporating innovative additives. The study centers on incorporating recycled Low-Density Polyethylene (LDPE) and a tailored Carnauba-Soybean Oil Additive, advancing asphalt mixtures with a Control mix, LDPE (5%) + Control, and LDPE (5%) + 3% Oil + Control. A critical aspect of the research involves subjecting these mixtures to 30 wetting and drying cycles, simulating the conditions prevalent in tropical flood-prone areas. The incorporation of innovative additives in asphalt mixtures has demonstrated significant improvements across various performance parameters. Tensile Strength Ratio (TSR) tests revealed enhanced tensile strength, with the LDPE (5%) + 3% Oil-modified mixture exhibiting an impressive TSR of 85.7%. Dynamic Modulus tests highlighted improved rutting resistance, showcasing a remarkable increase to 214 MPa in the LDPE (5%) with a 3% Oil-modified mixture. The Semi-Circular Bending (SCB) test demonstrated increased fracture resistance and energy absorption, particularly in the LDPE (5%) with 3% Oil-modified mixture. Hamburg Wheel-Tracking (HWT) tests indicated enhanced moisture resistance and superior rutting resistance at 20,000 cycles for the same mixture. Cantabro tests underscored improved aggregate shatter resistance, with the LDPE (5%) + 3% Oil-modified mixture exhibiting the lowest weight loss rate at 9.820%. Field tests provided real-world insights, with the LDPE (5%) + 3% Oil mixture displaying superior stability, a 61% reduction in deflection, and a 256% improvement in surface modulus over the control mixture. This research lays the groundwork for advancing the development of sustainable, high-performance road pavement materials, marking a significant stride towards resilient infrastructure in flood-prone areas.

Stabilizing Top Interface by Molecular Locking Strategy with Polydentate Chelating Biomaterials toward Efficient and Stable Perovskite Solar Cells in Ambient Air.

The instability of top interface induced by interfacial defects and residual tensile strain hinders the realization of long-term stable n-i-p regular perovskite solar cells (PSCs). Herein, one molecular locking strategy is reported to stabilize top interface by adopting polydentate ligand green biomaterial 2-deoxy-2,2-difluoro-d-erythro-pentafuranous-1-ulose-3,5-dibenzoate (DDPUD) to manipulate the surface and grain boundaries of perovskite films. Both experimental and theoretical evidence collectively uncover that the uncoordinated Pb2+ ions, halide vacancy, and/or I─Pb antisite defects can be effectively healed and locked by firm chemical anchoring on the surface of perovskite films. The ingenious polydentate ligand chelating is translated into reduced interfacial defects, increased carrier lifetimes, released interfacial stress, and enhanced moisture resistance, which should be liable for strengthened top interface stability and inhibited interfacial nonradiative recombination. The universality of the molecular locking strategy is certified by employing different perovskite compositions. The DDPUD modification achieves an enhanced power conversion efficiency (PCE) of 23.17-24.47%, which is one of the highest PCEs ever reported for the devices prepared in ambient air. The unsealed DDPUD-modified devices maintain 98.18% and 88.10% of their initial PCEs after more than 3000h under a relative humidity of 10-20% and after 1728h at 65 °C, respectively.

Facile-Solution-Processed Silicon Nanofibers Formed on Recycled Cotton Nonwovens as Multifunctional Porous Sustainable Materials.

Limited efficiency, lower durability, moisture absorbance, and pest/fungal/bacterial interaction/growth are the major issues relating to porous nonwovens used for acoustic and thermal insulation in buildings. This research investigated porous nonwoven textiles composed of recycled cotton waste (CW) fibers, with a specific emphasis on the above-mentioned problems using the treatment of silicon coating and formation of nanofibers via facile-solution processing. The findings revealed that the use of an economic and eco-friendly superhydrophobic (contact angle higher than 150°) modification of porous nonwovens with silicon nanofibers significantly enhanced their intrinsic characteristics. Notable improvements in their compactness/density and a substantial change in micro porosity were observed after a nanofiber network was formed on the nonwoven material. This optimized sample exhibited a superior performance in terms of stiffness, surpassing the untreated samples by 25-60%. Additionally, an significant enhancement in tear strength was observed, surpassing the untreated samples with an impressive margin of 70-90%. Moreover, the nanofibrous network of silicon fibers on cotton waste (CW) showed significant augmentation in heat resistance ranging from 7% to 24% and remarkable sound absorption capabilities. In terms of sound absorption, the samples exhibited a performance comparable to the commercial standard material and outperformed the untreated samples by 20% to 35%. Enhancing the micro-roughness of fabric via silicon nanofibers induced an efficient resistance to water absorption and led to the development of inherent self-cleaning characteristics. The antibacterial capabilities observed in the optimized sample were due to its superhydrophobic nature. These characteristics suggest that the proposed nano fiber-treated nonwoven fabric is ideal for multifunctional applications, having features like enhanced moisture resistance, pest resistance, thermal insulation, and sound absorption which are essential for wall covers in housing.

Feasibility of Carnauba Wax Rejuvenators for Asphalt Concrete with Vacuum Tower Bottom Binder

This study addresses the need for effective rejuvenators in asphalt concrete mixtures containing Vacuum Tower Bottom (VB) binder, a by-product of petroleum refining. We investigated the use of a softening rejuvenator, comprising Carnauba (5.5%), Soybean oil (3%), water (81%), surfactant (1.5%), and additive (3%) from a Korean refining company, to mitigate the brittleness of VB binder. Laboratory experiments were conducted to compare the performance of the modified binder with the original hardened binder. The results showed that adding the rejuvenator improved the properties of the VB binder. Optimal asphalt grades were achieved with a 2% content of the softening additive in the VB binder. The rejuvenator enhanced moisture resistance, leading to settlements comparable to the control asphalt. Settlements after 20,000 load repetitions were 11.49 mm for the modified mixture, which were slightly better than the control material at 12.44 mm. Moisture stripping points occurred at around 16,000 cycles for the modified mixture, while the control material experienced them at approximately 13,000 cycles. Under freeze-thaw cycles, the modified mixture exhibited enhanced durability compared to the control mixture. The control mixture experienced a significant increase in rutting value of approximately 59.7% (from 12.4 mm to 19.7 mm), while the modified mixture showed a relatively lower increase of approximately 37.4% (from 11.5 mm to 15.8 mm). Additionally, the modified VB mixture demonstrated approximately 7.8% higher dynamic modulus at lower temperatures, indicating improved mechanical properties. It also displayed superior fatigue crack resistance, with a fatigue life of 18,385 cycles compared to 15,775 cycles for the control asphalt. Field results confirmed that the VB asphalt mixture with the rejuvenator achieved comparable site compactness to the control mixture, indicating successful compaction performance. These findings highlight the rejuvenator’s efficacy in mitigating binder stiffening and restoring the original state of aged asphalt binders.

Monodisperse Y-type CoO hierarchical nanostructure/reduced graphene oxide for improved NO2 detection at room temperature with enhanced moisture resistance

The fabrication of high-performance gas-sensitive materials with enhanced moisture resistance is an important research topic. In this work, monodisperse Y-type CoO hierarchical nanostructures with a branch length of about 16 nm have been prepared, and then uniformly dispersed on the surface of reduced oxide graphene (rGO) by hot injection method. The composite exhibited a rapid response to NO2 at room temperature. The optimal response was about 40–100 ppm NO2, the response time was 620 s to 10 ppm NO2 and the detection limit was 0.01 ppm. It was due to the combination of more NO2 adsorption active sites of Y-type CoO and faster carrier transfer of rGO. Even at high relative humidity (RH) conditions of 80%, the sensor still retained a high response value of about 90% of that measured at the normal RH (25%). The effective wrapping of stearate ligands inhibited the entrance of water vapor molecules, which could effectively improve the hydrophobic properties of the composite and resulted in enhanced moisture resistance. It may provide a new path for improved NO2 detection with enhanced moisture resistance at room temperature.

Enhanced moisture resistance and catalytic stability of ethylene oxidation at room temperature by the ultrasmall MnOx cluster/Pt hetero-junction

Ethylene elimination can effectively inhibit the rapid aging of fruits and vegetables in storage and transportation. Improving the low-temperature activity, moisture resistance, and stability of Pt based catalysts is a challenge for catalytic oxidation of ethylene which is an effective elimination method. Herein, we constructed ultrasmall MnOx cluster (< 1 nm) on Pt particles via an alloy in situ transformation strategy, which created a large number of MnOx/Pt interfaces. Among all of the samples, 1.89Pt2.20Mn/TiO2 showed the highest catalytic activity in the oxidation of ethylene at a space velocity of 20,000 mL/(g h): T50% = 34 oC and T90% = 43 oC, specific reaction rate at 35 oC = 33.0 µmol/(gPt s), and turnover frequency at 35 oC = 6.5 × 10–3 s−1. In addition, Pt2.20Mn/TiO2 also exhibited better water resistance and stability than Pt/TiO2. The results of XPS, H2O-TPD, C2H4-TPD, in situ DRIFTS, and H218O isotopic tracing characterization revealed that the MnOx/Pt interfacial sites accelerated desorption of CO2 and enhanced the activation of surface active oxygen species (O2 to O22−). Meanwhile, the numerous interfaces provide more active sites for ethylene adsorption and activation, reducing the inhibitory effect of adsorbed water on ethylene adsorption. It was concluded that the prohibited CO2 adsorption, and increased adsorbed oxygen species were responsible for the excellent catalytic performance and good stability of 1.89Pt2.20Mn/TiO2, while the more active sites for ethylene adsorption and activation were responsible for the good water resistance of 1.89Pt2.20Mn/TiO2.

Effects of Chitosan Nanoparticles and 4,4' Methylene-Diphenyl Diisocyanate on the Polylactic Acid/Poly (Butyleneadipate-Co-Terephthalate) Composite Properties.

Polylactic acid (PLA) is considered a mature alternative to synthetic plastics made from petroleum by-products, possessing the advantages of good mechanical strength. However, it also has some disadvantages such as brittleness and low toughness. In order to overcome and improve some of these unfavorable properties, PLA/PBAT composites were prepared by blending PLA with Poly (butylene adipate-co-terephthalate) (PBAT), and adding 4,4'-methylene diphenyl diisocyanate (MDI) and chitosan nanoparticles (ChNPs) as compatibilizers to investigate the effects of different compatibilizers on the properties of the composites. The main observations are as follows: FT-IR indicated that MDI did not add new groups, while the addition of ChNPs added a substantial amount of hydroxyl and methylene groups. The addition of both MDI and ChNPs did not have any effect on the crystalline shape of the composites, but could potentially reduce their crystallinity, increase the melt peak temperature, wet the boundary of the PLA and PBAT phases, decrease the size of the dispersed phases, reduce the number of dispersed phases, and improve interfacial compatibility. The incorporation of MDI increased the tensile strength from 13.02 MPa to 19.24 MPa, whereas the addition of ChNPs substantially enhanced the elongation at the break from 3.84% to 19.24%. Furthermore, the inclusion of MDI conferred enhanced moisture resistance, whereas the addition of ChNPs seemed to weaken the resistance to moisture.

Enhanced Moisture Resistance of Salt Core through 2D Kaolinite Colloidal Solution Coating

Enhanced Moisture Resistance of Salt Core through 2D Kaolinite Colloidal Solution Coating

Feasibility of Pellet Material Incorporating Anti-Stripping Emulsifier and Slaked Lime for Pothole Restoration

Climate change has caused a surge in abnormal weather patterns, leading to a rise in cracks, plastic deformation, and pothole damage on road surfaces. In order to fabricate a ready-mix admixture of warm asphalt mixture (WMA) for pothole restoration, this study aimed to develop a neutralized anti-stripping material in pellet form by extruding a combination of slaked lime and a liquid emulsifier additive. Slaked lime (1% by weight of aggregate) was chosen for its ability to enhance moisture resistance, while a liquid emulsifier (wax + vegetable oil + surfactant + water) was added to create a pellet-type stripping inhibitor for WMA. After successfully fabricating the pellet admixture, this study evaluated the performance of two asphalt mixtures: conventional Slaked Lime Hot Mix Asphalt (LHMA) and the Pellet-Type Anti-Stripping Warm Mix Asphalt (PWMA). Several compatibility tests were conducted to evaluate the quality of the developed material. The results showed that the fatigue resistance of the developed material (PWMA) improved by over 20%, indicating an extended fatigue life for the pavement. The LHMA and PWMA met the quality standard for asphalt mixtures, with a TSR value of approximately 83%. Both mixtures demonstrated improved rutting resistance compared to HMA. The PWMA required 16,500 cycles, while the LHMA required 19,650 cycles to reach a settlement of 20 mm, indicating better moisture resistance than the control mix (13,481 cycles). The modified mixture performed properly in the Cantabro test, with loss rates below 20%, indicating their ability to retain their aggregate structure. The PWMA also showed superior resistance to plastic deformation, with a 12.5% lower phase angle (35°) at a reduced frequency of 10−3. In general, the application of PWMA not only prolongs the pavement lifespan but also reduces the production temperature by over 20 °C, leading to lower emissions and energy consumption. This makes it an environmentally friendly option for pavement applications and contributes to sustainable road construction practices.

Perovskite Grain-Boundary Manipulation Using Room-Temperature Dynamic Self-Healing "Ligaments" for Developing Highly Stable Flexible Perovskite Solar Cells with 23.8% Efficiency.

Flexible perovskite solar cells (pero-SCs) are the best candidates to complement traditional silicon SCs in portable power applications. However, their mechanical, operational, and ambient stabilities are still unable to meet the practical demands because of the natural brittleness, residual tensile strain, and high defect density along the perovskite grain boundaries. To overcome these issues, a cross-linkable monomer TA-NI with dynamic covalent disulfide bonds, H-bonds, and ammonium is carefully developed. The cross-linking acts as "ligaments" attached on the perovskite grain boundaries. These "ligaments" consisting of elastomers and 1D perovskites can not only passivate the grain boundaries and enhance moisture resistance but also release the residual tensile strain and mechanical stress in 3D perovskite films. More importantly, the elastomer can repair bending-induced mechanical cracks in the perovskite film because of dynamic self-healing characteristics. The resultant flexible pero-SCs exhibit promising improvements in efficiency, and record values (23.84% and 21.66%) are obtained for 0.062and 1.004cm2 devices; the flexible devices also show overall improved stabilities with T90 >20000bending cycles, operational stability with T90 >1248h, and ambient stability (relative humidity=30%) with T90 >3000h. This strategy paves a new way for the industrial-scale development of high-performance flexible pero-SCs.

Spontaneous gas–solid reaction on sulfide electrolytes for high-performance all-solid-state batteries

Sulfide solid electrolytes modified by CO2/O2 deliver enhanced moisture resistance and superior cathodic interfacial stability.

Synthesis and characterization of an ultra-thin BiOCl/MXene heterostructure for the detection of NO2 at room temperature with enhanced moisture resistance

Two-dimensional ultrathin MXenes (Ti3C2Tx) have gained crucial attention in the field of gas sensing owing to their unique chemical and physical properties.

High performance sky-blue perovskite light-emitting diodes enabled by a bifunctional phosphate molecule

Defects such as uncoordinated lead ions and surface charged defects are still one of critical issues for perovskite light-emitting diodes (PeLEDs). The presence of these defects can trap excitons, resulting in enhanced nonradiative recombination and thus poor efficiencies of PeLEDs. Defect passivation via passivation agents is an effective way to solve this issue. In this work, we introduce a bifunctional phosphate molecule 6,6′-(ethane-1,2-diyl)bis(dibenzo[c,e][1,2]oxaphosphinine 6-oxide) (DIDOPO) as a passivation agent into the perovskite, where DIDOPO can bind with the perovskite via the chemical interaction between the PO groups and uncoordinated Pb ions. Thus, the incorporation of DIDOPO effectively passivates the defects, leading to improved radiative recombination. Simultaneously, the as-prepared perovskite film produces dense and smooth morphology, which is favorable to good contact with the adjacent charge transport layers and the reduction of leakage current. As a result, the sky-blue PeLEDs modified by DIDOPO show improved efficiency with the maximum external quantum efficiency (EQEmax) of 5.52% and the average EQEmax of 5.09%. Furthermore, attributed to the alkyl chain as the bridge between the phosphate groups, DIDOPO accumulated at the perovskite surface is able to decrease hydrophilic behavior of the perovskite. The PeLEDs containing DIDOPO possess enhanced moisture resistance, remaining ca. 91–92% of the initial EQE after storage for 120 h in ambient atmosphere with the humidity of ca. 40%.