Energy Transfer Phenomenon Research Articles

Stimulated Brillouin Scattering Gain of Waveguides Calculated with Acoustic Perturbation Method

Abstract Stimulated Brillouin Scattering (SBS) is a phenomenon of energy transfer from an optical pump beam to longer wavelengths of light through its interaction with the medium via acoustic phonons. Previous studies have reported a calculation of the SBS gain based on the optical force approach, where the gain is not only affected by the classical paradigm of intrinsic material’s nonlinear effects in the form of electrostriction but also due to radiation pressure. In this work, the acoustic perturbation approach is applied in analyzing the optical and mechanical response of the waveguide, wherein calculating the scattering process, the changes of the waveguide structure due to photoelasticity (PE), termed Moving Boundary (MB), are considered. This acoustic perturbation method avoids uncertainties related to optical force contributions. To validate its applicability, the present method is used to calculate the SBS gain of various waveguide structures, namely an unsuspended Silicon nano-waveguide, ridge Lithium Niobate (LiNBO3) nano-waveguide on Sapphire (Al2O3) substrate and buried Arsenic trisulfide (As2S3) in Silicon dioxide (SiO2). The forward and backward SBS gain obtained using the present method of acoustic perturbation are similar to the reported values obtained from other methods of calculation as well as experiments.

Investigation of luminescence properties and energy transfer mechanism in Sm3+ and Eu3+ co-doped BaY2ZnO5 red phosphors

In this investigation, the photoluminescence properties, energy transfer phenomenon of BaY2ZnO5:Sm3+/Eu3+ doped/co-doped phosphor are reported and synthesized by high temperature solid state reaction method. The crystal structure, micromorphology, optical diffuse reflectance and photoluminescence properties of the samples were studied. The results show that concentration quenching phenomenon is found. With the increase of Eu3+ ion concentration, the emission peaks of Sm3+ gradually decrease, indicating that energy transfer between Sm3+ and Eu3+. The optimal concentrations are 0.05 mol and 0.2 mol for single doping Sm3+ and Eu3+, respectively. The energy transfer efficiency is calculated to be 78.47–95.19 %. The BaY2ZnO5 phosphors have potential application value in the fields of white light LEDs and anti-counterfeiting.

Investigation of the temperature-dependent photoluminescence characteristics in Mn2+-doped (PEA)2PbBr4 perovskite

The two-dimensional organic-inorganic hybrid perovskites demonstrate significant potential for use in photodetectors and white light-emitting diodes. In this study, we successfully synthesized pure and Mn2+-doped (PEA)2PbBr4 perovskite via rapid crystallization. The morphology, structure, magnetic properties, and optical characteristics of them were comprehensively characterized. The unusual behavior of free exciton emission is mainly attributed to electron-phonon coupling and negative thermal quenching effects. The self-trapped exciton emission results from self-trapped excited states and electron-phonon coupling. Moreover, energy transfer phenomena are observed between free exciton emission, self-trapped exciton emission, and Mn2+ emission. These findings offer valuable insights into the luminescence mechanism of two-dimensional layered perovskites.

Adsorption behaviour of transition metal atoms on pristine and defective two-dimensional MgAl2S4 monolayer

The electronic structures and magnetic properties of two-dimensional MgAl2S4 monolayer, as well as the adsorption configurations, adsorption energy, and charge transfer phenomena of transition metal atoms adsorbed on both pristine and defective monolayer MgAl2S4 surfaces were systematically investigated. The results show that MgAl2S4 at equilibrium is a nonmagnetic indirect semiconductor with a bandgap of 1.908 eV. The adsorption energies of the adsorbed structures on both pristine and defective MgAl2S4 surfaces are negative, indicating good stability for all configurations. The adsorption of transition metal atoms leads to the transformation of the MgAl2S4 monolayer from non-magnetic semiconductor to magnetic semiconductor, bipolar magnetic semiconductor, half-metal, and metal. In addition, there is a good modulation of the bandgap. The significant charge transfer between MgAl2S4 monolayer and the transition metal atoms implies the formation of chemical bonds. The lower work function implies that the MgAl2S4 and transition metal atom adsorption structures benefit electron emission. Thus, research has revealed that the adsorption configurations of transition metal atoms on the surface of MgAl2S4 monolayer offers new possibilities for the fabrication of spintronic devices, the design of highly efficient catalysts, and the application of emission devices.

Theoretical model of donor–donor and donor–acceptor energy transfer on a nanosphere

In this study, we introduce a novel advancement in the field of theoretical exploration. Specifically, we investigate the transfer and trapping of electronic excitations within a two-component disordered system confined to a finite volume. The implications of our research extend to energy transfer phenomena on spherical nanoparticles, characterized by randomly distributed donors and acceptors on their surface. Utilizing the three-body Padé approximant technique, previously employed in single-component systems, we apply it to address the challenge of trapping within our system. To validate the robustness of our model, we conduct Monte Carlo simulations on a donor–acceptor system positioned on a spherical nanoparticle. In particular, very good agreement between the model and Monte Carlo simulations has been found for donor fluorescence intensity decay.

PH Sensitivity of YFPs is Reduced Upon AlphaRep Binding: Proof of Concept in Vitro and in Living Cells.

Yellow fluorescent proteins (YFPs) are commonly used in biology to track cellular processes, particularly as acceptors in experiments using the Förster Resonant Energy Transfer (FRET) phenomenon. However, their fluorescence intensity is strongly pH-dependent, limiting their utility in acidic environments. Here, we explore the pH sensitivity of YFPs upon binding with an artificial repeat protein (αRep) both in vitro and in living cells. We show that αRep binds to Citrine, with high affinity in the nanomolar range at physiological and acidic pHs, leading to increased thermal stability of the complex. Moreover, αRep binding reduces Citrine's pKa by 0.75 pH units, leading to a decreased sensitivity to pH fluctuations. This effect can be generalized to other YFPs as Venus and EYFP in vitro. An efficient binding of αRep to Citrine has also been observed in living cells both at pH 7.4 and pH 6. This interaction leads to reduced variations of Citrine fluorescence intensity in response to pH variations in cells. Overall, the study highlights the potential of αReps as a tool to modulate the pH sensitivity of YFPs, paving the way for future exploration of biological events in acidic environments by FRET in combination with a pH-insensitive cyan donor.

Upconversion, downshifting, quantum cutting and back energy trasfer from Yb3+ to Er3+ in Er3+/Yb3+ co-doped CaTiO3 phosphor, intense NIR generation for communication

The perovskite based phosphor materials are widely used to increase the efficiency of solar cells. In this work, Er3+ doped and Er3+/Yb3+ co-doped CaTiO3 perovskite phosphor samples have been synthesized by solid state reaction technique at 1473 K. The phosphor samples show orthorhombic phase with Pnma (62) space group. The average crystallites and particles size of CaTiO3 are increased in presence of Er3+ and Yb3+ ions. Er3+ doped CaTiO3 phosphor samples give downshifting emission under 379 nm excitation. Though upconversion emission is seen in Er3+ under 980 nm excitation without Yb3+ ions in this host. The emission intensity of Er3+ ion is enhanced by 46 and 16 times for green and red emissions, respectively in presence of Yb3+. An intense quantum cutting (QC) emission is observed at 980 nm in presence of Yb3+ in CaTiO3:0.5Er3+ phosphor under 379 nm excitation. The QC efficiency has been found to be 119 % for CaTiO3:0.5Er3+/5 Yb3+ phosphor. Further an interesting phenomenon of back energy transfer (BEnT) from Yb3+ to Er3+ giving an intense NIR emission from Er3+ at 1002 and 1550 nm have been observed. The phosphor sample also shows an intrinsic optical bistablity (IOB) by upconversion. Thus, the prepared phosphor samples may be useful to increase the efficiency of c-Si solar cell, NIR emission for communication, bistable material and green light emitting source.

S+E+O-band luminescence and enhancement in Nd3+/Tm3+/Ce3+ doped tellurite glass

A new, to our knowledge, doped combination of Nd3+, Tm3+, and Ce3+ ions was developed in tellurite glass with a fundamental composition of TeO2-ZnO-WO3-Bi2O3, and the structural, thermal, and especially near-infrared (NIR) luminescent properties in O-, E-, and S-bands were explored. The XRD pattern confirmed the amorphous nature of synthesized tellurite glass, the Raman spectrum disclosed different structural units that make up the glass network, the DSC curve confirmed good host thermal stability, while XPS measurement revealed that cerium mainly exists in the trivalent form in a glass network. Upon being pumped with an 808 nm laser, a 1.34 µm band fluorescence from Nd3+:4F3/2level→4I13/2 level transition and a 1.46 µm band fluorescence from Tm3+:3H4level→3F4 level transition were observed, which in turn formed a wide luminescence band from 1260 to 1560 nm in the tellurite glass containing both Nd3+ and Tm3+ ions owing to their spectral overlapping. The measured full width at half maximum (FWHM) for the aforementioned wideband luminescence was about 203 nm with Nd2O3 and Tm2O3 concentrations of 0.015 mol. % and 0.5 mol. %, respectively, and exhibited a further ∼60% increase in peak intensity after the incorporation of 0.4 mol. % amount of CeO2, which arises from the phenomena of cross relaxation and energy transfer among the three trivalent rare earth ions. The experimental evidence presented in this work shows that tellurite glass containing Nd3+, Tm3+, and Ce3+ has potential as an active material for S-, E-, and O-band wideband luminescence.

Multi-step FRET systems based on discrete supramolecular assemblies.

Fluorescence resonance energy transfer (FRET) from the excited state of the donor to the ground state of the acceptor is one of the most important fluorescence mechanisms and has wide applications in light-harvesting systems, light-mediated therapy, bioimaging, optoelectronic devices, and information security fields. The phenomenon of sequential energy transfer in natural photosynthetic systems provides great inspiration for scientists to make full use of light energy. In recent years, discrete supramolecular assemblies (DSAs) have been successively constructed to incorporate donor and multiple acceptors, and to achieve multi-step FRET between them. This perspective describes recent advances in the fabrication and application of DSAs with multi-step FRET. These DSAs are categorized based on the non-covalent scaffolds, such as amphiphilic nanoparticles, host-guest assemblies, metal-coordination scaffolds, and biomolecular scaffolds. This perspective will also outline opportunities and future challenges in this research area.

Energy analysis of a nonlinear gas-spring dynamic vibration absorber subjected to seismic excitations

Nonlinear control methods and devices have been widely used in seismic vibration reduction of engineering structures. A nonlinear gas-spring dynamic vibration absorber (NGSDVA) has been recently proposed by the authors and demonstrates a wideband vibration suppression capability across various excitation amplitudes. In this study, an energy analysis method for a multi-story structure with NGSDVA attached under seismic excitation is proposed through experimental and numerical simulation analysis. The energy distribution of the controlled structure and the energy transmission process between the main structure and the damping system are analyzed. It is found that the intermodal energy transfer phenomenon occurs in the five-story steel frame structure during the energy transmission process, while the first-order modal energy is converted to high-order modal energy simultaneously. A series of energy-based parametric studies are further conducted, and the consistency of the parameter influence rules under four different seismic waves is proved, indicating the advantages of energy evaluation indicators for optimizing the design of this nonlinear damper with amplitude-frequency characteristics.

Natural Pigments-Based Two-Component White Light Emitting Systems.

In this paper, a new class of two component white light emitting systems viz, JaB (java plum + beetroot) {I}, and CaB (carrot + beetroot) {II} were developed through resonance energy transfer (RET) phenomenon by using a fruit (java plum) and two vegetable (carrot and beetroot) extracts. In these white light emitting systems, java plum and carrot are the donors while beetroot is the acceptor. The primary fluorescent pigments present in the natural extracts (i.e., anthocyanin in java plum, β-carotene in carrot, and betanin in beetroot) were responsible for the white light emission. The CIE (Commission Internationale d'Eclairage) coordinates for I and II were {0.32, 0.34} and {0.33, 0.33}, respectively, in solution phase. Interestingly, the white light emission (WLE) was also achieved in agar-agar gel medium. In gel medium, the CIE values were {0.31, 0.34} and {0.33, 0.32} for I and II, respectively. The donor-acceptor distance (r) for I and II were found to be 0.5 and 0.4nm, respectively. Furthermore, the rate of energy transfer was also quantified with the values of 2.78 × 109s-1 for JaB (I) and 1.02 × 108s-1 for CaB (II) systems. The mechanistic investigation of the two white light systems was further supported by DFT studies.

Photoluminescence properties of double perovskite Ca2LuTaO6:Bi3+/Sm3+ white light emitting phosphors

The high-temperature solid state reaction approach was used to successfully synthesize novel tunable-color emitting Ca2LuTaO6 phosphors with double perovskite structure that were un-doped, single-doped, and co-doped with Bi3+/Sm3+ ions. The crystal structure, microstructure, steady-state photoluminescence, time-resolved luminescence measurements, and thermal quenching features of the material were studied. The density functional theory method was used to compute the band gap of the Ca2LuTaO6, and Ca2LuTaO6: Bi3+, Sm3+ phosphors. The blue emission at 407 nm (with 313 nm excitation) is due to the host's luminescence, while the cyan emission at 480 nm (under 365 nm excitation) is related to the distinctive 3Pn − 1S0 transitions (n = 0, 1, 2) of Bi3+. Similarly, efficient red emission is observed in the case of Sm3+ single-doped Ca2LuTaO6 phosphors. In addition, the Ca2LuTaO6: 0.04Bi3+, 0.05 S m3+ phosphors exhibit energy transfer phenomena and have excellent thermal stability, the fluorescence intensity at 150 °C maintains 73% of that at 25 °C and has a small chromaticity shift. The intense blue emission at 407 nm was effectively converted to cyan, red, and white light through doping with Bi3+ and Sm3+, and the resulting energy transfer. The results obtained confirm that Ca2LuTaO6: Bi3+, Sm3+ phosphors as a single matrix have great potential for high-power WLED applications.

An Enhanced Nonlinear Energy Sink for Hybrid Bifurcation Passive Mitigation and Energy Harvesting From Aeroelastic Galloping Phenomena

Abstract Galloping is a self-excited vibration problem that structures immersed in fluid flow can experience. Due to its essential nonlinear phenomena, the structure exhibits limit cycle oscillations (LCOs), which, at high levels, can lead to failure of the systems. This work proposes an investigation of electromagnetic-enhanced nonlinear energy sinks (NES-EH) for the hybrid mitigation of aeroelastic LCOs and energy harvesting. The study focuses on a prismatic bluff body with a linear suspension immersed in the airflow, using classical steady nonlinear modeling for aerodynamic loads. The conventional NES approach is adopted, employing cubic stiffness and linear damping. Additionally, a linear electromagnetic transducer is included in the assembly for the energy harvesting process. By combining the method of multiple scales with the Harmonic Balance Method, analytical solutions are derived to characterize the system's dynamics under the influence of the device. The different response domains and their respective boundaries induced by the NES-EH are characterized based on the bifurcation diagrams. Furthermore, a slow invariant manifold (SIM) characterization is presented for each induced response domain, and its significant features are discussed. Parametric studies are carried out based on bifurcation analyses to assess the effect of NES-EH parameters on the galloping system dynamics, which allows for designing the absorber parameters. The electrical resistance is optimized to maximize the harvested power. The optimal design of NES-EH is then compared with classical energy harvesting solutions for the galloping problem. Additionally, a thorough analysis of the Target Energy Transfer phenomenon is performed.

Numerical simulations of Williamson fluid containing hybrid nanoparticles via Keller box technique

In this investigation, a Williamson hybrid nanoliquid flow over a stretchy surface has been considered. Furthermore, the convective boundary condition is incorporated for the analysis. In view of the practical applications thermal radiation is used to analyze the energy transfer phenomenon. The momentum and energy expressions are solved numerically by employing the KB approach (Keller Box Technique). The energy transfer rate has been discussed in the table. Further, velocity, temperature and Nusselt number impacts against thermal radiations are discussed in detail. This research portrayed that with the growth of suction/injection factor, the energy transmission and skin friction increase. Moreover, the heat transfer rate decreases for both (Al2O3+CuO)/SA\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${(Al}_{2}{O}_{3}+CuO)/SA$$\\end{document} and Al2O3/SA\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${Al}_{2}{O}_{3}/SA$$\\end{document} the on the growth of Weissenberg parameter. In the same vain heat transfer rate improves for the increment in the convective parameter.

Energy transfer mechanism and luminescence properties of green phosphors Sr2YF7: Dy3+, Tb3+

In this study, color-adjustable Sr2YF7: xDy3+, and yTb3+ light-emitting phosphors were synthesized through the hydrothermal method. Systematic experiments were performed to determine the optimal doping concentration for Sr2YF7: xDy3+ phosphor with x = 0.03, resulting in a distinctive light blue emission band attributed to the 4F9/2 → 6H15/2 transition. The energy transfer within the double-doped system of Sr2YF7: Dy3+, yTb3+ (y = 0, 0.06–0.1) was examined by analyzing spectral overlap and reductions in emission lifetimes. Moreover, the mechanism governing this energy transfer phenomenon was investigated. The concentration proportion of Dy3+/Tb3+ in Sr2YF7 phosphors was modulated to achieve color modulation, transitioning from light blue to vibrant green emissions in Sr2YF7: Dy3+, Tb3+ samples. The intensity of green emission increased with increasing Tb3+ ion concentrations because of the dynamics of energy migration from Dy3+ to Tb3+ levels (4F9/2 + 7F6 → 6H15/2 + 5D4). Based on calculations using steady-state rate equations, Tb3+ ion doping effectively reduced ionic spacing and consequently amplified the green emission. Furthermore, the results indicated that the luminous intensity ratio of Sr2YF7: 0.03Dy3+, 0.07 Tb3+ phosphors at 423/303K was notably high at 93.59 %, indicating high thermal stability. Thus, Sr2YF7 phosphors co-doped with Dy3+ and Tb3+ emerge as potential candidates for application in advanced illumination technologies.

Energy transfer in near-infrared photoluminescent PbS/CdS quantum dot-based three-dimensional networks and films.

Nanocrystal (NC) assemblies, such as films or NC-based three-dimensional networks, provide insight into the nanoscopic properties of their building blocks, and are macroscopic materials. In NC assemblies in general, interactions between the building blocks have to be considered, since a decrease of the distance between the NCs allows phenomena such as energy transfer to occur. Novel quantum dot-based aerogels with optical properties in the near-infrared (NIR) region are not characterized in terms of these important properties in the literature, while the structural complexity of these networks raises questions about the interactions within. Since knowledge about the physical phenomena is vital for applications, we here investigate the photoluminescence (PL) of PbS/CdS QD-based assemblies, namely drop-cast films and aerogels with steady-state measurements at cryogenic temperatures and time-resolved measurements at room temperature. We find multiple emissive in-gap states (IGS), and a correlation between the number of nearest QD neighbors, the distance between the QDs in the assemblies and the non-radiative recombination rate by linking the observations to different energy transfer phenomena.

Polymorphism and flexibility of six-porphyrin nanorings in the solid state.

Butadiyne-linked porphyrin nanorings are fascinating nanometer-sized platforms for exploring electronic delocalization and aromaticity, and they mimic ultra-fast photosynthetic energy-transfer phenomena in plants and purple bacteria. However, little is known about how they interact in the solid state. Here, we compare the crystal structures of several pseudopolymorphs of a six-porphyrin nanoring template complex, and report the structure of the free-base nanoring co-crystallized with C60. The structures differ not only in the molecular packing; they also feature different molecular conformations. The template is slightly too small for the cavity of the nanoring, and this size mismatch can be accommodated by two types of distortion: either the zinc atoms are pulled away from the planes of the porphyrins, or the nanorings contract by adopting a ruffled conformation, with butadiyne links alternatingly above and below the plane of the six zinc centers. The template-bound ring forms sheets and tubular stacks with interdigitated aryl groups. Upon demetallation, the nanoring becomes more flexible, adopting a highly elliptical conformation on co-crystallization with C60. The structure of this free-base nanoring features infinite solvent filled channels with a channel diameter of 13.5 Å. The high porosity of these materials points towards possible applications as porous light-harvesting frameworks.

Переменный электрический ток в угольных шахтах: электромагнитная энергия и превращение её в электрический ток

The article addresses the challenge of improving the competence and basic knowledge of specialists working with alternating electric current. The purpose of this work is to explain the magnetic properties of substance, generation of magnetic field and electric current with due account for the known laws of physics and the Quantum theory. We believe that addressing these tasks needs to begin with the energy produced by the magnet. The method of inducing electric energy using magnetic field of a permanent magnet is chosen as the research subject. The historical mythological bases of interpreting the induction of electric energy are shown. Modern instruments prove that the magnetic field is the electromagnetic emissions of magnets. A hypothesis regarding the origin of magnetic properties of substance is developed based on analysis of the known magnetic properties of alpha-iron. Two features of the magnetic properties of substance have been revealed, which differ from Ampere's ideas. The first is the local volume of atoms combined by short-acting covalent bonds, forming a natural crystalline or artificially elongated structure. The second is that the frequency of electromagnetic emissions by the valence electrons of all the atoms in Hertz is approximately the same. The total radiation of energy by all the atoms in local formations generates a magnetic field. The hypothesis is confirmed by circuits and information on instruments that measure the emission of magnets in Hertz. When the energy absorbed by electrons increases, the bond between atoms is broken and magnetic emissions cease. All substances in liquid and solid aggregate state begin to radiate electromagnetic emissions to other substances under the impact of external electromagnetic emissions. This is confirmed by photographic evidence of the performed experiments. A hypothesis is proposed, which differs from the ideas about the movement of free electrons by the fact that the formation of electric current is the result of absorbing electromagnetic emissions of the magnet by valence electrons of the electrical conductor and their transfer into the electric network. The physical phenomena of energy transfer between the transformer windings in an electric circuit prove that electric current is a concentrated flow of electromagnetic emissions, which are a wave form of energy.

Augmentation of the photoluminescence intensity via the incorporation of Eu3+ ions into single-phase Ba2La4Zn2O10 nanocrystalline material for advanced photonic applications

Strong red-emission is observed in the new Eu3+ activated Ba2La4Zn2O10 nanocrystalline material series fabricated via solution combustion methodology. A tetragonal crystal framework withspace group I4/mcm (140) having irregularly shaped grains with sizes between 33 and 62 nm is formed. Morphological aspects are examined via scanning and transmission electron microscopy (SEM and TEM). On near-UV excitation, the photoluminescence spectrum presents a fair red emission at 16129 cm−1 wavenumbers consistent with the electronic transition 5D0→7F2. The energy transfer phenomena are also discussed. The highest luminous intensity is observed for 5.0 mol% of Eu3+ composition with 394 nm excitation. d-d exchanges authorized the presence of the concentration quenching phenomenon. Diffuse reflectance spectroscopy was taken into use to explore the energy band gap which lies in the semiconductor domain. The CIE coordinates lay in the reddish zone of the chromaticity plot, thus confirming their latent contention in pc-WLEDs and other advanced photonic applications.

Unlabelled LRET biosensor based on double-stranded DNA for the detection of anthraquinone anticancer drugs.

Based on upconversion nanoparticles (UCNPs) as energy donor and herring sperm DNA (hsDNA) as molecular recognition element, an unlabelled upconversion luminescence (UCL) affinity biosensor was constructed for the detection of anthraquinone (AQ) anticancer drugs in biological fluids. AQ anticancer drugs can insert into the double helix structure of hsDNA on the surface of UCNPs, thereby shortening the distance from UCNPs. Therefore, the luminescence resonance energy transfer (LRET) phenomenon is effectively triggered between UCNPs and AQ anticancer drugs. Hence, AQ anticancer drugs can be quantitatively detected according to the UCL quenching rate. The biosensor showed good sensitivity and stability for the detection of daunorubicin (DNR) and doxorubicin (ADM). For the detection of DNR, the linear range is 1-100 μg·mL-1 with a limit of detection (LOD) of 0.60 μg·mL-1, and for ADM, the linear range is 0.5-100 μg·mL-1 with a LOD of 0.38 μg·mL-1. The proposed biosensor provides a convenient method for monitoring AQ anticancer drugs in clinical biological fluids in the future.