Energy Storage Technologies Research Articles

Efficient sodium ion transport enhanced by anionophilic sites in polymer-supported plastic crystal electrolyte for high performance sodium metal anode

The design of sodium metal batteries (SMBs) is seen as an excellent solution to solve the request of next-generation energy storage technologies with high energy density, high safety, low cost, and environmental friendliness. However, the direct use of sodium metal as an anode produces the dendritic sodium, which harms the normal operation of battery. Inspired by solid-state lithium metal batteries, solid-state electrolyte (SSE) designed for SMBs effectively solves this shortcoming. Herein, a novel SSE with mask-based polymer membrane supporting plastic crystal electrolyte with ZIF-67 (MPPZ) is designed. The experimental results and density functional theory (DFT) calculations indicate that the addition of ZIF-67 in MPPZ electrolyte availably fixes TFSI− and achieves high Na+ transference number. Additionally, a protective layer of NaF is formed in situ on the surface of sodium metal to avoid side reactions between Na and MPPZ electrolyte while further guide the uniform deposition of Na. Accordingly, Na||Na symmetric battery with NaF-coated Na metal anode and MPPZ electrolyte has a stable deposition and stripping of Na for 3000 h. The assembled room temperature solid-state sodium-sulfur battery (RTSSSSB) exhibits a good cycle stability. This study provides an innovative thinking for the construction of high performance dendrite-free SMBs.

Fast kinetics for lithium storage rendered by Li3VO4 nanoparticles/porous N-doped carbon nanofibers

Li3VO4 (LVO) has been recognized as an alternative anode material for lithium-ion batteries (LIBs) because of its appropriate lithium storage potential and capacity merits. However, its practical application is seriously hindered by slow reaction kinetics stemming from poor electronic conductivity. Herein, Li3VO4/porous N-doped carbon nanofibers (LVO/PNC NFs) are firstly designed and fabricated via an electrospinning method, utilizing the thermal decomposition characteristics of polylactic acid (PLA). The porous N-doped carbon nanofibers provide efficient electrolyte diffusion paths and facilitate ion transport. In addition, LVO nanoparticles are uniformly dispersed along the nanofibers to effectively inhibit particle aggregation. The obtained LVO/PNC NFs are evaluated as anodes for LIBs and deliver high reversible capacity of 768 mAh g−1 after 300 cycles at 0.2 A g−1, along with excellent rate capability (average capacity of 355 mAh g−1 at 8 A g−1 after 6 periodic rate testing) and long cycling life (286 mAh g−1 after 2000 cycles at 4 A g−1). The special porous nanofiber represents an effective strategy for improving the electronic conductivity, inhibiting particle aggregation, and ensuring rapid ion/charge transport towards advanced energy storage technologies.

Core-shell Cu7S4@PDA nanoboxes as a novel cathode for aluminum batteries

Battery energy storage technology is key to unlocking green renewable power's full potential. Cathode material is a key factor affecting the performance of aluminum batteries (ABs). In this paper, a novel core-shell Cu7S4@PDA nanobox cathode material for ABs was designed and prepared by a reasonable method. At 0.2 A/g, the Cu7S4@PDA nanoboxes can provide a reversible capacity of 142 mAh/g after 100 cycles, and the coulombic efficiency (CE) of almost all cycles is maintained around 100 %. Even at 3 A/g, Cu7S4@PDA can deliver a capacity of 68 mAh/g. The results show that PDA coating reduces the irreversible dissolution of S in Cu7S4, prevents the pulverization and agglomeration of Cu7S4, and improves its structural stability and conductivity.

Advances in the Application of Graphene in Lithium-ion Batteries

The search for effective energy storage options has escalated due to the rising global energy demands and environmental concerns. Lithium-ion batteries (LIBs) emerge as a key technology. However, the performance of traditional LIBs still needs to be improved. Therefore, choosing new nanomaterials for the modification of LIBs has become an effective solution. Graphene, as a nanomaterial, is an excellent candidate material for modification. This paper delves into the application of graphene in enhancing the performance of LIBs. Graphene, with its superior electrical conductivity and substantial specific surface area, offers the potential to enhance the performance of both anode and cathode materials in LIBs. This can lead to significant improvements in the overall cycle life, energy density, and power density of these batteries. This work emphasizes the application of graphene in cathode and anode materials. In cathode materials, the layered structure of graphene enables lithium-ion with high theoretical capacity. Meanwhile, graphene helps improve the electron and lithium ion mobility of anode materials. Despite the promising developments, challenges such as lithium loading capacity and coulombic efficiency still remain. The continued exploration of graphene applications is expected to drive LIBs to unprecedented performance metrics. This is in line with the global quest for sustainable and efficient energy storage technologies.

Configurational Design of a Hybrid System Based on an Air–Water Heat Pump and Biomass Boiler for a Rural Dwelling

Hybrid energy systems combine multiple energy sources and storage technologies to enhance performance and meet diverse energy needs. Hybrid heat pump systems are particularly suitable for heating and cooling buildings in rural areas. Air-source heat pumps have two well-known disadvantages during the coldest period of the year, when the building’s heating load is at its peak: the heat pump’s capacity is reduced and it needs to perform defrost cycles. A potential solution is to size the heat pump to cover only a portion of the peak load and to use a second heat generator in a hybrid heat pump system. There is a gap in the literature regarding the configurational analysis of hybrid heat pump (HHP) systems, particularly in terms of combining heat pumps and biomass boilers, and evaluating their efficiency, economic aspects, and environmental impact. Thus, in this research, a dynamic model of a HHP system, consisting of an air-to-water heat pump paired with a biomass boiler as a backup, is presented. Various configurations of the HHP system have been developed to evaluate key performance indicators, such as efficiency, emissions, operational costs, and other relevant factors. The findings of this paper indicate that the energy performance of HHP systems is significantly affected by the system layout, heat pump size, cut-off temperature, and the control algorithm used to activate the heat generators. Moreover, series operation of HHP systems is not only more efficient than parallel operation but also results in lower emissions and reduced operation costs. As expected, the energy loss associated with defrost cycles significantly impacts the overall performance of a hybrid system based on an air-source heat pump. Finally, the impact of the cut-off temperature on the key parameters in the configuration analysis was examined, and the optimal performance of the HHP system, in terms of minimizing operational costs and emissions, was depicted using a heat map diagram.

Economic evaluation of kinetic energy storage systems as key technology of reliable power grids.

In recent years, energy-storage systems have become increasingly important, particularly in the context of increasing efforts to mitigate the impacts of climate change associated with the use of conventional energy sources. Renewable energy sources are an environmentally friendly source of energy, but by their very nature, they are not able to supply the required amount of energy in a uniform distribution. This study evaluated the economic efficiency of short-term electrical energy storage technology based on the principle of high-speed flywheel mechanism using vacuum with the help of an innovative approach based on life cycle cost analysis (LCC). The innovative potential of high-speed flywheel energy storage systems (FESS) can be seen in increasing the reliability of the electricity transmission system with the possibility of providing control power to compensate for residual loads caused by volatile renewable power sources and power sinks. Based on the research conducted, the LCC method was selected in this study as the most appropriate method to evaluate the economic efficiency of a high-speed FESS used to compensate for short-term fluctuations in an upgraded electric transmission system. As a result, the adjusted LCC per MWh values were compared with the average intra-hour margin realisable in the Intra-Day OTE Market, while the margin calculation also considered the efficiency of the inertial storage. Under the modelled technical and economic conditions, it was found that a high-speed FESS project that can compensate for short-term fluctuations in the electricity transmission system can be economically efficient in the Czech Republic.

Current development, optimisation strategies and future perspectives for lead-free dielectric ceramics in high field and high energy density capacitors.

To meet the United Nations' sustainable development goal of affordable and clean energy, there has been a growing need for low-cost, green, and safe energy storage technologies. High-field and energy-density capacitors have gained substantial attention from academics and industry, particularly for power electronics, where they will play a key role in optimising the performance of management systems in electric vehicles. The key figure of merit, energy density (Wrec), for high-field applications has dramatically increased year-on-year from 2020 to 2024, as evidenced by over 250 papers, demonstrating ever larger Wrec values. This review briefly introduces the background and principles of high energy density ceramics, but its focus is to provide constructive and comprehensive insight into the evaluation of Wrec, Emax, ΔP, and η, and more importantly, the normalised metrics, Wrec/Emax and Wrec/ΔP in lead-free dielectric ceramics. We also present several optimisation strategies for materials modification and process innovation that have been recently proposed before providing perspectives for the further development of high-field and high-energy density capacitors.

An Evaluation of the Levelised Cost of Storage of Buoyancy Energy Storage Technology at Smaller Scales

Buoyancy Energy Storage Technology (BEST) offers a promising solution to the intermittency of renewable energy sources like wind and solar. This paper aims to evaluate the feasibility of using BEST for small- scale energy storage applications. The methodology involves calculating the levelized cost of storage (LCOS) and energy capacity of two BEST variants: Fabric BEST and Reeling BEST. Results indicate that Fabric BEST can store 96 kWh per cycle with an LCOS of $356.73/MWh, while Reeling BEST stores less energy at a significantly higher cost of $683/MWh.

Thermo-economic analysis on trans-critical compressed CO2 energy storage system integrated with the waste heat of liquid-cooled data center

Compressed CO2 energy storage (CCES) technology has the advantages of high energy storage density, low economic cost, low carbon emission, which is suitable for the construction of large-scale and long-time energy storage system. Besides, as a scene with massive heat, the electricity consumption of servers in data center is mostly converted into heat. Thus, the purpose of this work is to integrate a trans-critical compressed CO2 energy storage system with the waste heat of data centers, so as to improve the system performance and reduce the operating cost of data center. Based on different operating principles of compressors, a single-stage compression system (System-CP) and a double-stage compression system (System-VP) are constructed. To analyze and compare the energy and exergy performance of these two systems under design conditions, a quasi-dynamic model is developed by considering the variations of pressure and temperature in the storage tank. On this basis, an economic model is developed to obtain the economy performance for the systems. The obtained results show that the round-trip efficiency (RTE) of System-CP and System-VP are 64.67 % and 67.41 %, respectively. For the energy storage capacity 15 MW × 5 h, volumes of high-pressure S-CO2 storage tank are 314,387.51 m3 and 287,982.91 m3 for System-CP and System-VP, respectively. Thereby, the energy storage density (ESD) of System-CP and System-VP are 0.24 kW·h/m3 and 0.26 kW·h/m3, respectively. Meanwhile, the total capital cost (TCC) is $477.84 × 106 for System-CP, and $437.41 × 106 for System-VP, and the corresponding payback period (PBP) are 14.76 years and 12.39 years respectively. Further, the effect of key parameters on systems performance is revealed. The results show that with the decrease of slip-pressure range decreases, RTE, TCC and the volume of storage tanks increase linearly.

An investigation of the electrochemical characteristics of NiO-Co3O4/graphite/PVDF composites for the development of a supercapacitor with ultrahigh stability

Abstract Supercapacitor is a groundbreaking electrical energy storage technology that falls between batteries and dielectric capacitors which has undergone significant progress in recent years. Among the several elements influencing a supercapacitor's capacitance, the choice of electrode materials plays a crucial role. Nanomaterials formed from transition metal oxides with incorporated 3-D graphite are said to possess high capacitance, conductivity, increased area of active site, distinct redox properties, and several valence shells, making them an appropriate material for electrode synthesis. Therefore, in this study, three composites of NiO and Co3O4 are prepared in the ratio 2:8, 3:7 and 4:6 using facile sol-gel method. To the prepared composites, graphite and PVDF are added in equal quantities. The resultant samples are characterized using XRD, SEM, FTIR and UV-Vis spectroscopy. The samples are further integrated on an FTO electrode and subjected to CV, GCD and EIS for electrochemical study. The highest specific capacitance is obtained for NiO and Co3O4 composite in the ratio 3:7 and is equal to 156.66F/g at a sweep rate of 10 mV/s. This material is further used for a two-electrode study to check the feasibility of a symmetric solid-state device, which demonstrated a specific capacitance of 36F/g with 100% capacitive retention.

UV‐Triggered In Situ Formation of a Robust SEI on Black Phosphorus for Advanced Energy Storage: Boosting Efficiency and Safety via Rapid Charge Integration Plasticity

AbstractBlack phosphorus (BP) emerges as a highly promising electrode material for next generation of energy‐storage systems. Yet, its full potential is hindered by the instability of the solid‐electrolyte interphase (SEI) and the inflammability of its liquid systems. Here a pioneering UV‐induced in situ strategy is introduced for SEI construction, which leverages rapid electron supply to fracture sulfur‐dihalide bonds. This technique yields internal dihalide inorganic components and an external polymer segment, with any excess organic material being purged through pores. The (E)‐2‐chloro‐4‐((3′‐chloro‐4′‐hydroxyphenyl)diazinyl)phenyl acrylate (CA), with chlorine‐terminated groups, is initially in situ transformed into a flame‐retardant phenyl carboxylic acid (PCA), and then encapsulated within an ultrathin BP nanostructure, further nested in nitrogen (N), boron (B) co‐doped carbon (C) sheets that accommodate cobalt (Co) single atoms/nanoclusters (Co‐NBC). The Co‐NBC@BP@PCA construct demonstrates an impressive initial Coulombic efficiency (ICE) of 99.1% and maintains exceptional stabilities in terms of mechanical, chemical, and electrochemical performancecritical for prolonged cycle and calendar life. This research sheds light on the interplay between the rapid charge supply integrated in situ plasticity (RSIP) approach and the proactive establishment of an artificial SEI layer, offering profound insights into enhancing the durability and providing a solid foundation for advancements in energy storage technology.

Covalent Carbide Interconnects Enable Robust Interfaces and Thin SEI for Graphite Anode Stability under Extreme Fast Charging.

Carbonaceous and carbon-coated electrodes are ubiquitous in electrochemical energy storage and conversion technologies due to their electrochemical stability, lightweight nature, and relatively low cost. However, traditional reliance on conductive additives and binders leads to impermanent electrical pathways. Here, a general approach is presented to fabricate robust electrodes with a progressive failure mechanism by introducing carbide-based interconnects grown via carbothermal conversion of (5 wt%) titanium hydride nanoparticles. This method concurrently enhances both electrical and mechanical properties within the electrode architecture. The resulting chemical bonding between active materials establishes a novel mechanism to maintain stable electrical pathways during cycling. Employed as Li-ion battery anodes, these electrodes exhibit improved cyclability, achieving 80% capacity retention after 800 fast-charge cycles at moderate loading (1 mAh cm- 2). High loading cells with areal capacity of 3 mAh cm-2 show significantly improved cycle lifeover the same number of cycles. This performance improvement is attributed to the absence of significant impedance growth and a thinner solid electrolyte interphase (SEI) layer formed at high current densities (4C) as demonstrated by X-ray photoelectron spectroscopy and transmission electron microscopy studies. The enhanced conductivity facilitates SEI formation, lowering ionic impedance and mitigating lithium plating, ultimately leading to the reported extended cycle life.

Predicting interfacial tension in brine-hydrogen/cushion gas systems under subsurface conditions: Implications for hydrogen geo-storage

Underground hydrogen storage (UHS) critically relies on cushion gas to maintain pressure balance during injection and withdrawal cycles, prevent excessive water inflow, and expand storage capacity. Interfacial tension (IFT) between brine and hydrogen/cushion gas mixtures is a key factor affecting fluid dynamics in porous media. This study develops four machine learning models— Decision Trees (DT), Random Forests (RF), Support Vector Machines (SVM), and Multi-Layer Perceptrons (MLP)—to predict IFT under geo-storage conditions. These models incorporate variables such as pressure, temperature, molality, overall gas density, and gas composition to evaluate the impact of different cushion gases. A group-based data splitting method enhances the realism of our tests by preventing information leakage between training and testing datasets. Shapley Additive Explanations (SHAP) reveal that while the MLP model prioritizes gas composition, the RF model focuses more on operational parameters like pressure and temperature, showing distinct predictive dynamics. The MLP model excels, achieving coefficients of determination (R2) of 0.96, root mean square error (RMSE) of 2.10 mN/m, and average absolute relative deviation (AARD) of 3.25%. This robustness positions the MLP model as a reliable tool for predicting IFT values between brine and hydrogen/cushion gas (es) mixtures beyond the confines of the studied dataset. The findings of this study present a promising approach to optimizing hydrogen geo-storage through accurate predictions of IFTs, offering significant implications for the advancement of energy storage technologies.

Facilitating Ion Storage and Transport Pathways by In Situ Constructing 1D Carbon Nanotube Electric Bridges between 2D MXene Interlayers.

Multiple van der Waals (vdW) gaps invoke abundant opportunities for contriving artificial architectures and tailoring desired properties via the intercalation route beyond the reach of conventional concepts. Intriguingly, the electrochemical intercalation strategy can precisely and reversibly tune the intercalation stage of charged functional species. This study presents a valid structural editing protocol facilitated by electrochemical intercalation to engineer MXene interlayers, ultimately incorporating in situ constructed carbon nanotube (CNT) electric bridges for enhanced ion storage and transport pathways. The method allows for the precise modulation of electrochemical forces to tailor materials for specific applications. Deep intercalation and in situ growth processes establish robust anchoring sites and connectivity hubs between MXenes and CNTs, ensuring structural homogeneity and stability in advanced electrode materials. The results demonstrate the effectiveness of electrochemistry-mediated interlayer nanoengineering in MXenes, offering a versatile approach to design vdW heterostructures with tailored functionalities for energy storage and conversion applications. This work highlights the potential of electrochemical modulation in advancing materials engineering strategies for next-generation energy storage technologies.

A review on progress and prospects of diatomaceous earth as a bio-template material for electrochemical energy storage: synthesis, characterization, and applications

AbstractThis comprehensive review explores the remarkable progress and prospects of diatomaceous earth (DE) as a bio-template material for synthesizing electrode materials tailored explicitly for supercapacitor and battery applications. The unique structures within DE, including its mesoporous nature and high surface area, have positioned it as a pivotal material in energy storage. The mesoporous framework of DE, often defined by pores with diameters between 2 and 50 nm, provides a substantial surface area, a fundamental element for charge storage, and transfer in electrochemical energy conversion and storage. Its bio-templating capabilities have ushered in the creation of highly efficient electrode materials. Moreover, the role of DE in enhancing ion accessibility has made it an excellent choice for high-power applications. As we gaze toward the future, the prospects of DE as a bio-template material for supercapacitor and battery electrode material appear exceptionally promising. Customized material synthesis, scalability challenges, multidisciplinary collaborations, and sustainable initiatives are emerging as key areas of interest. The natural abundance and eco-friendly attributes of DE align with the growing emphasis on sustainability in energy solutions, and its contribution to electrode material synthesis for supercapacitors and batteries presents an exciting avenue to evolve energy storage technologies. Its intricate structures and bio-templating capabilities offer a compelling path for advancing sustainable, high-performance energy storage solutions, marking a significant step toward a greener and more efficient future. Graphical Abstract

ZIF‐67/ZIF‐8 and its Derivatives for Lithium Sulfur Batteries

AbstractLithium–sulfur batteries (LSBs), renowned for their superior energy density and the plentiful availability of sulfur resources, are progressively emerging as the focal point of forthcoming energy storage technology. Nevertheless, they presently confront fundamental challenges including insulation of sulfur and its discharge product, the lithium polysulfides (LiPSs) shuttle phenomenon, and the growth of lithium dendrites. Zeolite imidazole framework materials (ZIFs), particularly ZIF‐8 and ZIF‐67, are significant members of the metal–organic frameworks (MOFs) family. Owing to their high porosity, exceptional adsorption capacity, high structural tunability, and straightforward synthesis process, these materials have demonstrated unique application potential in the field of LSBs. This review initially provides a comprehensive summary of the developmental status and challenges associated with LSBs. Subsequently, it delves into an in‐depth analysis of the distinctive properties and synthesis strategies of ZIFs, with a particular emphasis on ZIF‐8 and ZIF‐67, as well as their composites and derivatives. The review systematically categorizes innovative application examples of these materials in the design of cathode structures and optimization of separators in LSBs. It also presents a forward‐looking perspective and insights on the potential future trajectory of ZIF‐67 materials, informed by the latest research advancements in the field.

Rapid and controllable microwave synthesis of nickel cobalt sulfide electrodes for high-performance asymmetric supercapacitors

The efficient and controllable synthesis method of high-performance energy storage electrode materials is crucial for advancing the development of energy storage technologies. Herein, by leveraging microwave heating technology in the sulfidation of nickel cobalt MOF, we effectively enhanced the efficiency of the synthesis process. Notably, sulfidation time emerged as a pivotal factor in tuning the crystalline phase structure and conductive properties of the material, leading to the successful development of NCS2 electrode material with a unique structure through optimized sulfidation conditions. Electrochemical performance tests of the NCS2 material revealed exceptional results; it exhibited a specific capacity of 1311 Fg[Formula: see text] at a current density of 1 Ag[Formula: see text] and retained 73.4% of its initial capacity when the current density increased to 10 Ag[Formula: see text], demonstrating outstanding rate performance. The composite NCS2//AC supercapacitor exhibits an energy density of 24.2 Whkg[Formula: see text] at power density of 800 Wkg[Formula: see text], even though after 1000 consecutive charge-discharge cycles, the capacity retention rate remained high at 77.1%, validating the exceptional stability and reliability of the NCS2 material during cycling. This work employs microwave sulfidation for the rapid and controlled synthesis of nickel cobalt sulfides, providing a green and efficient synthetic strategy for metal sulfide active materials.

Homogeneous Complexation Strategy to Manage Bromine for High‐Capacity Zinc–Bromine Flow Battery

AbstractZinc–bromine flow batteries (ZBFBs) have received widespread attention as a transformative energy storage technology with a high theoretical energy density (430 Wh kg−1). However, its efficiency and stability have been long threatened as the positive active species of polybromide anions (Br2n+1−) are subject to severe crossover across the membrane at a high concentration. Herein, a novel highly hydrophilic complexing agent, N‐methyl‐N, N‐bis(2‐hydroxyethyl)‐1‐propanaminium bromide (PMDA), is developed to effectively manage bromine in a homogeneous posolyte, which realizes a low bromine crossover at a high operating concentration in ZBFBs. Both theoretical and experimental results suggest that the PMDA interacts with Br2n+1− and forms a larger‐size complex PMDABr2n+1. When adding 0.40 m PMDA, the bromine stays homogeneous at a high concentration up to 1.20 m, and its permeability is remarkably decreased by 74%. For demonstration, the ZBFB achieves a operating capacity record of 57.2 Ah L−1 in a homogeneous bromine posolyte with a high Coulombic efficiency of ≈90.0% and superior cycling stability (capacity retention rate of 100.0% per cycle). This work provides one innovative bromine management strategy to realize a high capacity and superior stability in ZBFBs.

Intercalation of g-C3N4/Ag2S heterostructure on boronized Ni-MOF for enhanced water splitting and energy storage applications

The increasing global demand for energy conversion and storage technologies including water electrolysis, fuel cells, batteries & supercapacitors depend critically on the performance of their electrode components. Metal Organic Frameworks (MOFs), particularly Nickel Zeolite Imidazole Frameworks (Ni-ZIF) have drawn significant attention due to their greater electrocatalytic performance. Still, their restricted active sites & stability hinder their broader implementation in alkaline/saline water electrolysis & supercapacitor applications. Here, we are reporting the intercalation of heterostructure consisting of silver sulfide (Ag2S)/graphitic carbon nitride (g-C3N4) on Boronized Ni-ZIF (B:NZ) for empowered alkaline/saline water splitting and supercapacitor applications. These heterostructure addition over Boronized Ni-ZIF demonstrated minimal overpotentials for the oxygen evolution reaction (OER) (324 mV at 10.0 mA cm-2) and the hydrogen evolution reaction (HER) (78 mV at 10.0 mA cm-2) in alkaline medium (1 M KOH). The observed improvement in activity is ascribed to the decreased charge transfer resistance (Rct) & the augmented electrochemical active surface area (ECSA). Furthermore, Ag2S/g-C3N4/Boronized Ni-ZIF exhibited high specific capacitances of 1076.6 F/g and areal capacitance of 2584 F/cm2 at 0.50 A g-1 in supercapacitor applications. The incorporation of the g-C3N4 layer has enhanced the surface area and roughness facilitating stronger adhesion between hybrid layers which in turn resulted in prolonged stability exceeding 20 h in water splitting and 86 % retention in supercapacitor application.

Non-consumable gamma-cyclodextrin additive constructing anti-solvation interphase realizing dendrites free and high-performance lithium metal batteries

Relying on surpassing high theoretical capacity (3,865 mAh/g) and the lowest relative electrode potential (0 V vs. metallic Li), lithium metal batteries (LMBs) have been regarded as the “holy grail” of next-generation energy storage technology. Whereases, the instability of pristine solid electrolyte interphase (SEI) layers and the disorderly growth of lithium dendrites are still significant challenges to the commercialisation of LMBs. In this study, a novel approach is introduced to homogenise Li deposition by incorporating an environmentally friendly electrolyte additive, gamma-cyclodextrin (γ-CD), in ether-based electrolytes. Through host-guest interactions, γ-CD additives not only form inclusion complexes to improve Li+ transference number to 0.86 but also encapsulate TFSI- anions and other solvent molecules within the “cavity effect” to relieve unfavourable solvent effect. Electrochemical characterisations demonstrate that introducing 1 wt% γ-CD elevates the oxidation decomposition voltage of ether electrolytes to 4.15 V, thereby inhibiting the decomposition of ether electrolytes and reducing the fracture of SEI layers. According to reduce the nucleate potential, the Li//Cu half battery exhibits improved stability for 100 cycles, with an improved average Coulombic efficiency (CE) maintained above 98.4 %. Even if applied at high current densities of 5.0 mA cm−2 for a capacity of 1.0 mAh cm−2, the Li//Li symmetric battery can cycle for over 800 h, and the Li//Li4Ti5O12 (LTO) full battery retains 98.8 % of the initial capacity after 1,400 cycles.