In this paper, we discuss the stability of isotropic pressure conditions for a spherically symmetric dissipative fluid distribution in the framework of f(G,T) gravity. We consider the fluid to be composed of seen and exotic matter particles. The Gauss Bonnet terms represent exotic matter particles. For the physical significance of the pressure isotropy conditions, we transform the system into the hydrostatic equilibrium approximation. We observe the presence of shear, dissipative fluxes, energy density inhomogeneities, and prominently, the exotic matter tends to abandon isotropy leading to pressure anisotropy. It is found that exotic matter and dissipation are major factors that induce matter anisotropy in the evolving stellar system. In order to discuss the physical significance of the stellar model in f(G,T) gravity, the behaviour of stellar structure is explored according to the observational data of a compact star 4U1820 − 30. It is found that f(G,T) terms indicating the exotic material in the stellar model plays a vital role in governing the dynamics of the evolution. To strengthen the results, we also incorporate some arguments by choosing an axially symmetric case.