Empty Fruit Bunch Research Articles

Synthesis and characterisation of biodegradable carboxymethyl cellulose microcarriers from oil palm empty fruit bunch for therapeutic applications

Synthesis and characterisation of biodegradable carboxymethyl cellulose microcarriers from oil palm empty fruit bunch for therapeutic applications

Immobilization of urea on beads based on OPEFB cellulose-alginate via blending to fabricate sustained release fertilizer

Transforming oil palm empty fruit bunches (OPEFB) waste into value-added cellulose as a reinforcement agent for eco-friendly slow-release fertilizer (SRF) composites is a strategy to achieve clean and sustainable production. OPEFB cellulose was isolated by alkalization (10 % w/v NaOH) for 1 h and bleaching (30 % v/v H2O2) for 1.5 h. The treatment increased the cellulose content to 80.88 %, reduced the non-cellulosic component, and improved the fiber crystallinity to 58.40 %. The hydrogel composite was cross-linked by blending urea in an OPEFB cellulose fiber (w/w) (0 %, 0.5 %, and 1 %) and sodium alginate (3 % w/w). Then, the wet beads were freeze-dried to fabricate SRF composites. Each material was evenly dispersed in the matrix, had a porous structure, and could bind total nitrogen up to 20.0 %, confirmed by the Kjeldahl method. Adding cellulose increased crystallinity (significant at 1 % w/w cellulose), decreased bulky density (significant at 0.5 % and 1 % w/w cellulose), increased swelling capacity (significant at 0.5 % w/w cellulose), and water-retention capacity. Reinforced composite with 0.5 % (w/w) cellulose released nitrogen into the soil (Fickian diffusion) following the Higuchi model (R2 = 0.957) with K = 0.0394 and equilibrium at around t1/2 = 1.8 h. Changing SRF composite properties are likely related to the porous structure loaded with urea crystals.

Lignin-Chitosan-Based Bioplastics from Oil Palm Empty Fruit Bunches for Seed Coating

Lignin is a hydrophilic-hydrophobic biopolymer known for its antioxidant activity, which could make it a suitable coating material. In this research, a bioplastic based on the combination of alkali lignin from oil palm empty fruit bunches and chitosan was developed for seed coating via a dipping method. Chili seeds were used as a model in this study. The bioplastic was prepared via a modified solvent casting method at lignin:chitosan:glycerol weight ratio of 0.25:1.0:0.2. For the isolated lignin, the antioxidant activity, total phenolic content, methoxyl content, and equivalent weight were measured; for the bioplastic lignin, contact angle, swelling, antioxidant activity, mechanical properties and biodegradability were assessed. The presence of the coating was observed by Cryo-EM while the suitability of lignin-chitosan bioplastics for seed coating was evaluated by the germination rate, root length, height, and dry weight of the sprouts. The results showed that isolated lignin enhances the antioxidant activity of the lignin-chitosan liquid bioplastic by up to 84%. The addition of isolated lignin increased the contact angle and reduced the swelling rate of the bioplastics. The presence of lignin increases the tensile strength and elastic module in the biofilm. The microscopical investigation demonstrated the presence of the coating and no alteration in the seed surface morphology under the coating layer. The application of chitosan-lignin-based bioplastics maintain the quality of the seed during its shelf life. The germination rate of the coated chili seeds increased by up to 100% after one week of storage and 40–80% after five weeks of storage.

Characterization of the Agronomic Properties of Different Vermicompost from the Co-composting of Oil Palm Empty Fruit Bunches and Green Waste

The accumulation of palm oil industries waste is one of the causes of environmental pollution that is becoming an increasingly concern in Côte d'Ivoire. However, this waste, combined with other simple plant substrates, can be used in the vermicomposting process. That is the context in which this study is conducted, with the aim of determining the agronomic properties of different vermicompost made of oil palm empty fruit bunches combined with green waste (Chromolaena odorata leaves and grass clippings). For this purpose, plastic boxes of 1.5 L in volume were first filled with 800 g of soil. Then, 300 g of the different pre-composted substrates and 4 earthworms were added. In total, 4 treatments of 25 repetitions each were carried out. For all the treatments, treatments T3 (oil palm empty fruit bunches + Grass cutting + earthworms) and T4 (oil palm empty fruit bunches + Chromolaena odorata + Grass cutting + earthworms) presented the best values of the substrate decomposition capacity and physicochemical properties. The same is true for the mineral materials obtained. For these two treatments mentioned, the C/N ratio was around 15 and significantly higher than those of treatments T1 (oil palm empty fruit bunches + earthworms) and T2 (oil palm empty fruit bunches + Chromolaena odorata + earthworms), which were around 12. The pH values being variable at the beginning of vermicomposting were close to neutral at the end, thus indicating the maturity of the different vermicompost produced. Vermicompost resulting from co-composting of empty fruit bunches of oil palms and green waste appears to improve nutrient availability, structure and microbial activity of the vermicompost to promote good development of cultivated plants.

Computational Prediction of Co-firing with Various Biomass Waste Using Turbulent Non-Premixed Combustion

Co-firing in coal power plants has limitations because the existing combustion systems are designed to provide optimal performance only with coal. Therefore, investigating the combustion aspects of co-firing by mixing coal with biomass before applying it to existing coal power plants is necessary. To address this, a new numerical model was developed to predict the co-firing behavior of coal with various types of biomass waste, specifically focusing on temperature and pollutant behavior. This study developed a co-firing model in a Drop Tube Furnace (DTF) using a composition of 25% Wood Chips (WC), 25% Solid Recovered Fuel (SRF), 25% Empty Fruit Bunch Fibers (EFFR), and 25% Rice Husk (RH). A structured grid arrangement and the Probability Density Function (PDF) were utilized to depict the relationship between chemical combustion and turbulence. The distributions of temperature and mass fractions of pollutants along the furnace axis were predicted. The highest temperature was observed with 25% EFFR, attributed to its highest volatile matter content. The simulation predicted that 25% RH would be the lowest SO2 emitter. However, it also showed a slight increase in NO and CO levels due to the increased oxygen content when coal was mixed with biomass. The simulation with 25% EFFR predicted a decrease in CO2 emissions compared to other biomass types. The results of this parametric investigation could support the implementation of biomass co-firing technology in existing coal-fired power plants.

Sodium carbonate pulping of oil palm empty fruit bunches for paperboard production

Abstract This study investigated the use of sodium carbonate pulping in oil palm empty fruit bunch (OPEFB) pulp production for paperboard manufacturing. The pulping varying the active alkali (AA) (4.5 %, 6.5 %, 8.5 %), NaOH fraction (F) (10 %, 20 %, 30 %), and cooking time (T) (30′, 60′, 90′). The performance was evaluated based on screened pulp yield, kappa number, and delignification selectivity. Furthermore, the functional groups, S/G ratio, and morphological structure of the optimum pulp were observed. The tensile and tear indices of the OPEFB pulp paperboard were also measured. The results suggest sodium carbonate pulping at a low chemical dose successfully produced OPEFB pulp. Based on the highest delignification selectivity value of 12.74, the most effective pulping conditions were achieved with AA-6.5 %, F-30 %, and T-90′. The optimum OPEFB pulp analysis revealed a decrease in lignin proportion with the dominant degradation of the syringyl unit. Thus, the fibers are easily separable during mechanical treatment. These characteristics influenced the paperboard, resulting high tensile and tear indices of 7.90–8.15 Nm g−1 and 15.09–16.25 mN m2 g−1, respectively. Overall, this study demonstrated the potential of sodium carbonate pulping to produce high-quality pulp and paperboard from OPEFBs, highlighting the thoroughness of the research process in the pulp and paper manufacturing field.

Growth and Reproduction Performance of the Earthworm (Eudrilus eugeniae) Fed with Different Substrates Made of Palm Oil Empty Fruit Bunches: A Case of Vermicompost Production, Abidjan, Côte d'Ivoire

The objective of the present study is to analyze the growth capacity and activity of the worm species Eudrilus eugeniae in different substrates based on palm oil empty fruit bunches as part of the production of vermicompost. To this end, 4 treatments were carried out by adding to palm oil empty fruit bunches other substrates readily available in the environment, notably Chromolaena odorata leaves and grass clippings. 1.5 L plastic boxes were filled with 800 g of soil and 300 g of various precomposted substrates. In each box, 4 earthworms (Eudrilus eugeniae) were seeded. A total of 4 treatments were carried out: T1 (palm oil empty fruit bunches + earthworms), T2 (palm oil empty fruit bunches + Chromolaena odorata + earthworms), T3 (palm oil empty fruit bunches + grass clippings + earthworms) and T4 (palm oil empty fruit bunches + Chromolaena odorata + grass clippings + earthworms). For the different vermicomposts based on palm oil empty fruit bunches, growth parameters and Eudrilus eugeniae activity were better in treatments T3 and T4. These same treatments also showed significant variation in substrate quantity after vermicomposting. The combination of palm oil empty fruit bunches and green waste (Chromolaena odorata and grass clippings) would be ideal for the production of vermicompost with good agronomic potential to be applied as an organic amendment to cultivated plants.

Exergy Analysis of Hydrogen-Rich Syngas Production System Utilizing Palm Oil Empty Fruit Bunch using Pyrolysis Connected with Steam Methane Reformer

Fossil fuel consumption on a large scale continues to increase yearly, causing a shortage of energy sources. Hydrogen can help to overcome the shortage of energy sources. It can be produced from renewable energy sources, such as oil palm Empty Fruit Bunch (EFB) as biomass using pyrolysis processes equipped with steam methane reformer and water gas shift reactions. This research was conducted to determine the amount of hydrogen that can be produced and to analyze the exergy of the existing systems in the hydrogen production process. Aspen Plus has been used to design and analyze pyrolysis processes, steam methane reform, and water gas shift reactions. The results showed that when 6.54 kg Empty Fruit Bunch was used as raw material in a pyrolysis reactor, hydrogen could be produced in the amounts of 0.435 kg. The exergy values of raw materials and fuels are relatively high because the chemical exergy values of the compounds contained therein are also high. Based on the calculations, it is found that the combustion process is the process that experiences the most significant exergy destruction. The exergy efficiency of this hydrogen production process system is 22.77%.

Synthesis of graphitic carbon from empty palm oil fruit bunches through single-step graphitization process using K2FeO4-KOH catalyst as lithium ion battery anode

This research aims to optimize the graphitization process of carbon derived from Empty Palm Oil Fruit Bunches (EPOFB), a renewable biomass source, using a single-step K₂FeO₄-KOH impregnation-activation method. The results demonstrate that increasing the mass of K₂FeO₄, up to the optimal level, enhances the degree of graphitization, as confirmed by XRD and Raman spectroscopy. Optimal performance is observed with a catalyst mass of 0.11 g K₂FeO₄ in the C_ K₂FeO₄(0.11)KOH_800 sample, which exhibits a d002 spacing of 0.3356 nm, an IG/ID ratio of 2.42, a high surface area of 787.767 m²/g, and clearly defined graphitic layers in TEM images. Electrochemical testing of C_ K₂FeO₄(0.11)_KOH_800 reveals promising results, including the lowest charge transfer resistance (Rct) of 87.18 Ω, a significant area under the curve in cyclic voltammetry, a charging capacity of 330.3 mAh g⁻¹ at 0.1 C, with an excellent rate capability of 183 mAh g⁻¹ at 1 C after 100 cycles, maintaining a retention rate of 68.2 %. The single-step K₂FeO₄-KOH impregnation-activation method effectively enhances the graphitization of EPOFB-derived carbon, offering potential applications in high-performance lithium battery anodes.

Influence of Chemical and Thermal Pre-Treatment on Pyrolysis Product Constituents of Palm Empty Fruit Bunches

Influence of Chemical and Thermal Pre-Treatment on Pyrolysis Product Constituents of Palm Empty Fruit Bunches

Preparation and Charcterisation of Acetate Cellulose Laurate Ester in Sodium Acetate/Zinc Chloride Systems

The objective of this study was to explore the preparation and characterisation of acetate cellulose laurate ester in sodium acetate/zinc chloride systems. The cellulose used in the study was obtained from oil palm empty fruit bunch and oil palm frond. The characterization of both the isolated cellulose and the acetate cellulose laurate ester was carried out using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Differential thermogravimetric (DTG), and Thermogravimetric analysis (TGA). The FT-IR analysis of the acetate cellulose laurate ester revealed the presence of C=O, confirming its modification. The crystallinity of the isolated cellulose and the acetate cellulose laurate ester was found to be 67-72% and 51-54%, respectively. The thermal stability of the isolated and modified cellulose esters was found to be 360-340 ℃ and 380-365 ℃, respectively. The solubility test showed that the prepared acetate cellulose laurate esters were soluble in different solvents. However, this study found that the synthesis of acetate cellulose laurate ester in an aqueous medium is not feasible. The improved hydrophobic character, good thermal stability, water retention value, and excellent solubility in different solvents of the acetate cellulose laurate ester reported in this study make it a potential material for applications in bioplastics, and packaging materials.

Effect of toughening agent and flame‐retardant additives on the recycled polypropylene/oil palm empty fruit bunch laminated composites

AbstractThe increasing awareness of the environmental problems caused by the use of plastics has led to a demand for sustainable materials. The concept of turning waste into wealth has been considered in the study where the waste materials are value‐added into new composite materials that are recyclable, durable, and fire‐resistant. This effort aims to meet global environmental goals and the demand for high‐performance and sustainable building materials. The purpose of this current study is to develop laminated composites based on the combination of recycled plastic and oil palm empty fruit bunch (OPEFB). The addition of various loading of ammonium polyphosphate (APP) and 6 wt% of ethylene vinyl acetate (EVA) in the formulation was considered to enhance the performance of the composite laminates. The rPP and additives were compounded using a two‐roll mill. Then the rPP sheet and OPEFB were laminated using compression molding techniques. Results showed that rPP with addition of 30 wt% APP and 6 wt% EVA exhibited the highest thermal stability and the lowest melt flow index (MFI) value compared to other samples. Composites with 20 wt% APP and 6 wt% EVA showed 56% increase in flexural properties and 33% increase in impact strength compared to that of rPP/OPEFB composite sample without EVA. Addition of 30 wt% in recycled PP and OPEFB demonstrated self‐extinguished properties when exposed to fire compared to other samples. These findings indicated that rPP/OPEFB laminated composites with the addition of APP and EVA have a potential to be used in applications that require good strength and fire performance. The use of rPP/OPEFB composites with addition of APP and EVA has a potential to reduce virgin plastic consumption and agriculture material waste and establishing an environmentally friendly material for construction sector.Highlights Additives included in recycled PP enhance its thermal stability and reduce MFI. Recycled PP with OPEFB composite self‐extinguished at 30 wt% APP. The highest flexural strength is shown by composite laminates with 20 wt% APP and 6 wt% EVA. rPP/OPEFB laminates are ideal for building materials.

Nitrogen-doped activated carbon derived from oil palm empty fruit bunch (OPEFB) for sustainable lithium-ion battery

Nitrogen-doped activated carbon derived from oil palm empty fruit bunch (OPEFB) for sustainable lithium-ion battery

Production and Characterization of Bio-oil Derived from Empty Fruit Bunch (EFB) using Fast Pyrolysis

Production and Characterization of Bio-oil Derived from Empty Fruit Bunch (EFB) using Fast Pyrolysis

Evaluating the efficacy of palm waste in adsorption processes for wastewater treatment: A review

AbstractThe growing environmental concerns related to industrial effluents and waste underscore the urgent need for sustainable and cost‐effective wastewater treatment solutions. This review investigates the efficacy of palm waste‐derived adsorbents for removing heavy metals and organic pollutants from wastewater. It explores various modifications—including physical, chemical, and nanomaterial enhancements—applied to palm waste materials such as palm kernel shells, empty fruit bunches, and palm oil fuel ash, aimed at improving their adsorption capacities. The review reveals that these modified palm waste adsorbents demonstrate high removal efficiencies for contaminants like Cu(II), Pb(II), and organic dyes, often surpassing conventional adsorbents. Nonetheless, challenges remain, such as optimizing adsorbent preparation, understanding adsorption mechanisms in multi‐component systems, and enhancing adsorbent reusability. This review highlights the need for continued research to address these issues and advance the application of palm waste‐based materials in sustainable wastewater treatment.

Conversion of Oil Palm Empty Fruit Bunch Fiber Waste into Green Liquid Organic Fertilizer

Solid wastes generated from the oil palm industry contain valuable nutrients like nitrogen, phosphorus, and potassium that can significantly enhance plant growth and potentially elevate fertilizer production. This study aims to identify the optimal formulation of liquid organic fertilizer (LOF) derived from oil palm empty fruit bunch (OPEFB) fiber waste. Three formulations of LOF were prepared, comprising OPEFB waste, molasses, noni fruit, and cattle urine, designated as Formulation A, B, and C. These formulations underwent a 14-day anaerobic incubation period. The formulated OPEFB LOF was then analyzed for nutrient content, electrical conductivity, and total dissolved solids. This study also examines the soil properties and plant growth outcomes following the application of the formulated OPEFB LOF. The results indicated that Formulation A exhibited the highest nutrient concentrations, specifically 485 ppm nitrogen, 95 ppm phosphorus, and 1007 ppm potassium. In comparison to the other two OPEFB LOF formulations, Formulation A showed the lowest values for total dissolved solids (502 ppm) and electrical conductivity (8.14 dS/m). The findings demonstrated that Formulation A displayed the most favorable growth characteristics in terms of leaf count, plant height, leaf length, and leaf width. This is attributed to the nitrogen-boosting properties of cattle urine, along with the complementary effects of molasses and noni fruit as soil improver and bio-activator. This study confirms the viability of utilizing green organic fertilizer derived from OPEFB substrate in agriculture, replacing conventional inorganic fertilizers.

Utilization of Agricultural Waste as a Total Mixed Ratio Pellet Material for Rex Rabbit Feed

This study aimed to evaluate the quality of Total Mixed Ration (TMR) pellets derived from agricultural waste and assess their potential as feed for Rex rabbits. The research employed an experimental approach, utilizing agricultural and plantation waste to produce TMR pellets. The study was conducted in two stages: pellet production and rabbit feeding trials. Three formulations of TMR pellets were developed with varying concentrations of oil palm empty fruit bunches (EFB): P1 (5% EFB), P2 (10% EFB), and P3 (15% EFB). The optimal formulation was subsequently used for the feeding trials. Rabbit feed treatments included T0 (60% commercial pellet + 40% forage), T1 (40% commercial pellet + 20% TMR pellet + 40% forage), T2 (30% commercial pellet + 30% TMR pellet + 40% forage), and T3 (60% TMR pellet + 40% forage). Results from the pellet analysis indicated no significant differences in organoleptic properties among the formulations. The durability test yielded the highest value of 98.77%, while the proximate analysis of the P1 formulation showed a dry matter content of 85.67%, ash content of 10.35%, organic matter of 89.65%, crude protein of 18.65%, crude fat of 18.72%, and crude fiber of 19.18%. In the rabbit feeding trials, there were no significant differences in rabbit performance when compared to those fed with commercial pellets. Based on these findings, it can be concluded that agricultural waste can be effectively utilized as a raw material for rabbit feed pellets, offering comparable quality to commercial alternatives. This research highlights the potential of agricultural waste in reducing environmental pollution while providing an economically viable alternative for animal feed.

Experimental study of hydrothermal treatment for reducing potassium content on palm oil empty fruit bunch (EFB)

Abstract This study investigated the effects of the potassium content of EFB biochars after hydrothermal treatment (HT). The experiments were carried out in a 3000 mL reactor and treated for 60 min. Two parameters were studied in detail: water (liquid) to EFB (solid) ratio or L/S (5:1 and 10:1) and varied temperature (150, 180, 210, and 230°C). The ash content of biochars decreased gradually due to the increasing temperature, with values varying from 6.55% to 12.79%. The sodium of the treated biochars was removed entirely for each HT process, while the potassium notably reduced with the removal efficiency reached 75.34-93.79%. HT at temperature 230°C was the optimum condition to reduce the Agglomeration Index (AI), which 230H5 and 230H10 resulted in 0.26 and 0.31, respectively. Although the mass yield significantly reduced, the 230H5 was highly recommended when used for co-combustion fuel because it had the highest HHV (21.36 MJ/kg), the lowest AI (0.26), and the high removal efficiency of potassium (93.76%).

Enhancing thermophilic methane production from oil palm empty fruit bunches through various pretreatment methods: A comparative study

This study investigated the effects of various pretreatment methods on the anaerobic digestibility of oil palm empty fruit bunches (EFB) for methane production. Pretreatment methods included weak alkaline (2 % Ca(OH)2), weak acid (2 % acetic acid), acidified palm oil mill effluent (POME), biogas effluent, hydrothermal (180 °C, 190 °C, and 200 °C), and microwave pretreatments. All pretreatment methods enhanced methane yield compared to untreated EFB (189.45 mL-CH4/g-VS), with weak alkaline pretreatment being the most effective (277.11 mL-CH4/g-VS), followed by hydrothermal pretreatment at 180 °C (244.33 mL-CH4/g-VS) and biogas effluent pretreatment (238.32 mL-CH4/g-VS). The enhanced methane yield was attributed to increased cellulose content (45.5 % for weak alkaline pretreatment), reduced hemicellulose (18.0 % for hydrothermal pretreatment at 200 °C), and lignin contents (19.0 % for hydrothermal pretreatment at 200 °C), decreased crystallinity index (40.0 % for hydrothermal pretreatment at 200 °C), and increased surface area. Weak alkaline pretreatment also showed the highest net energy balance (8.73 kJ/g-VS) and a short break-even point (2 years). Microbial community analysis revealed that weak alkaline pretreatment favored the growth of syntrophic acetate-oxidizing bacteria and hydrogenotrophic methanogens, contributing to improved methane yield. This study demonstrates the potential of EFB pretreatment, particularly weak alkaline and biogas effluent pretreatment, for enhancing methane production and sustainable management of palm oil mill waste.

Furfural purification and production from prospective agricultural waste of oil palm empty fruit bunch: Simulation, design and economic assessments

Furfural is potentially produced from lignocellulose waste of biorefinery processes and is widely used as a value-added in various chemical industries. However, the purification of furfural should be conducted to obtain high purity. This work aims to synthesize, design, and optimize the furfural production using some alternative distillation processes by simulation using Super Pro and ASPEN software. The pretreatment process of producing crude furfural from empty fruit bunch waste is also evaluated. The production cost of $0.23/kg of crude furfural (5%) was obtained in the preliminary process. In the purification process, the sequenced distillation process was less prospective than the extractive distillation based on the simulation basis and economic evaluation. The extractive distillation using n-butyl chloride performed better than toluene and benzene as the furfural recovery, and the purity was 98.60% and 99.94%, respectively. The payback period (PBP), internal rate return (IRR), and net present value (NPV) also indicated the great performance of the extractive distillation process with values of 1.24 years, 36.04%, and $14,591,500, respectively. Therefore, the simulation, design, and economic evaluation presented promising results that are feasible for plant establishment.