Elements In Road Dust Research Articles

Long-term open-pit mining activities at the world's largest light rare earth mine significantly affect light rare earth elements in road dust over long distances

The long-term effects of decades of open-pit mining at the Bayan Obo deposit, the world's largest light rare earth mine, on the concentrations of several elements in road dust over long distances are unknown. Here, bulk road dust (BRD) and resuspended road dust (RRD) were collected from different distances from the mine for subsequent analysis of mining impacts. As a result of mining activities, light rare earth elements (LREEs), especially La, Ce, Pr and Nd, show different statistical and spatial variations compared to other elements. These LREEs decrease with increasing distance from the mine, and the values found in RRD are higher than those in other particle sizes. Mining emissions and soil have the most significant influence on these LREEs compared to other factors. Spatially, these four LREEs changed significantly over a large area (up to 60km from the mine) due to mining emissions. However, long-term mining activities affect these elements mainly through mining-contaminated soil as opposed to mining emissions. This study confirms the significant impact of mining activities on LREEs in road dust via a comprehensive data-driven framework, emphasizing the significant environmental effects of long-term open pit mining.

Spatial distribution, sources, and health risk assessment of elements in road dust (

This research delves into the spatial distribution of 17 elements (Al, B, Ba, Bi, Cd, Co, Cr, Cu, Fe, Li, Mg, Mn, Ni, Pb, Sr, Te, and Zn) within the < 20 μm size fraction of road dust samples collected from 177 locations within 65 grid cells (each 5×5 km2) throughout Delhi in February 2021. Notably, Fe and Al emerge as the predominant elements in the road dust samples. Using Principal Component Analysis (PCA), Absolute Principal Component Score (APCS), and Multiple Linear Regression (MLR) techniques, it is observed that crustal sources (58%), non-exhaust vehicular emissions (21%), and two distinct industrial origins (2% and 19%) are major contributors to the road dust composition. Bi and Te exhibited the highest geo-accumulation indices, indicating significant pollution levels, with notably high contamination factors, surpassing a contamination degree of 24. Elements like Cd posed the highest potential ecological risk, dominating 95% of the risk assessment. The hazard index analysis highlighted that urban populations, especially children, face the greatest risk through ingestion, followed by dermal exposure, and least through inhalation. Notably, Cd, Pb, Cr, and Ni were identified as elements posing a very high carcinogenic risk to the general populace.

The relationship between the inhalation bioaccessibility of potentially toxic elements in road dust from a heavily polluted industrial area and the source of their pollution

One of the sources of chronic exposure to potentially toxic elements (PTE), especially in polluted environments, is the inhalation of resuspended road dust (RD). The aim of this study is to assess the inhalation bioaccessibility of PTE in RD from highly polluted environments from mining/smelting industries and traffic, and to identify any correlations between the bioaccessibility fraction of PTE and the physicochemical characteristics of the particles. RD from the studied area contains extremely high total concentrations of Cr, V, and Mn, which are likely due to pollution from the smelting industry. Additionally, elevated total concentrations of other elements associated with traffic emissions including Zn, Cu, Pb, Sb, and Sn were also measured. The bioaccessibility of PTE was assessed using two synthetic extraction solutions - Gamble's solution (GS) and Artificial Lysosomal Fluid (ALF). The majority of elements showed negligible bioaccessibility in GS. However, quite high inhalation bioaccessibility was observed for Zn, Pb, Sb, Cd, and Mn in the ALF solution, with a mean bioaccessible fraction of 49, 51.5, 41, 50, and 40% respectively. The highest bioavailable fraction was measured for Cd (97%) in a sample collected near a steel production facility and for Pb (95%) in a sample collected near the highway. These results indicate that increased mobility of the elements in inhaled particles occurs only in the case of phagocytosis. The lowest inhalation bioavailability was measured for Cr (mean is 3%). Differential individual particle analysis revealed that about 60% of phases, mostly major (Cr,Ti,V)-bearing metallic alloys, silicates, oxides and sulphides, are stable in ALF solution, while 40% of phases, mostly (Fe,Ca,Mn)-bearing oxides, silicates, sulphides, metals and metallic alloys originating from steel production, ferrochrome, ferrosilicon and vanadium production and from traffic emissions have been heavily corroded or completely dissolved. The study provides valuable information to further assess health hazards from various emission sources.

Hazardous Elements in Road Dust from Petrol Stations in Rzeszów (Podkarpackie, Poland): Toxicological Assessment Using Field Portable X-ray Fluorescence (FP-XRF) as ‘White Analytical Technique’

AbstractSamples of road dust (RD) from petrol stations (n = 20) located in Rzeszów (Podkarpackie, Poland) were analysed to find potential markers of traffic-related pollution. The level (μg/g) of: Mo, U, As, Hg, Th, Pb, Ni, Cu, Cr, Be, Sr, Zr, Zn, Mn and Fe were measured using field portable X-ray spectroscopy (FP-XRF) as a direct, rapid and ‘white analytical technique’. Our research demonstrated for the first time the utility of using FP-XRF for environmental toxicological assessment of RD from petrol stations. The qualitative and quantitative composition of the dust samples tested provides valuable research material for creating and updating regulations and finding pollution hotspots such as petrol stations. It was possible to find potential markers of traffic-related pollution (e.g., Zr and Fe forms of disk brakes or brake pads). Certain elements of the study give ambiguous signals related to fuel distribution and road traffic. They can come from various sources of environmental contamination. The adoption of evidence-based policies to minimise pollution, conserve the environment, and protect the well-being of people living or working near gas stations is anticipated to be aided by these findings for policymakers, regulatory authorities, and stakeholders. Incorporating toxicological risk assessment framework, this study pioneers the investigation of human exposure to hazardous elements in RD, an in-depth evaluation of both carcinogenic and non-carcinogenic health risks associated with such exposure including lifetime average daily dose. Our findings contribute novel insights into the environmental toxicology of urban areas, emphasising the need for tailored interventions to mitigate these risks.

Pollution Indices and Health Risks Associated with Toxic Trace Elements in Road Dust in Southern Tehran

Pollution Indices and Health Risks Associated with Toxic Trace Elements in Road Dust in Southern Tehran

The geochemical and fractionation study on toxic elements in road dust collected from the arterial roads in Kraków

The geochemical and fractionation study on toxic elements in road dust collected from the arterial roads in Kraków

Risk assessment of potentially toxic elements in street dust from Mahd Ad Dhahab gold mine, Saudi Arabia

ABSTRACT The current study evaluated the contamination level of potentially toxic elements (PTEs) and their associated risk in street dust in the vicinity of Mahd Ad Dhahab gold mine, KSA. 25 street dust samples were collected and then subjected to magnetic susceptibility (χ) measurements and analysed for Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Pb and Zn contents. The results revealed that the study area is contaminated by Cd, Zn, Hg, Cu, Pb and As, since their concentrations were higher than the background and displayed high values of coefficient of variation (41.86, 14.9, 11.05, 10.1, 8 and 5.3, respectively) combined with high enrichment factor (181.7, 167.5, 183.6, 122.8, 151.7 and 33.95, respectively). The higher concentrations of these elements, associated with higher χ values, were recorded close to the mining area. The correlation coefficient and heatmap categorized the studied PTEs into two groups; The first group comprised Al, Co, Cr, Fe, Mg and Mn of geogenic origin; the second included As, Cd, Cu, Hg, Pb and Zn, along with χ, which controlled by anthropogenic sources. Ecological risk assessment values indicated that 28% of the samples have very strong ecological risk. Regarding human health risk, among different pathways, ingestion is a primary pathway of PTEs harming human health. The non-carcinogenic risks from Cd, Cu and Pb and carcinogenic risk from As exceeded the acceptable level to local children. The study demonstrated that mining activities are the main source of street dust contamination in the area.

Monitoring the spatial distribution patternaccording to urban land use and health risk assessment on potential toxic metal contamination via street dust in Ankara, Türkiye.

The urbanization processes with growing vehicle numbers cause heavy metal pollution in street dust, and high populations in metropolitan cities are exposed to pollutants. This paper aims to monitor the spatial distribution of heavy metals and evaluate the concentrations via health risk assessment of HMs (Cu, Ni, Cd, Co, Pb, and Zn) that expose the inhabitants to health hazards. According to the results of the current study, sixty street dust samples were applied to the acid digestion technique and quantification by inductively coupled plasma-mass spectrometry (ICP-MS). The spatial distribution of the selected heavy metals in the street dust was investigated using the spatial analysis tool in ArcGIS 10.0 according to population density and land use. In the present study, we used hazard index and cancer risk methods to estimate the public health risk of the pollutants exposed to street dust in Ankara. The concentrations range of the elements in street dust over the study area ranged from 3.34-4.50, 31.69-42.87, 16.09-21.54, 42.85-57.55, 0.00-3.51, and 23.03-30.79, respectively. The overall decreasing order of mean concentration of metals was observed as follows: Pb > Cu > Ni > Co > Cd > Zn. Vehicle traffic and industrial activities seem to be the most critical anthropogenic sources responsible for dust pollution in the study area. The risk assessment of Pb and Ni exposure was the highest, and the hazard index values were 2.42E + 00 and 2.28E + 00 mg/kg/day for children. However, the effect on adults was 2.62E-01 and 2.37E-02 mg/kg/day, followed by inhalation and dermal contact with street dust was almost negligible. The decreasing concentration is modeled spatially along the western development corridor of the city. The risk to public health is high in areas with high densities close to the city center and the main artery.

A review on toxic metal pollution and source-oriented risk apportionment in road dust of a highly polluted megacity in Bangladesh.

Heavy metal enrichment in road dust has resulted from intensive anthropogenic activity, particularly urbanization, industrial activities and traffic emission, posing a hazard to urban ecosystems and human health. To promote optimal road dust management in urban environments, it is necessary to assess the possible ecological and health impact of toxic elements in road dust. In a heavily populated megacity like Dhaka, Bangladesh, large-scale risk assessments of contamination in road dust with heavy metals are limited. The present study aims at presenting a concentration of twenty-five metals in road dust (Na, K, Cs, Rb, Mg, Ca, Sr, Ba, Al, Zn, Cd, Pb, As, Sb, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zr and W) in Dhaka megacity. We used a critical source-based positive matrix factorization model, source-oriented potential ecological risks and health risks. Out of the studied metals, Na, Ca, Zn, Cd, Cu, Zr and W exceeded the shale value. About 73%, 48%, 29% and 32% of sampling sites showed a higher level of pollution based on PLI, NIPI, PER and NIRI, respectively. PMF model identified that Cd (85.3%), Cr (62.4%), Ni (58.2%), Zn (81.8%) and Mn (65.9%) in road dust were primarily attributed to traffic emission, fuel combustion, metal processing, transport sources and natural sources, respectively. Fuel combustion and metal processing posed considerable and high risks based on modified potential ecological risk and NIRI. Based on health hazards, traffic emission posed a high cancer risk in adult males (29%), whereas transport sources contributed to females (21%) and children (23%).

Spatial distribution, contamination levels, source identification and human health risk assessment of potentially toxic elements in street dust in urban area in Libya

ABSTRACT Street dust samples were collected from 31 sampling sites which were classified into four different groups in Zawiya, Libya, covering different traffic, city center, junkyards, oil refinery, farming, and household activities. Since the potentially toxic elements (PTEs) in street dust have a non-negligible impact on health, the aim of this study is to investigate the sources, pollution level and human health risk of PTEs. In this study, wavelength distribution X-ray fluorescence device was used to determine the concentration of PTEs. The spatial distribution, contamination levels, sources, and human health risks of PTEs in road dust were evaluated. The PTEs content of the street dust were found as Cr>Mn>Zn>Pb>Cu>Ni>Co. The average concentration of most PTEs (Co, Cu, Mn, Ni and Zn) was higher in junkyards and heavily traffic areas than in other areas. Cobalt and Cu has the highest geo accumulation index (Igeo) values, and due to these values, the study area was evaluated as moderately to heavily contaminated. Enrichment factor (EF) values of Cr, Pb and Zn exhibited a significant enrichment, indicating that some sampling sites were affected by anthropogenic sources. There was no lifetime cancer risk for exposure to PTEs in street dust by inhalation in Zawiya. Each hazard quotient (HQ) and hazard index (HI) for all PTEs were less than 1, indicating that exposure to PTEs in street dust did not have significant non-carcinogenic risks for both adults and children. In conclusion, Zn, Pb, Cu, Mn, and Cr were represented by the largest portion of the total data variance in the principal component analysis (PCA), and they were positively correlated. It was seen that study area was influenced by anthropogenic sources rather than natural sources, but there was no health risk.

Pollution characteristics and risk assessment of potentially toxic elements of fine street dust during COVID-19 lockdown in Bangladesh.

Due to the COVID-19 pandemic, Bangladesh government took the measure like partial lockdown (PL) and complete lockdown (CL) to curb the spread. These measures gave a chance for environmental restoration. In this study, street dust samples were collected during PL and CL from four main urban land use categories in Dhaka city, such as industrial area (IA), commercial area (CA), public facilities area (PFA), and residential area (RA). Ten potentially toxic elements (Cr, Mn, Zn, Fe, Pb, Cu, Co, Ni, As, and Cd) in fine street dust particles (diameter < 20 μm) were determined following aqua-regia digestion and measured by inductively coupled plasma mass spectrometry (ICP-MS) to evaluate distribution, pollution sources, and potential risks to ecological systems and human health. Results showed that during PL, the concentrations of toxic elements in the dust were higher than that of CL. Cd and Fe were lowest and highest in concentration with 1.56 to 41,970 µg/g and 0.82 to 39,330 µg/g in partial and complete lockdown period respectively. All toxic elements were detected at high levels above background values where Fe with the highest and Cd with lowest concentrations, respectively. By land use, the levels of toxic elements pollution followed IA > PFA > RA > CA. Correlation analysis (CA), principal component analysis (PCA), and hierarchal cluster analysis (HCA) revealed that the sources of these analyzed toxic elements were mainly from anthropogenic which are related to industrial and vehicular or traffic emissions. Enrichment factor (EF), geoaccumulation index (Igeo), contamination factor (CF), and pollution load index (PLI) also suggested that the dust was more polluted during PL. Exposure of toxic elements to human was mainly via skin contact followed by ingestion and inhalation. Hazard quotient (HQ) values were < 1 except for Mn through dermal contact at all sites during partial and complete lockdown, similar to hazard index (HI), while Cr further showed high non-carcinogenic risks to children. Generally, children HI values were about 5–6 times higher than those of adults, suggesting a greater vulnerability of children to the health concerns caused by toxic elements in street dust. Carcinogenic risk (CR) values via ingestion pathway indicated all elements (except Pb) had significant health effect, while CR value by inhalation results showed no significant health effect. Cumulative carcinogenic risk (CCR) value had significant health effect except Pb in all land use categories. CCR values decreased during CL and reached at acceptable limit for most of the cases. This research provides a message to the local governments and environmental authorities to have a complete assessment of toxic elements in the street dust of Dhaka megacity in order to assuring public health safety and ecological sustainability.Supplementary InformationThe online version contains supplementary material available at 10.1007/s11356-022-22541-8.

Comprehensive insight into heavy metal(loid)s in road dust from industrial and urban areas in northern Vietnam: concentrations, fractionation characteristics, and risk assessment

ABSTRACT Road dust samples were collected from 6 cities and provinces in northern Vietnam to evaluate contamination levels and distribution characteristics of 5 toxic elements, including Cu, Zn, Pb, Cd, and As. Total concentrations of 5 elements in road dust samples ranged from 18.4 to 470 (median 96.4) mg/kg, in declining order of Zn > Cu > Pb > As > Cd. Pollution levels in urban road dust from Hanoi (median 266; range 205–366 mg/kg) were generally higher than those measured in samples taken from other industrial areas (median 91.1; range 18.4–470 mg/kg). Our results showed that the emission of some heavy metals from urban areas with high population density and heavy traffic was comparable to or even higher than in manufacturing areas of electronic components, construction materials, and mining. The chemical fractions of heavy metals in road dust were also evaluated. More than 60% of heavy metals are present in the potential mobile phases, indicating that the anthropogenic metals are still in a relatively weakly bound form. These metals can be mobile and bioaccumulative, affecting ecosystems and humans. The geological accumulation indexes indicate moderate contamination of heavy metals in many locations of this study. Cd poses an ecological threat in several urban and industrial sites. There were no serious human health risks associated with heavy metals in road dust. However, relatively high levels of Cu and Pb in road dust imply a health risk for children living in some urban and industrial areas. Further monitoring and risk assessment studies on toxic elements in road dust should be conducted, especially in developing countries’ highly urbanised and industrialised areas.

Pollution characteristics, risk assessment, and source apportionment of potentially toxic elements in road dust at two industrial parks in Trinidad and Tobago, West Indies.

Potentially toxic elements can enter the environment through natural and anthropogenic processes, with the latter considered the primary contributor. Road dust samples from two industrial parks on the island of Trinidad were investigated for heavy metal content, and the pollution status, potential health risks, and source apportionment were evaluated. Samples were acid-digested and analysed by flame atomic absorption spectroscopy. The average levels of cadmium, chromium, copper, manganese, nickel, lead, and zinc in road dust at the Frederick Settlement Industrial Park were 1.14 μg/g, 15.13 μg/g, 66.42 μg/g, 768.49 μg/g, 37.95 μg/g, 55.90 μg/g, and 573.04 μg/g, respectively, while average concentrations at the O'Meara Industrial Park were 1.20 μg/g, 16.97 μg/g, 42.72 μg/g, 482.65 μg/g, 21.12 μg/g, 136.77 μg/g, and 358.70 μg/g, respectively. Contamination assessments evaluated both Fredrick Settlement and O'Meara as typically uncontaminated to moderately polluted, with the overall ecological risk deemed low at all locations. Hazard index values at all sampling areas were lower than 1, indicating no potential non-carcinogenic risks to children or adults, while the carcinogenic exposure risks for cadmium, chromium, and nickel were considered low. Principal component analysis and cluster analysis revealed two main sources of contamination for Fredrick Settlement, and three main sources for O'Meara. Based on the groupings obtained, the presence of potentially toxic elements was attributed primarily to specific anthropogenic activities within the industrial parks, with lesser contributions from vehicular-related sources.

Analysis, sources and health risk assessment of trace elements in street dust collected from the city of Hamedan, west of Iran

Analysis, sources and health risk assessment of trace elements in street dust collected from the city of Hamedan, west of Iran

Pollution levels and health risk assessment of potential toxic elements in road dust from different functional areas of Plateau city in SW China

Pollution levels and health risk assessment of potential toxic elements in road dust from different functional areas of Plateau city in SW China

Potentially toxic elements in street dust from an urban city of a developing country: ecological and probabilistic health risks assessment.

Anthropogenic activities in and around the urban highways followed by aerodynamic processing generate street dusts, which can cause adverse health effects through different exposure pathways. Hence, considering the high degree of industrialization, concomitant unplanned urbanization, and rapid demographic augmentation, street dust samples from an urban city (Gazipur, Bangladesh) were investigated in terms of potentially toxic elements (using ICP-MS) to evaluate their ecological and health risks. Mean concentrations (± SD) of lead (Pb), copper (Cu), chromium (Cr), cadmium (Cd), zinc (Zn), nickel (Ni), and arsenic (As) in the analyzed air-dried samples were 40.9 ± 13.6, 44.9 ± 15.4, 83.3 ± 19.0, 9.1 ± 5.4, 239.1 ± 34.7, 33.5 ± 10.4, and 2.1 ± 0.8 mg/kg, respectively with heterogeneous distribution which were 0.2 (As) to 82.7 (Cd) times higher than the available internationally recommended limits. Element-specific environmental indices revealed that contamination levels followed the descending order as Cd > Zn > Cu > Pb > Cr > Ni > As, whereas individual ecological risks followed the descending order as Cd > Cu > Pb > Ni > Zn > Cr > As. Sampling site-specific composite indices indicated that sampling sites with high loadings of traffic, population, industrialization, and urbanization were mostly polluted. Multivariate statistical approaches also deduced the similar origins of the studied elements. In terms of the investigated elements, the study site possessed high potential ecological risks, although non-carcinogenic and carcinogenic risks through different pathway's exposures seem insignificant, where children are more vulnerable than adults.

Source and Health Risk Assessment of PM2.5-Bound Metallic Elements in Road Dust in Zibo City

To study the pollution characteristics, sources, and ecological and health risk of PM2.5-bound metallic elements in road dust in Zibo City, a total of 97 dust samples were collected in eight districts between October 2016 and May 2017, and particles smaller than 2.5 μm were suspended filtered using a resuspension system. Inductively coupled plasma mass spectrometry (ICP-MS) and optical emission spectrometry (ICP-OES) were used to investigate 18 metal elements within the dust samples. The results showed that the mass fraction of Ca[ω(Ca)] was highest with an average of 120307.7 mg·kg-1, which was 7.2 times higher than the soil background values for Shandong Province. The mean values of ω(Zn), ω(Cu), ω(Sb), and ω(Cd) were 13.9, 11.7, 13.3, and 29.6 times higher than the background values, respectively. The geo-accumulation index (Igeo) indicated high levels of Cd, Zn, Cu, and Sb pollution, especially in winter. Enrichment factors (EFs) also indicated high concentrations of Cd, Zn, Sb, and Cu in the road dust, which were notably affected by human activities. Principal component analysis (PCA) showed that biomass combustion, coal burning, vehicle emissions, iron and steel smelting, and soil dust are the five main sources of metal elements in road dust in Zibo City. The potential ecological risk of Cd and the total potential risk were extremely high during three seasons and was highest in winter. Health risk assessment showed that As and Pb had a non-carcinogenic risk for children, while Cr presents a carcinogenic risk. In conclusion, pollution from PM2.5-bound metallic elements in road dust in Zibo City is derived from anthropogenic sources and is most severe during winter. Importantly, the levels of pollution detected represent potential ecological risk as well as some non-carcinogenic and carcinogenic risks for children. Therefore, the source control of road dust requires particular attention.

Pollution Caused by Potentially Toxic Elements Present in Road Dust from Industrial Areas in Korea

We examined the pollution characteristics of potentially toxic elements (PTEs) in road dust (RD) from nine industrial areas in South Korea to assess PTE pollution levels and their environmental risks for devising better strategies for managing RD. The median concentrations (mg/kg) were in the order Zn (1407) &gt; Cr (380) &gt; Cu (276) &gt; Pb (260) &gt; Ni (112) &gt; As (15) &gt; Cd (2) &gt; Hg (0.1). The concentration of PTEs was the highest at the Onsan Industrial Complex, where many smelting facilities are located. Our results show that Onsan, Noksan, Changwon, Ulsan, Pohang, and Shihwa industrial areas are heavily polluted with Cu, Zn, Cd, and Pb. The presence of these toxic elements in RD from the impervious layer in industrial areas may have a moderate to severe effect on the health of the biota present in these areas. The potential ecological risk index (Eri) for PTEs was in the decreasing order of Cd &gt; Pb &gt; Hg &gt; Cu &gt; As &gt; Zn &gt; Ni &gt; Cr, indicating that the dominant PTE causing ecological hazards is Cd owing to its high toxicity. Our research suggests the necessity for the urgent introduction of an efficient management strategy to reduce RD, which adds to coastal pollution and affects human health.

Spatial distribution and sources of potentially toxic elements in road dust and its PM10 fraction of Moscow megacity

For the first time, the contents of potentially toxic elements (PTEs) in road dust and in its PM10 fraction were studied in Moscow from June 09 to July 30, 2017 on roads with different traffic intensities, inside courtyards with parking lots, and on pedestrian walkways in parks. The contents of PTEs in road dust and PM10 fraction were analyzed by ICP-MS and ICP-AES. The main pollutants of road dust and its PM10 fraction included Sb, Zn, W, Sn, Bi, Cd, Cu, Pb, and Mo. PM10 was a major carrier of W, Bi, Sb, Zn, Sn (accounts for >65% of their total contents in road dust); Cu (>50%); and Cd, Pb, Mo, Co, Ni (30–50%). PM10 fraction was 1.2–6.4 times more polluted with PTEs than bulk samples. Resuspension of roadside soil particles accounted for 34% of the mass of PTEs in road dust and for 64% in the PM10 fraction. Other important sources of PTEs were non-exhaust vehicles emissions (~ 20% for dust and ~14% for PM10) and industrial emissions (~20% and ~6%). The road dust and PM10 particles were most contaminated in the central part of the city due to the large number of cars and traffic congestions. Local anomalies of individual PTEs were observed near industrial zones mainly in the west, south, and southeast of Moscow. In the yards of residential buildings the total enrichment of road dust and PM10 with PTEs was only 1.1–1.5 times lower than that on major roads which poses a serious danger to the population spending a significant part of their lives in residential areas. The spatial pattern of the PTEs distribution in road dust and its PM10 fraction should assist in more efficient planning of washing and mechanical cleaning of the road surface from dust to minimize the risk to public health.

A comprehensive exploration of risk assessment and source quantification of potentially toxic elements in road dust: A case study from a large Cu smelter in central China

Large-scale industrial activities emit large amounts of potentially toxic elements (PTEs) in the form of particulate pollutants. Most of these pollutants settle on the road and eventually mix into the road dust. In the long-term, they will have adverse effects on ecosystems and human health. In this research, various analytical methods were used to assess the pollution characteristics of the 12 PTEs (Mn, Ni, Cu, Zn, Hg, Cd, As, Cr, Pb, Tl, Co, and Sb) in the study area, and geo-statistics served to analyze the spatial distribution characteristics of PTEs. Combining the potential ecological risk method and health risk assessment with positive matrix factorization (PMF) from different sources entailed a quantitative evaluation. Taking a large Cu smelter in central China as an example, three sources were quantitatively apportioned, these being smelting emissions and transportation activities (54.04%), daily human activities and natural existence (33.36%), as well as coal-fired activities of industrial production (12.60%) separately. The results showed that in more than 90% of the samples, Cd, Cu, Hg, Pb, As, Zn, Tl and Sb indicated high levels of contamination. In terms of spatial distribution, the high-value PTEs were mainly distributed near the smelter. Regarding ecological risk, smelting emissions and transportation activities were the greatest source, followed by coal-fired activities. As for human health risk, adults did not have significant non-carcinogenic risk, but children had obvious non-carcinogenic risk. Among different sources, the risk of smelting emissions and transportation activities were the highest. After calculating the value of carcinogenic risks, it emerged there was no obvious carcinogenic risk for children and adults in the study area. The comprehensive approach combining risk assessments with source identification is very effective in identifying prior pollutants and important sources of pollution. They can provide a good theoretical reference for effective prevention and control of pollution.