Electrostatic Charging Tendency Of Oil Research Articles

Impact of various stresses on the streaming electrification of transformer oil

In this contribution the influence of various stresses and their combined impact on the electrostatic charging tendency of oil is studied. Various physicochemical properties were measured according to ASTM Standards to detect changes in oil quality. A free radical reagent, 2.2 diphenyl-1-picrylhydrazyl (DPPH), was added to oil before and after the application of stresses to determine free radical concentration. The results obtained show that the application of stresses contributes to an increase in the electrification current. These results also demonstrate that electrification current is affected by the quantity of the free radicals.

Influence of various compounds on electrostatic charging tendency in insulating oil

AbstractThe influence of various compounds on the increase of the electrostatic charging tendency (ECT) in insulating oil was investigated. Sulfide compounds, which are contained in new mineral oil, are identified for the first time as the original materials involved in the increase of the ECT. This is verified by heating tests of alkylbenzene with the addition of various compounds. Coexistence with copper and injection of oxygen enhance the increase of the ECT. Some sulfide and sulfoxide compounds increase the ECT markedly. On the other hand, the influence of sulfones, which are oxidation products of sulfoxides, is negligible. Although sulfonic acids, which are oxidation products of sulfones, markedly increase the ECT, the polarity is reverse. Thus, the ECT is influenced by the kinds and the molecular structures of additive sulfur compounds. The influence of nitrogen compounds and that of oxygen compounds are confirmed to be smaller than that of sulfur compounds. Since the amounts of nitrogen compounds and oxygen compounds are much smaller than those of sulfur compounds in mineral insulating oils, the influence of these compounds is considered negligible. Since the ECT of oils with the addition of sulfides or sulfoxides increases after heating, the other compounds should be created from these compounds that increase the ECT directly. Thus, the increase of the ECT is mostly caused by the oxidation of sulfides, which creates sulfoxides. Then certain compounds, which directly increase the ECT, are created from sulfoxides. If sulfones or sulfonic acids are created by the oxidation of sulfoxides, the ECT decreases because of the influence of these compounds on the ECT. It is most likely that some process other than oxidation occurs in the creation of the compounds that increase the ECT directly. © 2011 Wiley Periodicals, Inc. Electr Eng Jpn, 176(3): 29–36, 2011; Published online in Wiley Online Library (wileyonlinelibrary.com). DOI 10.1002/eej.21112

Electrostatic charging tendency and correlation analysis of mineral insulation oils under thermal aging

In order to investigate the electrostatic charging tendency (ECT) of transformer oil under thermal aging and understand its correlations to the other insulation parameters, a series of accelerated aging tests were carried out on two types of mineral insulation oils, A and B, both of which were mainly used in 500 kV power transformers in China. Oil samples were pre-processed by degassing and dehydrating, and then aged at 120°C for various periods up till to 675 h, meanwhile, different contents of oxygen and copper/pressboard/silicon steel sheet were also added into the oil samples for sensitive study. The results indicate that the ECT of oil A increases notably with aging time, the ECT of oil B however does not change so much during the whole aging period. Injection of oxygen in the samples enhances the ECT of oil A, such a promotion effect is minor for oil B. The correlations between the ECT and other parameters, such as tanδ, volume resistivity (ρ <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">v</sub> ) and acid number were analyzed as well. There are linear correlations between ECT and tanδ, acid number and log (ρ <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">v</sub> ) of oil A, of which ECT and tanδ has the highest correlation coefficient of 0.881. Regarding oil B, there is only a positive linear correlation between ECT and acid number.