Electron Backscatter X-ray Diffraction Research Articles

Microstructure characterization and tensile properties of CMT-based wire plus arc additive manufactured ER2594

A wall component of super-duplex stainless steel was developed using cold metal transfer (CMT)-based wire + arc additive manufacturing (WAAM) technique with an ER2594 wire. The microstructure of the as-deposited wall was explored using optical microscopy and electron backscattered x-ray diffraction (EBSD) analysis. Ferrite count analysis indicated that the austenite-ferrite phase balance was altered along the as-deposited wall body. The average ferrite count near the as-deposited wall was 24.5%, compared with 32.3% in the root region. Widmanstätten and grain boundary austenite were formed near the wall boundary, and intragranular austenite was observed in the different layers. Secondary austenite in the transition layer was also observed. EBSD analysis revealed the sigma (σ) phase and austeno-ferritic phases across the WAAM wall. The tensile and yield strengths of the samples of the as-developed WAAM wall were almost identical regardless of orientations/tropism.

Direct ageing response on the microstructure and mechanical properties of electron beam welds of Ni-Cr-Fe alloy used in vacuum insulated tubing

Incoloy 925 joints of 5 mm thick were accomplished by adopting high energy density, electron beam welding (EBW) process. Although the weld seam microstructure was completely austenitic and free from solidification cracking, the heat-affected zone (HAZ) of EBW joints experienced liquation cracking. The mechanical behaviour of the EB weld seams in the as-welded and direct aged (DA) at 732 °C for 4 h and air-cooled conditions were compared. Electron backscattered X-ray diffraction (EBSD) analysis revealed the formation of strengthening precipitate γ′ in the matrix and the precipitation of sigma (σ) phase, M7C3, M23C6 and Ti-rich carbides formed along the crystallite boundaries in the DA condition. The tensile property outcomes opined that the joint efficiency of the weld seams in the DA condition (99.32 %) was found to be better than the ones in the as-welded condition (71.32 %). Also, the yield strength has been considerably improved in the EB weld seams subjected to DA conditions. The carbide precipitation along the grain boundaries is discontinuous and also not effective in pinning the dislocations under impact loads.

Calcite Twinning in the Ordovician Martinsburg Formation, Delaware Water Gap, New Jersey, USA: Implications for Cleavage Formation and Tectonic Shortening in the Appalachian Piedmont Province

A traverse across the Stone Church syncline in the Ordovician Martinsburg turbidites reveals an axial planar cleavage (N40°E, SE dips) in regional thrust-related folds (N40°E, shallow plunges) and five phases of sparry calcite. Calcite fillings are bedding-parallel, cleavage-parallel, and one vein set cross-cuts both earlier phases; the youngest calcite filling is a bedding-parallel fault gouge that crosscuts the cleavage and preserves top-down-to-the-southeast normal fault kinematics. Calcite veins unique to disharmonically-folded calcareous siltstones (Maxwell, 1962) were also analyzed. Stable isotopic analysis (O, C) of all of the calcite phases indicates a uniform fluid source (δ13C −2.0, δ18O −13.3 VPDB) and, potentially, a similar precipitation and mechanical twinning age. The twinning strains (n = 1341; average Δσ = −32 MPa; average ε1 = −2.9%) in the calcite suite are consistent with SE-NW thrust shortening, and sub-horizontal shortening perpendicular to evolving axial planar cleavage planes in the Stone Church syncline. Calcareous siltstone layers within the Martinsburg Fm. turbidites share concordant bedding planes and are unique, chemically (XRF), but folded and cleaved differently than the surrounding clay-rich Martinsburg turbidites. Neither sediment type yielded detrital zircons. Electron backscatter X-ray diffraction (EBSD) and calcite twinning results in a folded calcareous siltstone layer preserving a layer-normal SE-NW shortening strain and Lattice Preferred Orientation (LPO). Shortening axes for the five-phase calcite suite trends ~N40°W, consistent with tectonic transport associated with crystalline nappe emplacement of the Reading Prong within the Piedmont province.