Electron Backscatter Diffraction Measurements Research Articles

Unraveling factors affecting the reversibility of martensitic phase transformation in FeNiCoAlTi shape memory alloys: Insights from HR-EBSD and acoustic emission analysis

The reversibility of the martensitic phase transformation is crucial for the functionality of shape memory alloys. The easier the martensite is pinned, the faster occurs the degradation of the shape memory effect during cyclic loading. This study investigates various factors influencing the stabilization of martensite during deformation of single-crystalline states of the FeNiCoAlTi system. In order to investigate early pinning mechanisms in more detail a 〈011〉 single crystal with expected lower reversibility of the martensitic phase transformation and, consequently, lower superelasticity was chosen. Complementary in situ methods, such as digital image correlation and acoustic emission, were used to characterize the evolution of the martensitic phase transformation and the role of dislocations during deformation. Thereby, experimental evidence was elaborated pointing at mechanisms that so far have been underrated in terms of functional degradation. Beside interaction of martensitic variants and dislocation activity, detwinning, associated with high acoustic energy, was identified as an additional significant factor contributing to reduced reversibility and superelasticity. In addition, high-resolution electron backscatter diffraction measurements were applied for the first time to identify residual stresses in the austenitic matrix, which significantly contribute to the reverse transformation. Micro-mechanical experiments using pillar compression tests were carried out to study the influence of residual back stresses of the austenitic matrix on the reversibility of the martensitic phase transformation. A reduced reversibility was found in the case of the absence of back stresses. The findings from this study foster the understanding of pinning mechanisms during loading of the FeNiCoAlTi shape memory alloy eventually enabling targeted optimization for enhanced superelastic material behavior.

Influence of Heat Treatment on Microstructure Evolution and Yield Surfaces of Ni/PU Hybrid Foams

Metal foams are characterized by low weight, high resource efficiency, high relative stiffness, and exceptional energy absorption capacity under compressive load. Nickel/polyurethane (Ni/PU) hybrid foams consist of an open‐cell polyurethane foam coated with a layer of nickel produced by electrochemical deposition. The coating of the PU foams takes place in a flow reactor, in which the electrolyte is pumped through the foam at a defined flow velocity. The macromechanical properties of foam‐like structures depend on the structure of the skeleton, the inherent material properties and, in the case of Ni/PU hybrid foams, the properties of the electrochemically generated nickel layer. To influence their mechanical properties, the Ni/PU hybrid foams are subjected to heat treatment. In the given experimental setup, the parameters flow velocity, temperature, and duration of the heat treatment are each investigated at two different levels. Thus, interactions between the initial microstructure and the type of heat treatment are evaluated by means of X‐ray diffraction (XRD) and electron backscatter diffraction (EBSD) measurements. Interactions between initial mechanical properties and heat treatment are investigated by uniaxial compression tests and superimposed compression‐torsion tests. The knowledge gained is used to control the macromechanical properties of the hybrid foam.

Microstructure-Based Modeling of Deformation and Damage Behavior of Extruded and Additively Manufactured 316L Stainless Steels.

In this study, we investigated the micromechanical deformation and damage behavior of commercially extruded and additively manufactured 316L stainless steels (AMed SS316L) by combining experimental examinations and crystal plasticity modeling. The AMed alloy was fabricated using the laser powder bed fusion (LPBF) technique with an orthogonal scanning strategy to control the directionality of the as-fabricated material. Optical microscopy and electron backscatter diffraction measurements revealed distinct grain morphologies and crystallographic textures in the two alloys. Uniaxial tensile test results suggested that the LPBFed alloy exhibited an increased yield strength, reduced elongation, and comparable ultimate tensile strength in comparison to those of the extruded alloy. A microstructure-based crystal plasticity model was developed to simulate the micromechanical deformation behavior of the alloys using representative volume elements based on realistic microstructures. A ductile fracture criterion based on the microscopically dissipated plastic energy on a slip system was adopted to predict the microscopic damage accumulation of the alloys during plastic deformation. The developed model could accurately predict the stress-strain behavior and evolution of the crystallographic textures in both the alloys. We reveal that the increased yield strength in the LPBFed alloy, compared to that in the extruded alloy, is attributed to the higher as-manufactured dislocation density and the cellular subgrain structure, resulting in a reduced elongation. The presence of annealing twins and favorable texture in the extruded alloy contributed to its excellent elongation, along with a higher hardening rate owing to twin-dislocation interactions during plastic deformation. Moreover, the grain morphology and defect state (e.g., dislocations and twins) in the initial state can significantly affect strain localization and damage accumulation in alloys.

Nanoscale speckle patterning for combined high‐resolution strain and orientation mapping of environmentally sensitive materials

AbstractScanning electron microscopy‐based high‐resolution digital image correlation (HRDIC) is now an established technique, providing full‐field strain and displacement measurement at the microscale. Techniques for generating speckle patterns for sub‐micron strain mapping can often be either substrate dependent or rely on applying aggressive conditions which may alter the microstructure of interest or damage the substrate in highly sensitive materials. We detail a modification of a methodology successfully applied in the literature to allow its use with metallic materials that are particularly sensitive to the corrosive media, such as copper‐base alloys. Nanometre‐thick silver films, applied with physical vapour deposition, are remodelled using NaBr in non‐aqueous isopropanol, replacing the aqueous solution of NaCl in the original method, forming a uniform dispersion of silver islands highly suitable for digital image correlation (DIC) measurement. The entire procedure is performed at ambient temperature. We find that the DIC pattern is suitably electron transparent to allow electron backscatter diffraction (EBSD) measurements without pattern removal, producing diffraction patterns of sufficient quality for cross‐correlation based high‐angular resolution EBSD. This property facilitates simultaneous EBSD and DIC mapping experiments, providing deeper insights into the kinematics of plastic deformation in crystalline materials. Sub‐100 nm islands are achieved through control of the sputter coating parameters, resulting in DIC cross‐correlation subwindows of 140 nm with a 50% overlap. This resolution is sufficient to capture the fine detail of strain localisation phenomena during plastic deformation, demonstrated here with a case study in CuCrZr, a precipitation‐hardened heat sink material for application in nuclear fusion components. Here, we extract full‐field displacement data with DIC and corresponding orientation information using EBSD without the need for pattern removal.

Directed energy deposition of 18NiM300 steel: effect of process and post processing conditions on microstructure and properties

ABSTRACT This current study investigates the effect of Direct Energy Deposition (DED) process conditions on the properties and microstructure of M300 maraging steel samples. The investigation centers on two key factors: laser power and deposition environment. The microstructure of this tool steel is analyzed by computing the Primary Cellular Arm Spacing. The findings revealed a significant influence of both inert atmosphere and laser power on cooling conditions. These different cooling rates influence the phase content as demonstrated by X-Ray Diffraction and Electron Backscatter Diffraction measurements. It was demonstrated the presence of different content of residual austenite at cell boundaries. These distinct microstructural features caused variations in the hardness values of the printed samples. Furthermore, a direct aging heat treatment was implemented, that was chosen from Differential Scanning Calorimetry measurements results. This heat treatment proves effective in achieving consistent hardness increases and eliminated the differences among samples built in different process conditions. This outcome suggests the possibility of selecting the most economically viable DED parameters for optimal results.

A Study of {10-12} Twinning Activity Associated with Stress State in Mg-3Al-1Zn Alloy during Compression

An eight-sided prism sample, obtained from a hot-rolled AZ31 magnesium alloy sheet, was compressed at room temperature along the transverse direction to investigate the influence of local strain on twinning behavior using electron backscatter diffraction (EBSD) measurements, hardness distribution, and metallographic observations. The octagonal surface of the sample was divided into distinct regions based on hardness distribution and metallographic observations. Combined analysis of the Schmid factor (SF) and the strain compatibility factor (m’) was employed to study twin variant selection. Basal on SF ratio distribution, the Schmid factor criterion, can predict over 75% of observed twin variants in regions A and D (normal stress samples). In contrast, 64% of twin variant selection behavior in region C (shear stress sample) can be effectively explained using a pure shear model. Twin variants with high strain compatibility factors may prefer activation to reduce stress concentration. The strain compatibility factor is more appropriate than the Schmid factor for analyzing the effect of local strain on the selection behavior of twin variants.

Micro-mechanics investigation of heterogeneous deformation fields and crack initiation driven by the local stored energy density in austenitic stainless steel welded joints

This work investigates the heterogeneous deformation and failure of HR3C austenitic stainless steel welded joints at room and typical service temperatures. Such types of welded joints are widely used in the new generation of fossil fuel power stations and are known to suffer from premature high temperature failure. Observation of in-service failures revealed that cracks may nucleate either in the heat affected zone or in the weld metal. The main objective of this work is to identify the local microstructural conditions and stress–strain fields responsible for both ductile failure and micro-crack nucleation within the weldment at low and high temperatures, respectively. To that purpose, a novel multi-scale micromechanics-based modelling framework is proposed. It relies on representative weld microstructure models digitally reconstructed from electron backscatter diffraction measurements, and dislocation density-based crystal plasticity models to describe the behaviour of individual grains in each weld region. A novel thermo-dynamically consistent relation for the configuration stored energy per unit volume is derived from the crystal plasticity framework.The single crystal models are calibrated and validated from a combination of uniaxial tensile tests on cross-weld specimens using high resolution digital image correlation techniques, representative volume elements of the polycrystals at the macro-scale, as well as micropillar compression tests at the scale of the individual grains. Predictions of heterogeneous inelastic deformation fields within the weldment at both 22 °C and 665 °C, and of micropillar compression behaviour of the individual weld single crystal phases are consistent with experimental data. The experimentally observed ductile failure of the weld metal at room temperature is successfully predicted using a Gurson-type void nucleation, growth and coalescence constitutive model. The suitability of the stored strain energy density and the accumulated plastic strain as crack initiation/creep failure indicators is investigated. It was found that predicted creep lifetimes with either indicator were very similar, and that they were relatively accurate for low stress levels.

Fatigue Analysis of the Nickel-Based Superalloy Inconel 617 by Fatigue Experiments and EBSD Data-Based Finite Element Simulations in Correlation with E·m Theories

Nickel-based superalloys exhibit pronounced elastic anisotropy and, hence, the local grain orientation strongly affects the stress and strain distribution in the material under mechanical loadings. Therefore, the crack initiation and failure behaviour of components made from nickel-based superalloys are complex and hardly predictable. A better fundamental understanding of the phenomena that occur in nickel-based superalloys under a quasistatic and cyclic load is therefore desired. Previously, a continuum mechanics-based model has been successfully developed, considering the grain structure, the elastic anisotropy, and the Schmid factor, based on data from electron backscatter diffraction (EBSD). The E·m model was confirmed by the finite element method (FEM) simulations and experimental observations regarding the resulting average stresses and strains in the individual grains as well as the formation of slip bands under a quasistatic load with few restrictions. The behaviour under cyclic loadings has been investigated in this work to correlate the mechanical behaviour, simulated by the previously developed FE models, with the local stiffness and Schmid factors considering fatigue failure. For this purpose, the fatigue behaviour of Inconel 617 samples was characterised up to the high-cycle fatigue (HCF) regime, accompanied by EBSD measurements for stress amplitudes that resulted in strains close to the elastic–plastic regime. The EBSD data were used to create digital twins of the samples to simulate the mechanical reaction to a displacement similar to the associated strain of the fatigue tests. An analysis of the fractured samples by scanning electron microscopy was performed to retrace the location of the crack initiation supported by the EBSD measurements before and after fatigue testing. Two samples were investigated in detail that showed different fracture types. Sample 1 showed transcrystalline failure in a grain that showed a high Young’s modulus, Schmid factor, and resolved shear stress that indicates a failure due to the properties of the grain itself. In contrast, an intercrystalline failure was observed for sample 2 that showed large differences in the orientation and, hence, largely different mechanical properties in the area of failure as well. The observed failure types, the resulting stresses and strains calculated by the FE model, and the consideration of the E·m model showed an agreement of all the methods. Therefore, the findings of this work complement previous investigations of the mechanical behaviour of coarse-grained anisotropic nickel-based superalloys with a focus on the orientations of the grains towards the loading direction.

Ultrasonic scattering from polycrystals with transversely isotropic material texture

During laser-based metal additive manufacturing (AM), the melted powder is subjected to rapid cooling and the resulting microstructures often have material texture. In many cases, the texture is uniaxial (i.e., transversely isotropic) such that one symmetry axis defines the material response. Therefore, ultrasonic inspection methods that exploit the scattering from the microstructure are complicated by the resulting texture which affects the coherent propagation and scattering. In this presentation, a generalized approach is described in which the covariance of the elastic modulus tensor for a uniaxial ensemble of cubic crystals is expressed in terms of a fundamental set of constants. These constants are determined for an arbitrary texture from synthetic polycrystals created using DREAM.3D. With this information, calculations for wave velocity, attenuation, and diffuse scattering can be made efficiently for any wave type and propagation direction relative to the material symmetry axis. Results are compared with analytical expressions for simplified cases and then more generalized textures are examined. Finally, prospects for characterization of components created using metal AM are discussed within the context of input data from electron backscatter diffraction measurements. These results are expected to provide insight regarding the inversion of measurement data for texture characterization.

Comparative study about the results of HAZ physical simulations on different high-strength steel grades

With continuous improvements, structural steels are available in even higher strength grades above 1000 MPa yield strength. As the great majority of these steels are used in welded structures, their weldability needs to be taken into account. Several factors can cause difficulties during welding of these steels, but in this paper the softening behavior and the toughness characteristics of the heat-affected zone (HAZ) are examined. As the critical parts of the HAZ in a real welded joint are relatively small, their investigating ability is limited. However, the physical simulation provides a way of evaluating specimens made from a given material to produce the specified HAZ areas in a suitable size range for subsequent testing. In this research work, three different strength categories of high-strength structural steels (with yield strength of 960 MPa, 1100 MPa, and 1300 MPa) are investigated by physical simulation. In the case of different technological variants of gas metal arc welding (GMAW) process, the effect of the cooling time t8/5 is investigated in different HAZ subzones considered to be critical. The thermal cycles were determined according to the Rykalin 3D model. The investigated cooling times were t8/5 = 5 s, 15 s, and 30 s. The properties of the selected coarse-grained, intercritical and intercritically reheated coarse-grained zones are analyzed by laser scanning microscope, scanning electron microscope, hardness test, and instrumented Charpy V-notch impact toughness test. Furthermore, additional investigation like JMatPro calculations, electron backscatter diffraction measurements, and prior austenite grain size calculation were carried out. As a result of the tests, the investigated heat-affected subzones indicated higher sensitivity to the welding heat input compared to conventional structural steels. Overall, the results of the tests show that the application of shorter t8/5 cooling time can be beneficial for the investigated high-strength steel grades, since significant toughness reduction and the risk of softening occur in the whole cooling time range.

Seismic Anisotropy of Mafic Blueschists: EBSD‐Based Constraints From the Exhumed Rock Record

AbstractSeismic anisotropy constitutes a useful tool for imaging the structure along the plate interface in subduction zones, but the seismic properties of mafic blueschists, a common rock type in subduction zones, remain poorly constrained. We applied the technique of electron backscatter diffraction (EBSD) based petrofabric analysis to calculate the seismic anisotropies of 14 naturally deformed mafic blueschists at dry, ambient conditions. The ductilely deformed blueschists were collected from terranes with inferred peak P‐T conditions applicable to subducting slabs at or near the plate interface in active subduction zones. Epidote blueschists display the greatest P wave anisotropy range (AVp ∼7%–20%), while lawsonite blueschist AVp ranges from ∼2% to 10%. S wave anisotropies generate shear wave splitting delay times up to ∼0.1 s over a thickness of 5 km. AVp magnitude increases with glaucophane abundance (from areal EBSD measurements), decreases with increasing epidote or lawsonite abundance, and is enhanced by glaucophane crystallographic preferred orientation (CPO) strength. Two‐phase rock recipe models provide further evidence of the primary role of glaucophane, epidote, and lawsonite in generating blueschist seismic anisotropy. The symmetry of P wave velocity patterns reflects the deformation‐induced CPO type in glaucophane—an effect previously observed for hornblende on amphibolite P wave anisotropy. The distinctive seismic properties that distinguish blueschist from other subduction zone rock types and the strong correlation between anisotropy magnitude/symmetry and glaucophane CPO suggest that seismic anisotropy may be a useful tool in mapping the extent and deformation of blueschists along the interface, and the blueschist‐eclogite transition in active subduction zones.

Suppression of spiking defects in deep penetration electron beam welded ETP copper

The electron beam is an appropriate tool to weld pure copper due to its high absorptivity on the copper surface, a high power density and inert vacuum environment. However, deep penetration electron beam welding of pure copper often produces the spiking defect. In this work bead on plate electron beam welding was done on Cu-ETP. A critical welding speed was determined for the distinction between a conduction-determined (at lower welding speed) and a non-conduction-determined welding speed range (at higher welding speed). The influence of high preheating temperatures was shown. The welds were investigated by light optical microscopy, electron backscatter diffraction measurements, ultrasonic testing, in situ thermal imaging, electrical resistance measurements and tensile tests. It was shown that in the conduction-determined welding speed regime without preheating, full and partial penetration welds exhibited root porosity. This effect was related to the overheating of the weld pool in combination with the phenomena causing spiking. Low defect root formation was achieved by using welding speeds greater than the critical value or by applying high preheating temperatures. The joints reached up to 98% of the international annealed copper standard in terms of specific electrical conductivity. Rupture took place within the joints during tensile tests. The joints exhibited up to 77% of the ultimate tensile strength of the base metal. Welds carried out with preheating exceeded the base metal regarding the fracture strain.

AM Bench 2022 Macroscale Tensile Challenge at Different Orientations (CHAL-AMB2022-04-MaTTO) and Summary of Predictions

The additive manufacturing benchmarking challenge described in this work was aimed at the prediction of average stress–strain properties for tensile specimens that were excised from blocks of non-heat-treated IN625 manufactured by laser powder bed fusion. Two different laser scan strategies were considered: an X-only raster and an XY raster, which involved a 90∘\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$^\\circ $$\\end{document} rotation in the scan direction between subsequent layers. To measure anisotropy, multiple tensile orientations with respect to the build direction were investigated (e.g., parallel, perpendicular, and intervals in between). Benchmark participants were provided grain structure information via electron backscatter diffraction measurements, as well as the stress–strain response for tensile specimens manufactured parallel to the build direction and produced by the XY scan strategy. Then, participants were asked to predict tensile properties, like the ultimate tensile strength, for the remaining specimens and orientations. Interestingly, the measured mechanical properties did not vary linearly as a function of tensile orientation. Moreover, specimens manufactured with the XY scan strategy exhibited greater yield strength than those corresponding to the X-only scan strategy, regardless of orientation. The benchmark data have been made publicly available for anyone that is interested [1]. For the modeling aspect of the challenge, five teams participated in this benchmark. While most of the models incorporated a crystal plasticity framework, one team chose to use a more semiempirical approach and to great success. However, no team excelled at all the predictions, and all teams were seemingly challenged with the predictions associated with the X-only scan strategy.

Mechanical properties and microstructural evolution of 5052 aluminumalloys by multi-pass stretching and induced electro-pulsing treatment

A compound-forming method that combines multi-pass stretching and induced electro-pulsing treatment (IEPT) is proposed. The effects of induced current on the microstructure and mechanical properties of material were investigated using transmission electron microscopy and electron backscatter diffraction measurements. The samples stretched by 5% each time showed 145% increase in elongation after 4 stretching and IEPT cycles. The IEPT caused “stress drop” in pre-deformed sheets, while the plasticity increased. Meanwhile, the dislocation density decreased, the deformation structure changed to the substructure, and the grain size increased slightly. The material anisotropy was reduced and a new 《111》//TD texture appeared after IEPT. The combination of electrical effect and Joule heating enhanced dislocation mobility and vacancy movement. The temperature distribution, with a maximum temperature reaching 144.7 °C, was simulated using ANSYS software. The theoretical calculation results were consistent with experimental data.

In-situ directed energy deposition of Al based low density steel for automotive applications

This work deals with the fabrication of one low density steel by mixing AISI S2 tool steel and AlSi10Mg powders using powder-based directed energy deposition (P-DED) technique. Two approaches of mixing powders were compared-continuous mixing during the process (in-situ) and mixing the powder prior to the process (premixed). The P-DED sample was characterised by a variety of techniques such as optical microscopy, scanning electron microscopy, electron backscatter diffraction, X-ray diffraction, and hardness measurement. Our findings demonstrate the successful achievement of steel with a 8 wt. % AlSi10Mg addition when two dissimilar powders are premixed, resulting in approximately 12% reduction in the density of S2 steel. Optimizing the powder feed rate and the ratio of AlSi10Mg powder contribute to an improvement of printability, eliminating materials separation, leading to a homogenous deposited part. Compared to the in-situ mixing case, the premixed process within the current process window generates a more homogeneous microstructure consisting of three phases: Ferrite, Fe3Al and Fe3AlC carbide. Whereas, the in-situ sample exhibits only two phases Ferrite and Fe3Al. The hardness of the premixed sample is found to be slightly higher compared to the in-situ sample.

Hierarchical Phonon Scattering from Nano to Macro Scale in Ag-Nano/TiO2-Micro Particle-Decorated p-type Bismuth Telluride Bulk Composites.

We study the thermoelectric properties of a p-type Bi0.4Sb1.6Te3.4 (BST) composite with Ag nanoparticle-decorated TiO2 microparticles (US-Ag/TiO2). The dispersion of US-Ag/TiO2 particles, synthesized by an ultrasonication (US) method, into the matrix effectively decreases lattice and bipolar thermal conductivity, attributed to the scattering centers formed at nano and micro scales. The electron backscattering diffraction (EBSD) measurements revealed smaller grain sizes within the BST composite when paired with the US-Ag/TiO2 particle dispersion. These reduced grain sizes, alongside nanoparticle-decorated microparticles dispersed throughout the matrix, scatter phonons effectively from long- to short-wavelength phonons and subsequently decrease lattice thermal conductivity. While the power factors of the composites are reduced, significant suppression of lattice and bipolar thermal conductivity has led to an increase in the maximum zT value (1.4 at 325 K) for a 0.9 wt % US-Ag/TiO2 particle dispersion within the BST matrix. This particle dispersion in the BST composite consistently demonstrates a high zT value across an extensive temperature spectrum, leading to an exceptionally high average zTavg value (1.38 up to 400 K), which is superior to the other values from reported BST composites. Thus, this research indicates that the dispersion of nanoparticle-decorated microparticles within a thermoelectric material matrix can significantly improve thermoelectric performance, which has promising implications for practical applications in thermoelectric cooling and sustainable and economical energy harvesting technologies.

In-situ heating-stage EBSD validation of algorithms for prior-austenite grain reconstruction in steel

Prior-austenite grain (PAG) structures play a critical role in determining steel microstructures and properties. Over recent years, the use of algorithms that reconstruct PAGs from electron backscatter diffraction (EBSD) measurements of martensitic or bainitic microstructures have become commonplace. These appear to work well, but there has yet to be a comparison made of the reconstructed PAG microstructure to the true PAG microstructure of a steel measured above Ae3 before transformation. Here, in-situ EBSD was used to record the austenite grain structure (at 1000 °C) before transformation, as well as the progress of subsequent martensitic and bainitic transformations. The resulting dataset, which we have made available to the community here: https://doi.org/10.5281/zenodo.8348372, was used to assess of two popular algorithms for PAG reconstruction. They were found to be accurate enough for PAG size measurement and general texture analysis, although the exact morphologies of some PAG and twin boundaries are sometimes lost.

Weighted Burgers Vector analysis of orientation fields from high-angular resolution electron backscatter diffraction

The Weighted Burgers Vector (WBV) method can extract information about dislocation types and densities present in distorted crystalline materials from electron backscatter diffraction (EBSD) maps, using no assumptions about which slip systems might be present. Furthermore, high-angular resolution EBSD (HR-EBSD) uses a cross-correlation procedure to increase the angular precision of EBSD measurements by an order of magnitude compared to conventional EBSD. However, the WBV technique has not previously been applied to HR-EBSD data and therefore it remains unclear as to which low-angle substructures can be reliably characterised by WBV analysis of conventional EBSD data and which require additional HR-EBSD processing. To establish some practical examples that can be used to guide future data-acquisition strategies, we compare the output of the WBV method when applied to conventional EBSD data and HR-EBSD data collected from the most common minerals in Earth's lower crust (plagioclase feldspar) and upper mantle (olivine). The results demonstrate that HR-EBSD and WBV processing are complementary techniques. The increase in angular precision achieved with HR-EBSD processing allows low-angle (on the order of 0.1°) structures, which are obscured by noise in conventional EBSD data, to be analyzed quantitatively using the WBV method. Combining the WBV and HR-EBSD methods increases the precision of calculated WBV directions, which is essential when using information about active slip systems to infer likely deformation mechanisms from naturally deformed microstructures. This increase in precision is particularly important for low-symmetry crystals, such as plagioclase, that have a wide range of available slip systems that vary in relative activity with changing pressure, temperature and differential stress. Because WBV directions are calculated using no assumptions about which slip systems may be present, combining this technique with HR-EBSD to refine the precision of lattice orientation gradients is ideal for investigating complex natural materials with unknown deformation histories.

An EBSD analysis of a commercial immiscible Cu43%Cr alloy after high-pressure torsion processing and annealing

ABSTRACT The influence of high-pressure torsion (HPT) and annealing on microstructure, texture and thermal stability of an immiscible composite Cu43%Cr alloy was studied using electron backscatter diffraction, X-ray diffraction and microhardness measurements. As-received alloy samples were subjected to HPT and subsequent annealing treatment in the range of 210–850°C for 1 h in order to develop ultrafine-grained (UFG) microstructures and highlight their thermal stability. The Cu and Cr grains were refined to ∼0.45 and ∼0.39 µm, respectively and exhibited equiaxed morphology. The crystallographic texture was of shear type in both Cu and Cr with the domination of C and F orientations, respectively. The UFG microstructure and texture were retained in the Cu43%Cr alloy up to 850°C. The global results show that the immiscible composite Cu43%Cr alloy exhibits a high thermal stability up to 850°C. The evolution of the microstructure, texture and thermal stability of the UFG Cu43%Cr alloy was compared to published data and available models.

Crystallography of stress-induced martensitic transformation and giant elastocaloric effect in a A textured Ni27Cu21Mn46Sn6 shape memory alloy

Shape memory alloys exploit the latent heat yielded by stress-induced martensitic transformation to achieve elastocaloric effect, being suited for solid-state cooling technology as an alternative to conventional vapor-compression refrigeration. In this work, the crystallography of stress-induced martensitic transformation and elastocaloric effect in a polycrystalline Ni27Cu21Mn46Sn6 shape memory alloy with <001>A preferential orientation produced by means of directional solidification were studied. By performing ex-situ electron backscatter diffraction (EBSD) measurements, the transition from austenite to a single variant of 6 M martensite induced by compressive loading was evidenced, following a specific transformation orientation relationship of {1 0 1}A//{1 –2 –6}M and <1 0 − 1>A//<–6 –6 1>M between two phases. Moreover, owing to the synergistic effect of large transformation entropy change tailored through manipulating the lattice volume change across the phase transformation and microstructure texturing promoted by temperature gradient effect during solidification process, the present alloy can demonstrate very remarkable elastocaloric effect, with an extremely high value of adiabatic temperature variation up to –31.8 K upon releasing a moderate compressive loading of 460 MPa. This work is expected to give insight into stress-induced martensitic transformation crystallography and offer some inspirations for designing high-performance elastocaloric materials.