Multifunctional metasurfaces have exhibited extensive potential in various fields, owing to their unparalleled capacity for controlling electromagnetic wave characteristics. The precise resolution is achieved through numerical simulation in conventional metasurface design methodologies. Nevertheless, the simulations using these approaches are inherently computationally costly. This paper proposes the Physical Insight Self-Correcting Convolutional Network (PISC-Net), which enables rapid prediction of infrared radiation spectra of metasurfaces with remarkable generalization capacity. In contrast to preceding prediction networks, we have enhanced the cognitive ability of the network to recognize physical mechanisms by designing parameter-communication modules and integrating a priori knowledge grounded in the parameter association mechanism. Additionally, we proposed an effective strategy for constructing data sets that facilitate precise tuning of absorption bands in the entire spectral range (3-14 μm) and serves to reduce the costs associated with data set development. Transfer learning is employed to obtain precise predictions for large-period metasurfaces from limited data sets. This approach demonstrates that a network trained exclusively on simulation data could predict experimental outcomes accurately, as proved by the comparative analysis between simulation, experimental testing, and prediction results. The average mean square error is less than 4%.