Electrolysis Process Research Articles

Enrichment of lithium ions for battery application by electrolysis through a nanoporous membrane

In recent years, lithium (Li) has become a valuable commodity widely used in rechargeable batteries. The present study aims to extract battery-grade lithium-ion, as lithium hydroxide (LiOH), from lithium chloride (LiCl) solution by the membrane electrolysis process. Experiments are performed using a commercial cation exchange membrane and an indigenous High flux-Nanofiltration 300 alkali resistant (HF-NF 300 AR) nanoporous membrane. The dual-chamber electrolytic cell incorporates a selective membrane to separate the feed and concentrate chambers containing LiCl solution and deionized water. These two chambers are connected with titanium electrodes through the external circuit. The in-situ design of the compact two-chambered acrylic electrolytic cell helps to separate metal ions from ionizable salts of sodium, lithium, magnesium, potassium, etc. The experiment is conducted on a laboratory scale by varying the LiCl concentration at voltages of 24 V and 36 V. The feed and concentrate solutions are analyzed for pH, conductivity, and total dissolved solids. Inductively coupled plasma-optical emission spectrometry evaluates the presence of metal ions in the solution. The study shows effective metal ion recovery and separation to achieve battery-grade Li.

Synthesis of a Hard Anodic Oxide Coating with a Structure Allowing for Its Modification by Nanoparticles

A hard anodic oxide coating’s characteristic porous structure allows for its modification by the incorporation of nanoparticles. However, achieving an appropriate microstructure requires an optimal pore arrangement and shape, which is influenced by the electrolyte composition, current densities, temperature, and processing time. To achieve pores with a diameter of about 50 nm and the most regular structure, a range of these parameters were tested. Using a two-stage manufacturing process had a beneficial effect on increasing the microporosity of the coating. The addition of phthalic acid at 0 °C did not increase the pore diameter, but allowed for the process to be carried out at higher temperatures. However, the coating produced at 20 °C had a larger pore diameter, but numerous defects. The coating obtained from the three-component solution had the most regular structure, but the smallest pore diameter.

A novel integrated solar-driven system with Ag@SiO2 nanofluid filters for generating hydrogen using seawater: Parametric assessment and optimization

Both renewable energy and fresh water inputs are required to develop sustainable green hydrogen. However, there is still a lack of an integrated system generating hydrogen cleanly. Therefore, this study aims to develop a full spectrum solar energy-driven system to co-generate fresh water and hydrogen. The seawater desalination and proton exchange membrane (PEM) electrolysis are introduced into a Ag@SiO2 nanofluid-filtered photovoltaic/thermal (PV/T) system. The desalinated seawater can be directly used for the electrolysis, realizing the self-supply of water for the hydrogen production process. A comprehensive examination is performed via modelling the integrated system to assess the influences of mass flow rates and nanofluid parameters on system function. Results reveal that the system performance is more sensitive to the mass flow rate of nanofluid than that of coolant, and concentrated nanofluids can easily affect system performance by adjusting their depth. Furthermore, mass flow rates and nanofluid parameters are optimized using a genetic algorithm with multiple-objectives. It was determined that the direct contact membrane distillation (DCMD) unit is capable of producing sufficient water for the electrolysis process. The optimal system attains a hydrogen production rate of 1.95 × 10−5 kg/s, a specific thermal energy consumption of 310.18 kWh/m3, and a system efficiency of 22.39%.

Utilizing electrooxidation for textile effluent wastewater treatment and simultaneous electrocatalytic hydrogen production: Transforming waste into energy and promoting water reuse in a circular economy context

Textile effluent wastewater poses a serious environmental risk because of its high concentration of pollutants, which include organic compounds, heavy metals, and dyes. The present study investigates the technical and economic feasibility of hybrid water electrolysis performances. Specifically, real textile effluent wastewater was utilised to examine simultaneous abatement and electrochemical hydrogen production. The treated water can be recycled in the textile mill, offering the benefits of trash-to-treasure and cost savings through the circular economy. In addition to reducing the environmental impact of textile wastewater, the synergistic approach seeks to maximise its potential for producing hydrogen as clean energy. Here, the commercially available stainless sheet was used as the anode in the electrochemical setup system and the two-dimensional Ti3C2TX MXene was used as the catalyst embedded cathode. The optimal electrode-electrolyte parameter settings resulted in an 83 % decrease in COD level and a degradation efficiency of about 88 %. The potential for widespread adoption in the textile industry is highlighted by the discussion of the economic viability and environmental advantages of using wastewater from textile effluents for pollutant degradation and hydrogen production. Hence, the energy estimation was looked at and estimated in order to evaluate the process viability. For instance, the hybrid electrolysis process uses a very small amount of electricity (0.825 kWh m−3 order−1) and has an apparent operating current (30 mA/cm2). This work could serve as a guide for the methodical assessment and choice of hybrid water electrolysis using actual wastewater. The electrode's recyclability and reuse were proven for possible commercial applications. The stability of the Ti3C2TX electrode over a wide pH range was investigated in order to produce hydrogen on a big scale at a reasonable cost.

APPLICATION OF ELECTROLYTE BASED ON SODIUM CARBONATE FOR ELECTROLYTEPLASMA SURFACE HARDENING OF STEEL 45

This article evaluates the electrolyte-plasma hardening (EPH) of steel 45 using an electrolyte based on sodium carbonate (Na₂CO₃). Theoretical foundations of the electrolysis process of a sodium carbonate aqueous solution were studied during the course of the work. The mechanical and tribological properties of 45 steel samples after EPH were studied. It was found that with an electrolyte composition of 20% Na₂CO₃ and 80% distilled water, a hardened zone with a thickness of up to 5 mm is formed after EPH. The increase in microhardness reached up to 690 HV, which corresponds to a 3–3.5 times increase compared to the initial state. The results of tribological tests showed that the friction coefficient of steel 45 decreased after EPH, indicating a significant improvement in tribological characteristics compared to the initial value before hardening. Electrochemical tests on the corrosion resistance of steel 45 were also carried out. After EPH, the corrosion rate significantly decreased for steel 45 samples, indicating its highest corrosion resistance.

Techno-economic performance analysis of biomass-to-methanol with solid oxide electrolyzer for sustainable bio-methanol production

The analysis of the technical and economic performance of an integrated biomass to methanol and solid oxide electrolysis process (BtM-SOEC) is studied to find more sustainable process of bio-methanol production. The oil palm empty fruit branch (EFB) which is abundant in Thailand is used as biomass feedstock. Modeling of the BtM-SOEC is done using Aspen Plus. For technical aspects, the production rate of oxygen and hydrogen from the SOEC can be enhanced through an appropriate adjustment of the number of cells and cell temperature. The BtM-SOEC offers higher methanol yield and overall efficiency, while consumes less energy than the conventional biomass to methanol process (BtM). The maximum methanol production rate of 0.4995 kmol h-1 derived from BtM-SOEC is achieved at a number of cells of 325 cells and a cell temperature of 700 oC, at this condition the overall efficiency is 64.79 %. The economic assessment indicates that the conventional BtM and BtM-SOEC are still not economically feasible. However, the conventional BtM is more economically feasible than the BtM-SOEC. The methanol cost of BtM-SOEC can turn out to be economically feasible when renewable electricity cost and SOEC cost decrease substantially. The methanol cost of the BtM-SOEC (620 USD ton-1) can be competitive to that of the BtM (703 USD ton-1) when the cost of input renewable electricity decreases by 80%. Consequently, this research highlights the potential of BtM-SOEC from agricultural residues for sustainable bio-methanol production in the future market condition that the cost of renewable electricity tends to continuously decrease with the technology development and increased technology adoption and the carbon policy tends to be tightened to relieve global warming.

Quantitative Analysis of Complex Aluminum Electrolytes by X-Ray Fluorescence.

The future production of electrolytic aluminum will be characterized by low temperature, low carbon emissions, and environmental friendliness, which will result in a more complex electrolyte system. Real-time analysis of electrolytes can significantly enhance the efficiency of the electrolytic process. However, accurately analyzing the composition of complex aluminum electrolytes online has been a technical challenge. This research primarily focuses on determining the ingredient contents of complex aluminum electrolytes based on elemental concentrations measured using X-ray fluorescence (XRF) according to an applicable standard. Calibration curves were established based on 53 standard samples of complex aluminum electrolytes to establish relationships between XRF fluorescence intensity and real concentrations. Analysis conducted on industrial complex electrolytes confirms that these newly constructed curves effectively reduce relative errors to less than 3%. Additionally, a feasible solution is proposed for determining the cryolite ratio (CR) in aluminum electrolytes using XRF. Results demonstrate an average deviation as low as approximately 0.02, fully meeting industrial production requirements. This technique offers numerous benefits including rapid analysis, ease of use, and cost savings.

SWEL-V: A low-cost salt-water electrolyzer. Comparative analyses with the proton exchange membrane, PEM, electrolyzer

Seawater is the largest resource on earth which makes the hydrogen production directly from seawater an economically attractive solution if the corrosion problems are solved. Traditionally in the electrolysis analysis, both electrodes are made of metals. The produced oxygen and chlorine in the electrolysis process cause high rates of corrosion resulting in using expensive alloys to slow down the corrosion process. A novel solution to the corrosion problem is introduced, tested, and experimentally proved. The novelty of the solution relies on replacing the classic high-cost positive electrodes with a non-metallic, low cost, one [1,2]. The non-metallic electrode is made of surface rock portions with high pore volume and high pores connectivity and saturated with saline water. The experimental results are compared to the freshwater Proton Exchange Membrane PEM electrolyzers. The comparison proved that the novel solution solved the corrosion challenges of the metallic electrodes with excellent efficiency and hydrogen purity.

Novel Gel method MXene-Supported Dual-Site PtNi-NiO for Electrocatalytic Water Reduction and Urea Oxidation.

Compared to the traditional oxygen evolution reaction (OER), the urea oxidation reaction (UOR) generally exhibits a lower overpotential during the electrolytic process, which is conducive to the hydrogen evolution reaction (HER) at the cathode. The superior structure and abundant sites play a crucial role in promoting the adsorption and cleavage of urea molecules. Therefore, this paper introduces a simple metal cation-induced gelation method to prepare an electrocatalyst with PtNi alloy-NiO dual sites supported on Ti3C2Tx, which simultaneously exhibits excellent UOR and HER performance. PtNi-NiOx/Ti3C2Tx demonstrates good catalytic activity for the urea oxidation reaction, requiring only 1.364V (overpotential of 0.994V) to achieve a current density of 100mAcm-2 in UOR, and also exhibits remarkable catalytic activity in the hydrogen evolution reaction, with PtNi-NiOx/Ti3C2Tx achieving a current density of 10mAcm-2 in HER with only 24mV of overpotential. In the UOR//HER two-electrode electrolysis cell, it requires only 1.361 and 1.538V to reach current densities of 10 and 100mAcm-2, respectively. According to density functional theory (DFT) calculations, the dual active sites can intelligently adsorb the electron-donating/electron-withdrawing groups in urea molecules, activate chemical bonds, and thereby initiate urea decomposition.

In Situ Transformed CoOOH@Co3S4 Heterostructured Catalyst for Highly Efficient Catalytic OER Application.

The deprived electrochemical kinetics of the oxygen evolution reaction (OER) catalyst is the prime bottleneck and remains the major obstacle in the water electrolysis processes. Herein, a facile hydrothermal technique was implemented to form a freestanding polyhedron-like Co3O4 on the microporous architecture of Ni foam, its reaction kinetics enhanced through sulfide counterpart transformation in the presence of Na2S, and their catalytic OER performances comparatively investigated in 1 M KOH medium. The formed Co3S4 catalyst shows outstanding catalytic OER activity at a current density of 100 mA cm-2 by achieving a relatively low overpotential of 292 mV compared to the pure Co3O4 catalyst and the commercial IrO2 catalyst. This enhancement results from the improved active centers and conductivity, which boost the intrinsic reaction kinetics. Further, the optimized Co3S4 catalyst exhibits admirable prolonged durability up to 72 h at varied current rates with insignificant selectivity decay. The energy dispersive X-ray spectroscopy (EDX) and Raman spectra measured after the prolonged OER stability test reveal a partial transformation of the active catalyst into an oxyhydroxide phase (i.e., CoOOH@Co3S4), which acts as an active catalyst phase during the electrolysis process.

Effect of cobalt-doped iron oxide as an electrocatalyst for water splitting and photocatalytic hydrogen evolution

Developing cost-effective and efficient electrocatalysts for the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is a significant challenge for economically viable energy conversion devices, such as electrolyzers, rechargeable metal-air batteries, and regenerative fuel cells. Here, we have synthesized cobalt doped iron oxides (CoFe2O3) with different Co:Fe wt%. Among them, Co[1:3]Fe2O3 catalyst demonstrated outstanding performance and stability positioning it as a standard electrocatalyst for OER and HER, and as a photocatalyst for H2 production. The catalysts were characterized using various techniques, including field emission scanning electron microscopy (FESEM), X-ray diffraction spectroscopy (XRD), and energy dispersive X-ray spectroscopy (EDS) demonstrating successful application in water electrolysis. Specifically, the onset potentials for OER and HER were 1.63 V/RHE and −0.23 V/RHE, respectively. The overpotential (η) required to achieve 10 mA/cm2 for OER (in alkaline medium) and HER (in acidic medium) was 0.44 and −0.3 V/RHE, respectively. Additionally, the developed OER and HER catalyst exhibited high current and potential stability over a 13-hour period. This approach is considered a promising avenue for making water electrolysis for hydrogen (H2) energy viable by minimizing the energy requirements of the electrolytic process. Similarly, the performance of the fabricated catalyst was also examined for the photocatalytic generation of H2 gas in a photo-reactor. Where the highest generation rate of 97.77 mL. (g.min−1) was recorded for Co[1:3]Fe2O3 as a photocatalyst. As a result, the Co[1:3]Fe2O3 catalyst has the potential to function as both a photocatalyst and an electrocatalyst for water splitting.

Experimental investigation on the electrical and hydrogen-production performance of a novel PEM electrolyzer driven by CdTe PV with a tracking system

Addressing the challenges of intermittent and variable energy supply, solar hydrogen production via electrolysis has garnered significant attention due to its unique advantages, emerging as a hot topic in the scientific research domain. However, the application of this technology is currently mainly related to the non-tracking system, which undergoes a rapid change in solar irradiation during the day. To expand the matching relationship of solar irradiation, PV characteristics, and electrolyzer, this paper proposes the development of a Proton Exchange Membrane (PEM) electrolyzer driven by Cadmium Telluride (CdTe) photovoltaic (PV) modules with a tracking system for hydrogen production. An experimental platform was set up in Chengdu and the performance tests were carried out for different operating modes during summer. The experimental results demonstrate that the average electrical and hydrogen production efficiencies of the system are 13.11% and 7.88%, respectively, on a sunny day, with a total of 566.7 L of hydrogen produced within 7 h of operation. Furthermore, the solar irradiation received by the tracking surface of the system is significantly enhanced by 10.29% in comparison to the horizontal surface. On a cloudy day with an electrolyzer inlet water temperature of 45 °C, the system has the potential to achieve a hydrogen production efficiency of 11.15 %. At a constant current density of 1.0 A/cm2, the efficiency of the electrolysis process increased by 2.07% and 1.25% for each 10 °C increase in the temperature of the electrolyzer, having an inlet temperature of 35 °C. This study offers a novel approach for a PV-PEM system with a higher hydrogen production efficiency while also establishing a robust foundation for technology optimization and broader implementation.

New hybrid system of PV/T, solar collectors, PEM electrolyzer, and HDH for hydrogen and freshwater production: Seasonal performance investigation

A new hybrid energy system of PV/T, flat plate collector, PEM electrolyzer, and humidification-dehumidification desalination is introduced here. A comprehensive mathematical model for the system seasonal performance is constructed and solved numerically using MATLAB software. A year-round comparison between the traditional PV/T performance and its concentrated counterpart indicates that the latter performs better compared to power, hydrogen, and freshwater production and system overall efficiency. The maximum monthly achieved PV/T efficiency, electrolyzer efficiency, desalination system Gain Output Ratio, and overall system efficiency are 52 %, 62 %, 4.8 %, and 44 %, respectively at a concentration ratio of 4 and maximum allowable PV temperature. The system produces 82,200 kWh of energy annually and provides 77,700 kWh and 1500 kWh to the electrolyzer and the electric heater, respectively. Moreover, the system produces an annual freshwater production of about 52,700 kg, out of which approximately 10,000 kg are consumed in the electrolysis process, and an annual hydrogen production of approximately 1120 kg.

CBS-YOLOv5: fault detection algorithm of electrolyzer plate with low-resolution infrared images based on improved YOLOv5

Abstract In the process of copper electrorefining, accurate detection of electrode plate faults is extremely challenging due to the low resolution of captured infrared images, significant noise interference, and dense electrode plate arrangements. To address these challenges, this paper proposes an improved YOLOv5-based electrode plate fault detection algorithm called CBS-YOLOv5. This algorithm introduces several innovations over the original YOLOv5, including: the incorporation of coordinate attention to enhance the ability of the feature extraction network to separate target information from noise; the construction of a small object detection module to improve the detection of dense small objects by increasing the resolution of the feature map; the replacement of the traditional path aggregation network with a Bi-directional Feature Pyramid Network (BiFPN) for more flexible multi-scale feature fusion; and the integration of the swin transformer to optimize the cross-stage partial bottleneck structure, significantly enhancing the model’s ability to detect densely packed small objects. Experimental results show that the proposed CBS-YOLOv5 model achieves an accuracy of 88.1%, which is an improvement of 5.7% over the base model. Furthermore, this algorithm demonstrates exceptional detection capabilities for dense small objects in low-resolution infrared images while maintaining real-time detection speed, making it suitable for various complex industrial scenarios, including fault detection in non-ferrous metal electrolysis processes. CBS-YOLOv5 not only improves detection accuracy and robustness but also has broad application prospects, offering a new solution for intelligent manufacturing and industrial inspection.

Groundwater renewal time by environmental tritium isotopes as a tracer for sustainable water resource management

Studying groundwater renewal time is a valuable tool to deepen the comprehension of sustainable groundwater resources specific to arid regions. Tritium is a radioactive isotope of hydrogen often used as an environmental tracer to study groundwater renewal time. The present work reports groundwater renewal times by the environmental tracer tritium to understand sustainable water resources in arid regions. First, groundwater samples were collected from wells in northeastern arid regions of Saudi Arabia. Then, an electrolysis process was employed to significantly increase the tritium level from twenty-five to thirty times the original concentration. Subsequently, the enriched water was analyzed using a liquid scintillation counter under optimized measurement conditions to determine the tritium concentration precisely. Two internationally recognized tritium laboratories conducted independent assessments to validate the estimated tritium levels. The verified tritium concentration was then used to estimate the groundwater renewal time using the Morgenstern and Pimenta curves. The results suggest that most of the monitored wells in the surveyed areas are more than a century old. Conversely, a few monitoring wells exhibit renewal times of several hundred years and may be considered nonrenewable water sources. These studies help to understand the geochemical characteristics of arid regions to ensure the sustainable management and protection of groundwater resources.

Unlocking sustainable lithium: A comparative life cycle assessment of innovative extraction methods from brine

The surging demand for lithium, driven by the widespread adoption of electric vehicles and renewable energy storage systems, underscores the urgent need to develop sustainable lithium extraction methods. This study presents a comprehensive Life Cycle Assessment Using the TRACI method to evaluate and compare the environmental impacts of solvent extraction, adsorption, nanofiltration, and membrane electrolysis as direct lithium extraction methods for recovering lithium from brine to produce lithium carbonate. In terms of global warming, the carbon dioxide emission for each process was determined as follows: solvent extraction emits 52.7 kg CO2eq/kg of lithium carbonate, adsorption emits 47.9 CO2eq/kg of lithium carbonate, nanofiltration emits 17.7 kg CO2eq/kg of lithium carbonate, and membrane electrolysis emits 80.57 kg CO2eq/kg of lithium carbonate. As a result, the nanofiltration process emerges as the most environmentally friendly method, offering a promising solution to the environmental challenges of lithium extraction. In contrast, the membrane electrolysis process has the highest environmental impact.

Green Hydrogen Synthesis from Human Urine as Sustainable Bioenergy Resources

With the earths cry for help as pollution rate increases, researchers are faced with a common task of tackling pollution resulting from dependence on fossil fuel as well as delivering sustainable energy. Renewable energy resources such as solar, wind, hydro to mention a few are currently finding applications within the world energy mix but some limitations which range from meteorology of locations to expected maximum energy output attainable. Hydrogen, the most abundant element in the world stand chance of abating this problem. However conventional method of its producing, poses severe treat to the atmospheric environment with the release of oxides of carbon hence, referred as blue hydrogen. Contrarily, green hydrogen from human urine stands a more sustainable and environmentally friendly energy resource. This study was aimed to empirically model the synthesis of green hydrogen from urea in human urine by an electrolytic process. The synthesized hydrogen was characterized on physiochemical properties of conductivity, turbidity, pH, specific gravity and colour, while the precursor urine characterized on gender, exposure duration and storage temperature. The synthesis process was modelled using Microsoft excel solver for the overall cell energy or polarization curve model, the Faraday’s efficiency model and gas purity model at electrolyte concentrations of 25 wt./wt., 30 wt./wt. and 35 wt./wt. of potassium oxide (buffer} to urea over a five-temperature interval range of 45 to 85 oC. Findings revealed that the gas produced was 99.88% hydrogen at the cathode. Also, hydrogen produced increased with increase in electrolyte concentration and moderate temperature with optimal conditions at 35 w/w electrolyte concentration and 65 oC. However, the minimum cell voltage was 2.06 V at 85 oC and 35 w/w electrolyte concentration. With an exception of the Faraday’s efficiency model at 30 wt./wt. electrolyte concentration across the system’s operating temperature range yielding an R2 value of 0.711, all the models yielded coefficient of determination values in the range of 0.96 and 0.99, indicating good fit for the alkaline urine electrolysis for green hydrogen synthesis from human urine.

Dynamic sparse x-ray nanotomography reveals ionomer hydration mechanism in polymer electrolyte fuel-cell catalyst.

Tomographic imaging of time-evolving samples is a challenging yet important task for various research fields. At the nanoscale, current approaches face limitations of measurement speed or resolution due to lengthy acquisitions. We developed a dynamic nanotomography technique based on sparse dynamic imaging and 4D tomography modeling. We demonstrated the technique, using ptychographic x-ray computed tomography as its imaging modality, on resolving the in situ hydration process of polymer electrolyte fuel cell (PEFC) catalyst. The technique provides a 40-time increase in temporal resolution compared to conventional approaches, yielding 28 nm half-period spatial and 12 min temporal resolution. The results allow a quantitative characterization of the water intake process inside PEFC catalysts with nanoscale resolution, which is crucial for understanding their electrochemical mechanisms and optimizing their performance. Our technique enables high-speed operando nanotomography studies and paves the way for wider application of dynamic tomography at the nanoscale.

Frustrated Lewis Pair Mediated f‐p‐d Orbital Coupling: Achieving Selective Seawater Oxidation and Breaking *OH and *OOH Scaling Relationship

The development of materials for hydrogen production via seawater electrolysis at high current densities plays a crucial role in producing renewable hydrogen energy. However, during the seawater electrolysis process, the anode inevitably undergoes chloride oxidation reaction (ClOR) due to Cl‐ adsorption, making the seawater electrolysis process difficult to sustain. Inspired by the selective permeability of cell membranes, we propose a biomimetic design of frustrated Lewis pairs (FLPs) layers. Combining experimental results and molecular dynamics simulations, it has been demonstrated that cerium dioxide layers with FLPs sites can decompose water molecules, capture hydroxyl anions, and repel chloride ions simultaneously. DFT theoretical analysis indicates that the FLP sites regulate the Ce 4f‐O 2p‐Ni 3d gradient orbital coupling, providing additional oxygen non‐bonding (ONB) to stabilize the Ni‐O bond and optimize the adsorption strength of intermediates, thereby breaking the *OH and *OOH scaling relationship. Assembled anion exchange membrane electrolyzers exhibit an efficiency of 95.7% at a current density of 0.1 A cm‐2 and can stably operate for 250 hours at a current density of 0.2 A cm‐2.

Frustrated Lewis Pair Mediated f-p-d Orbital Coupling: Achieving Selective Seawater Oxidation and Breaking *OH and *OOH Scaling Relationship.

The development of materials for hydrogen production via seawater electrolysis at high current densities plays a crucial role in producing renewable hydrogen energy. However, during the seawater electrolysis process, the anode inevitably undergoes chloride oxidation reaction (ClOR) due to Cl- adsorption, making the seawater electrolysis process difficult to sustain. Inspired by the selective permeability of cell membranes, we propose a biomimetic design of frustrated Lewis pairs (FLPs) layers. Combining experimental results and molecular dynamics simulations, it has been demonstrated that cerium dioxide layers with FLPs sites can decompose water molecules, capture hydroxyl anions, and repel chloride ions simultaneously. DFT theoretical analysis indicates that the FLP sites regulate the Ce 4f-O 2p-Ni 3d gradient orbital coupling, providing additional oxygen non-bonding (ONB) to stabilize the Ni-O bond and optimize the adsorption strength of intermediates, thereby breaking the *OH and *OOH scaling relationship. Assembled anion exchange membrane electrolyzers exhibit an efficiency of 95.7% at a current density of 0.1 A cm-2 and can stably operate for 250 hours at a current density of 0.2 A cm-2.