Electrochemical Supercapacitors Research Articles

Cerium oxide anchored free-standing silicon nanowires as potential anode materials for electrochemical supercapacitor

Free-standing 1 D silicon nanowires (Si-NWs) were synthesized by the metal-assisted chemical etching (MACE) technique and subsequently decorated with cerium oxide (CeO2) nanoparticles synthesized by a solvothermal process. Morphological characterization of the CeO2/Si-NWs nanocomposite validates the homogeneous growth of spherical CeO2 nanoparticles around the Si-NWs, while the N2 adsorption-desorption study indicates a large specific surface area (SSA) and the presence of ink-bottle-shaped pores possessing a significant portion of mesopores. This CeO2/Si-NWs composite electrode demonstrates excellent electrochemical behavior, attaining an impressive specific capacitance (Csp) of 830 F g–1 at a current density of 1.0 A g–1, the anodic material delivers an energy density of 19 Wh kg–1 at a power density of 2.5 kW kg–1, along with exceptional durability, retaining 94% of its capacitance after 2000 charge-discharge cycles. The results show that the CeO2/Si-NWs composite electrode has great potential as an emerging category of anodic material for supercapacitors.

Zr-MOF composites with zipped and unzipped carbon nanotubes for high-performance electrochemical supercapacitors.

Metal-organic frameworks (MOFs) have gained considerable interest as crystalline porous materials with notable characteristics, such as high surface area and excellent electrochemical performance, particularly in supercapacitor applications. The combination of MOFs with various nanocarbon materials further enhances their performance. This study investigated the combination of zirconium-based MOFs (Zr-MOFs) with graphene oxide nanoribbons (GONRs), zipped carbon nanotubes, and functionalized carbon nanotubes (FCNTs) to fabricate composites with elevated electrical conductivity, adjustable surface area, chemical robustness, mechanical strength, and customizable attributes for specific applications. Zr-MOFs exhibit remarkable capacitance, making them promising electrode materials for supercapacitors. GONRs and FCNTs have recently emerged as focal materials owing to their unique properties, which make them promising materials for electrochemical energy storage devices. A thorough investigation of the supercapacitive behavior of GONRs, FCNTs, Zr-MOFs, Zr-MOFs/FCNTs, and Zr-MOFs/GONRs in 1 M H2SO4 using different evaluation systems (three- and two-electrode systems) revealed a significant enhancement in the capacitance of Zr-MOFs after the introduction of GONRs and FCNTs. Employing Zr-MOF/GONR and Zr-MOF/FCNT composites as positive electrodes and GONRs as negative electrodes in two-electrode measurements demonstrated remarkable cycling stability by retaining their specific capacitances (Cs) even after 10 000 consecutive charge/discharge cycles at a high current density of 10 A g-1. Moreover, they feature a broad potential window of 1.7 V in the three-electrode system. This extends to 2 V in the two-electrode system, achieving high Cs. This highlights the remarkable electrochemical performance of the Zr-MOF/GONR and Zr-MOF/FCNT composites, offering a compelling approach for energy storage applications.

Synthesis, and structural characterization of FeMoO4/r-GO nanocomposite as an electrode material for energy storage application

Improving the energy density of electrochemical supercapacitors requires the urgent development of novel electroactive materials. Metal molybdate-based nanostructures are promising candidates as effective electrode materials for the next generation of energy storage solutions. In the present work, a FeMoO4/r-GO nanocomposite was synthesized via the hydrothermal method and used as anode material for supercapacitor application. The structural, and topographical properties were investigated by XRD, FE-SEM, and TEM analysis. Field Emission Scanning Electron Microscopy (FE-SEM) and Transmission electron microscope (TEM) images of FeMoO4/reduced graphene oxide (r-GO) composites show an irregular, rod-like structure coated with r-GO sheets. The FeMoO4/r-GO nanocomposite electrode material exhibited a remarkable specific capacitance of 240 F/g at the current density of 1 A/g, which is significantly higher than the 167 F/g capacitance of pure FeMoO4. The continued charge–discharge (GCD) (5,000) life cycle performance of FeMoO4/r-GO was the retention and coulombic efficiency of 90 % to 86 % after 10 A/g.

Facile synthesis and characterization of zinc molybdate (ZnMoO4) nanosheets for electrochemical supercapacitor application

Abstract This study explores the synthesis and characterization of zinc molybdate (ZnMoO4) nanosheets with emphasis on their potential application for energy storage devices particularly supercapacitors. The synthesis of ZnMoO4 nanosheets was done through co-precipitation followed by examination of their structure, morphology, optical, thermal behaviour and electrochemical performance by various characterization techniques. X-ray diffraction (XRD) analysis confirmed that the formation of monoclinic ZnMoO4 phase with the average crystallite size 17.93 nm. Scanning electron microscopy (SEM) and Transmission electron microscopy (TEM) revealed that this material had nanosheets-like structure which helps to increase ion transport and surface area; these two factors are essential for enhancing the material’s supercapacitor efficacy. The semiconductor characteristics were determined using UV–Visible diffuse reflectance spectroscopy (UV-DRS) which indicated a band gap energy of 4.2 eV. Fourier transform infrared (FTIR) analysis confirmed that the presence of Zn–O and Mo–O bonds in their crystal lattice. Thermogravimetric analysis (TGA) showed that the ZnMoO4 nanosheets had thermal stability since they experienced only a slight mass loss of 2.57 % up to 800 °C. Cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) tests were undertaken to find out the specific capacitance and the value is 618 F g⁻1 at a current density of 1 A g⁻1.

Novel asymmetrical oxime ligand-based coordination compounds in conducting copolymer as a useful electrodes for electrochemical supercapacitors

Novel asymmetrical oxime ligand-based coordination compounds in conducting copolymer as a useful electrodes for electrochemical supercapacitors

Modified organic-template synthesis of Co3O4 as high-performance electrode with superior capacitive storage

Electrochemical supercapacitors (ESCs) have great potential in many energy storage technologies because of their outstanding performance. Transition metal oxides with high theoretical specific capacity are promising for ESC electrodes, but their low utilization of capacitive active components and poor cycle stability limit their practical usage. Herein, we have prepared a novel cobalt metal cyanometallic framework (Co-CMF) and further thermally modified it to easily produce a Co3O4 positive electrode with excellent capacitive storage performance. As a result, the electrode exhibits fast, stable and reversible electrochemical performance with a high specific capacity of 241.9 C g−1 and long-term stability with as low as 0.004 % decline per cycle in the 5 M KOH aqueous electrolyte, which are confirmed by in-situ Raman investigation and electrochemical tests, further demonstrating that this modified approach provides a new idea for the development of promising high-capacity electrode materials for large-scale energy storage.

A crumpled sphere-like NiMn metal-organic phosphate as electrode material for electrochemical supercapacitor

The present study investigates a crumpled sphere-like binary Ni Mn metal–organic phosphate (Ni10Mn1-MOPh) sample for its potential application in electrochemical supercapacitors. Additionally, control samples of NixMny-MOPhs with varying proportions of Ni and Mn were also prepared. It is noteworthy that NixMny-MOPh samples with different molar ratios of Ni:Mn display different morphologies and electrochemical supercapacitor properties. Compared with other as-prepared NixMny-MOPhs, Ni10Mn1-MOPh modified electrode showed more complete sphere, bigger active surface area, and faster electrical conduction, applying for the hydrothermal condition is pivotal factor for the practical applications of NixMny-MOPhs. The synthesized Ni10Mn1-MOPh demonstrates a remarkable specific capacitance value of 986.8F/g at 2 A/g and exhibits exceptional reversible charge/discharge capability with an approximate retention rate of 81.9 % after 5000 cycles at 6 A/g. As a proof-of-concept, we synthesized bare Ni-MOPh and MnO2, thereby further confirming that the optimization electrochemical performance is associated with the synergistic effect of diverse active metals, their respective ratios, and the appropriate morphology of the NiMn-MOPh samples.

Ternary g-C3N4/Co3O4/CeO2 nanostructured composites for electrochemical energy storage supercapacitors

Extensive use of fossil fuels causes heavy discharge of carbon dioxide, depleting energy resources and this requires environmentally friendly and effective energy storage materials. Hybrid supercapacitors (HSCs) are recently developed as effective energy storage materials enabling high capacitance retention rate and quick charging. Herein, synthesis of two-dimensional g-C3N4 nanosheets supported onto three-dimensional flower-like Co3O4/CeO2 (CoCe) ternary synergistic heterostructures are developed as effective electrodes for hybrid supercapacitor applications. Addition of g-C3N4 produces substantial surface active sites, enabling its synergistic effect with CoCe to enhance electrochemical performance having exceptional conductivity. The CoCe/g-C3N4 ternary composite electrode exhibits a higher specific capacitance of 1088.3 F g−1 at 1 A g-1 with 96 % of recycling stability over 5000 cycles, which is ∼5.5 and ∼5 folds higher specific capacitance than the pristine g-C3N4 and CoCe electrodes. EIS analysis revealed that CoCe/g-C3N4 electrode offered reduced charge transfer resistance compared to pristine electrodes. The fabricated two-electrode HSC device displays outstanding retention after 10,000 cycles with an ultra-high specific capacitance of 119.8 F g−1, excellent energy density 37.4 Wh kg−1 and power density of 749.9 W kg−1. This research showcases the perspectives of CoCe/g-C3N4 ternary electrodes in hybrid supercapacitors and other renewable energy storage devices.

Synthesis and Characterization of Synergetic Pd/MoO3–rGO Hybrid Material as Efficient Electrode for Supercapacitor Application

In this work, study synthesized Pd–rGO and Pd/MoO3–rGO nanocomposites via a one-pot hydrothermal method, serving as efficient electrodes for supercapacitor applications. Various analytical techniques, including XRD, XPS, HRTEM, BET, and Raman spectroscopy, were employed to characterize the structural, morphological, and physiochemical properties to assess the electrochemical supercapacitor performance of nanocomposite materials. The analyses confirmed that the charge transfer mechanism between the MoO3-NR with Pd-rGO in Pd/MoO3–rGO samples has significantly improved the electrochemical performance of Pd/MoO3–rGO by 2.7 times compared to Pd-rGO sample (105.00 F/g at 0.5 A/g). Remarkably, the Pd/MoO3–rGO hybrid material exhibited excellent electrochemical activity, boosting a specific capacitance of 291.50 F/g at a current density of 0.5 A/g, accompanied by energy density and power density values of 18.06 Wh/kg and 250.00 W/kg, respectively. Furthermore, it demonstrated noteworthy stability over prolonged usage, retaining 88.46% of its capacity after 1,000 cycles at a constant current density of 1.0 A/g. These findings underscore the promising potential of the Pd/MoO3–rGO nanocomposite as a highly effective electrode material for supercapacitors.

Carbon nanostructures for high-frequency line-filtering supercapacitors

Supercapacitors (SCs) are considered one of the front-runner energy storage devices for future electronic and automobile device applications. Even though their high-power densities, fast charge/discharge, and long cycling stabilities make them promising for future applications, their charge-discharge takes place below 1 Hz, a major issue for using them as capacitors for line filtering applications. Therefore, developing ultrafast electrochemical supercapacitors with alternating current (AC) line filtering functions has gained research attention to replace conventional aluminum electrolytic capacitors (AEC). Most available SCs possess resistive features rather than capacitive at 120 Hz because of the electrode geometry and configurations, which is a bottleneck in the research of line-filtering SCs. Addressing this challenge could be possible by developing novel electrode materials using hybrid nanostructures to meet the critical requirements for line filtering functions. This mini-review focuses on the advancement and challenges of carbon nanostructure-based electrode materials for AC line filtering applications and the future directions of this growing research area.

Enhancement of capacitance retention of ZnCo2S4@Metal organic framework composite electrodes by hydrothermal process

Metal organic framework-derived materials are promising electrodes for electrochemical supercapacitors due to their surface area, porosity, and excellent redox behaviors. In the present study the fabrication of ZnCo2S4 and ZnCo2S4@ZIF-67 composites synthesized by solid-state grinding and hydrothermal processing for supercapacitor utilization. Studies using XRD, XPS, FTIR, BET, FE-SEM, and HR-TEM are employed to validate the morphological, surface, and structural characteristics. Highly conductive ZnCo2S4 nanostructured materials are intercalated with MOF surfaces to enhance electron transport. The high number of active sites involved in the rapid electrochemical phase fluctuation using 1 M KOH electrolyte may be the cause of this. ZnCo2S4 and ZnCo2S4@ZIF-67 composites are used to create the working electrode, while a 1 M KOH electrolyte is used for the supercapacitor. By employing a three-electrode design, the created composite electrodes improve cyclic retention with specific capacitances of 245 and 447.14F/g at 1 A/g, respectively. Two electrode configurations are used to build ZnCo2S4@ZIF-67/1M KOH/SSC, which produced results of 151.42F/g at 1 A/g, 85.2 % capacitance retention at 7 A g−1 of 7000 cycles, and 18.93 Wh kg−1 energy density at 642.85 W kg−1 power density. Thus, the fabricated composite electrodes may find application in electrochemical symmetric supercapacitor via two electrode configuration systems.

Compositing LaSrMnO3 perovskite and graphene oxide nanoribbons for highly stable asymmetric electrochemical supercapacitors

The anticipated large contribution of renewable energy resources to the sector of energy production strongly motivated the development of energy storage technologies, of which supercapacitors have drawn a lot of attention. In this work, Lanthanum-Strontium-Manganese-oxide (LSMO) perovskite nanoparticles, graphene oxide nanoribbons (GONRs), and LSMO-GONRs composite were synthesized and tested as electrode materials for supercapacitor applications. The LSMO was synthesized using the co-precipitation/calcination method, while the GONRs were synthesized using the oxidative unzipping of multi-walled carbon nanotubes. The physical/chemical structures were studied using XRD, FT-IR, SEM, TEM, SAED, and XPS. In 1 M KOH, the LSMO-GONRs electrode exhibited a specific capacitance of 490F/g compared to 342F/g and 294F/g for GONRs and LSMO electrodes, respectively, at 1 A/g, showcasing a performance that is not just superior but truly impressive, to the different types of perovskite/carbon-based material composites. The fabricated asymmetric SC device of LSMO-GONRs//GONRs exhibited a potential window of 1.7 V, a specific capacitance of 92.3F/g, an energy density of 38 Wh/kg, and a power density of 860 W/kg at 1 A/g. Moreover, the LSMO-GONRs//GONRs device showed excellent capacity retention and Coulombic efficiency after 10,000 cycles at 10 A/g, revealing the promising employment of LSMO-GONRs composite as a highly stable material for supercapacitor applications.

Advancement of Graphite-Clay Composite Electrodes via Different Compositions to Improve the Synergetic Matrix Effect Towards General Electroanalytical and Energy Storage Applications

Modern electrode technology trends for enhancing multifunctional electrodes, prioritizing energy storage and electroanalytical prospects. This study anticipates fabricating electrodes by incorporating cement and colloidal graphite, to improve the performance via synergetic interactions of the composite matrix. Graphite-montmorillonite-cement ternary composite electrode (GMMTCeCE) and graphite-colloidal graphite-montmorillonite-cement quaternary composite electrode (GCGMMTCeCE) are fabricated, as two types of electrodes. GMMTCeCE reflects the lowest peak-to-peak separation in Ce3+/Ce4+ (0.098 V), greater sensitivity towards [Fe(CN)6]4- (2.68 A·m·mol-1) and [Fe(CN)6]3- (2.64 A·m·mol-1), showing comparatively better performance in analyte detection than GCGMMTCeCE. Multilayered polyaniline (PANI) nanofibers network, which is unique in GMMTCeCE electropolymerization, accounts for very low serial (0.38 Ω) and charge transfer (0.59 Ω) resistances, while densely packed nanofibers of PANI in GCGMMTCeCE is responsible for the lowest ohmic resistance (1.31 Ω). Supercapacitor device fabricated by PANI-GMMTCeCE, achieved higher capacitance (1,002 F·g-1 at 5 mV·s-1) and showed greater cyclic stability, in contrast to relatively lower specific capacitance (685 F·g-1 at 5 mV·s-1) attained by PANI-GCGMMTCeCE, demonstrates the superiority of the supercapacitor of GMMTCeCE over GCGMMTCeCE for energy-storage purposes. Therefore, GMMTCeCE outperformed GCGMMTCeCE in electroanalysis and energy storage, confirming better synergetic interactions of the ternary composite matrix over the quaternary one. Besides, further improvements in graphite-clay composite matrix properties facilitate the advancement of electrochemical sensors and supercapacitor devices.

Investigation of the electrochemical properties of SnS/r-GO nanocomposite for aqueous supercapacitor applications

Consolidation of transition metal sulfide with r-GO is materialized to improve the charge-storing capacity of the electrochemical supercapacitors due to the large surface area, superior electric conductivity, and ample active sites. Herein, SnS/r-GO nanocomposite was prepared using solvothermal procedure. The electrochemical properties of anode material were quantified for SnS/r-GO nanocomposite electrode with a remarkable capacitance of 195.73 Fg−1 for an applied current of 1 Ag−1 and capacitance retention of 84.96 % after 3000 cycles. For the first time, SnS/r-GO//AC asymmetric device was fabricated for delivering decent energy and power density of 22.45 Wh/kg and 1494.5 W/kg accompanying with greater stability of 82.39 % after 3000 cycles. These results proposed that SnS/r-GO //AC has been paying attention is as favorable energy storage device for future electronic applications.

Oxygen-functionalization of unique hierarchical carbon nanosheet fishtail-like for synergistically enhanced capacitive performance supercapacitor

The optimization of high-performance supercapacitors with enhanced electrochemical properties using biomass-based activated carbon is a challenging task. To overcome this, a novel strategy was used to create functional nanocarbon with a hierarchical-nanosheet structure based on bio-waste of Clausena Excavata Burm F (CEBF) leaves. The precursor was optimized through different chemical impregnation concentrations without the addition of any other substances. This resulted in a unique hierarchical carbon nanosheet fishtail-like with a specific surface area of 828.679 m2 g−1. The high carbon content of CEBF (up to 88.58%) and 4.46% oxygen as heteroatoms showed a beneficial pseudocapacitance effect. The electrochemical properties of CEBF-activated carbon were excellent, with a specific capacitance of 248 F g−1. The optimal energy density reached 33.8267 Wh kg−1, and the power density was 4.755 kW kg−1 at 10 A g−1. These findings suggest that CEBF biomass has significant potential as a source of hierarchical carbon nanosheet that enhances high-performance electrochemical supercapacitors.

Recent advances in polyaniline/graphene nanocomposites for supercapacitor applications: Synthesis, properties, and future directions

Electrochemical capacitors or supercapacitors have attracted the attention of researchers and industries in the recent past because of the differences in the features and potential applications in comparison to the Li-ion batteries. Supercapacitors have been one of the most investigated applications in literature based on graphene-related materials. This review aims to provide the most recent advancement on the use of graphene and polyaniline (PANI) nanocomposite towards enhancing the supercapacitor properties. The synthesis methods of the graphene and PANI nanocomposite, the characteristics of the nanocomposite and its utilization in supercapacitors are discussed. Graphene and PANI are both well-known materials that possess fascinating physical and electrochemical characteristics, and in the last several years, they have been investigated for numerous applications by many researchers. Together with such advantages as enhanced physical and electrochemical characteristics, mechanical strength, and density, composites of both materials can be a potent material for supercapacitor usage.The preparation methods of graphene, PANI, and its composites described by the authors of the research article include in-situ polymerization, chemical vapor deposition, and hydrothermal-assisted polymerization. These characterization techniques include SEM, TEM, FTIR, XRD, DSC, and TGA to determine other properties of the nanocomposite which shows enhanced properties of graphene and PANI. The electrochemical properties of the nanocomposites are evaluated through cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) and the achieved values indicate high specific capacitance, cycling stability, and charge-discharge abilities. These outcomes demonstrate the excellent applicability of PANI/graphene nanocomposites as high-performance supercapacitors and encourage the confidence in the effectiveness of the study. Several factors affecting properties of the nanocomposites have been reported in the previous studies, and it is clear from this study how various properties and their relation affects the overall performance of the nanocomposite. Altogether, PANI/graphene nanocomposites have the potential to be used as next-generation supercapacitors, which is still unexplored fully to meet the demands to enhance the high-performance energy storage devices.

Preparation and characterization of high performance super activated carbon based on coupled coal/sargassum precursors

High electrochemical performance supercapacitors require activated carbon with high specific surface area, suitable pore size distribution and surface properties, and high electrical conductivity as electrode materials, whereas there exists a trade-off relationship between specific surface area and electrical conductivity, which is not well met by a single type of carbon source. To solve this problem, the coal and sargassum are adopted to obtain the coupling product via co-thermal dissolution, followed by carbonization and KOH activation. The effects of mixing mass ratio and activation temperature on the prepared activated carbon (AC) are investigated using single factor experimental method. The experimental results show that AC1/3-800 has abundant micropore and mesopore content, good pore structure connectivity, high electrical conductivity and good wettability, and superior electrochemical properties compared with other activated carbons prepared in this experiment. Its total specific surface area is up to 2098.5 m2·g−1, the pore volume is up to 1.33 cm3·g−1, the content of mespores with diameter of 6–8 nm is significantly increased, and the pore size distribution is wide and uniform. When the current density increases from 0.1 A·g−1 to 10 A·g−1, the gravimetric capacitance decreases from 219 F·g−1 to 186 F·g−1 with a capacitance retention of 84.9%, the equivalent series resistance is very small, and the rate performance and reversibility of charging and discharging have also been excellent.

Covalently linked 4-Aminopyridine on reduced graphene oxide for high performance electrochemical supercapacitor electrode material

The portability of electrical devices requires the demanding but essential task of improving supercapacitor energy density while preserving stability. Introducing an amine heterocyclic compound on a reduced graphene oxide (rGO) layer can enhance its capacity for energy storage. Here, we employed Catharanthus roseus flower extract as a green reducing agent to prepare rGO for the first time. A stable covalently linked 4-AP-rGO was produced through combining of 4-Aminopyridine on the rGO layer via nucleophilic substitution reaction process. The synthesized materials were systematically characterized by FT-IR, UV–visible, Raman, powder XRD, XPS, SEM, and TEM. Furthermore, the screen-printed carbon electrode (SPCE) was modified with 4AP-rGO (4AP-rGO/SPCE) to evaluate the electrochemical properties using CV, GCD, and EIS in 1 M H2SO4. The electrochemical performance of the 4AP-rGO/SPCE modified electrode was compared with unfunctionalized rGO. The pseudocapacitive efficacy of the 4AP-rGO was exceptional as evidenced by its high energy density (12.27 × 10−4 Wh kg−1), high power density (350.6 × 10−3 W kg−1), and high specific capacitance of (180.3 × 10−3 F g−1) at 1 A g-1. Over 10,000 cycles at 1 A g-1, it maintained 98.8 % capacitance, exhibiting exceptional cycling stability. The energy density of 4-AP-rGO is 2.1 times higher than that of rGO, indicating that it is a suitable candidate for energy storage applications.

Effects of Crumpling Stage and Porosity of Graphene Electrode on the Performance of Electrochemical Supercapacitor.

The performance characteristics of supercapacitors composed of crumpled graphene electrodes and aqueous NaCl electrolytes are investigated through Molecular Dynamics (MD) simulations using a newly developed crumpled graphene-based supercapacitor model. Results suggest that the three-dimensional configuration of crumpled graphene boosts electrolyte-electrode interaction. This improved interaction, which includes a larger ion-accessible zone, increases the specific capacitance of the supercapacitor by roughly 400% (16.4 μF/cm2) compared to planar graphene electrodes. Examining the effect of different stages of crumpling and the inclusion of pores on the electrode surface shows that the stages of crumpling substantially influence the supercapacitor performance. A smaller crumpling radius, meaning fully crumpled stage, improves the performance as increased crumpling leads to better packing efficiency, which aids in more ion separation. Furthermore, adding pores on the surface of crumpled graphene improves the ion accessibility by creating additional adsorption sites. An exceptional capacitance of 19.8 μF/cm2 is obtained for a porosity of 20%. However, the results suggest that the in-plane-porosity of the electrode needs to be optimized as there is a decline in specific capacitance after that point (20% porosity), indicating a suboptimal relationship between the charge distribution, specific surface area (SSA) and the porosity of the electrode.

Carbonized porous zeolitic imidazolate framework as promising electrode for electrochemical supercapacitors

In order to manufacture effective supercapacitors with improved electrochemical performance, it is imperative to investigate greater surface area electrode materials. This work describes the development of a cost-effective method for the carbonization of porous zeolitic imidazole framework (ZIF8) to utilize as electrode of electrochemical supercapacitors. The electrode materials were prepared by synthesizing highly porous ZIF8-P followed by pyrolysis at 500 °C (ZIF8-P-500). The pyrolysis of ZIF-8 significantly strengthened the porous behavior by maintaining their hexagonal particles and obtaining high surface to volume ratio. The measurements using constant current charge/discharge (GCD) and cyclic voltammetry (CV) were used to evaluate the electrochemical capacitance characteristics of the synthesized ZIF8-P based electrode. The supercapacitor assembly using the optimized ZIF8-P electrode exhibited a high specific capacitance of ∼423.9 Fg–1 with exceptional cycle stability by maintaining capacitance of ∼86.7 % from its initial capacitance after 5000 cycles. Thus, the results indicate that the ZIF8-P based supercapacitor offers a compelling path for creating porous carbon electrodes from MOFs using low cost pyrolysis for advancing supercapacitor technology.