Acoustic emission (AE) sensors are widely used for testing and monitoring purposes, necessitating effective field-testing methods to assess their functionality during use, ideally resulting in a method for self-diagnostic. A novel approach for field-testing is to measure the electromechanical impedance (EMI) of the AE sensor. This method requires minimal additional equipment and eliminates human interaction, which is needed for current field-tests like pencil-lead break tests. However, the EMI includes the mechanical impedances of the sensor, the coupling layer, and the structure. Therefore, the measurements contain information about all three and influences of the structure and the coupling layer need to be investigated to be able to establish a method for self-diagnosis in field. Additionally, the piezoelectric effect is temperature-dependent, which affects the measured EMI spectra and may result in erroneous assessments of the sensor's condition if not accounted for. This work presents experimental studies on the influence of measuring equipment, environmental temperature, coupling-specific parameters and structural parameters on the EMI of AE sensors. Moreover, numerical simulations have been conducted to provide additional support and to extend the experimental studies of the latter two. To ensure reproducible sensor coupling to a structure, a setup was constructed to couple the sensor to the structure at the same position and with the same force. The thickness of the coupling layer is determined by a small amount of silicon carbide particles with a specific diameter. This setup is also used to examine the effect of structural parameters.