Effects Of Extraction Temperature Research Articles

Improvement of the production of bio-oil and biodiesel from Egyptian Jatropha seeds by using microwave and ultrasonic

Bio-diesel is used for engine as a replacement of diesel fuel which is characterized by lower emission, low pollution and renewable some of fuel. This study focus on how to enhance the production of bio-oil from Jatropha seeds by using microwave and ultrasonic as pre-treatments. To achieve that, the effects of extraction temperature (60, 80, 100 and 120 °C) and extraction screw speed (60, 90 and 120 rpm) on oil extraction yield and quality, extraction energy requirements and extraction time and were studied. Studying the effect of pretreatments by microwave and ultrasonic on the yield, energy and time of extraction were studied. The results most important indicate that the highest oil yield (25.1%) was recorded at 120 °C extraction temperature and 60 rpm screw speed. The energy required for extraction ranged from 8 to 11.5 W.h depending on temperature and speed of extraction. The results indicated that using both pretreatments improve the oil yield by 5.03% for microwave and by 6.75% for ultrasonic. Finally, the results concluded that to produce 1 kg of biodiesel you need 1.1 kg raw oil and consume from 2052.5 W.h energy requirement.

Effects of Extraction Temperature on Polyphenol Compounds and Antioxidant Activity of Golden Bladderwort (Utricularia aurea)

Effects of Extraction Temperature on Polyphenol Compounds and Antioxidant Activity of Golden Bladderwort (Utricularia aurea)

Waste orange seeds (Citrus sinensis seed) transformation, a viable industrial bio-oil: Oil extraction, physicochemical characterization and vital instrumental analyses studies

The processing of Petroleum-based oil has contributed to environmental challenges such as climate change. Recently, research attention has been shifted to oil extraction from different non-edible seeds as a suitable substitute. Accordingly, this study examines the physiochemical characterization, and the effect of extraction temperature on the yield of waste Citrus sinensis seed [orange seed (OS)] bio oil. Studies on the prevalent functional group, fatty acid methyl ester compositions and thermal oxidative stability were carried out using the Fourier transform infrared spectroscopy (FTIR), gas chromatography-mass spectroscopy (GCMS) and differential scanning calorimetry (DSC), respectively. The oil content of the OS bio oil was 46.26%w/w. The high iodine number (31.47 mg/100 g) and low pour point (4.50 °C) of the OS bio oil showed its high content of unsaturated fatty acid. The FTIR functional group of the OS bio oil showed predominantly alkane of CH stretching, aldehydes, esters, and carboxylic acid. The chemical composition of the OS bio oil as determined by GCMS (massHunter/library/NIST 14.1) showed the occurrence of octadecadienoic and oleic acids as poly-saturated and saturated fat found in plant glycosides and vegetable fats and oil. The DSC thermal stability analysis showed the possible existence of mixed triglycerides. Finally, the result from the physiochemical characterization compositions, and functional group the OS bio oil indicated its potential as a suitable substitute for petroleum-based oil.

Study of aromatic extraction from light cycle oil from the viewpoint of industrial applications

Light cycle oil (LCO) is a significant products of fluid catalytic cracking (FCC) process in refineries. Increasing the output of high-value chemicals from LCO is an important step towards achieving ‘dual carbon’ targets. Separating aromatic and non-aromatic components in LCO is crucial to producing valuable products. Extraction is a promising process for separating these components based on the principle of “polar similarity and solubility”. From the perspective of industrial applications, this study explores the development and application of novel functionalized extractants to produce valuable products. Ionic liquids (ILs) with alkyl-substituted imidazoles [CnMIM]+ and alkyl-substituted pyridines [CnMPy]+ as cations and tetrafluoroborate [BF4]− and hexafluorophosphate [PF6]− as anions were used. The effects of extraction temperature, IL-oil ratio, number of extraction stages, and reusability were systematically investigated. In addition, the basic physical properties data of ILs and residues in oil were studied in detail. The suitability of ionic liquids for industrial applications was evaluated based on their solubility with hydrocarbons, physical and chemical properties, selectivity for aromatics, and residues in oil. Following a thorough examination of the performance of ionic liquids for the extraction of aromatics from LCO, [C6MIM][PF6] was identified as the most suitable extractant. A multi-stage countercurrent extraction process was established and the conditions systematically studied. The results demonstrate that the aromatic content of the extracted oil is greater than 95 wt%, which can be utilized for producing BTX products. Meanwhile, the aromatic content of the raffinate oil is less than 10 wt%, which can function as a clean diesel blending component or as steam cracking feedstocks. This study has successfully promoted the industrial application of functionalized ionic liquids for the LCO dearomatization process and provided an essential reference for developing new functionalized extraction solvents.

Optimizing the Production of Antioxidant and Antibacterial Alkaloids from Macleaya cordata by Subcritical Water Extraction Technology.

In this work, the subcritical water extraction technology was used to extract alkaloids from Macleaya cordata, and the effects of extraction temperature and time on its yield were investigated to find the best extraction conditions. Moreover, the antioxidant capacity and antibacterial activity of Macleaya cordata extract were studied. Furthermore, through the single-factor method, it was found that properly increasing the extraction temperature and prolonging the extraction time was conducive to increasing alkaloid yield. Still, a considerable amount of alkaloids might be decomposed by heat, resulting in a decrease in their yield. The results showed that the optimal extraction temperature of alkaloids from Macleaya cordata with subcritical water is 190 °C, the time is 45 min, and the corresponding maximum yield is 35.19±0.12 mg/g (sanguinarine equivalent in raw materials). In addition, the antioxidation and bacteriostasis abilities of subcritical water extract are better than those of traditional hot water extract, indicating that it is a feasible method to extract alkaloids from Macleaya cordata with subcritical water.

Extraction of quinoline from toluene solution of wash oil using 1‑butyl‑3-methylimidazolium hexafluorophosphate ([BMIM] [PF6]): Experimental and molecular dynamics simulations

In this paper, a green solvent [BMIM] [PF6] ionic liquid was selected for the extraction and separation of quinoline from simulated wash oil. The effects of extraction temperature, extraction time, and solvent oil ratio on the extraction of quinoline from wash oil were studied. The optimal process parameters were obtained by changing single factor conditions and optimizing the experiment using response surface methodology. When the temperature is 71 ℃, the time is 60 min, and the solvent oil ratio is 3:5, the extraction efficiency can reach 67%. The ionic liquids were recovered and their properties were investigated by infrared spectroscopy. The mechanism of quinoline extraction by ionic liquids was analyzed using infrared spectroscopy and GROMACS kinetic simulation calculations.

Process Optimization of Microwave-Assisted Extraction of Chlorophyll, Carotenoid and Phenolic Compounds from Chlorella vulgaris and Comparison with Conventional and Supercritical Fluid Extraction

The production of bioactive products from microalgae biomass with efficient and environmentally friendly technologies is a field of great research interest. The present work focuses on the recovery of high-added value bioactive components from Chlorella vulgaris through microwave-assisted extraction (MAE) with aq. ethanol 90% v/v. The effect of extraction temperature (40–60 °C), duration (5–25 min), solvent-to-biomass ratio (20–90 mLsolv/gbiom), and microwave power (300–800 watts) was investigated regarding the extraction yield, extract’s chlorophyll, carotenoid and phenolic content, and antioxidant activity. MAE optimization at 60 °C, 300 watts, 14 min, and 22 mLsolv/gbiom led to 11.14% w/w yield, 63.36 mg/gextr total chlorophylls, 7.06 mg/gextr selected carotenoids of astaxanthin, lutein and β-carotene, 24.88 mg/gextr total carotenoids, 9.34 mgGA/gextr total phenolics, and 40.49 mgextr/mgDPPH IC50 (antioxidant activity indicator). Moreover, the conventional solid-liquid extraction (SLE) with aq. ethanol 90% v/v, the supercritical fluid extraction (SFE) with CO2, as well as SFE with cosolvent addition (10% w/w ethanol), were also performed for comparison purposes. The results revealed that SLE presented the highest yield. However, the non-conventional methods of MAE and SFE led to extracts of competitive or even better quality under significantly shorter extraction duration.

Chemical Influence of Scutellaria baicalensis—Coptis chinensis Pair on the Extraction Efficiencies of Flavonoids and Alkaloids at Different Extraction Times and Temperatures

The Scutellaria baicalensis—Coptis chinensis pair is an herbal combination used for the treatment of various heat-related diseases. During the extraction process, two herbs can mutually influence the extraction efficiency of the chemical constituents contained in each herb. The concentrations of five flavonoids from S. baicalensis and seven alkaloids from C. chinensis were compared in paired or single hot-water extracts at different temperatures (80, 90, and 100 °C) and extraction times (60, 90, and 120 min). Temperature- and time-dependent increases in marker compound concentrations were observed in both paired and single extracts, with the exception of baicalin, berberine, and coptisine in the paired extracts at 100 °C. However, the extractions of the compounds in the paired and single extracts were affected differently by the extraction conditions. Furthermore, the concentrations of most marker compounds in single extracts were 1.09–44.13 times those in paired extracts. The contents of baicalin, wogonoside, coptisine, and berberine, known to be easily aggregated by the flavonoid–alkaloid complex, were changed by 0.024–0.764-fold in the paired extract. The effect of extraction temperature and time on the formation of the flavonoid–alkaloid complex was not significant. The extraction efficiency of the flavonoids and alkaloids can be affected by the pair of S. baicalensis—C. chinensis, which is a primary factor in the chemical modification of two herb-containing herbal extracts.

Extraction of H3PO4 from low-grade phosphate rocks leachate of HCl-route by the mixture of TBP and IPE: Optimization, mass transfer and mechanism

The mixed solvent of tributylphosphate and isopropyl ether was used to extract H3PO4 and separate Ca2+ and Cl− from low concentration wet process phosphoric acid prepared by low-grade collophane and 30 wt% hydrochloric acid solution. Then, the effects of extraction temperature, composition of solvent mixture, aqueous/organic phase ratio, extraction time and extraction stage were investigated, respectively. The result shows that the extraction process of H3PO4 is an exothermic process and the enthalpy changes (ΔH) is −12.50 kJ mol−1. The McCabe–Thiele diagram shows two counter-current stages achieves about 76.9 wt% H3PO4 extraction at 293 K. Based on the mass transfer theory of liquid–liquid extraction, extraction yields for all tested component were summarized as an exponential function of cross-flow extraction stages. Meanwhie, extraction mechanism studies show that the comlex of αH3PO4 βTBP was formed in extraction process and higher Ca2+ concentration was beneficial for H3PO4 extraction. Meanwhile, the effects of stripping temperature, aqueous/organic phase ratio and stripping time on the re-extraction performance of H3PO4, Ca2+ and Cl− were studied, respectively. The result of experiment will provide some theoretical support for the industrial application of HCl-route wet process phosphoric acid on low-grade phosphate rock and phosphate tailings.

Optimization of the ultrasound-assisted extraction of flavonoids and the antioxidant activity of Ruby S apple peel using the response surface method

A Box–Behnken Design (BBD) was employed to optimize the extraction of antioxidants from Ruby S apple peel by ultrasound-assisted extraction (UAE). The effect of extraction temperature (20–40 °C), extraction time (15–45 min), and ethanol concentration (50–90%) in water on extraction yield, total phenol content (TPC), total flavonoid content (TFC), and DPPH radical scavenging activity of Ruby S peel extracts (RPEs) were investigated. The optimized extraction conditions that maximized extraction yield, TPC, TFC, and DPPH radical scavenging ability, were temperature 20 °C, extraction time 25.30 min, and ethanol concentration 50%. The validity of designed model was verified, and experimental values obtained under optimum conditions concurred with predicted values. Hyperoside, isoquercitrin, and phloridzin, were among the major flavonoids extracted. Our findings demonstrate the suitability of UAE and RSM for the optimization of Ruby S peel extraction and suggest the potential use of RPEs as bioactive functional materials.

Citric Acid Method Optimization for Pectin Extraction from Unripe ‘Saba’ Banana (<i>Musa acuminata X Musa balbisiana</i> BBB) Peels

The utilization of ‘Saba’ banana peels from processing wastes has shown potential as sources of pectin, which is widely used in the food and pharmaceutical industries. An optimized citric acid extraction of pectin from mature unripe 'Saba' banana peel wastes was developed using a three-factor Box-Behnken design considering the effects of extraction temperature (75-90°C), extraction time (1-5 hours), and agitated precipitation time (30-180 minutes) on the crude pectin yield. Results showed that the generated model is significant and that the extraction temperature and time significantly affected pectin yield and its equivalent weight. An increase in extraction temperature (up to 90°C) accompanied by prolonged extraction time can increase extraction yield. Optimum extraction conditions of 85°C for 5 h, with precipitation for 30 min resulted in the highest crude pectin yield (32.89% dry basis) in the experiment. The extracted pectin showed higher ash content (3.63%) and lower equivalent weight (513.05), methoxyl content (4.88%), moisture content (10.15%), and anhydrouronic acid (44.43%), than that of commercially available citrus pectin while degree of esterification did not vary.

Effect of Extraction Temperature on Bio-Functional Properties of <i>Cassia tora</i> Seed Processed by Germination and Roasting

Effect of Extraction Temperature on Bio-Functional Properties of <i>Cassia tora</i> Seed Processed by Germination and Roasting

Extraction and Characterization of Antioxidant Compounds in Almond (Prunus amygdalus) Shell Residues for Food Packaging Applications.

This work proposes the revalorization of almond shell (AS) wastes as an active additive for food packaging applications. A new microwave-assisted extraction (MAE) method to obtain extracts rich in polyphenolic compounds with high antioxidant capacity was optimized. An experimental design to optimize the MAE procedure through response surface methodology (RSM) using a Box–Behnken design was proposed. The effects of extraction temperature, irradiation time, ethanol:water concentration, and solvent pH at three levels were evaluated in terms of total phenolic content (TPC) and antioxidant activity (DPPH (2,2-diphenyl-1-picrylhydrazyl) and ferric reducing antioxidant power (FRAP) assays). The optimal conditions found were 57 min, 80 °C, pH 8, and 70% (v/v) ethanol. Optimized MAE extracts showed low soluble protein content (0.43 mg BSA g−1) and were rich in TPC (5.64 mg GAE g−1), flavonoids (1.42 mg CE g−1), and polysaccharides (1.59 mg glucose g−1), with good antioxidant capacity (2.82 mg AAE acid g−1). These results suggest the potential application of these extracts in the food industry as active additives. This strategy opens new pathways to valorize almond shell residues, contributing to the circular economy.

추출조건에 따른 생강 추출물의 항산화 활성 및 산화스트레스에 의한 근육세포 보호 효과

Ginger (Zingiber officinale Rosc.) root is known to have anti-oxidative effects. However, studies on the extraction conditions to obtain ginger extract (GE) with high antioxidant power have not yielded satisfactory results. Therefore, the effects of extraction temperature and time on the anti-oxidative effects of GE were investigated. The content of 6-gingerol and 6-shogaol in the GE was also analyzed. The results revealed that extraction carried out at 50°C for 5 h was optimal for maintaining the anti-oxidative activity of the GE. Further, GE obtained under these optimal conditions exhibited the highest DPPH and ABTS+ radical scavenging activities and cytoprotective effect against oxidative damage in L6 skeletal muscle cells and was rich in active compounds. Thus, the GE obtained under the optimal conditions could be useful for the development of functional food materials.

Extraction and Dyeing Techniques of Traditional Vegetable Dyestuffs.

In order to explore the influencing factors of the extraction of vegetable dyes, a research method for the extraction and dyeing of traditional vegetable dyes was proposed. In this paper, the effects of extraction temperature, extraction time, and the ratio of solid to liquid on the extraction effect were discussed through orthogonal experiments. The dyeing process of silk extract was used in this study. The silk fabric was directly dyed with natural dye from peach leaves, compared with the three dyeing methods of premordant, same-bath mordant, and postmordant, and the color fastness to soaping of the dyed fabric was tested. The results show that the color fastness to soaping of leaf-dyed fabrics conforms to the national standard of superior grades, which effectively proves the correctness of the algorithm and model nature and superiority.

Hot-Water Hemicellulose Extraction from Fruit Processing Residues.

Hemicelluloses are an abundant biopolymer resource with interesting properties for applications in coatings and composite materials. The objective of this investigation was to identify variables of industrially relevant extraction processes that increase the purity of hemicelluloses extracted from fruit residues. Our main finding is that extraction with subcritical water, followed by precipitation with alcohol, can be adjusted to yield products with a purity of at least 90%. Purity was determined based on the total concentration of glucose, galactose, xylose, arabinose, and mannose after hydrolysis with sulfuric acid. In the first experimental design (DoE methodology), the effects of extraction temperature (95–155 °C) and time (20–100 min) on yield and purity were studied. A clear trade-off between yield and purity was observed at high temperatures, indicating the selective removal of impurities. In the second experimental design, the influence of extract pH and alcohol concentration on yield and purity was investigated for the raw extract and a concentrate of this extract with 1/6 of the original volume. The concentrate was obtained by ultrafiltration through ceramic hollow-fiber membranes. The highest purity of 96% was achieved with the concentrate after precipitating with 70% alcohol. Key factors for the resource efficiency of the overall process are addressed. It is concluded that extraction with subcritical water and ultrafiltration are promising technologies for producing hemicelluloses from fruit residues for material applications.

Effect of Extraction Temperature on Pressurized Liquid Extraction of Bioactive Compounds from Fucus vesiculosus.

This study was aimed at investigating the effect of low polarity water (LPW) on the extraction of bioactive compounds from Fucus vesiculosus and to examine the influence of temperature on the extraction yield, total phenolic content, crude alginate, fucoidan content, and antioxidant activity. The extractions were performed at the temperature range of 120–200 °C with 10 °C increments, and the extraction yield increased linearly with the increasing extraction temperature, with the highest yields at 170–200 °C and with the maximum extraction yield (25.99 ± 2.22%) at 190 °C. The total phenolic content also increased with increasing temperature. The extracts showed a high antioxidant activity, measured with DPPH (2,2-Diphenyl-1-picrylhydrazyl) radicals scavenging and metal-chelating activities of 0.14 mg/mL and 1.39 mg/mL, respectively. The highest yield of alginate and crude fucoidan were found at 140 °C and 160 °C, respectively. The alginate and crude fucoidan contents of the extract were 2.13% and 22.3%, respectively. This study showed that the extraction of bioactive compounds from seaweed could be selectively maximized by controlling the polarity of an environmentally friendly solvent.

Effects of Extraction Temperature and Particle Size on Quality of Edible Oil from Podocarpus Falcatus Seed by Aqueous Method, Ethiopia

Introduction : The kernel from Podocarpus falcatus has potential for the production of edible oil . The oil is currently extracted using a traditional inefficient method for the purpose of house hold consumption. The objective of this study was to investigate the effects of particle size and extraction temperature on yield and quality of oil extracted from P. Falactus seeds by aqueous method. The experiment was carried out in a completely randomized design that comprised of three aqueous temperatures (70, 80 and 90 0 C) and three particle sizes (0.25, 0.50, and 0.75mm). Results: The maximum oil yield in this study was obtained 22.29 and 22.38±2.10% at extraction temperature of 70 0 C and at the particle size of 0.5mm respectively. Particle size and oil yield have correlation in that higher extraction was obtained (25%) as the particle size decreased. The particle size and temperature interaction had a positive effect on yield and maximum oil yield (25.25%) was obtained by the combination of 0.25mm particle size and 70 0 C. The peroxide, iodine and saponification values were obtained with acceptable range by the combination of 0.25mm and within the acceptable limit of edible oil 70 0 C. Yield and oil quality were influenced by extraction particle size and temperature. Keywords: Edible oil, Physicochemical, Aqueous, extraction, temperature, particle size, Podocarpus falcatus seed DOI: 10.7176/FSQM/114-01 Publication date: April 30 th 2022

Effects of Extraction Temperature and Particle Size on Quality of Edible Oil from Podocarpus Falcatus Seed by Aqueous Method, Ethiopia

Objective: The kernel from Podocarpus falcatus has potential for the production of edible oil. The oil is currently extracted using a traditional inefficient method for the purpose of household consumption. The objective of this study was to investigate the effects of particle size and extraction temperature on the yield and quality of oil extracted from P. Falactus seeds by the aqueous method. The experiment was carried out in a completely randomized design that comprised of three aqueous temperatures (70, 80, and 900C) and three particle sizes (0.25, 0.50, and 0.75mm). Results: The maximum oil yield in this study was obtained at 22.29 and 22.38±2.10% at an extraction temperature of 70°C and the particle size of 0.5mm respectively. Particle size and oil yield have a correlation in that higher extraction were obtained (25%) as the particle size decreased. The particle size and temperature interaction had a positive effect on yield and maximum oil yield (25.25%) was obtained by the combination of 0.25mm particle size and 70°C. The peroxide, iodine, and saponification values were obtained with an acceptable range by the combination of 0.25mm and within the acceptable limit of edible oil 70°C. Yield and oil quality were influenced by extraction particle size and temperature.

Temperature Optimization by Electrochemical Method for Improving Antioxidant Compound Extraction Efficiency from Origanum vulgare L. and Its Application in a Bread Production

This study aims to evaluate the effect of extraction temperature on the electrochemical activity of antioxidant compounds in oregano extract and its application in a bread production. Temperature optimisation was performed by determining the electrochemical index (EI), calculated on the parameters of individual peaks observed on the square wave voltammograms (SWV). The highest value of EI (2.5758 µA/V) was observed at 85 °C for the oregano extract. The composition of several types of bread with oregano extract or dried oregano leaves was then proposed. To specify bread samples, both newly prepared and during their storage, their antioxidant properties were determined using FRAP (Ferric Reducing Antioxidant Power) and CUPRAC (Cupric Reducing Antioxidant Capacity) methods. The study revealed that the addition of extract from oregano or oregano leaves increased the antioxidant compounds content in the bread from 30% to more than 138% compared to the control bread samples. The performed sensory evaluation of the bread samples revealed their high acceptability. It was found that the stored bread with oregano leaves changed sensory qualities to a lesser extent compared to the bread with oregano extract.