Materials with complex inner structure can be challenging to characterise in an effective way. The effective material parameters significantly depend on the structure, and thus on the interface properties. In the present paper, we focus on metal matrix syntactic foams, and we attempt to determine their effective thermal parameters. We supplement the results with their mechanical properties as well. For thermal characterisation, we use the heat pulse experiment to study their transient thermal response. We observed deviation from Fourier's law in multiple situations, and thus we propose an evaluation procedure for such experimental data using the Guyer–Krumhansl heat equation. We provide an iterative procedure to efficiently find the effective thermal diffusivity values provided by the Guyer–Krumhansl and Fourier equations based on the measured transient response. Furthermore, we studied the effective parameters, the specific heat, mass density, thermal conductivity and thermal diffusivity. We found that the standard estimations significantly overestimate the thermal conductivity. Furthermore, we propose a method for deducing a more reliable thermal diffusivity and thermal conductivity based on the transient temperature history, i.e., we propose to estimate Fourier's thermal diffusivity based on averaging the parameters of the Guyer-Krumhansl equation according to the observed diffusive time scales. We also found that for such metal matrix syntactic foams, even with knowing the constituents, the contact thermal resistance makes more challenging to provide a prior estimate for the effective thermal conductivity, but this difficulty can be resolved using proper effective thermal diffusivity values.
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