Saturable Absorption Effect Research Articles

Broadband nanotubes-based nonlinear modulators for erbium- and thulium-doped lasers

Carbon-based nanomaterials have become a long-term research hotspot in the fields of material science and nanotechnology. Carbon nanotubes as one-dimensional nanomaterials have shown great application value in the fields of electronics and optoelectronics. Herein, stable mode-locked pulsed lasers in both 1.5- and 2-μm bands were achieved by combining and balancing the stimulated emission effect of rare-earth ions and saturable absorption effect of carbon nanotubes. In the Er-doped fiber laser, pulses with a SNR of 61 dB and a peak power of 2.97 W were achieved at the wavelength of 1565.8 nm. Meanwhile, bound states were observed in the same laser, where the time delay of pulses was adjustable from 9.84 to 21.77 ps by tuning the pump power and polarization state. In the Tm-doped laser, output pulses were obtained at the wavelength of 1921.0 nm with a 60-dB SNR and a 12.82-W peak power. These results demonstrate that carbon nanotubes are ideal candidates for saturable absorber in mode-locked fiber lasers, which can be applied to a variety of applications, including fiber optic sensing, optical communication, and nanoscale processing.

Less is more: surface-lattice-resonance-enhanced aluminum metasurface with giant saturable absorption for a wavelength-tunable Q-switched Yb-doped fiber laser

Resonant metasurfaces provide a promising solution to overcome the limitations of nonlinear materials in nature by enhancing the interaction between light and matter and amplifying optical nonlinearity. In this paper, we design an aluminum (Al) metasurface that supports surface lattice resonance (SLR) with less nanoparticle filling density but more prominent saturable absorption effects, in comparison to a counterpart that supports localized surface plasmon resonance (LSPR). In detail, the SLR metasurface exhibits a narrower resonance linewidth and a greater near-field enhancement, leading to a more significant modulation depth (9.6%) at a low incident fluence of 25 μJ/cm2. As an application example, we have further achieved wavelength-tunable Q-switched pulse generation from 1020 to 1048 nm by incorporating the SLR-based Al metasurface as a passive saturable absorber (SA) in a polarization-maintaining ytterbium-doped fiber laser. Typically, the Q-switched pulse with a repetition rate of 33.7 kHz, pulse width of 2.1 μs, pulse energy of 141.7 nJ, and signal-to-noise ratio (SNR) of greater than 40 dB at the fundamental frequency can be obtained. In addition, we have investigated the effects of pump power and central wavelength of the filter on the repetition rate and pulse width of output pulses, respectively. In spite of demonstration of only using the Al metasurface to achieve a passive Q-switched fiber laser, our work offers an alternative scheme to build planar, lightweight, and broadband SA devices that could find emerging applications from ultrafast optics to neuromorphic photonics, considering the fast dynamics, CMOS-compatible fabrication, and decent nonlinear optical response of Al-material-based nanoplasmonics.

Interlayer engineered bilayered V₂O₅ NPs as saturable absorbers for infrared ultrashort pulse generation

Interlayer engineering offers a promising approach to modifying the structure of layered vanadium-based oxides, enhancing their saturable absorption effect and making them a desirable choice for developing infrared wavelength-range photonics devices. This experimental work synthesizes interlayer vanadium pentoxide (V2O5) using hydrothermal techniques to produce an excellent saturable absorber (SA). The interlayer engineering strategy enhances strong saturable absorption and self-defocusing effects in V2O5-based SA, enabling the generation of ultrashort pulses in the infrared region. Their superior nonlinear optical characteristics are demonstrated by a modulation depth of 13.9 % and saturation intensity of 0.42 GW cm−1, respectively. By utilizing a transmission coupling fiber-based V2O5-SA inside an Er-doped fiber laser cavity, a passively Q-switched (PQS) laser with a narrow pulse width of 2.78 μs and signal-to-noise ratio (SNR) ∼50 dB is realized for the first time. Furthermore, we explore a V2O5 NPs-SA long-term stability and high damage threshold. The results not only offer additional proof of the capable potential of interlayer V2O5 as a photo-bleaching absorber for realizing pulsed lasers in the NIR band but also cover the method for advancing their probable applications in optoelectronic devices.

Investigation on the characteristics of Q‐switched pulses in an EDFL based on the saturable absorption effect of germanene

AbstractIn this paper, an all‐fiber passively Q‐switched (QS) Er‐doped fiber laser (EDFL) was designed and successfully demonstrated by innovatively employing germanene as saturable absorber (SA). Due to its low‐warp honeycomb structure and remarkable zero bandgap property, germanene exhibits excellent potential for highly stable broadband pulse modulation. Based on the saturable absorption effect of germanene, a stable passive QS laser output was successfully achieved at 1530 nm under a threshold pump power of 63.7 mW. With the pump power increasing from 63.7 to 403.5 mW, the pulse repetition rate increases from 48.5 to 121.2 kHz accordingly. Meanwhile, we observe that the pulse width was shortened from 3.54 μs to 890 ns. The experimental results prove that germanene nanosheets have a promising future as a Q‐switcher in fiber lasers.

Dynamic of stationary soliton to soliton pulsation transition in spatiotemporal mode-locked fiber lasers

This paper presents the experimental observation of the transition from stationary spatiotemporal soliton (STS) to spatiotemporal soliton pulsation (STSP) in spatiotemporal mode-locked fiber lasers for the first time. Three STSs maintain an asynchronous pulsating state with the same period, while another STS remains in a stationary mode-locked state. Through numerical analysis, the dynamic transition process of STS to STSP is studied. Numerical analysis reveals that STSP occurs under specific cavity parameters when the energy is comparatively high. As pulse energy increases, a stationary STS gradually transitions to a pulsation state. The modes have undergone distinct evolutionary trajectories, and the pivotal role of the saturable absorption effect as well as the interaction among modes has been demonstrated to be crucial for STSP. Our study contributes to understanding the formation mechanism of STSP.

Saturable absorption properties of mixed lead-tin halide perovskites and their application in near-infrared ultrafast lasers

Mixed lead–tin halide perovskites, as highly sensitive materials in the near-infrared region, hold significant potential for optoelectronic device applications. Here, mixed lead–tin halide perovskite saturable absorbers (SAs) have been developed by coupling with the side-polished surfaces of the single-mode fibers and excellent saturable absorption effects of the mixed lead–tin halide perovskite SAs have been demonstrated in the near-infrared region. By constructing the in-gap site assisted carrier transfer mode, the saturation absorption process of the mixed lead–tin halide perovskite SAs can be well explained, in which defects as in-gap sites can help the photon-generated carriers transfer into the conduction band and promote the Pauli-blocking-induced absorption bleaching in the SA. Moreover, ytterbium-doped fiber lasers based on perovskite SAs have been fabricated, and mode-locked operations at 1040 nm are achieved using the mixed lead–tin halide perovskite SA, generating ultra-short pulses with a pulse width of 683 fs, 3 dB bandwidth of 4.88 nm, signal-to-noise ratio exceeding 49.74 dB, and a repetition rate of 3.74 MHz. Our findings demonstrate that the mixed lead–tin halide perovskite SAs have excellent optical modulation capability and promising applications in the field of ultrafast photonics.

Femtosecond nonlinear optical properties of Ti-doped In2Te3 thin films grown by magnetron co-sputtering

Herein, we successfully prepared Ti-doped In2Te3 and pure In2Te3 films by magnetron co-sputtering at room temperature. The film structure was measured using x-ray diffraction (XRD), scanning electron microscopy (SEM) equipped with energy dispersive x-ray spectroscopy (EDS), and x-ray photoelectron spectroscopy (XPS), while the linear optical constant of the films was measured using a spectroscopic ellipsometer (SE). The nonlinear optical properties of the films were examined using the Z-scan technique, wherein the samples were irradiated with 140 fs laser pulses at a wavelength of 800 nm and a repetition rate of 80 MHz, with an input intensity of 1.2GW/cm2. Ti incorporation led to decreased crystallinity and a reduction (redshift) in the optical bandgap (E g ). All films exhibit reverse saturation absorption (RSA) and self-focusing effect. A ninefold increase in the nonlinear refractive index (n2) and a fourfold increase in the nonlinear absorption coefficient (β) were observed for the Ti-doped S40 sample in comparison to the pure S0 sample. Adjusting the phase transition between amorphous and crystalline states in Ti-doped In2Te3 films further modulated their nonlinear optical properties. The optical limiting (OL) behavior of pure In2Te3 and Ti-doped In2Te3 thin films was investigated, and the results demonstrated that Ti-doped In2Te3 films show great promise as optical limiter devices in nonlinear photonics.

Surface plasmonic Au nanoparticles assisted CuO nanorods for broadband diverse ultrafast pulse generation

In virtue of the local surface plasmon resonance (LSPR) properties of metal nanoparticles to enhance the nonlinear optical response of the material, we successfully embed small-size Au nanoparticles into CuO nanorods. Then, theoretical and experimental methods verify that the assistance of ultrafast plasma response enhances the light-matter interaction. The LSPR characteristics and evanescent field distribution of the Au-CuO saturable absorber on the tapered fiber are studied by the finite element simulation method (FEM). By utilizing the Z-scan technology and twin-balanced detector system, excellent nonlinear optical (NLO) properties of the Au-CuO nanorods are demonstrated. Subsequently, depending on the remarkable nonlinear saturable absorption effect of Au-CuO, multiple operating states such as Q-switched, conventional soliton, double-subpulse soliton cluster, and noise-like pulse mode-locking are achieved in the erbium-doped fiber ring cavity at 1.5 μm. In addition, dual-wavelength mode-locking pulses with the center wavelengths of 1031 nm and 1035 nm are realized in the ytterbium-doped fiber ring cavity. This work describes an effective strategy to improve the NLO properties of CuO nanorods and indicates the great potential of Au-CuO in pulsed fiber lasers, opening a path for its application in ultrafast photonics and optoelectronics.

Design of Holographic Condenser Lens for Visible Light Lithography

Photolithography with visible light at λ = 405 nm utilizing the concept of nonlinear saturable absorption effect where the size of the spot is diminished to the nanometer scale as proposed by several researchers is an alluring proposition for cost-effective projection lithography. Costly conventional condenser lenses can be replaced by monochromatic aberration-free and cost-effective volume phase holographic lenses for visible light photolithography with enhanced resolution utilizing the concept of off-axis illumination. However, the diffraction efficiency of holographic lenses depends on the wavelength of illuminating light and the angle of illumination. Angular and spectral characteristics of volume phase holograms can be controlled by optimizing processing parameters. The results on the theoretical optimization of three important processing parameters, namely fringe spacing ( ∧ ), thickness of the film ( d ), and refractive index modulation ( Δ n ) in the light of coupled wave theory for recording holographic lenses of high diffraction efficiency at λ = 405 nm are presented. It is pointed out that a properly designed single holographic lens can be used for off-axis illumination of a photomask with a parallel beam of light, whereas a system of two identical holographic lenses cemented together has to be used to realize a condenser lens similar to a converging lens.

Broadband tunable single-frequency Yb-doped fiber laser with dual ring subcavity and Sagnac ring filter

We demonstrate a broadband tunable ultra-narrow linewidth single-frequency (SF) Yb-doped fiber laser (YDFL). A dual ring subcavity (DRS) as a filtering component to eliminate the dense longitudinal mode inherent in YDFL and theoretically analyzed its filtering characteristics. By inserting a 0.8 m unpumped polarization-maintaining Yb-doped fiber in the Sagnac ring, a dynamic narrowband grating (DNG) based on the saturable absorption (SA) effect is constructed to ensure SF laser output over the entire wavelength tuning range. We achieve a wide wavelength tunable SF laser output in the range of ∼74 nm, covering 1021.06 nm to 1094.98 nm. The laser has an optical signal-to-noise ratio (OSNR) of more than 62.5 dB, a slope efficiency of 3.57 %, and an ultra-narrow linewidth of 622 Hz over the entire tunable range. In addition, the stability of the wavelength and power fluctuations below 0.018 nm and 0.67 dB, respectively. This tunable SF fiber laser has a compact structure, lower cost, and excellent performance, and is expected to be used in the fields of coherent communications, precision metrology, and so on.

Generation of soliton molecules in a 1.5-μm ultrafast fiber laser based on Zinc 2,5-dihydroxyterephthalate saturable absorber

Two-dimensional (2D) Zinc 2,5-dihydroxyterephthalate (Zn-MOF-74) is a kind of metal–organic framework (MOF), which has been intensively studied in gas adsorption, gas storage, and catalysis. However, the potential applications of Zn-MOF-74 in the fields of optics, especially in the areas of nonlinear optical response and ultrafast optics need further exploration. Here, the nonlinear optical properties of Zn-MOF-74 are systematically investigated. In this work, we demonstrate that it gradually becomes saturated with the increase of the intensity of the incident pulse, which makes Zn-MOF-74 an effective saturable absorber in a mode-locked Er-doped fiber laser for ultrashort pulse generation. Our experiments yield stable single solitons as well as soliton molecules with tunable characteristics. When the pump power is 126 mW, conventional solitons with an output power of 2.35 mW and a pulse width of 0.93 ps are obtained. The generated pulses characterize a central wavelength of 1554.84 nm and a 3-dB bandwidth of 3.07 nm. By adjusting the pump power and polarization appropriately, the center wavelength of the soliton molecules is tunable from 1532.76 nm to 1554.24 nm. The experimental observations further proves that Zn-MOF-74 has great potential in ultrafast optics.

Composite porous 3D foam for solar-driven atmospheric water harvesting in low humidity natural environment

Solar-driven atmospheric water harvesting (SAWH) has been recognized as a promising strategy to alleviate the freshwater crisis. Herein, we developed an efficient porous polymeric foam, LiCl@CCP-PPy, which has low preparation cost, strong adaptability and portability, and is very suitable for use as a wicking material in SAWH systems. LiCl@CCP-PPy contains abundant –NH2 and –OH groups. These hydrophilic groups and excellent pore structure (porosity is 80.22 %) make it have a good moisture absorption effect even in low humidity environment. The moisture absorption capacity can reach 2.86 g/g at 35 % RH and 25 °C, and 4.48 g/g at 25 °C and 90 % RH. The saturated water absorption effect was 27.48 g/g. LiCl@CCP-PPy can be scaled up for production. In addition, LiCl@CCP-PPy has a high light absorption rate of more than 90 %, and the strong photothermal conversion ability of Polypyrene (PPy) enables the material to warm up rapidly under natural light, thereby accelerating the desorption process (96 % desorption rate at 1 kW/m2 for 3 h). Based on the above properties, LiCl@CCP-PPy was applied to the Tengger desert in northwest China. The final water production efficiency was 0.64 L/m2/d, and the collected water quality met the international drinking water standard.

Inorganic Material of Magnesium Nitrate Mg(NO3)2 Film as Q-Switcher in the C-Band Region

A novel inorganic material of Magnesium Nitrate (Mg(NO3)2) thin film is successfully investigated in the C-band region. The Q-switcher is Mg(NO3)2 thin film. The solvent casting method has been applied to prepare Mg(NO3)2 thin film before being positioned within the fiber ferrule duo to act as a Q-switcher. Thereby, the modulation depth and the saturation intensity of the Mg(NO3)2 thin film exhibit at 32.40% and 0.07 MW/cm2, respectively. It is possible to produce a steady Q-switched pulse fiber laser with a maximum pump power of 403.00 mW, a repetition rate of 72.56 kHz, and a pulse width of 3.00 µs. In addition, the tunable Q-switched pulse fiber laser is also examined using a figure-of-eight cavity design incorporating a tunable bandpass filter (TBF). Consequently, the operating wavelength is changed in the range of 1528 nm to 1552 nm, even while the pump power remains the same at 403.00 mW. During this time, the pulse width and repetition rate shifted from 2.10 µs to 4.10 µs and altered from 67.90 kHz to 35.80 kHz, respectively. Consequently, the Mg(NO3)2 thin film has the opportunity to be an effective saturable absorber for generating pulsed fiber lasers and can be applied in optical communications applications.

Passively mode-locked fiber lasers with broadband FeOOH saturable absorber

In this contribution, we synthesized iron oxide hydroxide (FeOOH) nanomaterials and successfully demonstrated the application of FeOOH-based saturable absorbers in ultrafast photonics at 1 μm and 1.5 μm. Various characterizations were conducted to analyze the morphological and structural features of FeOOH nanomaterials. Subsequently, a tapered fiber coated with FeOOH was integrated into the resonator as a saturable absorber, exhibiting the significant saturable absorption effect with modulation depths of 1.26 % at 1 μm and 2.61 % at 1.5 μm, respectively. In an Yb-doped fiber laser, stable noise-like mode-locking pulses were achieved with a pulse duration of 519 fs at the operating wavelength of 1037.2 nm with a full-width at half-maximum (FWHM) spectral bandwidth of 4.7 nm, yielding a maximum single pulse energy of 1.23 nJ with a high signal-to-noise ratio (SNR) of 47.8 dB. Meanwhile, the conventional soliton pulses were produced in the passively mode-locked Er-doped fiber laser, featuring a pulse duration of 1.02 ps, and an SNR of 42.5 dB at a peak wavelength of 1559.25 nm with a FWHM bandwidth of 2.8 nm. This work demonstrates the considerable nonlinear optical properties of FeOOH nanomaterials in the near-infrared range, proposing a promising saturable absorber for ultrafast photonics applications.

Wavelength-tunable quasi-unidirectional spatiotemporal mode-locked solitons in an isolator-free Er-doped fiber laser

In this letter, we have demonstrated the realization of the wavelength-tunable spatiotemporal mode-locked (STML) operation in an Er-doped partial multimode fiber laser without the intracavity isolator. The laser adopts an all-fiber structure and the saturable absorption effect is attributed to nonlinear multimode interference (NL-MMI) from the single mode fiber-graded index multimode fiber-single mode fiber (SMF-GIMF-SMF) design. The STML laser can operate in the quasi-unidirectional regime with an emission strength difference of larger than 30 dB for the two counter-propagating lasers. And the switching between the dominating operating directions in the clockwise (CW) or counter-clockwise (CCW) directions can be easily achieved by adjusting the MM polarization controller (PC). Both STML conventional solitons (CSs) and the STML soliton molecules are obtained with a similar tunable wavelength from ∼1.56 μm to ∼1.58 μm for the opposite operating directions. Furthermore, the spatial dynamics of the STML soliton are also investigated in detail. The experimental results are of great help for us to explore nonlinear spatiotemporal dynamics and provide potential applications in fields of all-optical signal processing, fiber sensing and information coding.

Wearable and interactive multicolored photochromic fiber display

Endowing flexible and adaptable fiber devices with light-emitting capabilities has the potential to revolutionize the current design philosophy of intelligent, wearable interactive devices. However, significant challenges remain in developing fiber devices when it comes to achieving uniform and customizable light effects while utilizing lightweight hardware. Here, we introduce a mass-produced, wearable, and interactive photochromic fiber that provides uniform multicolored light control. We designed independent waveguides inside the fiber to maintain total internal reflection of light as it traverses the fiber. The impact of excessive light leakage on the overall illuminance can be reduced by utilizing the saturable absorption effect of fluorescent materials to ensure light emission uniformity along the transmission direction. In addition, we coupled various fluorescent composite materials inside the fiber to achieve artificially controllable spectral radiation of multiple color systems in a single fiber. We prepared fibers on mass-produced kilometer-long using the thermal drawing method. The fibers can be directly integrated into daily wearable devices or clothing in various patterns and combined with other signal input components to control and display patterns as needed. This work provides a new perspective and inspiration to the existing field of fiber display interaction, paving the way for future human–machine integration.

Organic frame metal structure materials UIO-66 for picosecond ultrafast pulsed fiber lasers

The UIO-66 studied in this paper exhibits unprecedented thermal stability with a very high surface area and mechanical strength. This unique combination of properties opens up a wide range of promising applications. Here, we investigate the saturable absorption effects and ultrafast photonic applications of UIO-66. It shows that UIO-66 could emerge as a novel nonlinear material for ultrafast optics. By fabricating a real saturable absorber and incorporating it into a passively mode-locked Er-doped fiber laser, traditional solitons with a pulse duration of 0.96 ps at a repetition rate of 4.12 MHz have been obtained. The mode-locked spectrum centered at 1562.4 nm features a full width at half maximum of 3.5 nm. Our results may trigger follow-up investigations on the optical properties of UIO-66 and pave potential avenues for photonic and optoelectronic applications.

High-Precision Photoacoustic Nitrogen Dioxide Gas Analyzer for Fast Dynamic Measurement.

A high-precision photoacoustic (PA) gas analyzer for fast dynamic measurement of ambient nitrogen dioxide (NO2) was developed. The PA analyzer used a differential PA cell combined with two mufflers to achieve rapid gas flow gas detection. A high-power laser diode (LD) with a center wavelength of 450 nm was used as the PA signal excitation source. To reduce the saturated absorption effect of NO2, ambient air was pumped into the analyzer at a flow rate of 900 sccm. Two mufflers were combined with the differential PA cell to reduce the noise caused by the airflow and pump. The parameters of the mufflers were optimized by using a finite element method. The experimental results showed that the gas flow noise was suppressed by 95%. The response time of the PAS analyzer was 34 s. The detection limits of the analyzer were 0.64 and 0.17 ppb when the integration times were 1 and 15 s, respectively. A 120 h continuous monitoring result was compared with the data from the National Environmental Monitoring Station to demonstrate the high reliability of the analyzer.

Electronic intraband scattering in a transition-metal dichalcogenide observed by double-excitation ultrafast electron diffraction

Electronic dynamics in the excited state of transition-metal dichalcogenides (TMDs) has attracted great interest. To understand the ultrafast intraband scattering process of excited electrons in the conduction band, we demonstrated ultrafast time-resolved electron diffraction measurements with double-optical-pulse excitation and ultrafast transient reflectivity measurements of a TMD material, 2H-MoTe2. Due to the saturable absorption (or Pauli blocking) effect present in 2H-MoTe2, the system does not absorb the second excitation pulse until the excited electrons generated by the first excitation pulse with a specific fluence are scattered in the conduction band. By exploiting the Pauli blocking effect in ultrafast time-resolved electron diffraction measurements with double-optical-pulse excitation, we found that the excited electrons were scattered within 100 fs comparable to the excitation optical pulse duration. Furthermore, the excited electrons were relaxed to the lowest energy level of the conduction band (K- or Σ-valley) within 1–2 ps.

Nonlinear optical properties of methyl green investigated by the femtosecond Z-scan technique

The third-order optical nonlinearities of methyl green in aqueous solution are studied by the Z-scan technique using a femtosecond laser at 800 nm. The valley shape in the open aperture measurements reveals the presence of reverse saturable absorption effect, which is ascribed to the three-photon absorption process. The closed aperture Z-scan traces demonstrate a negative sign for the nonlinear refractive coefficient, indicating the self-defocusing optical nonlinearity. Furthermore, the magnitudes of the nonlinear refractive index n 2, the three-photon absorption coefficient α 3, and the real part of the third-order nonlinear optical susceptibility Re χ (3) are determined and found to be linearly proportional to the dye concentration within the investigated range. Our results suggest that methyl green may be a hopeful candidate for applications in nonlinear optics.