Effective Regulation Strategies Research Articles

Adsorption and Catalysis Effects of LaMnO3 Nanosheets for High‐Performance Li–S Batteries

In this article, an effective redox regulation strategy of Li–S batteries is illustrated by introducing a unique petal‐like LaMnO3 nanosheet (LMO‐NS) into the sulfur cathode. It is found that the LMO‐NS with abundant active sites offers strong chemical affinity toward the sulfur species, which play key roles in immobilizing the produced polysulfides during charge/discharge operation and then accelerating their redox conversion. Consequently, the Li–S reaction kinetics is remarkably boosted and the polysulfide shuttle is greatly alleviated owing to the adsorption‐catalysis effects of the LMO‐NS, which endows the composite cathode with increased reversible capacity and improved cycle and rate capability.

Composition and zoogeography of marine-estuarine fish from a lagoon system in a temperate-tropical transition zone of the Eastern Pacific

We present an updated systematic checklist of fishes from the Bahía Magdalena-Almejas lagoon system (Mexico), including notes on taxonomy, zoogeography, and conservation status, supported by field samplings and the critical review of published and online data. The ichthyofauna is composed by 2 classes, 30 orders, 104 families, 240 genera and 416 species, mainly represented by the class Actinopterygii. Zoogeographically, the fishes showed highest affinity to the San Diego (87.2%), Cortez (81.4%) and Mexican (70%) provinces, reflecting the ancient relationship between the Californian and Tropical Eastern Pacific regions and the existence of a transitional zone in the Baja California Peninsula for fish assemblages from boreal-temperate and warm-tropical derivation, standing out the presence of the endemic Paraclinus magdalenae. The 91% of the ichthyofauna is included by the IUCN Red List as Lower Concern, Data Deficient and Not Evaluated, while Holacanthus clarionensis and Hippocampus ingens, are under Special Protection by the Mexican regulation. Ecologically, 233 species are marine-euryhaline and 177 marine-stenohaline, which preferentially inhabit soft (57%) and rocky (27.5%) bottoms; most species are demersal (60%), benthic (25%) and pelagic (14.4%). The updated checklist could improve the design and implementation of effective fishing regulation strategies and conservation programs for fishes inhabiting this coastal ecosystem.

Skin cancer risk behaviors in sexual minority men: A mixed methods approach.

Sexual minority men experience disproportionately elevated rates of skin cancers, likely driven by excess ultraviolet radiation exposure-namely through tanning behaviors. However, limited integrated theoretical models exist to explain sexual minority men's elevated skin cancer risk. The aim of the current study is to further test and refine an integrated theory of skin cancer risk behaviors among sexual minority men by incorporating minority stress into the integrated health behavior model of tanning. The study employed a parallel mixed methods design, with a Phase 1 qualitative stage (N = 30) and a Phase 2 quantitative stage (Model 1: N = 320; Model 2: N = 319). In both phases, participants were sexual minority men, equally stratified as those with versus without recent tanning exposure and were recruited from across the United States. Qualitative and quantitative data supported the overall integrated model, with some quantitative paths varying depending on the tanning behavior outcome. Overall, appearance-related motives to tan and beliefs that tanning regulates affect emerged as the most consistent proximal predictors. Minority stress significantly predicted holding more positive attitudes toward tanning as an effective affect regulation strategy. The results from this mixed methods study support the inclusion of minority stressors into the adapted integrative health behavior model of tanning. Replication within prospective designs would strengthen the evidence for this model, which may be helpful in guiding future skin cancer prevention programs tailored to sexual minority men. (PsycInfo Database Record (c) 2024 APA, all rights reserved).

A Simplified Power Regulation Strategy for Grid-tied PMSG-based Marine Current Turbine System in High-speed Marine Current Conditions

Marine current turbine systems (MCTSs) play a crucial role in harnessing renewable energy from ocean currents. These systems are designed with specific rated values of marine current speed, dictating their optimal operational parameters. However, the dynamic nature of marine currents can lead to fluctuations, occasionally exceeding the rated values for which these systems are designed. This poses significant challenges to the efficient and safe operation of MCTSs, necessitating the development of effective power regulation strategies. In response to these challenges, this paper presents a simplified power regulation strategy to address the complexities of high-speed marine current conditions. The strategy focuses on constraining the reference torque command, a pivotal parameter governing power generation within MCTS. By precisely managing the reference torque command, the strategy aims to ensure that power output remains within designated limits, thereby safeguarding the MCTS despite high-speed marine current conditions. The proposed strategy leverages a computational approach to determine the generator's reference torque command, utilizing key parameters such as the rated power of the MCT and the mechanical angular rotor speed. It facilitates seamless transition between unconstrained reference torque command (URTC) and constrained reference torque command (CRTC) modes, enabling precise power regulation. This flexibility empowers the MCTS to respond promptly to changes in marine current conditions, facilitating precise and responsive power regulation. To validate the effectiveness of the proposed strategy, the paper conducts a comprehensive analysis of MCTS performance across both URTC and CRTC modes utilizing Typhoon HIL604 real-time simulator. Through detailed examinations of MCT speed responses, generator torque, output power, and grid-side parameters, the study provides valuable insights into the dynamics of MCTS operation. This comprehensive understanding enhances the stability and adaptability of MCTSs across diverse operating conditions, thereby advancing their potential as a sustainable energy solution.

Optimization of the BiO8 polar group of BiVO4 by Cl--embedded modification to manipulate bulk-surface carrier separation for achieving efficient Piezo-PEC water oxidation

BiVO4 is a promising photoanode material. However, achieving only a 2.67 % maximum ABPE while having a theoretical solar conversion efficiency of 9.2 % highlights the need for an effective carrier regulation strategy. In this study on the piezoelectric material BiVO4, Cl--embedded modification through synthetic post-treatment changes the oxygen evolution reaction (OER) pathway and suppresses surface charge recombination. In addition, the surprising finding of Cl- bonding with Bi3+ causing distortion in the BiO8 polar groups not only enhances the piezoelectric response but also significantly improves the performance of piezo-photoelectric chemical (Piezo-PEC) water oxidation. In the absence of any co-catalyst or sacrificial agent, the photocurrent density of Cl--embedded modified BiVO4 reached 0.268 mA/cm2 at 1.23 VRHE (5 times that of bare BiVO4). The data indicate that the piezoelectric polarized electric field successfully reduces electron-hole recombination. Cl--embedded modification amplifies the electric field intensity of the surface electric dipole in an ultrasonic environment, facilitating hole access to the catalytically active sites on the surface. Furthermore, the modified surface layer creates a rapid channel for hole migration, with the hole trapping process intricately linked to isolated electrons and intermediate Cl atoms. This embedded modification of polar groups serves as a reference for further exploration into the macroscopic polarization of piezoelectric materials and offers an optimization concept for the field of Piezo-PEC catalysis.

Metal−support interaction in single-atom electrocatalysts: A perspective of metal oxide supports

The discovery of single-atom catalysts (SACs) represents a groundbreaking advancement in the field of catalysis over the past decades. With the in-depth exploration of relevant structure-activity relationships, the metal−support interaction (MSI) is widely adopted to elucidate variations in electronic structure and coordination configuration of atomic active sites on various kinds of supports. Herein, we briefly summarize the metal oxide supports for SACs fabrication, including the distinctive characteristics of metal oxide supports, enlightening advancements in metal oxide support-based SACs (MO-SACs), feasible preparation methods for MO-SACs and effective regulation strategies of MSI effect in MO-SACs. In addition, we present our viewpoints and outlook in this field to stimulate rational design and construction of novel MO-SACs applied in diverse renewable energy devices, while some universal suggestions are sincerely given to provoke thoughtful considerations during the research process.

A UV-related risk analysis in ophthalmic malignancies: Increased UV exposure may cause ocular malignancies

PurposeTo explore the role of ultraviolet radiation (UVR) in the occurrence and development of various ocular malignancies. MethodsIn this article, we retrieved ocular malignancy data from the Global Cancer Observatory (GCO) and performed correlation analysis with the global UV index and sunshine duration. We searched for associated studies using the following databases: Embase, Pubmed, Cochrane Library, and Google Scholar. We conducted the literature by searching the Mesh terms denoting an exposure of interest ("UV radiation", "ultraviolet rays", and "ocular malignancies", All studies included are published until December 30, 2023 without language restrictions. ResultsThe mechanisms and epidemiological statistics of UVR on the onset and progression of eyelid malignancies are the most studied and clear. The role of UVR in conjunctival melanoma is similar to that in eyelid melanoma. The relationship between uveal melanoma and UVR is controversial, however, it may have at least a certain impact on its prognosis. UVR causes ocular surface squamous neoplasia by further activating HPV infection. ConclusionsUVR is a decisive risk factor for ocular malignancies, but the incidence of ultraviolet-induced tumors is also affected by many other factors. A correct and comprehensive understanding of the mechanisms of UVR in the pathogenesis of ocular malignant tumors can provide patients with more effective and selective immune regulation strategies.

Catalytic Effect of Ammonium Thiosulfate as a Bifunctional Electrolyte Additive for Regulating Redox Kinetics in Lithium-Sulfur Batteries by Altering the Reaction Pathway.

Sluggish sulfur redox kinetics and incessant shuttling of lithium polysulfides (LiPSs) greatly influence the electrochemical properties of lithium-sulfur (Li-S) batteries and their practical applications. For this reason, ammonium thiosulfate (AMTS) with effective redox regulation capability has been proposed as a functional electrolyte additive to promote the bidirectional conversion of sulfur species and inhibit the shuttle effect of soluble LiPSs. During discharging, the S2O32- in AMTS can trigger the rapid reduction of LiPSs from long chains to short chains by a spontaneous chemical reaction with sulfur species, thereby decreasing the accumulation of LiPSs in the electrolyte. During charging, the NH4+ in the AMTS enhances the dissociation/dissolution of Li2S2/Li2S by hydrogen-binding interactions, which alleviates the electrode surface passivation and facilitates the reversible oxidation of short-chain sulfides back to long chains. The enhanced bidirectional redox kinetics brought about by AMTS endows Li-S cells with high reversible capacity, excellent cycle stability, and rate capability even under lean electrolyte conditions. This work not only illustrates an effective redox regulation strategy by an electrolyte additive but also investigates its catalytic reaction mechanism and Li corrosion behavior. The crucial criteria for screening additives that enable bidirectional redox mediation analogous to AMTS are summarized, and its application perspectives/challenges are further discussed.

Rational Design of Janus Metal Atomic‐Site Catalysts for Efficient Polysulfide Conversion and Alkali Metal Deposition: Advances and Prospects

AbstractAlthough metal–sulfur batteries (M–S batteries, M = Li, Na, K) are promising next‐generation energy‐storage devices because of ultrahigh theoretical energy density, low cost, and environmentally friendliness, their practical applications are significantly hindered by the shuttle effect of polysulfides and growth of alkali metal dendrites. These issues can be mitigated by using Janus metal atomic‐site catalysts, which possess the maximum atom utilization efficiency (≈100%), adjustable electronic structures, and tailorable catalytic sites, thereby effectively improving the electrochemical performance of M–S batteries. In this review, the recent progress and development of Janus metal atomic‐sites on the properties, synthesis, and characterizations are reviewed. Then, the recent advances in Janus metal atomic‐site catalysts intended for accelerating polysulfide conversion and regulating alkali metal deposition, briefly introducing the working principles of the Janus metal atomic‐site catalysts in M–S batteries, are systematically summarized. Furthermore, a high emphasis is placed on effective regulation strategies for the rational design of Janus metal atomic‐site catalysts in M–S batteries. Finally, the current challenges and future research directions are also presented to develop high‐efficiency Janus metal atomic‐site catalysts for high‐energy M–S batteries.

Effective Knowledge Dissemination Modeling and Regulation in Blended Learning Networks

Blended learning networks (BLNs) based on the integration of online learning networks and offline learning environments provide new opportunities and platforms for people to acquire and update useful knowledge and carry out all kinds of learning activities anytime and anywhere. Effective modeling and regulation of the knowledge dissemination process can accurately grasp its dissemination process, promote knowledge innovation and collaborative sharing among learners, and accelerate the maximization of knowledge dissemination. However, it is a challenge to establish a comprehensive dynamics model and adopt the optimal regulation for the knowledge dissemination process under the constraints of a limited budget in large-scale BLNs with diverse learners. To this end, we first explore the evolution process of knowledge dissemination in BLNs and the blended learning interaction process of learners. Based on the system dynamics modeling theory, a dynamics model of knowledge dissemination is established. Second, two kinds of effective regulation strategies are proposed. We establish an optimal regulation system intending to maximize the dissemination of knowledge and use the optimal control theory to tackle the optimal solution distribution of regulation strategies. Then, we propose a knowledge dissemination regulation task allocation method based on the collaborative participation of users, and the reverse auction theory is used to quickly solve the task allocation scheme while ensuring performance. Finally, we demonstrate the effectiveness of proposed models and methods through extensive simulation experiments based on real datasets.

Nicotinamide mononucleotide alleviates seizures via modulating SIRT1-PGC-1α mediated mitochondrial fusion and fission.

Both human and animal experiments have demonstrated that energy metabolism dysfunction in neurons after seizures is associated with an imbalance in mitochondrial fusion/fission dynamics. Effective neuronal mitochondrial dynamics regulation strategies remain elusive. Nicotinamide mononucleotide (NMN) can ameliorate mitochondrial functional and oxidative stress in age-related diseases. But whether NMN improves mitochondrial energy metabolism to exert anti-epileptic effects is unclear. This study aims to clarify if NMN can protect neurons from pentylenetetrazole (PTZ) or Mg2+ -free-induced mitochondrial disorder and apoptosis via animal and cell models. We established a continuous 30-day PTZ (37 mg/kg) intraperitoneal injection-induced epileptic mouse model and a cell model induced by Mg2+ -free solution incubation to explore the neuroprotective effects of NMN. We found that NMN treatment significantly reduced the seizure intensity of PTZ-induced epileptic mice, improved their learning and memory ability, and enhanced their motor activity and exploration desire. At the same time, invitro and invivo experiments showed that NMN can inhibit neuronal apoptosis and improve the mitochondrial energy metabolism function of neurons. In addition, NMN down-regulated the expression of mitochondrial fission proteins (Drp1 and Fis1) and promoted the expression of mitochondrial fusion proteins (Mfn1 and Mfn2) by activating the SIRT1-PGC-1α pathway, thereby inhibiting PTZ or Mg2+ -free extracellular solution-induced mitochondrial dysfunction, cell apoptosis, and oxidative stress. However, combined intervention of SIRT1 inhibitor, Selisistat, and PGC-1α inhibitor, SR-18292, eliminated the regulatory effect of NMN pre-treatment on mitochondrial fusion and fission proteins and apoptosis-related proteins. Therefore, NMN intervention may be a new potential treatment for cognitive impairment and behavioral disorders induced by epilepsy, and targeting the SIRT1-PGC-1α pathway may be a promising therapeutic strategy for seizures.

Strategies for the effective design and regulation of carbon-based metacomposites: a review

Effective design and regulation strategies of carbon-based metacomposites classified based on their composition, structure, interface and defect engineering, and external field for adjustable performance.

Constructing hollow core-shell Z-scheme heterojunction CdS@CoTiO3 nanorods for enhancing the photocatalytic degradation of 2,4-DCP and TC.

Constructing Z-scheme heterojunctions incorporating an exquisite hollow structure is an effective performance regulation strategy for the realization of high quantum efficiency and a strong redox ability over photocatalysts. Herein, we report the delicate design and preparation of a core-shell hollow CdS@CoTiO3 Z-scheme heterojunction with a CdS nanoparticle (NP)-constructed outer shell supported on a CoTiO3 nanorod (NR) inner shell. The in situ growth synthetic method led to a tightly connected interface for the heterojunction between CdS and CoTiO3, which shortened the transport distance of photoinduced charges from the interface to the surface. The promoted charge carrier separation efficiency and the retained strong redox capacity caused by the Z-scheme photoinduced charge-transfer mechanism were mainly responsible for the boosted photocatalytic performance. Additionally, the well-designed core-shell structure afforded a larger interfacial area by the multiple direction contact between CdS and CoTiO3, ensuring sufficient channels for efficient charge transfer, and thus further boosting the photocatalytic activity. As an efficient photocatalyst, the optimized CdS@CoTiO3 nanohybrids displayed excellent 2,4-dichlorophenol (2,4-DCP) and tetracycline (TC) degradation efficiencies of 91.3% and 91.8%, respectively. This study presents a Z-scheme heterojunction based on ecofriendly CoTiO3, which could be valuable for the development of metal perovskite photocatalysts for application in environmental remediation, and also demonstrated the tremendous potential of integrating a Z-scheme heterojunction with the morphology design of photocatalyts.

Magnetically treated water drip irrigation combined with carboxymethyl cellulose (CMC) application: A regulating strategy for enhancing the jujube yield and quality in southern Xinjiang of China

Developing effective regulation strategies for improving the efficiency of irrigation water and fertilizers, and preventing further expansion of desertification in southern Xinjiang, China, is crucial. Magnetically treated water (MTW) has been shown to have a positive effect on plant growth. The carboxymethyl cellulose (CMC) has been widely used as an efficient soil amendment to improve soil aggregation and hydraulic properties. This study aimed to explore the optimal mode of combining MTW drip irrigation and CMC application for high-quality jujube production. Conventional freshwater irrigation was set up in both 2021 and 2022 (control group, CK). CMC treatments under MTW drip irrigation included C0 (0), C150 (150 kg/ha), C250 (250 kg/ha), C350 (350 kg/ha), and C450 (450 kg/ha) in 2021, and C0 (0), C150 (150 kg/ha), C300 (300 kg/ha), C450 (450 kg/ha), and C600 (600 kg/ha) in 2022. The results showed that CMC significantly increased soil porosity, water-holding capacity, and decreased soil bulk density and soil saturated hydraulic conductivity. CMC contributed 2.88 % to 27.96 % of large aggregates (>0.25 mm), significantly improving soil aggregate stability. Water and fertilizer (N, P, K) productivity increased by 4.5 % to 11.0 % and 1.9 % to 11.3 %, respectively. Jujube yield increased by 2.75 % to 15.98 %, and MTW increased jujube yield by 3.10 % compared to the CK. The recommended optimal CMC application rate was approximately 430 kg/ha. This mode provides a reliable theoretical reference for jujube industry development and soil desertification improvement in southern Xinjiang, China.

Academic Emotions and Regulation Strategies: Interaction with Higher Education Dropout Ideation

(1) Introduction: This article addresses the relationship between students’ emotional experiences—mediated by their regulation strategies—and their intention of dropping out. (2) Materials and Methods: An ad hoc questionnaire was designed based on Pekrun’s Control-Value Theory of Achievement Emotions focusing on three different settings (study, classroom, and exam). Data were collected from 2183 university students. Descriptive, frequency, and correlation analysis were conducted. Also, linear regression analyses and scatter plots were performed. A comparative regression analysis was used with the aim of facilitating the understanding of the mediating effect of emotional regulation strategies. (3) Results: Academic emotions were found to have a significant impact on dropout ideation. The effects of emotional regulation strategies as significant moderators in this relationship were observed, exhibiting variations depending on the context. (4) Discussion: Dropout ideation escalates in the presence of elevated levels of unpleasant emotions and diminished levels of pleasant emotions. The utility of possessing effective emotional regulation strategies becomes evident in mitigating dropout ideation during emotionally challenging academic situations.

Genetically engineered M2-like macrophage-derived exosomes for P. gingivalis-suppressed cementum regeneration: From mechanism to therapy

Cementum, a thin layer of mineralized tissue covering tooth root surface, is recognized as the golden standard in periodontal regeneration. However, current efforts mainly focus on alveolar bone regeneration rather than cementum regeneration, and rarely take Porphyromonas gingivalis (Pg), the keystone pathogen responsible for periodontal tissue destruction, into consideration. Though M2 macrophage-derived exosomes (M2-EXO) show promise in tissue regeneration, the exosome-producing M2 macrophages are induced by exogenous cytokines with transitory and unstable effects, restricting the regeneration potential of M2-EXO. Here, exosomes derived from genetically engineered M2-like macrophages are constructed by silencing of casein kinase 2 interacting protein-1 (Ckip-1), a versatile player involved in various biological processes. Ckip-1 silencing is proved to be an effective gene regulation strategy to obtain permanent M2-like macrophages with mineralization-promoting effect. Further, exosomes derived from Ckip-1-silenced macrophages (sh-Ckip-1-EXO) rescue Pg-suppressed cementoblast mineralization and cementogenesis. Mechanismly, sh-Ckip-1-EXO delivers Let-7f-5p targeting and silencing Ckip-1, a negative regulator also for cementum formation and cementoblast mineralization. More deeply, downregulation of Ckip-1 in cementoblasts by exosomal Let-7f-5p activates PGC-1α-dependent mitochondrial biogenesis. In all, this study provides a new strategy of genetically engineered M2-like macrophage-derived exosomes for cementum regeneration under Pg-dominated inflammation.

Mitigation of microbial nitrogen-derived metabolic hazards as a driver for safer alcoholic beverage choices: An evidence-based review and future perspectives.

Alcoholic beverages have been enjoyed worldwide as hedonistic commodities for thousands of years. The unique quality and flavor are attributed to the rich microbiota and nutritional materials involved in fermentation. However, the metabolism of these microbiota can also introduce toxic compounds into foods. Nitrogen-derived metabolic hazards (NMH) are toxic metabolic hazards produced by microorganisms metabolizing nitrogen sources that can contaminate alcoholic beverages during fermentation and processing. NMH contamination poses a risk to dietary safety and human health without effective preventive strategies. Existing literature has primarily focused on investigating the causes of NMH formation, detection methods, and abatement techniques for NMH in fermentation end-products. Devising effective process regulation strategies represents a major challenge for the alcoholic beverage industry considering our current lack of understanding regarding the processes whereby NMH are generated, real-time and online detection, and the high degradation rate after NMH formation. This review summarizes the types and mechanisms of nitrogenous hazard contamination, the potential risk points, and the analytical techniques to detect NMH contamination. We discussed the changing patterns of NMH contamination and effective strategies to prevent contamination at different stages in the production of alcoholic beverages. Moreover, we also discussed the advanced technologies and methods to control NMH contamination in alcoholic beverages based on intelligent monitoring, synthetic ecology, and computational assistance. Overall, this review highlights the risks of NMH contamination during alcoholic beverage production and proposes promising strategies that could be adopted to eliminate the risk of NMH contamination.

Family functioning and suicidal ideation in college students: a moderated mediation model of depression and acceptance.

To explore the mediating role of depression in the relationship between family functioning and suicidal ideation (SI) in college students, and to explore whether acceptance (It is one of the core components of psychological flexibility) plays a moderating role in this mediating model. In a cross-sectional study, questionnaires were distributed to college students during November and December 2022. The sample of Chinese college students (n = 592, 43.07% male, 56.93% female, mean age 19.40 years, SD = 1.24 years) completed the Family Adaptability and Cohesion Evaluation Scale (FACES III), the Center for Epidemiological Depression Scale (CES-D), the Positive and Negative Suicide Ideation Inventory (PANSI), and the Acceptance and Action Questionnaire-Second Edition (AAQ II). SPSS 25.0 for Windows and PROCESS 2.15 macros were used for data analysis. There was a significant negative correlation between family functioning and SI, and depression played a mediating role in this relationship. Acceptance moderated the indirect effects of depression and SI in college students. In college students with a lower acceptance level (i.e., higher experiential avoidance level), depression had more influence on SI, while the influence of depression on SI was less in college students with a higher acceptance level (i.e., lower experiential avoidance level). Family functioning indirectly influenced SI through the moderation of acceptance. Mental health educators in colleges and universities should pay more attention to identifying and relieving depression in college students, thereby dealing with suicide risk more effectively. At the same time, college students should be discouraged from excessive use of experiential avoidance strategies, and instead taught to master effective emotional regulation strategies such as mindfulness, distress tolerance, and radical acceptance skills to improve their acceptance level and alleviate the influence of depression on SI.

The regulating effect of twisted angle on the photocatalytic overall water splitting for C3N/C3B heterojunction

The construction of van der Waals heterojunctions for photocatalytic overall water splitting is a promising strategy for obtaining clean energy. Good carrier separation, broadened photo-absorption, and efficient catalytic activity are crucial factors remaining significantly challenging. Herein, based on first-principles calculations, taking C3N/C3B as an example, we demonstrate that the suitable twisted angle (θ) formed in the layered structure is an efficient strategy to regulate photocatalytic properties of two-dimensional materials. For the heterojunctions stacked with θ = 19.1° and 40.9°, the layer-to-layer interaction introduced by the moiré pattern provides an electrostatic potential difference of up to 2.1 eV, about 0.8 eV higher than non-twisted. The enhanced built-in electric field not only alleviates the redox potential limit of water splitting but also promotes the transfer of photogenerated carriers. Meanwhile, the twisted C3N/C3B improves the visible light response by opening the transition channels in the low-energy region. Especially for the difficult four-electron oxygen evolution reaction, the overpotential is reduced from 0.70 to 0.52 V based on the moiré potential, which can be easily conquered for the twisted C3N/C3B with sufficient redox potential. Interlayer torsion provides an effective regulation strategy to improve the photocatalytic overall water splitting performance for metal-free heterojunctions.

Interface engineered Ni3Se2/Ni3S2/NF heterostructure as a highly efficient electrocatalyst for robust oxygen evolution reaction

Transition metal chalcogenides has been reported to be an efficient catalyst toward oxygen evolution reaction (OER) catalysts. Developing a reliable heterogeneous structure strategy to modulate the electronic structure of electrocatalyst is a key challenge. Herein, we investigate an efficient and stable Ni3Se2/Ni3S2/NF catalyst with heterogeneous structure toward OER. The catalyst exhibits excellent OER performance with a low overpotential of 251 and 312 mV at 50 and 100 mA cm−2, respectively. Experiment result shows that the interface of Ni3Se2 /Ni3S2/NF heterostructure triggers abundant catalytically active sites, while regulates the electronic structure of Ni central active site resulting in fast charge-transfer capacity and superior electrochemical performance. This work provides an effective interface regulation strategy for developing applications of other advanced heterostructures.