Accidental release of pressurized CO2 pipeline in carbon capture and storage involves the interaction of phase change and heavy-gas dispersion. However, the effect of the phase change of water vapor in air on the performance of cold CO2 dispersion is usually neglected. In this study, a three-dimensional two-phase computational fluid dynamics (CFD) model is developed to evaluate the cold CO2 dispersion by considering the phase change of water. A phase-change model based on the homogeneous relaxation model is used to describe the evaporation and condensation of water. The effects of terrain roughness, atmospheric stability, and turbulence models on the dispersion are also considered. The numerical results show that the model that uses the k–ω turbulent equations is superior to the other models. The results in which the phase change of water is considered exhibit a better agreement with the data from the experiments than those that do not consider it. The model is subsequently used in urban areas, which results in over-predicted CO2 concentration in the near field and under-predicted CO2 concentration in the far field when the phase change of water vapor is considered than that when it is neglected. Therefore, we proposed that the phase change of water vapor in the atmosphere should not be overlooked in the more accurate modeling of cold CO2 dispersion.
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