Corrosion fatigue properties of ultrafine grained (UFG) Fe-20%Cr steel by equal channel angular pressing was investigated in term of grain refinement and stored energy. The corrosion fatigue life of the ECAP processed and the post-ECAP annealed sample was analysed. Under annealing temperature of 773 K, due to the recrystallization stage, there was a little difference in microstructure from the four passes ECAP. After the annealing process, the strength of the samples pressed four passes decreases, while the elongation showed more ductile. Two mechanisms for crack propagation have been well recognized for stainless steel. One is slipping step dissolution mode. In this model, the slip step formed by active dislocation at a crack tip is anodic dissolution reaction, so that crack tip advance to further distance. The other is stress adsorption mechanism. The corrosion fatigue cracks initiation and cracks propagation process of iron-chromium alloy can be characterized by corrosion pits and intergranular fracture, respectively. The corrosion fatigue behaviour of non-equilibrium and equilibrium grain boundary of iron-chromium alloy was occupied by crack initiation.
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