This paper aims to develop a multiscale thermo-mechanical coupling model across from meso-scale to macro-scale to study the tensile thermos-mechanical behavior of fiber-reinforced cementitious composite (FRCC) on the base of thermodynamics. In meso-scale, the coupling process of thermal effect and the development law of a single crack were creatively presented and formulated in energy potential function. The effects of fiber dispersion on cracking behavior and crack strength of matrix were determined. In macro-scale, the multiple-fine-cracks and strain-hardening/softening behavior under tension were defined and studied. The bridging action stress of fibers is calculated by considering the bonding stress in the interface transition zone (ITZ). The model can be upgraded for FRCC materials ranges from strain-hardening cementitious composite (SHCC) and engineered cementitious composite (ECC). The numerical calculations of the proposed model were conducted based on the Fortran program for validation. The residual tensile strength, multiple-fine-cracks and strain-hardening/softening behaviors of FRCC were predicted. The behaviors of FRCC with different fiber types were accurately captured in a range of temperature from 20°C to 600°C through the comparative study with six groups test results in literatures. A sensibility study was carried out to analyze the impact of modelling parameters and thermal effect on the strain-hardening/softening behaviors of FRCC.