Listed state-owned highway companies face problems such as low operational efficiency, a fixed operation period, and a limited scale of road assets. This paper presents the current situation of listed state-owned highway companies and analyses the mechanism of executive compensation and cooperate governance based on principal-agent theory, management power theory, and Maslow’s hierarchy of needs theory. The research constructs the index assessment system, selects the data of 20 listed state-owned highway companies from 2012 to 2021 as samples, and applies the principal component analysis (PCA) to measure the comprehensive performance of listed state-owned highway companies. Using a fixed-effects panel model, the impact of executive remuneration on corporate performance is examined along three dimensions: executive monetary compensation, executive pay gap, and executive on-the-job consumption. The research proposes recommendations to address the problems of executive compensation system, with a view to improving corporate performance in listed state-owned highway companies.