Abstract In this investigation a novel material has been developed comprising of Silicon Carbide (ceramic), Aluminium honeycomb (metal) and Poly Ether Ketone (PEK)—Poly Phynelene Benzobisoxaole (PBO) fiber based blast proof composite. The experimental results proved that this polymeric composite is highly suitable for 9 mm pistol bullet with 430 m s−1 at distance of 5 m as well as for improvised explosive devices blast to absorb the sharpnels/splinters. This investigation also highlights an efficient back layer for a blast-proof sandwich composite. Layer optimization was carried out by finite element method (FEM) analysis of blast effect on the multi-layer polymer composite panel by ANSYS Explicit Dynamics (LS DYNA Solver). The resultant optimal layers of PEK-PBO composites then tested to validate results of FEM analysis. Experimentally it is proved that polymeric composite with 10 layers of PBO fabric when test fired under 9 mm pistol bullet with 430 m s–1 at distance of 5 m, the bullet penetrates, however, when the polymeric composite is made with a total of 20 layers of PEK-PBO fabric, all the test fired bullets are stopped. Therefore, under SNANAG 4569 blast test, the polymeric composite was essentially made with 20 layers of PBO fabric and it is experimentally proved that PEK-PBO composite is highly efficient as the back layer of hybrid composite and all the sharpnels of IED blast are completely absorbed.