Edible Packaging Materials Research Articles

Fabrication of collagen-sodium alginate based antibacterial and edible packaging material: Performance evaluation using Entropy-Combined Compromise Solution (CoCoSo)

In this research, we developed two alternative packaging materials: collagen-sodium alginate-pomegranate peel powder (CSP) and collagen-sodium alginate-chitosan (CSC), leveraging solid waste from both the leather and food industries. A comparative analysis was done between CSP and CSC film to evaluate their efficacy and potentiality as sustainable packaging material. CSC film showed reduced water solubility (39.4 %), water vapor transmission rate (27.3 gh-1m-2), and opacity (0.6 A600/mm) along with improved contact angle (69.7°) compared to CSP film. However, CSP film exhibited improved mechanical strength (10.9 MPa) and biodegradability (72.1 %) along with reduced oxygen permeability (0.6 meq/kg) compared to CSC film. Furthermore, CSP and CSC films showed significant inhibitory effect against two commonly available pathogen strains. A hybrid Entropy-Combined Compromise Solution (CoCoSo) analysis results demonstrated the superior performance of CSC films (γi=3.049) as packaging material. The edibility of the film was confirmed through pathogen test, in vitro cytotoxicity and stimulated digestibility assays. Additionally, from the thermal analysis it is apparent that the optimum degradation temperature for CSC film was 584 °C which is higher than any other green packaging material reported in the literature. Therefore, this study can pave the way for the fabrication of thermally stable edible packaging material from waste sources.

Edible packaging revolution: Enhanced functionality with natural collagen aggregates

With the growing emphasis on underlying food safety, the diverse requirements for edible packaging materials are becoming increasingly prominent. Collagen offers multifaceted applications in food packaging and preservation. However, the major scientific challenge for existing collagen-based edible packaging materials lies in engineering proper biosecurity without compromising the materials' mechanical properties, water resistance, barrier properties, and so on. Herein, a novel hierarchical controlled degradation strategy was proposed for the systematic extraction of new-generation collagen aggregates for collagen-based edible packaging revolution. This strategy ensured a high biosafety profile at the source by extracting collagen aggregates with the intact multi-hierarchical aggregate-structure of nature collagen (HL-Col), collagen molecules (Col), gelatin (Gel) from decellularized dermal matrix (GADM). Subsequently, HL-Col, Col, and Gel were further processed into edible food packaging films. Our results showed that HL-Col, with its structure homologous to natural skin, exhibited significantly enhanced biocompatibility, mechanical properties, water resistance, and resistance to enzyme degradation compared to the traditional Col and Gel. Notably, while biodegradable, it could be preserved intact even after 72 h of in vitro enzyme degradation. Application experiments substantiated that edible food packaging films made from HL-Col achieved a breakthrough shelf-life of 9 days, representing a 4-day extension compared to traditional PE films, substantiating the immense potential of HL-Col for edible food packaging materials and further providing pregnant references for the development of highly-safe edible materials.

Preparation and properties of liquid-core yogurt balls by layer-by-layer assembly of edible packaging materials

Abstract To address the issue of yogurt adhering to the inner walls of packaging, resulting in resource wastage, a controllable particle size of alginate-calcium yogurt liquid core ball (LC-Yoba) was prepared using a mold-reverse spherification method. The effectiveness of layer-by-layer (LBL) assembly techniques in enhancing the performance of LC-Yoba was investigated. The results showed that a multilayer structure composed of beeswax-chitosan (BW-CS) was successfully assembled on the surface of LC-Yoba, wherein the number of assembly layers significantly impacts its performance. Compared with the unassembled LC-Yoba, the bursting force of the assembled three layers of LC-Yoba increased by 194.67 %, the elasticity increased by 19.76 %, and the weight loss rate decreased by 86.58 %. In addition, the appearance of the three layers of LC-Yoba and the pH, acidity, and water holding capacity of the yogurt were maintained in a stable state within 72 h at room temperature.

Applications and characterization of anti-browning enzymatically modified potato starch (EPS) film associated with chitosan (CTS)/L-Cys/citric acid (CA) on fresh-cut potato slices

This study explores the influence of incorporating L-cysteine (L-Cys), chitosan (CTS), and citric acid (CA) on the enzymatic modification of potato starch (EPS) films to enhance anti-browning properties. Four types of EPS composite films were evaluated for preserving fresh-cut potato slices at low temperatures to inhibit browning. Their thermal, physiochemical, mechanical, and digestibility properties were assessed. Results indicate that the addition of CTS, CA, and L-Cys improved the anti-browning activity of the EPS films by increasing film thickness and reducing water vapor permeability (WVP), oxygen transmission rate (OTR), ultraviolet (UV) transmittance, and tensile strength (TS). Furthermore, these additives improved the film's microstructure, resulting in reinforced intermolecular interactions, increased elongation at break, heightened crystallinity, enhanced thermal stability, and favorable gastrointestinal digestibility. Overall, EPS/CTS/L-Cys/CA composite films show promise as edible packaging materials with effective anti-browning properties.

Development and Physicochemical Characterization of Edible Chitosan-Casein Hydrogel Membranes for Potential Use in Food Packaging.

The increasing global concern over plastic waste and its environmental impact has led to a growing interest in the development of sustainable packaging alternatives. This study focuses on the innovative use of expired dairy products as a potential resource for producing edible packaging materials. Expired milk and yogurt were selected as the primary raw materials due to their protein and carbohydrate content. The extracted casein was combined with various concentrations of chitosan, glycerol, and squid ink, leading to the studied samples. Chitosan was chosen due to its appealing characteristics, including biodegradability, and film-forming properties, and casein was utilized for its superior barrier and film-forming properties, as well as its biodegradability and non-toxic nature. Glycerol was used to further improve the flexibility of the materials. The prepared hydrogels were characterized using various instrumental methods, and the findings reveal that the expired dairy-based edible packaging materials exhibited promising mechanical properties comparable to conventional plastic packaging and improved barrier properties with zero-oxygen permeability of the hydrogel membranes, indicating that these materials have the potential to effectively protect food products from external factors that could compromise quality and shelf life.

Application of Plant Oils as Functional Additives in Edible Films and Coatings for Food Packaging: A Review.

Increasing environmental concerns over using petroleum-based packaging materials in the food industry have encouraged researchers to produce edible food packaging materials from renewable sources. Biopolymer-based edible films and coatings can be implemented as bio-based packaging materials for prolonging the shelf life of food products. However, poor mechanical characteristics and high permeability for water vapor limit their practical applications. In this regard, plant oils (POs) as natural additives have a high potential to overcome certain shortcomings related to the functionality of edible packaging materials. In this paper, a summary of the effects of Pos as natural additives on different properties of edible films and coatings is presented. Moreover, the application of edible films and coatings containing POs for the preservation of different food products is also discussed. It has been found that incorporation of POs could result in improvements in packaging's barrier, antioxidant, and antimicrobial properties. Furthermore, the incorporation of POs could significantly improve the performance of edible packaging materials in preserving the quality attributes of various food products. Overall, the current review highlights the potential of POs as natural additives for application in edible food packaging materials.

Edible packaging as sustainable alternative to synthetic plastic: a comprehensive review.

The choice of an appropriate packaging materials enhances the shelf life and improves quality of food during transportation, storage, and distribution. Development and innovations in food packaging systems have become essential in the food industry. Most widely used packaging materials are non-biodegradable plastics and are harmful to environment and human health. Thus, food industry is replacing non-biodegradable plastics with biodegradable plastics to reduce environmental pollution, health hazards, and food waste. Edible packaging may reduce food waste and keep perishables fresh. This review article compares edible packaging materials to synthetic ones and discusses their pollution-reducing effects. The several types of food packaging discussed in the review include those produced from polysaccharides, proteins, lipids, and composite films. The various characteristics of edible packaging are reviewed, including its barrier qualities, carrier properties, mechanical capabilities, and edibility. The carrier properties describe the capacity to transport and manage the release of active substances, and the edibility indicates acceptance of these items by the customers. Plasticizers, antimicrobials, antioxidants, and emulsifiers were included in the edible packaging to enhance the characteristics of the film. The development and implementation of edible packaging on food products from the laboratory to large-scale industrial levels, as well as their potential industrial applications in the dairy, meat, confectionary, poultry, fish, fruit, and vegetable processing sectors are addressed.

A tear-free and edible dehydrated vegetables packaging film with enhanced mechanical and barrier properties from soluble soybean polysaccharide blending carboxylated nanocellulose

The aim of the study was to develop soybean polysaccharide (SSPS) -carboxylated nanocellulose (CNC) blending films with enhanced mechanical and barrier properties to be used as a tear-free and edible packaging materials. The films were formed by casting method, with CNC as the strengthening unit and glycerol as the plasticizer. The effect of CNC on structural and physical performances of the SSPS-CNC films were studied. SEM indicated that the film will stratify with excess CNC (10 %), but the film remains intact and compact. Incorporation of CNC into SSPS films did not change peak position in the XRD pattern significantly. Hydrogen bonds among SSPS, glycerol and CNC were indicated by the FTIR spectra. The compounding of CNC greatly lessened the light transmittance and hydrophilicity (CA increased from 55.42° to 70.67°), but perfected the barrier (WVP decreased from 3.595 × 10−10 to 2.593 × 10−10 g m−1 s−1 Pa−1) and mechanical properties (TS improved from 0.806 to 1.317 MPa). The results of packaging dehydrated vegetable indicated that the SSPS-8CNC film can effectively inhibit the packaged cabbage absorption water vapor. As a consequence, SSPS film perfected by CNC is hopeful to pack dehydrated vegetables in instant foods.

Physicomechanical Properties of Edible Film-based Nata de Coco, Acetic Acid, and Chitosan

In recent years, edible films are on the rise as they have a wide variety of advantages, including the use of edible packaging materials over synthetic films. Edible films are environmentally friendly and do not cause environmental pollution. Several researchers have conducted studies on materials for making edible wraps, one of which comes from cellulosic sources. One source of cellulose from food is nata de coco. In this research, edible films based on nata de coco and chitosan were made by mixing and molding methods. The results of the tensile strength test of samples with a variety of 20 mL acetic acid showed a value of 17.805 MPa. This value meets the bioplastic standard (10–100 MPa) and the Indonesian National Standard (SNI) for conventional plastic (24–302 MPa).
 Keywords: edible film, nata de coco, chitosan, physicomechanical properties

Cradle-to-gate life cycle assessment of Spirulina bioplastic produced via plasticization with glycerol

Bioplastics have been used as alternatives to conventional petroleum-based plastics to lessen the burdens on marine and terrestrial environments due to their non-biodegradability and toxicity. However, recent studies have shown that not all bioplastics may be environmentally friendly. Microalgae, such as Spirulina that do not require arable land, have been identified as a potential bioplastic source. In this study, cradle-to-gate life cycle assessment (LCA) was carried out in openLCA program using the Agribalyse database, to evaluate the environmental impacts of Spirulina bioplastic, formed from plasticization of Spirulina powder with glycerol. Two processes were created for the inventories of (i) Spirulina powder and (ii) Spirulina bioplastic, where the output of the former served as an input for the latter. The extruded bioplastic sheets were food-grade and could be used as edible packaging materials. The bioplastic was also compared to conventional plastics and it was found that the energy consumption was 3.83 ± 0.26 MJ/kg-bioplastic, which was 12% and 22% higher than that of LDPE and PVC plastic films, respectively. The impacts on the environment showed that the chemical growth medium (Zarrouk medium) and electricity were the main contributors in most of the categories. Compared to the PVC and LDPE films, the Spirulina bioplastic's impacts on the aquatic ecosystems were 2–3 times higher. The global warming potential of the Spirulina bioplastic was 1.99 ± 0.014 kg CO2 eq, which was 23% and 47% lower than that of LDPE and PVC films, respectively. Sensitivity analysis was carried out by changing the electricity source and using alternative growth media. Except for the case of switching to solar energy, the results for other cases did not differ significantly from the base case scenario. Future studies were suggested to identify different greener alternatives to the growth medium as well as different energy mixes for more environmentally benign solutions.

Sheep's Second Cheese Whey Edible Coatings with Oregano and Clary Sage Essential Oils Used as Sustainable Packaging Material in Cheese.

Sheep's second cheese whey (SCW), the by-product resulting from whey cheese production, was used as a component of cheese coatings containing oregano (Origanum compactum) and clary sage (Salvia sclarea) essential oils (EOs). SCW powder was obtained by the ultrafiltration/diafiltration of SCW followed by reverse osmosis and freeze drying. The coatings were produced with a mixture of SCW and whey protein isolate (WPI) using glycerol as plasticizer. Model cheeses were produced with cow´s milk and those containing SCW:WPI coatings; those with and without EOs were compared to controls without coating and with a commercial coating containing natamycin. At the end of ripening (28 days), the cheeses containing EOs presented higher water activity (ca. 0.930) and moisture content, as well as lower titratable acidity. Concerning color parameters, significant differences were also observed between products and as a result of ripening time. However, the use of SCW:WPI coatings did not significantly influence the color parameters at the end of ripening. Regarding texture parameters, the cheeses containing SCW:WPI coatings presented significantly lower values for hardness, chewiness, and gumminess. Significant differences were also observed for all microbial groups evaluated either between products and as a result of ripening time. In all cases, lactobacilli and lactococci counts surpassed log 7-8 CFU/g, while the counts of yeasts and molds increased steadily from ca. log 3 to log 6 CFU/g. The lowest counts of yeasts and molds were observed in the samples containing natamycin, but nonsignificant differences between products were observed. In conclusion, SCW:WPI cheese coatings can successfully substitute commercial coatings with the advantage of being edible packaging materials manufactured with by-products.

Potential of Pinhão husk (Araucaria angustifolia) as a structural reinforcement agent in the properties of edible films of Pinhão flour and gelatin

AbstractIn this study, the use of Pinhão husk as a source of reinforcement material for development of edible films, where the Pinhão seed flour and bovine gelatin were used as matrices for the films. Mechanical properties, water vapor permeability, solubility and opacity, microstructure, and thermal degradation characterized the films produced. The films presented homogeneous and cohesive structures. Pinhão husk content positively affected film properties by increasing tensile strength (TS) and decreasing water vapor permeability (WVP), with Pinhão flour film formulations (5.0% Pinhão flour, 1.2% glycerol, and 0.4% Pinhão husk) and gelatin (5.0% gelatin, 2.0% glycerol, and 0.4% Pinhão husk) those that presented the best results (5.06 MPa for TS and 0.14 g.mm/kPa.h.m2 for WVP) and (3.88 MPa for TS and 0.28 g.mm/kPa.h.m2 for WVP), respectively The thermal degradation study revealed that the films are stable at temperatures below 150°C, losing only free water and volatile compounds of low molecular weight. Pinhão husk can reinforce films, making them suitable as biodegradable and edible packaging materials for eco‐friendly food products. This contributes to the circular economy, preserves biodiversity, and reduces plastic waste, offering promising sustainable packaging solutions.

Nanocellulose Composite Films in Food Packaging Materials: A Review.

Owing to the environmental pollution caused by petroleum-based packaging materials, there is an imminent need to develop novel food packaging materials. Nanocellulose, which is a one-dimensional structure, has excellent physical and chemical properties, such as renewability, degradability, sound mechanical properties, and good biocompatibility, indicating promising applications in modern industry, particularly in food packaging. This article introduces nanocellulose, followed by its extraction methods and the preparation of relevant composite films. Meanwhile, the performances of nanocellulose composite films in improving the mechanical, barrier (oxygen, water vapor, ultraviolet) and thermal properties of food packaging materials and the development of biodegradable or edible packaging materials in the food industry are elaborated. In addition, the excellent performances of nanocellulose composites for the packaging and preservation of various food categories are outlined. This study provides a theoretical framework for the development and utilization of nanocellulose composite films in the food packaging industry.

Development of functional, sustainable pullulan-sodium alginate-based films by incorporating essential oil microemulsion for chilled pork preservation

Developing safe, eco-friendly, and functionally edible packaging materials has attracted global attention. Essential oils, can be incorporated into packaging materials as antioxidant and antibacterial agents. However, their high volatility and discontinuous film matrix issues may cause a rough film surface, limiting the application in food packaging. In this study, thyme essential oil microemulsion (TEO-M) was prepared and incorporated into a pullulan-sodium alginate (PS) film. The TEO-M incorporation endowed the PS film with antioxidant and UV protection properties. The antioxidant activities of the TEO-M-incorporated PS film were significantly better than those of the TEO-C (thyme essential oil coarse emulsion)-incorporated PS film. In comparison to TEO-C, the distribution of TEO-M in the film is more uniform. Lipid oxidation and the growth of microorganisms in chilled pork were inhibited by incorporating TEO-M at a concentration of 50 mg/mL in the PS film (PS-50M). After 10 days of storage at 4 °C, the total viable count (TVC) of chilled pork preserved in the PS-50M material was significantly reduced compared to the control group (P < 0.05). This study shows that incorporating TEO-M in the PS film provides a method for applying essential oils in food packaging, which may have great potential in the food industry.

A Novel Approach about Edible Packaging Materials Based on Oilcakes-A Review.

Due to the growing global population and subsequent environment degradation, as well as changes in the climate, changing consumers' dietary habits is necessary to create strategies for the most efficient use of natural resources to eliminate waste in the food supply chain. The packaging of food is essential to preserve the food's properties, extend its shelf life and offer nutritional information. Food products are packaged in various materials of which the most used are plastics, but they have a negative impact on the environment. Various efforts have been made to address this situation, but unfortunately, this includes recycling rather than replacing them with sustainable solutions. There is a trend toward edible packaging materials with more additional functions (antioxidant, antimicrobial and nutritional properties). Edible packaging is also a sustainable solution to avoid food waste and environment pollution. Oilcakes are the principal by-products obtained from the oil extraction process. These by-products are currently underused as animal feed, landfilling or compost. Because they contain large amounts of valuable compounds and are low-cost ingredients, they can be used to produce materials suitable for food packaging. This review covers the recent developments in oilcake-based packaging materials. Special emphasis is placed on the study of materials and technologies that can be used to make edible film in order to research the most suitable ways of developing oilcake-based film that can be consumed simultaneously with the product. These types of materials do not exist on the market.

Dietary fiber extraction from citrus peel pomace: Yield optimization and evaluation of its functionality, rheological behavior, and microstructure properties.

Citrus fruits were widely used in processing and production, generating a large amount of peel pomace and a low utilization rate, resulting in substantial economic losses and environmental risks. It was important to extract compounds from citrus peel pomaces and find suitable preparation methods to improve their yield and physicochemical properties. Grapefruit peel pomace (GP) and navel orange peel pomace (OP) were used as raw materials in this study to prepare green and edible soluble dietary fiber (SDF) and insoluble dietary fiber (IDF). Analysis was done on the effects of solid-liquid ratio, cellulase hydrolysis time, cellulase dosage, and ultrasonic time on dietary fiber (DF) yield. To obtain the best DF preparation conditions, we used range analysis, variance analysis, and orthogonal experimental design. We also analyzed the structural, physicochemical, and rheological characteristics of SDF and IDF. According to the study's findings, SDF and IDF showed a loose and expansive structure with reduced particle size, higher specific surface area, and noticeably better physical and chemical properties after treating GP and OP with ultrasound-assisted composite enzyme method. Both SDF solution and IDF suspension were discovered through rheological analysis to be non-Newtonian pseudoplastic fluids, which was advantageous for expanding their applications in the field of food packaging. In conclusion, DF prepared using the ultrasound-assisted composite enzyme method was an excellent source of edible packaging materials, offering a benchmark for the recycling of other citrus peel wastes and ultimately paving the way for new methods of recycling citrus waste.

Edible Packaging: A Technological Update for the Sustainable Future of the Food Industry

This review aims to address the current data on edible packaging systems used in food production. The growing global population, changes in the climate and dietary patterns, and the increasing need for environmental protection, have created an increasing demand for waste-free food production. The need for durable and sustainable packaging materials has become significant in order to avoid food waste and environmental pollution. Edible packaging has emerged as a promising solution to extend the shelf life of food products and reduce dependence on petroleum-based resources. This review analyzes the history, production methods, barrier properties, types, and additives of edible packaging systems. The review highlights the advantages and importance of edible packaging materials and describes how they can improve sustainability measures. The market value of edible packaging materials is expanding. Further research on and developments in edible food packaging materials are needed to increase sustainable, eco-friendly packaging practices that are significant for environmental protection and food safety.

Physicochemical and preservative properties of tyrosinase-crosslinked sodium caseinate-EGCG-carboxymethyl chitosan composite packaging: Comparison of blended and layer-by-layer films

Bio-based packaging materials reduce the interactions of foods with their environment, which improves their quality, safety, and shelf life. Simple blending and layer-by-layer (LBL) deposition methods are commonly used film preparation methods. However, it is not clear which method has a better preservation effect. In this study, differences in the structures and properties of tyrosinase-crosslinked sodium caseinate (SC)-epigallocatechin gallate (EGCG)-carboxymethyl chitosan (CMC) composite packaging materials (coatings and films) prepared by these two methods were compared. Fruit preservation experiments were carried out by applying blend or LBL coatings to banana or strawberry. The structural properties of films prepared by the blend and LBL methods were analyzed to provide insights into their different performances. The adsorption of the coating solution onto the fruit surfaces, as well as the microstructure and properties of the coatings formed, were the main factors affecting fruit preservation. Strawberry or banana coated by blend coatings exhibited a good appearance after 7 or 14 days. Overall, the water vapor barrier properties of the blend films were better than those of the LBL films. Moreover, the mechanical and EGCG-release properties of the blend films were also good. In summary, the properties of the coatings/films prepared by the blending and LBL methods were compared. This study helps to facilitate the rational design of edible packaging materials for different applications.

Green Chitosan‐Flaxseed Gum Film Loaded with ZnO for Packaging Applications

AbstractThe possibility of manufacturing edible packaging materials with tailored properties and low cost has attracted much interest. This work presents a new material for edible packaging made from flaxseed gum (FSG) and chitosan (Ch) loaded with zinc oxide nanoparticles (ZnO‐NPs). ZnO‐NPs are synthesized in situ during the preparation of the edible film. The Ch/FSG/ZnO‐NPs films are prepared by casting Ch in different ratios of FSG (12.5%, 25%, 37.5%, and 50%). The resulting films are evaluated for their physicochemical, mechanical, and barrier properties to determine their suitability for coating or packaging food or bioproducts. By studying the antimicrobial activities of the ZnO‐NPs loaded films, we can see that ZnO‐NP's concentration highly affects these activities. In addition, the FSG improves mechanical properties. Films developed by incorporating ZnO‐NPs are proposed to be appropriate for low‐moisture food and pharmaceutical products, which can reduce environmental problems associated with synthetic packaging. Consequently, Ch/FSG composite films have the potential to replace conventional packaging.

Comprehensive Enzymatic Conversion of Starch for the Food Industry.

This study demonstrated the feasibility of comprehensive enzymatic conversion of starch for non-waste applications in food industry. Enzymatic conversion of starch gives rise to nano-sized particles that can be used for manufacturing biodegradable and edible packaging materials and glucose syrup for replacing sugar in confectionery formulations. The 96 h enzymatic hydrolysis yielded starch nanoparticles smaller than 100 nm. Films based on nano-sized starch particles have promising physicochemical properties for manufacturing biodegradable and edible packaging materials. Such properties as reduced moisture content, increased homogeneity, crystallinity, and high initial thermal stability improve the mechanical and performance characteristics of the final food packaging materials. During film formation from starch subjected to preliminary mechanical amorphization, the polymer chain is recrystallized. The C-type crystal structure of starch is converted to the B-type structure. The supernatant obtained by starch hydrolysis can be used for producing glucose syrup. The resulting glucose syrup can be used as a sugar substitute in production of confectionery products. No objective technological differences in properties of glucose syrup obtained by comprehensive conversion of starch and the commercially available glucose syrup derived from sucrose were revealed.