Ecological Risk Of Heavy Metals Research Articles

Quantitative assessment of ecological risk from pollution source based on geostatistical analysis and APCS-MLR model.

The safety of human health and agricultural production depends on the quality of farmland soil. Risk assessment of heavy metal pollution sources could effectively reduce the hazard of soil pollution from various sources. This study has identified and quantitatively analyzed pollution sources with geostatistical analysis and the APCS-MLR model. The potential ecological risk index was combined with the APCS-MLR model which has quantitatively calculated the source contribution. The results revealed that As, Cr, Cd, Pb, Zn, and Cu were enriched in soil. Geostatistical analysis and the APCS-MLR model have apportioned four pollution sources. The Mn and Ni were attributed to natural sources; As and Cr were from agricultural activities; Cu and Zn were originated from natural sources; Cd and Pb were derived from atmospheric deposition. Atmospheric deposition and agricultural activities were the largest contributors to ecological risk of heavy metals in soil, which accounted for 56.21% and 36.01% respectively. Atmospheric deposition and agricultural activities are classified as priority sources of pollution. The combination of source analysis receptor model and risk assessment is an effective method to quantify source contribution. This study has quantified the ecological risks of soil heavy metals from different sources, which will provide a reliable method for the identification of primary harmfulness sources of pollution for future studies.

Carcinogenic and non-carcinogenic health risks associated with the consumption of fishes contaminated with heavy metals from Manzala Lake, Egypt

Manzala Lake was sampled to assess the concentrations and possible ecological risks of heavy metals. The mean heavy metal levels in the muscles of Nile tilapia, Flathead grey mullets and African catfish were 0.01, 0.15 and 0.29 mg/kg, respectively, for mercury; 3.16, 4.25 and 4.74 mg/kg for arsenic; 1.01, 0.87 and 0.95 mg/kg for lead; and 0.05, 0.12 and 0.06 mg/kg for cadmium. The levels of heavy metals exceeded their maximum permissible limits in most samples. The EDIs of some metals were higher than their PTDIs or BMDLs. The THQs and TTHQs from metal intake were >1 for Hg and Cd. In addition, the TCR values of As in all fish species were higher than 1.0 × 10−4 indicating a potential health risks from consumption of fish species which need strict hygienic procedures to prevent fish contamination with heavy metals and ensure that their levels did not exceed the maximum permissible limits.

Heavy Metal Pollution Status and Potential Ecological Risk Assessment in Farmland Surface Soil Along River in Jiaozuo Area

A total of 41 surface soil samples were collected from the farmlands along Guangliji River and Jianggou River in Jiaozuo area, and 7 heavy metals such As Cr, Cu, Zn, AS, Cd, Pb and Ni were determined by ICP-MS (Varian-820).The soil accumulation index method, single factor pollution index method, Nemerow comprehensive pollution index method and potential ecological risk index method were used to evaluate the pollution status and potential ecological risk of heavy metals in the study area. The results showed that compared with the risk screening value (pH>7.5) given in the "Soil Quality Standard for Soil Pollution Risk Control of Agricultural Land" (GB15618-2018), Cd in farmland soil along the two rivers exceeded the screening value by 5.7 times and 1.5 times, respectively, and was the main local pollutant. The Nemero comprehensive pollution index of the farmland along Guangliji River and Jianggou River was 9.71 and 1.88, respectively, which were in the level of heavy pollution and light pollution. The comprehensive potential ecological risk index of farmland along the two rivers is 417.65 and 85.79, with strong ecological risk and slight ecological risk respectively. The comprehensive evaluation shows that there is a certain degree of heavy metal pollution in the farmland soil along the river in Jiaozuo area, especially Cd pollution, and the ecological risk in some areas has exceeded the acceptable level, which should arouse the attention of the local government and relevant departments.

Status and risk assessment of heavy metal pollution in farmland soil in the southern suburbs of Jiaozuo City

A farmland in the southern suburb of Jiaozuo City was selected As the research area, 36 surface soil samples were collected, and the contents of heavy metals (Cd, Cr, Zn, Ni, Cu, Pb and As) in soil were determined. The ecological risk of heavy metals in soil was assessed by single factor pollution index method, Nemerow comprehensive pollution index method and potential ecological risk index method. The results showed that the average contents of Cd, Cr, Zn, Ni, Cu, Pb and As in the soil were 1.25, 62.96, 79.00, 28.91, 22.60, 11.02 and 42.25mg/kg, respectively. Cd and As in soil exceeded the standard, and the exceedance rate was 92.75% and 83.5%. The single factor pollution index was Cd>As>Cr>Zn>Cu>Ni>Pb from large to small, and Cd reached the moderate pollution level. The results of Nemerow comprehensive pollution index showed that Cd reached the level of severe pollution, and As was the level of severe pollution. The evaluation results of potential ecological risk index showed that Cd was at the moderate risk level, As was at the slight risk level, and other heavy metals were at the slight risk level. The comprehensive potential ecological risk index RI value was 13.87-266.80, which was at the slight to moderate risk level. Cd and As were the main risk sources of soil heavy metals, and their contribution rates to the comprehensive potential ecological risk index were 79% and 18%, respectively.

Long-term and combined heavy-metal contamination forms a unique microbiome and resistome: A case study in a Yellow River tributary sediments

Microorganisms have developed mechanisms to adapt to environmental stress, but how microbial communities adapt to long-term and combined heavy-metal contamination under natural environmental conditions remains unclear. Specifically, this study analyzed the characteristics of heavy metal composition, microbial community, and heavy metal resistance genes (MRGs) in sediments along Mang River, a tributary of the Yellow River, which has been heavily polluted by industrial production for more than 40 years. The results showed that the concentrations of Cr, Zn, Pb, Cu and As in most sediments were higher than the ambient background values. Bringing the heavy metals speciation and concentration into the risk evaluation method, two-thirds of the sediment samples were at or above the moderate risk level, and the ecological risk of combined heavy metals in the sediments decreased along the river stream. The high ecological risk of heavy metals affected the microbial community structure, metabolic pathways and MRG distribution. The formation of a HM-resistant microbiome possibly occurred through the spread of insertion sequences (ISs) carrying multiple MRGs, the types of ISs carrying MRGs outnumber those of plasmids, and the quantity of MRGs on ISs is also higher than that on plasmids. These findings could improve our understanding of the adaptation mechanism of microbial communities to long-term combined heavy metal contamination.

Health and ecological risk of heavy metals in agricultural soils related to Tungsten mining in Southern Jiangxi Province, China.

Dayu County, a major tungsten producer in China, experiences severe heavy metal pollution. This study evaluated the pollution status, the accumulation characteristics in paddy rice, and the potential ecological risks of heavy metals in agricutural soils near tungsten mining areas of Dayu County. Furthermore, the impacts of soil properties on the accumulation of heavy metals in soil were explored. The geo-accumulation index (Igeo), the contamination factor (CF), and the pollution load index (PLI) were used to evaluate the pollution status of metals (As, Cd, Cu, Cr, Pb, Mo, W, and Zn) in soils. The ecological risk factor (RI) was used to assess the potential ecological risks of heavy metals in soil. The health risks and accumulation of heavy metals in paddy rice were evaluated using the health risk index and the translocation factor (TF), respectively. Pearson's correlation coefficient was used to discuss the influence of soil factors on heavy metal contents in soil. The concentrations of metals exceeded the respective average background values for soils (As: 10.4, Cd: 0.10, Cu: 20.8, Cr: 48.0, Pb: 32.1, Mo: 0.30, W: 4.93, Zn: 69.0, mg/kg). The levels of As, Cd, Mo, and tungsten(W) exceeded the risk screening values for Chinese agricultural soil contamination and the Dutch standard. The mean concentrations of the eight tested heavy metals followed the order FJ-S > QL > FJ-N > HL > CJ-E > CJ-W, with a significant distribution throughout the Zhangjiang River basin. Heavy metals, especially Cd, were enriched in paddy rice. The Igeo and CF assessment indicated that the soil was moderately to heavily polluted by Mo, W and Cd, and the PLI assessment indicated the the sites of FJ-S and QL were extremely severely polluted due to the contribution of Cd, Mo and W. The RI results indicated that Cd posed the highest risk near tungsten mining areas. The non-carcinogenic and total carcinogenic risks were above the threshold values (non-carcinogenic risk by HQ > 1, carcinogenic risks by CR > 1 × 10-4 a-1) for As and Cd. Correlation analysis indicated that K2O, Na2O, and CaO are main factors affecting the accumulation and migration of heavy metals in soils and plants. Our findings reveal significant contamination of soils and crops with heavy metals, especially Cd, Mo, and W, near mining areas, highlighting serious health risks. This emphasizes the need for immediate remedial actions and the implementation of stringent environmental policies to safeguard health and the environment.

Ecological risk assessment of heavy metals in desulfurized seawater discharged from a coal-fired power plant in Qingdao.

Despite the prevalence of discharge of large volumes of heavy-metal-bearing seawater from coal-fired power plants into adjacent seas, studies on the associated ecological risks remain limited. This study continuously monitored concentrations of seven heavy metals (i.e. As, Cd, Cr, Cu, Hg, Pb, and Zn) in surface seawater near the outfall of a coal-fired power plant in Qingdao, China over three years. The results showed average concentrations of As, Cd, Cr, Cu, Hg, Pb, and Zn of 2.63, 0.33, 2.97, 4.63, 0.008, 0.85, and 25.00 μg/L, respectively. Given the lack of data on metal toxicity to local species, this study investigated species composition and biomass near discharge outfalls and constructed species sensitivity distribution (SSD) curves with biological flora characteristics. Hazardous concentrations for 5% of species (HC5) for As, Cd, Cr, Cu, Hg, Pb, and Zn derived from SSDs constructed from chronic toxicity data for native species were 3.23, 2.22, 0.06, 2.83, 0.66, 4.70, and 11.07 μg/L, respectively. This study further assessed ecological risk of heavy metals by applying the Hazard Quotient (HQ) and Joint Probability Curve (JPC) based on long-term heavy metal exposure data and chronic toxicity data for local species. The results revealed acceptable levels of ecological risk for As, Cd, Hg, and Pb, but unacceptable levels for Cr, Cu, and Zn. The order of studied heavy metals in terms of ecological risk was Cr > Cu ≈ Zn > As > Cd ≈ Pb > Hg. The results of this study can guide the assessment of ecological risk at heavy metal contaminated sites characterized by relatively low heavy metal concentrations and high discharge volumes, such as receiving waters of coal-fired power plant effluents.

Assessment of the accumulation level and ecological risk of heavy metals in surface sediments of Bong Mieu River, Quang Nam Province, Vietnam.

This study assessed the accumulation levels and ecological risks associated with seven heavy metals (As, Pb, Cd, Hg, Cu, Cr, Zn) in the surface sediments of the Bong Mieu River in Quang Nam Province, Vietnam. The sampling encompassed 10 locations (S1-S10), considering areas both impacted and less impacted by gold mining activities. The findings revealed elevated levels of heavy metal pollution and associated ecological risks attributable to gold mining. Heavy metal content varied within specific ranges: As (70.6-341.2 mg/kg), Pb (216.3-504.1 mg/kg), Hg (0.138-0.252 mg/kg), Cd (0.91-1.51mg/kg), Cu (18.3-45.5 mg/kg), Cr (10.5-19.1 mg/kg), and Zn (49.3-84.1 mg/kg). Among these elements, Hg, Cu, Cr, Zn, and Cd adhered to the acceptable limits of VNTR 43:2017/MONRE (VNTR 43:2017/MONRE: National Technical Regulation/Ministry of Natural Resources and Environment of Vietnam). However, As and Pb content at all locations exceeded these limits significantly, with As being 4.1-20 times higher and Pb 2.3-5.5 times higher. The pollution of Pb and As was attributed to waste discharge from gold mining activities, which carry substantial amounts of these metals in various forms. The Igeo indicated heavy pollution of As and Pb in the sediments. Ecological risk factors were ranked as follows: (As) > (Pb) > (Hg) > (Cd) > (Cu) > (Cr) > (Zn). The potential ecological risk (RI) due to combined heavy metal impact varied across locations, with S2 > S8 > S9 > S6 > S7 > S10 > S1 > S3 > S4 > S5, exhibiting low to moderate risk (RI values ranging from 73.4 to 252.8). The study area demonstrated high contamination levels for As and Pb, coupled with low to moderate potential ecological risks.

Source Distribution and Ecological Risk Assessments of Heavy Metals from the Soils of Riruwai Mining Area, North-Western Nigeria

Mining is an important global economic driver, contributing to human civilization’s advancement and foreign exchange revenues. However, it causes significant environmental contamination, particularly in developing nations with inadequate waste management and ineffective mining legislation. In the present study, the source distribution and ecological risk of heavy metals (HMs) from the soils of the mining area around Riruwai town, northern Nigeria, were assessed. Soil samples were obtained from active and abandoned mining sites, farmlands, and control sites and were analyzed for physicochemical characteristics and HM contents. The measured concentrations of HMs were used to evaluate the source distribution and ecological risks. The study’s findings indicated that, with the exception of Mn, Hg, and Ni, all HM concentrations were above threshold levels in all sample locations aside from the control sites. The results of the correlation analysis showed that there was a significant correlation between the HMs, indicating that they came from comparable origins. Principal component analysis and hierarchical cluster analysis results indicated that As, Cr, Hg, Ni, and Zn might originate from similar anthropogenic sources, possibly mining activities, while Cd, Mn, and Pb might come from natural sources (parent material). Results of an ecological risk assessment revealed that the soils from active and abandoned mining sites were severely polluted by HMs. The degree of pollution has begun to extend onto farmland, signifying a critical need for adequate HM pollution control in the study area.

Ecological risk assessment of heavy metals in tea plantation soil around Tai Lake region in Suzhou, China

Tea plant [Camellia sinensis (L.) O. Kuntze] is one of the important foliar cash crops in China, and its root system absorbs heavy metal (HM) elements enriched in the soil and transports them to the over ground part. In order to ensure the safety of the soil ecological environment and tea raw materials in the tea production area, the HM contents of soil and tea plant leaves in Suzhou tea plantations were detected, the relationship between HMs and soil physicochemical properties was analyzed, and the ecological risk of HMs in tea plantation soils was evaluated by using relevant detection techniques and evaluation models. The results showed that the average pH of tea plantation soils around Tai Lake in Suzhou was within the range suitable for the growth of tea plants. The pH, soil organic matter, total nitrogen, available phosphorus and available potassium of tea plantation soil satisfying the requirements of high quality, high efficiency and high yield (‘3H’) tea plantation accounted for 47.06%, 26.47%, 8.82%, 79.41% and 67.65%, respectively. Site 2 fully met the requirements of ‘3H’ tea plantation. In addition, the contents of cadmium (Cd) and mercury (Hg) were extremely variable, and the average contents exceeded the background value of soil in Jiangsu Province, but the HM contents of tea leaves all met the pollution-free standard, and the HM contents of tea leaves around Tai Lake in Suzhou were generally at a safe level. The composite ecological risk index ranged from 0.05 to 0.60, and 32 of the 34 sample sites (except site 21 and site 23) are the most suitable agricultural land for tea plantations.

Distribution, Source, and Ecological Risk of Heavy Metals in Sewage Irrigation of Taiyuan, Shanxi Province, China.

The pollution of agricultural soil by heavy metals is a significant environmental issue that has a serious impact on human health and food security. This study focused on investigating the presence of heavy metal pollution in sewage-irrigated soils in Taiyuan city. A total of 110 soil samples were analyzed for the presence of As, Hg, Cd, Pb, Cr, Cu and Zn. The results showed that the concentrations of these metals ranged from 0.06 to 26.74 mg/kg for As, 0.00 to 0.84 mg/kg for Hg, 0.03 to 0.69 mg/kg for Cd, 44.32 to 100.09 mg/kg for Pb, 9.85 to 42.19 mg/kg for Cr, 13.38 to 53.72 mg/kg for Cu, and 42.77 to 145.47 mg/kg for Zn. The average concentrations of these metals were found to be below the risk values specified in the "Soil environmental quality (GB15618-2018)", except for As and Cd in three sampling points in Xiaodian District. The heavy metal pollution in these areas can be attributed to various sources, such as industrial activities, the use of fertilizers and pesticides, and the irrigation process. According to the geo-accumulation index, the agricultural soil in the Taiyuan irrigation area was found to be uncontaminated by Zn, Cr, Cu, and As, and lightly contaminated by Cd, Hg, and Pb. The Nemerow Pollution Index indicated that the soil at all sampling points exhibited a slight level of pollution. Moreover, the ecological risk assessment indicated that all heavy metals posed a slight level of pollution. The findings of this study provide a scientific basis for the development of effective policies and measures for soil environmental protection and pollution control.

Potential ecological risk from heavy metals in surface sediment of lotic systems in central region Peru

High Andean rivers are fragile ecosystems in the face of various threats, including heavy metal contamination. The objective of this study was to evaluate the potential ecological risk of heavy metals in surface sediment of lotic systems in the central region of Peru. Composite samples of surface sediments were collected from the Chía and Miraflores rivers and the concentrations of heavy metals were determined. The ecological risk analysis was carried out based on the contamination indexes and confirmed by the modified degree of contamination (mCd). The concentration of heavy metals in the sediment of the Chía river was in the following descending order: Fe > Mn > Zn > V > Pb > Cr > Ni > Cu > Mo > Hg, y en el río Miraflores fue: Fe > Mn > Zn > Ni > V > Cr > Cu > Pb > Hg > Mo. The mean concentration of Cu, Cr, Fe, Mn, Mo, Ni, Pb, and V in the sediment samples in both rivers did not exceed the threshold values of the continental crust concentration, nor the interim sediment quality guidelines of the Canadian Council of Ministers of the Environment. However, the mean concentration of Hg exceeded the guideline values in the Miraflores river and the likely effect (0.7 mg.kg−1) adverse effects. The values of the enrichment factor (EF), contamination factor (CF), geoaccumulation index (Igeo), and pollution load index (PLI) indicated low contamination in the sediments of the rivers studied, being confirmed by the modified degree of contamination (mCd). Finally, the risk assessment showed that heavy metals in the sediments presented a low potential ecological risk.

Enhanced vermicomposting of rice straw and pressmud with biogas slurry employing Eisenia fetida: Production, characterization, growth, and toxicological risk assessment

The biogas plant plays a dual role: it directly provides energy and indirectly promotes organic farming through outlet slurry. However, agricultural biomass wastes such as rice straws (RS) and pressmud (PM), which can't be used as fertilizers on their own, were vermicomposted (60 days) with biogas slurry (BS), using earthworm, into four blends: T1(BS, 100%), T2(3:2, BS: RS), T3(3:2, BS: PM), and T4(3:1:1, BS: RS: PM). The characterization, elemental analysis, and toxicological risk assessment of derived vermimanure were carried out using various analytical tools, such as an organic elemental analyzer such as CHNS, FT-IR, FESEM-EDXA, XPS, and ICP-OES. The pH, electrical conductivity, and C/N values were within 7.1–7.8, 3.2–6.0 dSm−1, and 12–15, respectively, for all treatments. The proportions of N (38%), P (70%), K (58%), Mg (67%), Ca (42%), and ash (44%), increased significantly (P < 0.05) over the initial feedstocks. The ecological risks of heavy metals (Zn, Cu, Ni, Pb, Cd, and Cr) in all feedstocks were found to be under WHO-permitted levels. The growth performance of earthworms was also considerably higher (P < 0.05) over the control feedstock group. The analytical methods verified that feedstock T4 (3:1:1, BS: RS: PM) was more porous, containing NH4+, PO43−, K+, and other nutrients. Pellets of all vermimanure groups keep 65–75% of the original volume. As well, when these pellets have been employed for agronomy and dispersed in the field, they will cause less dust than traditional or powdered compost or manure. In comparison to the control group, the synergistic approach of RS, PM, and BS in vermimanure significantly (P < 0.05) enhanced seed germination (83%), vigour index (42.5%), and decreased mean germination time by 27%. Furthermore, pot trials with Abelmoschus esculentus seed indicated that seedlings cultivated with 40% vermimanure of T4 (3:1:1, BS: RS: PM) mixed soil showed high growth in shoot, root, and plant yield.

Assessment of contamination and potential ecological risks of heavy metals in riverine sediments from gold mining and pristine areas in Ghana

This study explore the characteristics of heavy metal pollution, contamination levels, and potential ecological risks in riverine sediments found in both gold mining and pristine areas. Such investigations are vital for the ongoing monitoring and preservation of water bodies and overall ecosystem health. In total, 44 composite sediment samples were collected from seven pristine environments and four mining sites. These samples underwent preparation, digestion, and analysis for heavy metal content, utilizing the inductively coupled plasma emission mass spectrometer (ICP-MS). Various tools and models, including the geo-accumulation index, enrichment factor, and degree of contamination, were employed to assess the impact of pollution on the environment. Modified ecological risk index were also used to evaluate potential ecological risks. The average concentrations of heavy metals in pristine sites spanned from 0.01±0.01 (Cd) to 73,753.64 ± 388.15 mgkg−1 (Fe), while in mining sites, they ranged from 0.04±0.02 (Cd) to 56,394.25±400.66 mgkg−1 (Fe). Comparing these concentrations against the USEPA Ecological Screening Values, Mean Shales levels, and the Canadian ISQG, it became evident that Pb, Cd, Zn, Ni, Co, and Mn concentrations generally remained below the recommended guideline values in both pristine and mining areas. However, concentrations of Cr, As, Cu, and Hg exceeded the prescribed threshold limits, particularly in the mining regions. Through Principal Component Analysis (PCA) and Geometrical Analysis for Interactive Aid (GAIA) modeling, two primary sources of heavy metals were identified: anthropogenic-related and geogenic-related. GAIA and PCA together explained 78.53 % and 79.40 % of the total variability in heavy metal concentrations, respectively. Overall, the pollution and ecological risk assessment indicated low to moderate contamination levels, with a notable exception of high arsenic contamination in the Nyam river. The findings of this study hold significance for assessing sediment conditions and river quality in mining communities within Ghana and globally. They also provide empirical data to recommend measures for mitigating water contamination in such communities.

Health risk assessment of heavy metals in soils and crops in a mining area (Au-Ag-Cu-trona-oil et al.) of the Nanyang Basin, Henan Province, China

Heavy metal distribution in mining areas has always been a hot research topic due to the special environment of these areas. This study aims to explore the impact of heavy metal pollution on soils and crops in the study area, ensure the safety of local crops and the health of local residents, and provide a basis for the subsequent environmental restoration and the prevention and control of environmental pollution. Based on the analysis of the heavy metal concentrations in local soils and crops, the study investigated the spatial distribution, pollution degrees, and potential ecological risks of heavy metals in the farmland of a mining area in the southeastern Nanyang Basin, Henan province, China explored the sources of heavy metals and assessed the health risks caused by crop intake. The results of this study are as follows. The root soils of crops in the study area suffered heavy metal pollution to varying degrees. The degree of heavy metal pollution in maize fields is higher than that in wheat fields, and both types of fields suffer the most severe Cd pollution. Moreover, the root soils of different crops suffer compound pollution. The root soils in the maize fields suffer severe compound pollution at some sampling positions, whose distribution is similar to that of the mining area. Cd poses the highest potential ecological risks among all heavy metals, and the study area mainly suffers low and moderate comprehensive potential ecological risks. The principal component analysis (PCA) shows that the distribution of Zn, Cd, Pb, and As in soils of the study area is mainly affected by anthropogenic factors such as local mining activities; the distribution of Cr and Ni is primarily controlled by the local geological background; the distribution of Hg is mainly affected by local vehicle exhaust emissions, and the distribution of Cu is influenced by both human activities and the geological background. Different cereal crops in the study area are polluted with heavy metals dominated by Cd and Ni to varying degrees, especially wheat. As indicated by the health risk assessment results, the intake of maize in the study area does not pose significant human health risks; however, Cu has high risks to human health, and the compound heavy metal pollution caused by the intake of wheat in the study area poses risks to the health of both adults and children. Overall, the soils and crops in the study area suffer a high degree of heavy metal pollution, for which mining activities may be the main reason.©2023 China Geology Editorial Office.

Composition characteristics and metal binding behavior of macrophyte-derived DOM (MDOM) under microbial combined photodegradation: A state closer to actual macrophytic lakes

In actual lakes, the “unstable components” of macrophyte-derived DOM (MDOM) are always degraded and cannot exist abidingly, but the environmental impact brought by it is ignored. In this study, MDOM from Potamogeton crispus was extracted to carry out microbial combined photodegradation (M-Photodegradation) and fluorescence titration experiments. Then the traits and metal binding reaction of MDOM under M-Photodegradation were analysed and compared with the features of lake-derived DOM (LDOM) from point monitoring of Dongping Lake through EEM-PARAFAC, 2D-SF-COS, and 2D-FTIR-COS. The results showed that the features of MDOM after M-Photodegradation were closer to those of LDOM. The degradation amplitudes were 93.53% ± 0.53% for C4 in microbial degradation and 78.31% ± 0.74% for C3 in photodegradation. Correspondingly, both were hardly detected in LDOM. Protein-like substances and aliphatic C–OH were preferentially selected by Cu2+, while humic-like matter and phenolic hydroxyl O–H responded faster to Pb2+. Although the binding sequences remained unchanged after M-Photodegradation, the LogKCu and LogKPb of components decreased overall, indicating increased environmental risks. This study proves that the refractory MDOM retained after degradation was more consistent with the actual state of macrophytic lakes and provides more information for the treatment of heavy metal pollution in lakes.

Comprehensive assessment of occurrence, temporal-spatial variations, and ecological risks of heavy metals in Jiaozhou Bay, China: A comprehensive study

Heavy metals play a significant role in marine ecosystems, exerting notable impacts on the environment and human health. In this study, water, sediment, and aquatic organism samples from Jiaozhou Bay were investigated to comprehensively assess the distribution, temporal-spatial variations, and ecological risks of heavy metals. The results indicate that pollution from industrial wastewater discharge contributes to regional differences in the distribution of heavy metals, possibly being a major source of Zn, Cr, Cd, and Hg (r > 0.7, p < 0.05). Biological and physicochemical processes influence the distribution of Zn, Cr, and Pb in the water and sediment. Hg exhibits a polluted state in both the water and sediment, with As and Hg being the two highest-risk heavy metals in water and sediment, respectively. Among the organisms, crustaceans show significantly higher levels of heavy metal content and accumulation compared to mollusks and fish (p < 0.05), and the bioamplification of heavy metals occurs in the sediment-Rapana venosa-Portunus trituberculatus biological pathway. Portunus trituberculatus, Charybdis japonica, Oratosquilla oratoria, and Octopus ocellatus could pose risks to human health, especially for children and vulnerable populations. This study aims to enhance our understanding of the current status of heavy metal pollution in Jiaozhou Bay and to provide a scientific basis and favorable support for the ecological environmental protection and prevention of ecological risks associated with heavy metal pollution in Jiaozhou Bay and other bays in China.

Assessment of heavy metal content and ecological risk in offshore surface sediments of the Northern Persian Gulf: Implications for environmental management

Offshore surface sediment samples from fifty-five stations in the northern parts of the Persian Gulf and the Strait of Hormuz were examined to evaluate the content and ecological risk of heavy metals. The physicochemical characteristics of both surface water and deep water were measured using probes and CTD. To determine the source of pollution and assess the ecological risk, various indicators were used, including contamination factor (CF), contamination degree (CD), enrichment factor (EF), pollution load index (PLI), and risk index (RI). The average concentrations of heavy metals in sediment samples were Fe: 1.4 (0.2–2.7%), Cr: 72.9 (8−127), Ni: 59.8 (14−113), V: 43.4 (7−77), Zn: 35.7 (3−58), Cu: 17.5 (2−29), Pb: 12.1 (5−48), Co: 9.4 (1−17), As: 3.9 (1.7–7.2) ppm. Ni and Cr concentrations in almost all Persian Gulf stations especially in shallower parts were higher than their threshold effect level, while Pb, As, Zn, and Cu concentrations were below the threshold values in all stations. The results revealed that EF for all investigated metals in all stations was less than 1.5, which indicates that the studied region had low enrichment and the origin of the heavy metals is natural. However, human activities have contributed to Ni enrichment in the Jask and Bandar Abbas coasts. CD values varied between 11.7 and 14.6, exhibiting the range of moderate pollution to lowest possible pollution category. The PLI for all samples was in the range of 1.2–2.2, which demonstrates advanced pollution load. RI (=∑Eij) varied between 34 and 89, indicating a low ecological risk (IR<110).

Evaluating the Pollution Levels and Ecological Risks of Heavy Metals in Sediments of Apapa Port in Lagos, South-western Nigeria

Evaluating the Pollution Levels and Ecological Risks of Heavy Metals in Sediments of Apapa Port in Lagos, South-western Nigeria

Distribution of Heavy Metals in Surface Sediments of a Tropical Mangrove Wetlands in Hainan, China, and Their Biological Effectiveness

The distribution and ecological risk of heavy metals in sediments were studied through the systematic collection and analysis of mangrove wetland sediments in Dongzhai Harbor, Hainan. The main insights obtained were as follows: (1) The distribution characteristics and influencing factors of heavy metals in wetland sediments were analyzed by using the inverse-distance weight interpolation method. In terms of spatial distribution, the contents of heavy metals As, Ba, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Sr, Ti, and Zn in the western part of the wetland were significantly higher than in the eastern part. The contents of heavy metals Cd, Co, Cr, Cu, Hg, Mn, Ni, Zn, and Ti near the anthropogenic area were significantly higher than at other points. (2) The pollution sources and ecological risks of heavy metals in wetland sediments were explored by using correlation analysis, cluster analysis, and potential ecological risk index analysis. The results showed that As, Ba, Pb, and Sr mainly originated from natural processes; Co, Cr, Cu, Mn, Ni, Ti, and Zn mainly originated from industry; and agricultural heavy metals mainly originated from Cd and Hg. The ecological risk analysis showed that there were obvious ecological risks of heavy metals in the western and southeastern corners of the wetland, which were both located in the vicinity of land far away from the coastline and near the human activities, and featured mangrove forests with dense vegetation characteristics.