Exposures from plutonic roots to volcanic roofs in deeply eroded regions may disclose the architecture and igneous processes in ancient metamagmatic edifices, like it is the Early Tonian Salto da Divisa complex (SADICO) of Eastern Brazil. Field, petrographic, lithochemical and isotopic (in-zircon U-Pb and Lu-Hf, and whole-rock Sm-Nd) studies were conducted on the SADICO, a plutono-volcanic complex located in the northeast Araçuaí orogen. The SADICO magmatic record comprises (with U-Pb crystallization ages, and isotopic Hf and Nd data): i) pyroxenite (ε Nd(t) : +2.2 to −5.3; Nd T DM : 1.2–1.7 Ga); ii) mafic and intermediate dykes (ε Nd(t) :+2.1 to −5.9; Nd T DM : 1.2–1.8 Ga) and enclaves with OIB-like signature; ii) ferroan, A-type granitoid with mafic-felsic mingling-mixing features (885 ± 9 Ma; ε Hf(t) : −5 to −7, Hf T DM : 2.0–2.1 Ga; ε Nd(t) : −3.2 to −4.3, Nd T DM : 1.5–1.7 Ga); iii) fluorite-bearing, metaluminous to peraluminous, ferroan A-type granites, including biotite-amphibole granite (ca. 915 to 875 Ma; ε Nd(t) : −2.8 to −5.8, Nd T DM : 1.6–1.9 Ga), biotite granite (894 ± 10, ε Hf(t) : −4 to −11, Hf T DM : 1.9–2.3 Ga; ε Nd(t) : −1.6 to −8.0, Nd T DM : 1.4–2.2 Ga), and amazonite-bearing two-mica granite (ε Nd(t) : −4.0; Nd T DM : 1.7 Ga); iv) rhyolite (905 ± 24 Ma; ε Hf(t) : −1 to −8.7, Hf T DM : 1.8–2.2 Ga; ε Nd(t) : +3.1, Nd T DM : 1.1 Ga) and subvolcanic silica-undersaturated trachyte (912 ± 13 Ma, ε Hf(t) : −14 to −18, Hf T DM : 2.5–2.7 Ga; ε Nd(t) : +0.3, Nd T DM : 1.2 Ga), also with ferroan A-type signature. Our integrated petrogenetic model envisages mantle-derived magmas (ultramafic and mafic rocks) evolved by assimilation-fractional crystallization to felsic subvolcanic and volcanic rocks, interacting with granitic magmas produced by crustal anatexis (biotite-amphibole granite) and subsequently fractionated (biotite granite) and highly fractionated (two-mica granite) with the involvement of F-rich fluids up to subvolcanic levels. • Dissecting an Early Tonian, anorogenic, plutono-volcanic complex of Eastern Brazil. • Rift's igneous diversity: ultramafic to mafic rocks, granites, felsic volcanic rocks. • From plutonic root to volcanic roof of an ancient anorogenic igneous complex. • Field, lithochemical and isotopic data tracking rift-related igneous processes. • Integrated model for Early Tonian anorogenic igneous processes in the Araçuaí orogen.