Earth Elements In Surface Sediments Research Articles

Distribution, provenance, contamination, and probabilistic ecological risk of rare earth elements in surface sediments of Jiulong River estuary and adjacent watershed

Rare earth elements (REE) are increasingly recognized as emerging micropollutants in the environment, and concerns surrounding their presence are steadily growing. However, the understanding of possible pollution and ecological risks of REE in river sediments is relatively scarce. To address this, an investigation into the distribution, origins, pollution levels, and potential ecological risks of REE in sediments along the Jiulong River Estuary and adjacent watersheds was conducted. The results revealed that ΣREE in sediments ranged from 54.98 to 156.05 mg/kg along the Jiulong River and its estuary. The REE concentrations generally decreased from the Jiulong River to the estuary. Cluster analysis and geochemical parameter ratios suggested the high REE concentrations in Jiulong River may be derived from fertilizer and coal combustion. The sediments REE was normalized using the chondrites and exhibited apparent fractionation between LREE and HREE. Additionally, the REE in sediments was characterized by LREE enrichment and negative Ce and Eu anomalies. The evaluation of geo-accumulation and enrichment factors indicated that Gd, Yb, Lu, Tb and Dy were the elements most highly enriched in the sediments. Sites labeled S1–S3 and S5 were classified as moderately polluted, with Lu posing a moderate potential ecological risk, while other elements presented only mild ecological risks. Our findings suggest that anthropogenic activities significantly influence the pollution and potential ecological risks of REE in river sediments. Therefore, attention should be paid to the management of emerging contaminants in rivers and estuaries to protect ecosystems and local populations from potential risks associated with the accumulation of REE in sediments.

Nutrients and Rare Earth Elements in Surface Sediments of Hongze Lake (China) Using the DGT Technique: Spatial Distribution Pattern and Probabilistic Risk

Nutrients and Rare Earth Elements in Surface Sediments of Hongze Lake (China) Using the DGT Technique: Spatial Distribution Pattern and Probabilistic Risk

Application of diffusive gradients in thin films to determine rare earth elements in surface sediments of Daya Bay, China: Occurrence, distribution and ecotoxicological risks

Known as burgeoning contaminants, the bioavailability of rare earth elements (REEs) can be determined using diffusive gradients in thin films (DGT). As Daya Bay (South China) has been under serious anthropogenic influences, the present study examined the distribution of REEs in surface sediments and their possible ecological risks in the bay. The range of DGT-labile concentrations of REEs (∑REEs) was from 5.67 μg/L to 8.41 μg/L, with an average of 7.34 μg/L. Results of assessment of single REE toxicity revealed that the risk quotient (RQ) values of Y, Ce and Yb were >1, indicating that their potential negative impacts on the nearby environment. However, analysis of the integral toxicity of REE mixtures through assessment of probabilistic ecotoxicological risks showed that there was a negligibly low probability of toxicity of PRE surface sediments to aquatic organisms in the study area.

Distribution of rare earth elements in surface sediments of the western Sunda Shelf: Constraints from sedimentology and mineralogy

To understand the modern sedimentation and land-sea interaction processes in the Sunda Shelf, we evaluated the rare earth element (REE) compositions, the total organic carbon (TOC) contents, grain sizes, and detrital minerals of 39 surface sediments, collected from the western Sunda Shelf. All of the sampled sediments are characterised by a higher content of light REEs (LREEs) relative to the content of heavy REEs (HREEs) with negative Eu anomalies. The total content of REE (ΣREE) in the sediments ranges from 7 μg/g to 193 μg/g, with an average of 119 μg/g. Due to the uneven spatial distribution of REEs in the study area, a Q-cluster analysis is applied to the mean grain size (Mz), ∑REE, δEu, δCe, (La/Yb)N, and (Gd/Yb)N data. On this basis, the study area can be classified into three geochemical provinces. The north to central zone in the study area is designated as province I, which has the highest REE content among the three provinces. This is a result of the finer grain size, dominance of siderite, and higher TOC contents of the sediments in province I. The REE content of province II in the southwest coastal zone is lower than that of province I due primarily to a coarser grain size and high quartz, biodetritus, and plagioclase contents. Covering the central coastal zone, province III has the lowest REE content among the three provinces because of the extremely coarse grain size and very high quartz and biodetritus contents. The upper continental crust (UCC)-normalised REE patterns differ markedly among the three provinces, thereby indicating different provenances and transport mechanisms. Based on the provenance discrimination plot and the UCC-normalised REE patterns of these three provinces and adjacent rivers, we infer that province I is largely fed by the Mekong and Kelantan rivers. The fine-grained sediments from these rivers are transported to north and central zone by the northeast monsoon current. The Pahang River is identified as the main sediment source of province II. The coarse-grained sediments from this river mostly accumulate near the estuary via hydrodynamic sorting, while finer-grained sediments are transported to the south by the southward coastal currents. The sediments in province III are inferred as being primarily the result of coastal erosion due to the strong wave energy in this area, as well as offshore and longshore sediment transport acting, in parallel to the coast line. Our study can serve as a reference for studying the diffusion and transport processes of mountainous river sediment and the evolution of the paleoclimate and paleoenvironment in tropical low-latitude regions.

Distribution of rare earth elements in surface sediments of the western Gulf of Thailand: Constraints from sedimentology and mineralogy

To understand the modern sedimentation and land-sea interaction processes in the Asian margin seas, we analyze rare earth element contents (REE, i.e., La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) and grain sizes, detrital minerals from 158 surface sediment samples collected from the western Gulf of Thailand (GoT). The results reveal that the REE contents ranged from 25.42 μg/g to 201.21 μg/g, with an average value of 137.21 μg/g, and that the GoT is characterized by higher accumulations of LREE relative to HREE, together with negative Eu anomalies. Based on the spatial distribution characteristics of REE contents, δCe and δEu, the western GoT can be classified into three geochemical provinces. The Province I covers the northern and northwestern coastal zones of the GoT, including the entire upper GoT; its coarse size fraction and distribution pattern of hornblende- and quartz-dominated minerals caused REE contents to be the lowest, and these sediments were mainly derived from the rivers around the upper GoT, including the Chao Praya River and the Kea Klong River. The Province II is located in the central GoT and has the highest REE concentrations due to finer sediment composition and higher contents of zircon, authigenic pyrite, and biogenetic limestone. The Province II has two accumulation centers around Samui Island and Koh Chang Island, with REE spatial distribution influenced by the seasonal setting and mixed derived from multiple provenances around the GoT. The Province Ш is located in the lower GoT, close to Malaysia. The sediment type in this region is similar to that of Province I except for different detrital mineral compositions, especially the presence of siderite that is responsible for higher REE contents. The sediments in this region exhibits similar distribution patterns to those of terrestrial materials from the Malaysian peninsula such as that from the Kelantan River. The transportation processes of sediments in this region are mainly controlled by the coastal current.

Sources and distribution of yttrium and rare earth elements in surface sediments from Tagus estuary, Portugal

The distribution and sources of yttrium and rare-earth elements (YREE) in surface sediments were studied on 78 samples collected in the Tagus estuary (SW Portugal, SW Europe). Yttrium and total REE contents ranged from 2.4 to 32mg·kg−1 and 18 to 210mg·kg−1, respectively, and exhibited significant correlations with sediment grain-size, Al, Fe, Mg and Mn, suggesting a preferential association to fine-grained material (e.g. aluminosilicates but also Al hydroxides and Fe oxyhydroxides). The PAAS (Post-Archean Australian Shale) normalized patterns display three distinct YREE fractionation pattern groups along the Tagus estuary: a first group, characterized by medium to coarse-grained material, a depleted and almost flat PAAS-normalized pattern, with a positive anomaly of Eu, representing one of the lithogenic components; a second group, characterized mainly by fine-grained sediment, with higher shale-normalized ratios and an enrichment of LREE relative to HREE, associated with waste water treatment plant (WWTP) outfalls, located in the northern margin; and, a third group, of fine-grained material, marked by a significant enrichment of Y, a depletion of Ce and an enrichment of HREE over LREE, located near an inactive chemical-industrial complex (e.g. pyrite roast plant, chemical and phosphorous fertilizer industries), in the southern margin. The data allow the quantification of the YREE contents and its spatial distribution in the surface sediments of the Tagus estuary, identifying the main potential sources and confirming the use of rare earth elements as tracers of anthropogenic activities in highly hydrodynamic estuaries.

Rare earth elements in surface sediments of a marine coast under heavy anthropogenic influence: The Bohai Bay, China

Surface sediments along four river-to-sea transects from the coastal Bohai Bay were assessed using a four-step sequential extraction procedure to determine the concentrations of rare earth elements (REEs) and the geochemical fractions in which those elements were present. The concentrations of light REEs were slightly depleted than those of the middle REEs and the heavy REEs. No significant Ce anomaly was observed whereas slight Eu-positive anomaly was found. The sequential extraction results revealed that the geochemical fractions of REEs followed the order of residual > reducible > oxidizable > acid soluble. The residual fraction accounted for the majority of the total concentrations of REEs. Middle REEs were more easily leached than other REEs. No obvious river-to-sea transportation was observed and the concentrations of REEs in surface sediments of the coastal Bohai Sea were consistent with the data from the Post-Archean Australian Shale. This study further demonstrated on the basis of our previous inference that the geochemical features of REEs in coastal sediments were generally unaffected by heavy anthropogenic effects.

Speciation of rare earth elements in surface sediments of Lagoon of Aveiro (N Portugal)

Martins, V.A., Dias, J.A., Laut, L.M., Sobrinho, F., Santos, J.F., Rodrigues, M. A., Frontalini, F., Miranda, P., Terroso, D., Fernandez-Fernandez, S., Bernardes, C., Figueira, R., Sousa, S., Amaral, P., Mahiques, M., Bernabeu, A., Rey, D., Rubio, B., and Rocha, F., 2013. Speciation of rare earth elements in surface sediments of Lagoon of Aveiro (N Portugal). In: Conley, D.C., Masselink, G., Russell, P.E. and O’Hare, T.J. (eds.), Proceedings 12 th International Coastal Symposium (Plymouth, England), Journal of Coastal Research, Special Issue No. 65, pp. 64-69, ISSN 0749-0208. The goal of this work is to determine the distribution of the rare earth elements in the surface sediments in the Ria de Aveiro (N Portugal) coastal lagoon. Concentrations of REE (La, Ce, Nd, Sm) and related elements (Th, Y and Sc) were evaluated by total digestion of sediments in the fine fraction of 33 grab-samples of surface sediments. The same method was followed for Al, Ca, S and Zr, related to terrigenous sources, but also, in the cases of Ca and S, to biogenic and quimiogenic processes. Concentrations of REE and related elements were additionally assessed by a three-step sequential chemical extraction (E1-3) procedure coupled with ICP–MS determination. The geochemical results were processed by statistical analysis combining textural and mineralogical data (XRD techniques). The results show that mobile La, Ce, Nd, Sm and Y are mostly adsorbed by amorphous Mn hydroxide (E3), secondly associate with organic matter (E2) and only in a very small extent are adsorbed on clay mineral structural sheets or associated with carbonates (E1). Thorium and Sc are almost exclusively linked with E2. Ytrium shows a very high percentage of availability, whilst Ce, La, Sc and Th are by far less mobile. Results of cluster analysis reveals that sediments are enriched in: i) quartz, feldspars and anhydrite in the most hydrodynamic areas with good connection with the ocean, where tidal currents are stronger and water is salty and welloxygenated; ii) mud, TOC, phyllosilicates, siderite, pyrite and S in low hydrodynamic areas. In these areas, pyrite and siderite can result from reducing bacterial activity in subsurface sediments. Early diagenetic changes in the sediments would also influence the elements adsorption to clay minerals and their co-precipitation with carbonates (E1). The highest values of REE, in E1, occur in distal locations in relation to the mouths of rivers and streams. The retention of the elements in this phase may occur mainly in the lagoon, depending on the availability of carbonates and clay minerals and their assemblage’s composition. Concentrations of REE and related elements adsorbed by organic matter (E2) and by amorphous Mn hydroxide (E3) tend to rise near the rivers mouths and may be related to geochemical processes that take place upstream in the course of the rivers before the entry of sediments into the lagoon. Elemental concentrations retained in the structure of mineral phases (R), also tend to reach high values near the rivers mouths but in low hydrodynamic areas. There is some fractionation between Th and the light REE which is more evident in the Murtosa channel that is fed mainly by the Antua river.

Geochemical characteristics and provenance implication of rare earth elements in surface sediments from bays along Guangdong Coast, Southeast China

A systematic study of the granulometric properties and the occurrence and distribution of rare earth elements (REE) within surface sediments from ten bays situated along the coast of Southeast China has facilitated a more rigorous understanding of constraints on sediment provenance in the area. The results show that REE concentrations are similar within a single bay, but vary considerably (133.58–251.77 mg/kg) among the bays. The chondrite-normalized distribution patterns show the typical enrichment of light REEs (LREEs: La–Eu) relative to heavy REEs (HREEs: Gd–Lu), and an apparent depletion of Eu, which is diagnostic of a terrigenous sediment source. Obvious enrichments of the middle REEs (MREEs: Sm–Ho) in the PAAS-normalized (Post-Archean Australian Shale) distribution patterns of these bay sediments are similar to results reported from large rivers in China. Comparing the REE composition of the bay sediments with those of adjoining fluvial sediments and with the bedrock of the surrounding drainage basins, the latter are indicated as the dominant sediment source. The uniform REE distribution patterns, and MREE enrichments, prove that the sediments are derived from the material transported by the streams and rivers that discharge into the bays.

The Continental Crust: Its Composition and Evolution. Stuart Ross Taylor , Scott M. McLennan

Previous articleNext article No AccessReviewsThe Continental Crust: Its Composition and Evolution. Stuart Ross Taylor , Scott M. McLennan Allan K. GibbsAllan K. Gibbs Search for more articles by this author PDFPDF PLUS Add to favoritesDownload CitationTrack CitationsPermissionsReprints Share onFacebookTwitterLinkedInRedditEmail SectionsMoreDetailsFiguresReferencesCited by The Journal of Geology Volume 94, Number 4Jul., 1986 Article DOIhttps://doi.org/10.1086/629067 Views: 25Total views on this site Citations: 17Citations are reported from Crossref Copyright 1986 The University of ChicagoPDF download Crossref reports the following articles citing this article:Lishuang Liu, Fulai Liu, Jinghui Guo, Pinghua Liu, Wei Wang, Jia Cai Geochronological and geochemical constraints on the non-ultrahigh-pressure metasedimentary blocks of North China affinity within the Sulu ultrahigh-pressure belt, eastern China, and tectonic implications, International Geology Review 65, no.77 (Feb 2021): 1127–1157.https://doi.org/10.1080/00206814.2021.1882889Zi‐Tan Shu, Sheng‐Ao Liu, Dejan Prelević, Yu Wang, Stephen F. 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