Early Silurian Time Research Articles

Upwelling-driven biogenic silica accumulation in the Yangtze Sea, South China during Late Ordovician to Early Silurian time: A possible link with the global climatic transitions

Silica accumulation in the Yangtze Sea during the Ordovician–Silurian (O–S) transition appears to have coincided with global climatic fluctuations, widespread upwelling, and volcanism. There is a need to further evaluate their respective contributions to silica deposition and potential relationships among these factors. The current study selected siliceous deposits in the Wufeng and Longmaxi Formations from four sections spanning the inner to outer Yangtze Sea, South China, to gain a deeper understanding of the climatic and oceanographic evolution associated with silica enrichment. Al/(Al + Fe + Mn) values, the presence of radiolarians, and Si isotope values of samples recovered from the investigated shale successions offer compelling evidence that the silica is largely of biogenic origin with some terrigenous contributions. Further, various productivity and redox proxies suggest that biogenic silica (BSi) accumulated under conditions of enhanced marine productivity and anoxic bottom water conditions. Hg/TOC and Zr/Al2O3 profiles suggest intermittent volcanism during the BSi deposition in the Yangtze Sea. However, the lack of correlation between BSi and Hg/TOC values indicates that volcanic iron fertilization was not responsible for BSi accumulation. Instead, most BSi-rich samples are dominated by low MnEF × CoEF values (<0.5), consistent with BSi deposited in modern upwelling settings. Hydrographic reconstruction based on Mo–U covariation indicates a more open water setting in the outer Yangtze Sea, while the coeval inner Yangtze Sea was relatively restricted. Therefore, upwelling events appear to have been more vigorous in the outer Yangtze Sea. Published and new Chemical Index of Alteration (CIA), BSi, and MnEF × CoEF data for the Wufeng and Longmaxi Formations across the inner to outer Yangtze Sea demonstrate that temporal and spatial variations of BSi were controlled by climate-driven upwelling. In particular, cool-water upwelling contemporaneous with Hirnantian glaciation may have been responsible for the establishment of the cool-water fauna of the shallow-water Guanyinqiao Bed and enhanced silica deposition in deeper water. Moreover, a moderate negative relationship between compiled CIA and BSi contents suggests that enhanced upwelling driving BSi accumulation appears to have been favored during cooling events. Integrated analysis of BSi deposits of the Laurentia and Baltica continental margins further suggests that BSi accumulation on continental margins during the O–S transition was primarily influenced by global cooling. Therefore, we suggest that wind patterns or/and thermohaline circulation, influenced by climate fluctuations, induced widespread cold water upwelling events during the O–S transition. Moreover, elevated BSi production diluted accumulating OM resulting in the observed parabolic relationship of BSi and TOC.

Phylogeny of the Ordovician and Silurian members of the order Atrypida

Brachiopods belonging to order Atrypida originated in the Middle Ordovician and went extinct in the Late Devonian. Few cladistic studies have been undertaken for this group. Here we investigate their early evolution through Silurian time. We present a parsimony-based phylogenetic analysis of 41 characters and 70 genera representing all the early taxonomic groups within the order. The stratigraphical record of the fossil genera analysed strongly aligns with the phylogeny recovered from our parsimony analysis. Most currently recognized subfamilies and families may be identified within clades, except for the Atrypinae, Idiospirinae, and the Septatrypidae. This warrants subdivision of the former and redefinition of the latter two. The subfamily Atrypinae is redefined, and a new subfamily of the Atrypidae, the Protatrypinae, is split off. Tracing character evolution across the tree indicates that the calcified spiralia and a jugum or jugal processes characterize all members of the Atrypida, except the most basal clade, the Cyclospiridae, which lacks a calcified jugum. Ribs are a homoplasious character, occurring in numerous clades throughout the tree. Darriwillian through Sandbian ages represent times with rapid evolution when most new autapomorphies seen in the atrypides evolved. This interval is the first major part of the Great Ordovician Biodiversification Event (GOBE). Solid teeth, dorsal direction of spiralia, elaborate ornamentation, and frills evolved in the latest Katian into early Silurian time. Solid teeth seen in distantly related clades from latest Katian onwards may be an analogous feature. The Late Ordovician Mass Extinction (LOME) is indicated in the stratigraphical tree together with a possible event at the end of the Aeronian. The tree supports the long-held assumptions that the Plectatrypinae evolved from the Spirigerininae. It further suggests that the genus Tuvaella may be included with the Davidsonioidea. Likewise, the redefined Atrypinae is a sister group of the Lissatrypidae and a derived group in the phylogenetic tree.

Carbon and sulfur isotope variations through the Upper Ordovician and Lower Silurian of South China linked to volcanism

Pronounced excursions of carbon and sulfur isotopes (δ13C and δ34S) spanning the Ordovician–Silurian (O–S) transition have been recognized globally, yet the causes of these isotope events and their causal relationships to environmental changes, especially during Early Silurian time, remain the topics of debate. In this study, we present organic carbon and pyrite sulfur isotope (δ13Corg and δ34Spyr) records and elemental concentrations from a drill core spanning from the Upper Ordovician (Katian) to Lower Silurian (Aeronian) succession of the Yangtze Platform, China. The newly presented δ13Corg profile records previously recognized positive excursions, including the Hirnantian isotopic carbon excursion (HICE), the middle Rhuddanian excursion, and the early Aeronian positive carbon isotope excursion (EACIE). In addition, two negative δ13Corg excursions are recognized during the Katian to early Hirnantian and late Hirnantian to middle Rhuddanian stages. The δ34Spyr profile exhibits a great amount of variation (−17.8‰ to +19.6‰) but mimics the δ13Corg record. Coupled positive δ13Corg and δ34Spyr excursions during the middle Hirnantian and late Rhuddanian to Aeronian are associated with decreased total organic carbon (TOC) content and less reducing water column conditions, whereas the negative δ13Corg and δ34Spyr excursions during the Katian to early Hirnantian and late Hirnantian to middle Rhuddanian are associated with enhanced TOC values and the establishment of more strongly anoxic to euxinic conditions. The δ13C and δ34S excursions during the O–S transition, then, cannot be explained by changes in redox conditions or the burial of organic carbon and pyrite. The heavier and less variable middle Hirnantian and late Rhuddanian to Aeronian δ34Spyr values probably reflect low marine sulfate concentration. In contrast, negative Katian to early Hirnantian and late Hirnantian to middle Rhuddanian δ34Spyr excursions may reflect increased sulfate concentration. The two negative δ13Corg and δ34Spyr excursions associated with the Katian to early Hirnantian and late Hirnantian to middle Rhuddanian correspond with episodes of volcanism. We therefore propose that volcanism was the main driver of coupled negative δ13Corg and δ34Spyr excursions. As volcanism diminished during the middle Hirnantian and late Rhuddanian to Aeronian, both δ13Corg and δ34Spyr returned to more positive values. Our results indicate that volcanism played a crucial role in triggering carbon and sulfur isotope perturbations and environmental changes during the Late Ordovician and Early Silurian.

Early Silurian granitic rocks and associated enclaves as evidence of rapid cooling in a cognate magma system: the case of the Xuehuading–Panshanchong pluton, South China Block

AbstractThe study of enclaves in granitic plutons provides fundamental information on the petrogenesis of their host rocks. Here we combine U–Pb zircon ages, petrography, geochemistry and Nd–Hf isotope composition to investigate the origin of dioritic–granodioritic enclaves and their host granodiorites and biotite granites in the Xuehuading–Panshanchong area, which is a pivotal site to study the Palaeozoic intracontinental orogenic processes of the South China Block. Obtained ages indicate that the host rocks were formed in early Silurian time (c. 432 Ma). The enclaves are fine grained, but with mineral assemblages similar to their hosts and contain amphibole, biotite and plagioclase. All rocks have fractionated rare earth element patterns ((La/Yb)N = 2.86–8.16), except for one biotite granite that has a concave rare earth element pattern ((La/Yb)N = 1.50). Most rocks are depleted in Ta–Nb–Ti, and have negative Eu anomalies and ϵNd(t) (–8.86 to –5.75) and zircon ϵHf(t) (–13.30 to –4.11, except for one, –39.08). We interpret that the enclaves were formed at the borders of magma-ascending conduits, where the mafic mineral crystallization was enhanced by rapid cooling. Conversely, the biotite granites were produced by fractional crystallization from a related granodiorite magma. The sample with a concave rare earth element pattern may have been influenced by hydrothermal fluid–melt interaction. Geochemical modelling suggests that the granodiorites were likely generated by disequilibrium melting of heterogeneous amphibolites in the middle–lower crust. Considering the geological data for the Palaeozoic magmatic rocks in the South China Block, we propose that the Xuehuading–Panshanchong magmatism was likely triggered by piecemeal removal of the thickened lithospheric root and subsequent thermal upwelling of mantle, without a mantle-derived magma contribution to the granites.

СИЛУРИЙСКИЙ РИФ ЛЕДЯНСКОГО ПОДНЯТИЯ КАК ПОТЕНЦИАЛЬНЫЙ РЕЗЕРВУАР УГЛЕВОДОРОДОВ НА СЕВЕРЕ СИБИРСКОЙ ПЛАТФОРМЫ

The results of the lithological study of the Silurian sediments drilled in by wells within the Ledyansk uplift in the north of the Siberian platform are presented. It is found that in the early Silurian time on the territory under consideration a large organogenic buildup corresponding to typical Silurian reefs of a stable shelf was formed, the formation stage of its framework was confined to Wenlock. In Late Silurian, against the background of regression, the reef formations were overlain by lagoon-sebkha clayey-evaporite deposits. It is shown that the heterogeneity of the section affected the distribution of reservoir properties. The high primary porosity of the reef framework contributed to the processes of dissolution, stylolization, fracturing and formation of a high-capacity reservoir. The combination of various voids led to the development of a complex reservoir. The saline-sulfate rocks of the Upper Silurian – Lower Devonian act as a seal. The question of the prospects for the oil and gas potential of the Silurian reef deposits is of particular relevance in view of the wholesale development of organogenic buildups on the Siberian platform in the Wenlock time.

Sedimentology and hydrocarbon potential of the Late Ordovician glacial deposits on the Arabian Platform and Southeastern Turkey

The Late Ordovician glacial deposits are widespread and constitute a significant portion of the Early Paleozoic stratigraphic sequence of the cover rocks of the Arabian and African platforms. The glaciation lasted less than one million years between the Late Ashgillian (445 Ma) and Early Silurian (444 Ma) but it had a strong impact on the whole area. It has been proven that the glaciofluvial sandstones form important oil and gas reservoirs in Saudi Arabia and in North African and other Middle Eastern countries, including SE Turkey, but their heterogeneity and internal lithofacies characteristics have not been fully understood yet. In Saudi Arabia the hydrocarbon-producing glacial paleovalley systems forming the Sarah Formation extend 70 km in the W-E direction. In southern Turkey, similar glacial paleovalleys, defined as the Yurteri Formation, extend in a NW-SE direction. It consists of massive, well-sorted, porous reservoir sandstones of good quality and produces significant amounts of oil and sweet gas in SE Turkey. When the glaciation ceased in the Early Silurian time, the ice mass melted and released large volumes of water into the oceans. Returning waters resulted in rapid sea-level rise and onlap relations across the platforms. This widespread marine transgression deposited organic-rich, potential source-rock hot shale facies directly on the good-quality glaciofluvial reservoir sandstones. This publication is based on intensive outcrop and subsurface studies on the core samples of the reservoir sandstones and the source-rock shale facies in every part of Saudi Arabia and SE Turkey. These studies clearly indicated the hydrocarbon potentials of the Late Ordovician glaciation formed on the Gondwana plate. The aim of this paper is to demonstrate the presence of a close genetic relationship between the glaciofluvial reservoir sandstones and overlying hot shale source-rock facies and downward migration of oil and gas into the underlying porous sandstones mainly due to hydrostatic pressure.

Petrography and geochemistry of the Lower Silurian sandstones from the Angzanggou Formation in the North Qilian Belt, China: implications for provenance, weathering and tectonic setting

AbstractThe North Qilian Orogenic Belt is on the northeastern margin of the Tibetan Plateau. It is connected with the Alxa Block in the north and the Tethyan orogenic assemblage in the south. The Lower Silurian Angzanggou Formation, deposited in the northern area of the North Qilian Orogenic Belt, is the most important for revealing the architecture and orogenic processes of the North Qilian Belt. Provenance analysis of the Angzanggou Formation can reveal not only the tectonic evolution of the central orogenic belt of China but also Palaeozoic Asia plate reconstructions. Petrographic analysis indicated that the compositional and textural maturity of the sandstones was low. The detrital composition of the Angzanggou Formation samples consists of quartz (8–14 %), feldspar (6–29 %) and lithic fragments (56–86 %). The sandstones could be classified as litharenites or feldspathic litharenites. The detrital modal composition suggests that these sandstones were probably deposited in a fore-arc basin. The element ratios and some discrimination diagrams based on geochemistry indicate that felsic and intermediate rocks were the main source rocks. The SiO2/Al2O3 ratio, the index of chemical variability and the Th/Sc versus Zr/Sc discrimination diagram suggest that the compositional maturity and degree of recycling were moderate to low. The index of alteration (CIA) and the A–CN–K diagram indicate the intensity of weathering was moderate. The discrimination diagrams based on major and trace elements and petrographic discrimination diagrams imply that the Angzanggou Formation rocks were derived from a continental island arc, and a sedimentary cover probably overlaid the volcanic arc. Therefore, we infer that during Early Silurian time the North Qilian Belt sediments accumulated in a fore-arc basin.

Sedimentology, geochemistry and reservoir potential of the organic-rich Qusaiba Shale, Tabuk Basin, NW Saudi Arabia

Abstract The Qusaiba Shale Formation of the Qalibah Group is the most prolific source rock for the Paleozoic petroleum system in Saudi Arabia and is recently considered as a potential unconventional shale gas reservoir. Detailed sedimentological, petrographical, and geochemical analyses were undertaken on an ~31 m thick outcrop of this organic-rich shale exposed in the northwest of Tayma City, NW of Saudi Arabia to provide a better understanding of the vertical and lateral lithofacies variations and the effects of such variations on reservoir properties. X-ray diffraction analysis reveals that clay minerals (average: 50%) and quartz (average: 28%) dominate the bulk mineralogical composition while K-feldspar, plagioclase, and pyrite occur as common to minor components in the analyzed samples. An integration of the sedimentological description, petrography and mineralogical composition allows the subdivision of the investigated outcrop section into six lithofacies. These are: Laminated organic-rich shale, Graptolitic concretion, Massive organic-rich shale, Organic-lean shale, Siltstone-shale interbedded, and Cross-stratified siltstone/sandstone lithofacies. TOC content in the laminated and massive organic-rich shale lithofacies ranges between 0.5 and 6.1 wt% (average 2.52 wt%) then it decreases upward (0.04–0.35 wt%, average 0.18 wt%) in the overlying organic-lean shale and siltstone lithofacies. Trace elements (Cu, Mo, As, Ni, Co, U and V) show positive excursions in the lowermost 20 m of the organic-rich, dark-grey shale interval and display abrupt depletions at the contact with overlying organic-lean shale. The enrichment factors of these trace elements are characterized by similar distribution patterns as their measured concentrations. Like the elements, these factors also exhibit a significant depletion at the contact between the organic-rich shale and the overlying organic-lean shale. Out of all the redox indices, V/(V + Cr), V/(V + Ni), Th/U and [Mo]s/TOC were found to best distinguish between the organic-rich and the overlying organic-lean intervals. The laminated organic-rich shale lithofacies indicate deposition of hemipelagic sediments by a relatively low energy quiet anoxic bottom water, most likely in a sulfidic conditions that were associated with a strongly restricted bottom water mass circulation at the time of its deposition. This restricted hydrographic condition was likely enhanced in the study area due to the paleotopography that was created by the deglaciation of the Early Silurian time. The TOC richness, common occurrence of pyrite and high enrichment of redox elements Mo, U and V in the organic-rich shale intervals support the existence of anoxic bottom water at the time of deposition. The abrupt decrease of the TOC and the redox sensitive elements and their associated indices from the underlying organic-rich lithofacies to the overlying organic-lean shale lithofacies is likely due to a gradual increase in oxygen level. This improved bottom water oxygenation condition might have led to a reduction in organic productivity and limited organic matter preservation in the organic-lean shale lithofacies. The graptolitic concretion lithofacies found in the sequence, refers to an in-situ, syngenetic to early diagenetic origin formed close to the sediment-water layer when there was little or no deposition or at periods characterized by low sedimentation rates. The siltstone - fine sandstone lithofacies in the topmost part of the studied section, is interpreted to indicate the dominance of high energy and highly oxygenated shallow bottom water conditions during deposition, probably in a middle to inner shelf depositional settings. The kerogen in QS is a mixture of type III (gas prone) and type IV (inert kerogen), Tmax values with an average of 430 °C, and VRo values (average 0.58) calculated from the Tmax, assigned the studied section as immature. Qualitative evaluation of porosity allows the identification of three different types of porosity including inorganic porosity, organic porosity and natural fracture porosity. Although the ductile clay minerals are the most abundant minerals in the lower part of the studied QS (average 56%), the brittle minerals (Quartz, Feldspar, and Pyrite) form an average of 42% and exhibit a uniform distribution of brittleness in the organic-rich interval.

New U-Pb zircon age and carbon isotope records from the Lower Silurian Longmaxi Formation on the Yangtze Platform, South China: Implications for stratigraphic correlation and environmental change

The Ordovician–Silurian (O–S) transition was a period of dramatic climatic, environmental, and biological change. Numerous studies have documented the Late Ordovician glacial or mass extinction interval, but the Early Silurian has received significantly less attention. This study presents a U-Pb zircon age data and organic carbon isotope (δ13Corg) records from the Upper Ordovician to Lower Silurian succession of South China to better constrain carbon isotope perturbations and to evaluate their possible causes and relationships to paleoenvironmental change during Early Silurian time. A volcanic ash bed located at the top of the organic-rich Lower Silurian Longmaxi Formation yields a 206Pb/238U zircon age of 440 ± 3 Ma (MSWD = 1.4), which is consistent with the Rhuddanian–Aeronian (R–A) boundary age. The newly acquired age is similar to that documented an ash bed in Scotland (439.57 ± 1.13 Ma) perhaps indicating synchronous volcanism. The δ13Corg values show a negative excursion in the organic-rich lower Longmaxi Formation that is interrupted by a positive excursion in the organic-lean upper part of the unit. The positive excursion begins immediately above the dated ash bed thus assigning it to the R–A boundary. The documented δ13Corg trend is comparable to those of other sections throughout the world, and is suggestive of a global perturbation of carbon cycle. The negative δ13Corg excursion of the Rhuddanian stage was coeval with deposition of organic-rich shale under anoxic/euxinic conditions, whereas the subsequent positive δ13Corg excursion coincided with a change to suboxic conditions that could have diminished organic matter preservation. We propose that the negative δ13Corg excursion could be considered as the defining isotopic characteristic of the Rhuddanian oceanic anoxic event (Rhuddanian OAE). Results of the present study in tandem with published age data from the Guanyinqiao Bed immediately below the base of the Longmaxi Formation suggest that the negative δ13Corg excursion and associated Rhuddanian OAE persisted for approximately 3 Myr. This relatively long-lived event reflects a sustained addition of isotopically light carbon into the atmosphere-ocean system, possibly related to the release of volcanic CO2. The enhanced burial of organic carbon in association with the Rhuddanian OAE could have removed the substantial 12C from the carbon reservoir and lowered atmospheric pCO2 thus resulting in a subsequent positive δ13C excursion and global cooling at the R-A boundary.

The Anglo-Brabant Massif: Persistent but enigmatic palaeo-relief at the heart of western Europe

The surface geology of central England and Belgium obscures a large ‘basement’ massif with a complex history and stronger crust and lithosphere than surrounding regions. The nucleus was forged by subduction-related magmatism at the Gondwana margin in Ediacaran time. Partitioning into a platform, in the English Midlands, and a basin stretching to Belgium, in the east, was already evident in Cambrian/earliest Ordovician time. The accretion of the Monian Composite Terrane during the Penobscotian deformation phase preceded late Tremadocian rifting, and Floian separation, of the Avalonia Terrane from the Gondwana margin. Late Ordovician magmatism in a belt from the Lake District to Belgium records subduction beneath Avalonia of part of the Tornquist Sea. This ‘Western Pacific-style’ oceanic basin closed in latest Ordovician time, uniting Avalonia and Baltica. Closure of the Iapetus Ocean in early Silurian time was soon followed by closure of the Rheic Ocean, recorded by subduction along the southern margin of the massif. The causes of late Caledonian deformation are poorly understood and controversial. Partitioned behaviour of the massif persisted into late Palaeozoic time. Late Devonian and Carboniferous sequences show strong onlap onto the massif, which was little affected by crustal extension. Compressional deformation during the Variscan Orogeny also appears slight, and was focussed in the west where a wedge-shaped mountain foreland uplift was driven by orogenic indentation, splitting the massif from the Welsh Massif along the reactivated Malvern Line. Permian to Mesozoic sequences exhibit persistent but variable degrees of onlap onto the massif.

Detrital zircon U-Pb geochronology of the Magog Group, southern Quebec – stratigraphic and tectonic implications for the Quebec Appalachians

In the Quebec Appalachians, the Laurentian continental margin (Humber Zone) and adjacent oceanic domain (Dunnage Zone) were amalgamated during the Ordovician Taconian orogeny. The Dunnage Zone includes ophiolites and overlying synorogenic deposits of both the Saint-Daniel Melange and Magog Group. The latter consists of a ∼3 km-thick pile of sandstone, felsic volcaniclastic rocks and graphitic slate at the base (Frontiere, Etchemin and Beauceville formations) overlain by a ∼7 km-thick turbiditic flysch sequence, constituting the Saint-Victor Formation. The maximum upper age limit of the Magog Group was considered to be Darriwilian based on graptolite fauna. This was proven consistent with a 462+5/−4 Ma (U-Pb ID-TIMS) from a felsic tuff of the Beauceville Formation, but contradicts a detrital zircon U-Pb age of 424 ± 6 Ma recently measured in the Saint-Victor Formation. A new detrital zircon U-Pb geochronology study (HR-LA-ICP-MS and ID-TIMS), focused on the Saint-Victor Formation, yields young detrital populations that suggest that the Saint-Victor Formation is not exclusively Ordovician and extends into the Silurian, as indicated by a maximum age of sedimentation around 430 Ma. Detrital zircon U-Pb geochronology associated with fossil age constraints and stratigraphic correlations in adjacent areas attest that the Saint-Victor Formation should be considered as an upper Magog Group sequence that is separated from lower units (the Frontiere-Etchemin-Beauceville formations) by an unconformity corresponding to a sedimentary hiatus of ≤ 10 m.y. Regional tectonic considerations imply that the Magog Group evolved from a syn-Taconian forearc basin in Middle-Late Ordovician time to a syn-Salinic peri-continental basin in early Silurian time. Several NW and SE erosional sources are invoked for the sedimentation of the Magog Group, evolving from the erosion of both the southern Quebec ophiolites and adjacent sedimentary rocks of the Laurentia margin to the NW, and volcanic arc rocks of the Ascot Complex, Shelbourne Falls and Bronson Hill massifs to the SE. Potential sources for ca. 430 Ma zircons found towards the top of the Saint-Victor sequence are the Silurian Frontenac Formation and the East Inlet granitic pluton, both located in the vicinity of the Quebec-Maine border.

Depositional environment and organic matter accumulation of Upper Ordovician–Lower Silurian marine shale in the Upper Yangtze Platform, South China

The main controlling factors of organic matter accumulation in the Upper Ordovician Wufeng–Lower Silurian Longmaxi Formations are complex and remain highly controversial. This study investigates the vertical variation of total organic carbon (TOC) content as well as major and trace element concentrations of four Ordovician–Silurian transition sections from the Upper Yangtze Platform of South China to reconstruct the paleoenvironment of these deposits and to improve our understanding of those factors that have influenced organic matter accumulation in these deposits.The residual TOC content of the Wufeng Formation averages 3.2% and ranges from 0.12 to 6.0%. The overlying lower Longmaxi Formation displays higher TOC content (avg. 4.4%), followed upsection by consistent and lower values that average 1.6% in the upper Longmaxi Formation. The concentration and covariation of redox-sensitive trace elements (Mo, U and V) suggest that organic-rich intervals of the Wufeng Formation accumulated under predominantly anoxic conditions. Organic-rich horizons of the lower Longmaxi Formation were deposited under strongly anoxic to euxinic conditions, whereas organic-poor intervals of the upper Longmaxi Formation accumulated under suboxic conditions. Positive correlations between redox proxies and TOC contents suggest that organic matter accumulation was predominantly controlled by preservation. Barium excess (Baxs) values indicate high paleoproductivity throughout the entire depositional sequence, with an increase in the lower Longmaxi Formation. Increased productivity may have been induced by enhanced P recycling, as evidenced by elevated Corg/Ptot ratios. Mo–U covariation and Mo/TOC values reveal that the Wufeng Formation was deposited under extremely restricted conditions, whereas the Longmaxi Formation accumulated under moderately restricted conditions. During the Late Ordovician, the extremely restricted nature of ocean circulation on the Upper Yangtze Platform in tandem with enhanced stratification of the water column promoted anoxic conditions favorable for the preservation of organic matter. During Early Silurian time, organic matter accumulation was principally controlled by changes in sea level, which affected terrigenous flux, redox conditions, and the degree of nutrition recycling.

Oxygen isotope analysis of fossil organic matter by secondary ion mass spectrometry

We have developed an analytical procedure for the measurement of oxygen isotope composition of fossil organic matter by secondary ion mass spectrometry (SIMS) at the sub-per mill level, with a spatial resolution of 20–30μm. The oxygen isotope composition of coal and kerogen samples determined by SIMS are on average consistent with the bulk oxygen isotope compositions determined by temperature conversion elemental analysis – isotope ratio mass spectrometry (TC/EA-IRMS), but display large spreads of δ18O of ∼5–10‰, attributed to mixing of remnants of organic compounds with distinct δ18O signatures. Most of the δ18O values obtained on two kerogen residues extracted from the Eocene Clarno and Early Devonian Rhynie continental chert samples and on two immature coal samples range between ∼10‰ and ∼25‰. Based on the average δ18O values of these samples, and on the O isotope composition of water processed by plants that now constitute the Eocene Clarno kerogen, we estimated δ18Owater values ranging between around −11‰ and −1‰, which overall correspond well within the range of O isotope compositions for present-day continental waters. SIMS analyses of cyanobacteria-derived organic matter from the Silurian Zdanow chert sample yielded δ18O values in the range 12–20‰. Based on the O isotope composition measured on recent cyanobacteria from the hypersaline Lake Natron (Tanzania), and on the O isotope composition of the lake waters in which they lived, we propose that δ18O values of cyanobacteria remnants are enriched by about ∼18±2‰ to 22±2‰ relative to coeval waters. This relationship suggests that deep ocean waters in which the Zdanow cyanobacteria lived during Early Silurian times were characterised by δ18O values of around −5±4‰. This study, establishing the feasibility of micro-analysis of Phanerozoic fossil organic matter samples by SIMS, opens the way for future investigations of kerogens preserved in Archean cherts and of the O isotopic composition of ocean water at that period in time.

Petrogenesis of early Silurian intrusions in the Sanchakou area of Eastern Tianshan, Northwest China, and tectonic implications: geochronological, geochemical, and Hf isotopic evidence

ABSTRACTPalaeozoic intrusions in Eastern Tianshan are important for understanding the evolution of the Central Asian Orogenic Belt (CAOB). The Sanchakou intrusions situated in Eastern Tianshan (southern CAOB), are mainly quartz diorite and granodiorite. A comprehensive study of zircon U–Pb ages, zircon trace elements, whole-rock geochemistry, and Lu–Hf isotopes were carried out for the Sanchakou intrusive rocks. LA-ICP-MS zircon U–Pb dating yielded crystallization ages of 439.7 ± 2.5 Ma (MSWD = 0.63, n = 21) for the quartz diorite, and 430.9 ± 2.5 Ma (MSWD = 0.21, n = 21) and 425.5 ± 2.7 Ma (MSWD = 0.04; n = 20) for the granodiorites. These data, in combination with other Silurian ages reported for the intrusive suites from Eastern Tianshan, indicate an early Palaeozoic magmatic event in the orogen. In situ zircon Hf isotope data for the Sanchakou quartz diorite shows εHf(t) values of +11.2 to +19.6, and the two granodioritic samples exhibit similar εHf(t) values from +13.0 to +19.5. The Sanchakou plutons show metaluminous to weakly peraluminous, arc-type geochemical and low-K tholeiite affinities, and display trace element patterns characterized by enrichment in K, Ba, Sr, and Sm, and depletion in Nb, Ta, Pb, and Ti. The geochemical and isotopic signatures indicate that the Sanchakou dioritic and granodioritic magmas were sourced from a subducted oceanic slab, and subsequently underwent some interaction with peridotite in the mantle wedge. Combined with the regional geological history, we suggest the Sanchakou intrusions formed due to the northward subduction of the Palaeo-Tianshan Ocean beneath the Dananhu–Tousuquan arc during early Silurian time.

BIOMARKER CHARACTERISTICS OF POTENTIAL SOURCE ROCKS IN THE JABAL NAFUSAH AREA, NW LIBYA: PETROLEUM SYSTEMS SIGNIFICANCE

The Jifarah Arch of NW Libya is a structurally prominent feature at the eastern end of the regional Talemzane Arch, separating the Ghadamis hydrocarbon province to the south from the offshore Pelagian province to the north. The Arch has experienced a complex structural history with repeated episodes of uplift, exhumation and burial. This paper provides a provisional assessment of its hydrocarbon habitat based on detailed geochemical analyses of potential Triassic, Silurian and Ordovician source rocks encountered by wells drilled in the area.Twenty‐seven core and cuttings samples of marine shales were collected from eight widely‐ dispersed wells and analyzed using standard Rock‐Eval pyrolysis techniques. Kerogen types II‐III were identified in the majority of Triassic samples analysed, indicating a low hydrocarbon generation potential, but oil‐prone Type II kerogen was found in the basal Silurian Tanezzuft Formation and Ordovician Memouniat Formation. The presence of steranes and acyclic isoprenoids suggested variable inputs of algal, bacterial and terrestrial organic matter, while biomarkers including C30‐gammacerane and β–carotene and selected biomarker ratios (Pr/Ph ratio and homohopane index) were used to assess their depositional environment. Results indicate that extended zones with periodic (if not continuous) oxygen‐deficient conditions existed throughout the basin during Late Ordovician and Early Silurian time, favouring the preservation of organic matter.The thermal maturity of the samples was assessed by Rock‐Eval pyrolysis, zooclast reflectance, molecular ratios including C32‐22S/(22S+22R)‐homohopanes, Ts/(Ts+Tm), C29‐steranes and parameters based on the relative abundance of methylphenanthrene, methyldibenzothiophene and methylnaphthalene isomers. The results indicate significant variability in thermal maturity, with Ordovician and Silurian source rocks ranging from 0.6% to 0.7% VRo equivalent increasing to 1.0% locally. These values represent palaeo‐maturities achieved at different times in the past and are considered too low to have generated significant volumes of hydrocarbons directly. However the downdip equivalents of these source rocks in the adjacent Ghadamis Basin contributed to prolific petroleum systems. The absence of large petroleum accumulations on the Jifarah Arch contrasts with the western part of the geologically similar Talemzane Arch, which harbours several giant and supergiant oil and gas fields. This difference is attributed both to the complex structural history of the Jifarah Arch, which permitted post‐charge leakage of palaeo‐accumulations, and stratigraphic migration barriers which restricted migration between Tanezzuft source rocks and Ordovician and Triassic reservoirs.

First record of the early Sheinwoodian carbon isotope excursion (ESCIE) from the Barrandian area of northwestern peri-Gondwana

The delta C-13 record from an early Sheinwoodian limestone unit in the Prague Basin suggests its deposition during the time of the early Sheinwoodian carbon isotope excursion (ESCIE). The geochemical data set represents the first evidence for the ESCIE in the Prague Basin which was located in high latitudes on the northwestern peri-Gondwana shelf during early Silurian times.

Laurentia-derived detritus in the Badger Group of central Newfoundland: deposition during closing of the Iapetus Ocean1This article is one of a series of papers published in CJES Special Issue: In honour of Ward Neale on the theme of Appalachian and Grenvillian geology.2Geological Survey of Canada Contribution 20110273.

The Dunnage zone of central Newfoundland records the closing of an oceanic tract — the Iapetus Ocean. Within this tract, the Red Indian line separates arc terranes developed close to Laurentia (Notre Dame subzone) from those associated with the peri-Gondwanan terrane Ganderia (Exploits subzone). Sandstones and conglomerates of the Badger Group were deposited on the Exploits subzone, southeast of the Red Indian line, from Late Ordovician (Katian) to early Silurian (Llandovery) time. Two samples were collected from the base and top of the Badger Group for detrital zircon U/Pb dating. The lower sample yielded detrital zircon populations with a large statistical peak at ca. 1.0 Ga, and other features characteristic of derivation from Laurentian sources. Paleozoic zircons with ages from Late Cambrian to Late Ordovician were probably derived from the Notre Dame arc on the margin of Laurentia. The upper sample yielded a comparable age distribution, but with a much smaller proportion of Mesoproterozoic relative to Paleozoic detrital zircon. These results date the earliest arrival of Laurentia-derived detritus on the peri-Gondwanan Exploits subzone crust in the early Katian (ca. 455 Ma). However, the absence, in both samples, of Neoproterozoic grains suggests that there was still a seaway separating the Gander margin from arc terranes accreted to Laurentia until at least the middle Llandovery (ca. 436 Ma).

Cambrian to early Silurian ophiolite and accretionary processes in the Beishan collage, NW China: implications for the architecture of the Southern Altaids

AbstractThe mechanism of continental growth of the Altaids is currently under debate between models invoking continuous subduction-accretion or punctuated accretion by closure of multiple ocean basins. We use the Yueyashan–Xichangjing ophiolite belt of the Beishan collage (southern Altaids) to constrain the earliest oceanic crust in the southern Palaeo-Asian Ocean. Five lithotectonic units were identified from S to N: the Huaniushan block, a sedimentary passive margin, the structurally incoherent Yueyashan–Xichangjing ophiolite complex, a coherent sedimentary package and the Mazongshan island arc with granitic rocks. We present a structural analysis of the accretionary complex, which is composed of the incoherent ophiolitic melange and coherent sedimentary rocks, to work out the tectonic polarity. A new weighted mean206Pb–238U age of 533 ± 1.7 Ma from a plagiogranite in the Yueyashan–Xichangjing ophiolite indicates that the ocean floor formed in early Cambrian time. Furthermore, we present new geochemical data to constrain the tectonic setting of the Yueyashan–Xichangjing ophiolite. The Yueyashan–Xichangjing ophiolite was emplaced as a result of northward subduction of an oceanic plate beneath the Mazongshan island arc to the north in late Ordovician to early Silurian time. Together with data from the literature, our work demonstrates that multiple overlapping periods of accretion existed in the Palaeozoic in the northern and southern Altaids. Therefore, a model of multiple accretion by closure of several ocean basins is most viable.

Collisional accretion of a Late Ordovician oceanic island arc, northern Tasman Orogenic Zone, Australia

A distinctive Late Ordovician volcano-sedimentary terrane, embracing the Carriers Well Formation and Everetts Creek Volcanics and dismembered slivers now structurally intercalated in the adjoining Wairuna Formation, is located within the Broken River Province of the northern Tasmanides. It abuts a basement of mafic–ultramafic rocks (Gray Creek Complex) and overlying Early Ordovician deep marine sedimentary and volcanic strata (Judea Formation) which host tonalitic plutons. The terrane lies at the western, inboard-margin of the Camel Creek Subprovince, a broad tract of multiply deformed mid-Paleozoic turbidites with minor basalt and chert variously interpreted as the infill of a backarc basin or an accretionary wedge. U–Pb dates from detrital zircon indicate a maximum Late Silurian age for siliciclastic rocks from the previously undated Wairuna Formation. Geochemistry of volcanic rocks from the volcano-sedimentary terrane show them to be largely of mafic to intermediate compositions of calc-alkaline affinity, comparable with broadly coeval Macquarie Arc volcanic suites of the southern Tasmanides. Trace-element systematics identify a subduction relationship for the volcanic suite and V/Ti employed as a discrimination tool identifies the terrane as representing an oceanic island arc, consistent with its sedimentary facies which include volcaniclastic mass flow deposits, limestone, and radiolarian chert. Continent-derived sandstone in the sedimentary assemblage, confirmed by the ages of detrital zircon from a sandstone sample from the Carriers Well Formation, indicates that the oceanic island arc developed proximal to the Late Ordovician continental margin of East Gondwana. Its nature and location bear on the tectonic setting of the entire Camel Creek Subprovince, for which interpretation as an Early Silurian–Early Devonian accretionary wedge is favoured. Collision of the island arc with the continental margin, and associated deformation of part the intervening oceanic crustal tract, now represented by the Gray Creek Complex and its sedimentary cover (Judea Formation) registers the initiation of subduction accretion in late Early Silurian (Llandoverian) time. It marks early-stage orogenesis in the Broken River Province, accurately timed by stratigraphic relationships in the basinal succession developed in the Graveyard Creek Subprovince immediately to the west of the arc assemblage. Tectonism was regionally developed in north Queensland at this time, coeval with the Benambran Orogeny of the Lachlan Orogen in which the Macquarie Arc was likewise accreted to the East Gondwana margin. Benambran orogenesis marks a general phase of shortening, and removal by subduction, of oceanic crust and inversion of continent-derived overlying sedimentary cover along the East Gondwana margin.

The Llandovery–lowermost Wenlock sequence in the Baltic Sea between Saaremaa and Gotland; subdivision, thicknesses and correlation, based on marine seismic studies

The Llandovery–lowermost Wenlock sequence in the Baltic Sea between Saaremaa and Gotland has been studied by means of high resolution seismic reflection profiling. The number and the positions of the seismic reflectors within this sequence change considerably even within short distances, thus showing a high lateral inconsistency both in lithology and thickness. Stratigraphically two unambiguous (S 1 and S 2) and two roughly fixed trans-Baltic seismic reflectors (S 5 and S 7) enabled us to distinguish the pre-Adavere, the Adavere (S 1–S 2 and S 2–S 5) and the Mustjala seismic units (S 5–S 7) and to follow their east-westerly changes across the Baltic. The seismic signatures and thicknesses of these units undergo a sharp transformation midway Baltic, dividing between the Saaremaa type and the Gotland type of Llandovery–lowermost Wenlock sections. This is due to a short and steep northeast–southwest facies transect that was induced by a well differentiated bathymetry in the intracratonic Palaeobaltic basin, thus clearly distinguishing the shallow-shelf (basinal), the slope (transitional) and the deep-shelf (basinal) areas. The slope is furthermore accentuated by the intensive submarine erosion and channelling during the Late Ordovician and Early Silurian times. Thus, the Saaremaa type of section includes the inner to outer shallow-shelf transect, where the pre-Adavere and Adavere units are decreasing in thickness, and the Mustjala unit is increasing in thickness towards Gotland. In the slope area offshore Gotland, all the Llandovery–lowermost Wenlock units thin out rapidly towards the deep-shelf area in south to southeast and the thickness of the pre-Adavere and Adavere units approach zero. Similar features of submarine erosion on Gotland and around the Estonian Latvian border reveal that an unstable basinal slope, from the point of sediment accumulation, extended over large areas along the shallow-shelf edge of the Palaeobaltic basin during the latest Ordovician and earliest Silurian times. Seismic data suggest that the uppermost unidentified subsurface of the Silurian succession in northern Gotland includes a considerable amount of marlstone layers that are coeval with the Mustjala Member in Estonia.