Early Cambrian Sediments Research Articles

Origin of organic matter and depositional characteristics of early Cambrian Niutitang Formation from South China: New insights using molecular fossils

The early Cambrian Niutitang Formation is broadly developed in South China, especially in the Yangtze region. This research explains the nature of hydrocarbons through bitumen fractions of the early Cambrian sediments of the Niutitang Formation. For this purpose, source rock samples from two diverse outcrop sections are utilized for total organic carbon content (TOC), solvent extraction, and gas chromatography–mass spectrometry (GC–MS). Results show a lower quantity of extractable organic matter in these older sediments because of higher maturation history. The presence of monomethyl alkanes suggests the contribution of prokaryotic organisms, whereas the presence of hopanoids and C27–C29 steranes shows the occurrence of eukaryotic algal sources in organic matter. Likewise, C30‐4‐methyl sterane, dinosteranes, and ß‐carotene also suggested incorporating prokaryotic and eukaryotic sources during the early Cambrian period. Various hopanoid parameters, alkylated aromatic isomers, triaromatic steroids, and vitrinite reflectance via methyl‐phenanthrene index reveal mature to higher thermal evolution levels of these lower Palaeozoic sediments. Similarly, a higher abundance of polyaromatic pyrene and fluoranthene indicates mature organic matter, and their presence could be due to hydrothermal action. The higher gammacerane index, lower pristine/phytane, and the presence of C30 dimethyl steranes indicate the anoxic saline sedimentary condition throughout the deposition of these lower Palaeozoic Niutitang Formation. The early Cambrian Niutitang Formation is deposited in an oxygen‐deficient environment and contains an adequate amount of mature‐high mature organic matter that could have the potential to produce gaseous hydrocarbons.

Tonian and Cryogenian – Early Cambrian sedimentation in NW India: Implications on the transition from Rodinia to Gondwana

The Tonian Punagarh-Sindreth and Cryogenian – early Cambrian Marwar sequences in NW India encompass a geological record that could provide vital information for working out the tectonic evolution of this region and a better understanding of the Rodinia to Gondwana transition. The Tonian Punagarh and Sindreth sub-basins received a dominantly felsic detritus with negligible sorting of heavy minerals and mild to weak chemical weathering conditions. The clastic compositions and geochemical characteristics of the Punagarh and Sindreth groups suggest a back-arc basin setting and the detritus sourced from a volcanic arc and cratonic interior region. The Punagarh basin was proximal to the craton while the Sindreth basin was close to an arc system. In contrast, the Cryogenian – early Cambrian Marwar Supergroup clastic sequence contains mature quartz arenite whose high CIA (77.8–94.8) and low ICV (0.18–1.00) values suggest a strong chemical weathering in the source region and noteworthy physical sorting during transportation and sedimentation. An abundance of quartz grains (87–94%), enrichment of Zr, and detritus predominantly derived from the cratonic basement indicate deposition of Marwar sediments in a tectonically stable basin, temporally coinciding with the Gondwana assembly. Collectively, the ∼ 760 Ma active continental margin in NW India, documented by the provenance and tectonic setting of the Punagarh and Sindreth basins, is in agreement with the subduction of the peripherical Rodinia supercontinent during its breakup. On the other hand, the passive continental margin sedimentation in Marwar Supergroup points toward an open sea between NW India and western Gondwana during the Gondwana assembly.

Signals of combined chromium–cadmium isotopes in basin waters of the Early Cambrian – Results from the Maoshi and Zhijin sections, Yangtze Platform, South China

The combination of authigenic chromium and cadmium stable isotopes in marine sedimentary archives enables reconstruction of the redox conditions and levels of primary productivity in past oceans and basins. The Ediacaran to Cambrian Nanhua Basin (Yangtze Platform, South China) and its sedimentary sequences have been studied intensively in the past with respect to investigating the effects of post-Snowball Earth glaciations on the oxygenation of Earth's atmosphere, and intimately related, on the consequences of climate changes on the evolution of the ocean environment and of life during the Precambrian-Cambrian transition. Following recent propositions of using cadmium isotopes as a novel proxy for reconstructing the extent of primary productivity in paleooceans, we here present results from a combined cadmium (Cd)‑chromium (Cr) isotope study on metalliferous black shale, black shale and phosphorite sediments deposited during the Early Cambrian Niutitang Formation at the Maoshi and Zhijin sections. Results point toward strongly oxidized and highly productive surface water layers in the Nanhua Basin during this period. The samples have strongly positively fractionated δ114Cd and δ53Cr values up to +0.6‰ and + 1.4‰, respectively, similar to such values from carbonaceous sediments in modern oceans. The association of Cd with sulfides in the sediments, together with high Cd/TOC ratios particularly in the metalliferous black shales, implies a sulfide-controlled enrichment of Cd under restricted euxinic conditions. The lower Cd/TOC values in phosphorites and barren black shales and negatively fractionated δ114Cd values down to −0.33‰ point to less effective precipitation of Cd under more suboxic conditions as likely prevailing in an open shallow shelf. The Cr content in the sediments is mostly close to average shale, and the δ53Cr values are little fractionated in the 0–0.2‰ range, corroborated by flat shale-like rare earth element + yttrium (REE + Y) patterns. However, some metal-rich shale samples have clearly authigenic Cr isotope signatures with up to +1.4‰ δ53Cr, and the authigenic Cr component in the phosphorite samples is around 1‰ δ53Cr, indicating oxic surface waters. The latter sediments also depict seawater-like, middle REE enriched REE + Y patterns with distinct negative Ce and positive Y anomalies indicative of an oxygenated surface water layer, and with positive Eu anomalies which they likely received during phosphatogenesis in the euxinic bottom water environment. In accord with previous studies reporting on extreme trace metal enrichments (Mo, Ni, V, Hg, etc.) in these Early Cambrian sediments, our Cd and Cr isotope signatures favor a scenario of a strongly stratified basin in which high primary productivity thrived in an oxidized surface water layer, potentially as a result of increased nutrient supply from a strongly weathering continental hinterland in the aftermath of the last Snowball Earth glaciations in the Ediacaran.

Chronological and geochemical constraints on the pre-variscan tectonic history of the Erzgebirge, Saxothuringian Zone

A combined U–Pb zircon geochronological and whole-rock isotopic and geochemical study has been carried out on high-grade orthogneiss, meta-basite, and meta-sediments from the Erzgebirge. The results indicate multiple pulses of Ediacaran–Ordovician magmatism in a transitional volcanic-arc to rift-basin setting. Orthogneiss from high-pressure nappes exhibit a step-like pattern of inherited zircon ages and emplacement ages of 500–475 Ma. In contrast, granite gneiss from the medium-pressure core of the Erzgebirge is characterised by three pulses of magmatism in the Early Cambrian, Late Cambrian, and Early Ordovician. A trend of decreasing Th/U ratios in zircon is observed to c.500 Ma, after which significant increases in the trend and variability of the data is inferred to mark the transition from arc-related to rift-related magmatism. Sediments deposited in the Early Cambrian have continental island arc affinity. Major detrital peaks in the Ediacaran and subordinate Tonian, Palaeoproterozoic, and Neoarchaean data are consistent with an Avalonian-Cadomian Arc and West African Craton derivation. The Early Cambrian sediments were locally reworked by a thermal event in the Ordovician resulting in leucocratic banding and recorded in Ordovician zircon rims characterised by systematically lower Th/U ratios. Ptygmatically folded leucocratic bands containing Ordovician zircon rims, associated with low Th/U ratios, are further observed in the granite gneiss core of the Erzgebirge. Variscan ages are rare, except in a fine-grained high-pressure micaschist, which contains exclusively small, structure-less, zircon with a weighted mean age of 350 ± 2 Ma. These data, along with a re-evaluation of previously published data, have been interpreted as the product of flattening subduction during the Early Cambrian; followed by the opening of slab windows in the Late Cambrian; and finally delamination in the Early Ordovician. Delamination of the orphaned slab led to asthenospheric upwellings triggering extension, bimodal magmatic pulses, recycling of fertile crust, high-temperature metamorphism, and cratonisation of relatively young crust.

Earth\u2019s youngest banded iron formation implies ferruginous conditions in the Early Cambrian ocean

It has been proposed that anoxic and iron-rich (ferruginous) marine conditions were common through most of Earth history. This view represents a major shift in our understanding of the evolution of marine chemistry. However, thus far, evidence for ferruginous conditions comes predominantly from Fe-speciation data. Given debate over these records, new evidence for Fe-rich marine conditions is a requisite if we are to shift our view regarding evolution of the marine redox landscape. Here we present strong evidence for ferruginous conditions by describing a suite of Fe-rich chemical sedimentary rocks—banded iron formation (BIF)—-deposited during the Early Cambrian in western China. Specifically, we provide new U-Pb geochronological data that confirm a depositional age of ca. 527 Ma for this unit, as well as rare earth element (REE) data are consistent with anoxic deposition. Similar to many Algoma-type Precambrian iron formations, these Early Cambrian sediments precipitated in a back-arc rift basin setting, where hydrothermally sourced iron drove the deposition of a BIF-like protolith, the youngest ever reported of regional extent without direct links to volcanogenic massive sulphide (VMS) deposits. Their presence indicates that marine environments were still characterized by chemical- and redox-stratification, thus supporting the view that—despite a dearth of modern marine analogues—ferruginous conditions continued to locally be a feature of early Phanerozoic seawater.

Gyrolithes from the Ediacaran-Cambrian boundary section in Fortune Head, Newfoundland, Canada: Exploring the onset of complex burrowing

The beginning of the Cambrian explosion is characterized by the onset of infaunalization and the appearance of systematic patterns of burrowing. The trace fossil Gyrolithes is common in the Ediacaran-Cambrian Global Stratotype Section and Point, where it shows a higher diversity and burrow depth than previously reported from any Cambrian spiral vertical burrows. Two ichnospecies are present: G. scintillus isp. nov. exhibits a small burrow radius to whorl radius ratio, whereas G. gyratus (Hofmann) exhibits an exceptionally large ratio that formerly led to its identification as an aberrant ichnospecies of Skolithos. The helical morphology of these Cambrian Gyrolithes is interpreted as having served two purposes: as an anchor in a relatively high-energy environment, and as an optimal shape for maximizing surface area for bacterial gardening. These shallow-marine gardening burrows share a similar feeding strategy as graphoglyptids, suggesting that shallow early Cambrian sediments may have been relatively poor in organics and thus further supporting the model for onshore-offshore migration of gardening burrows.

Reconstruction of early Cambrian ocean chemistry from Mo isotopes

The Neoproterozoic–Cambrian transition was a key time interval in the history of the Earth, especially for variations in oceanic and atmospheric chemical composition. However, two conflicting views exist concerning the nature of ocean chemistry across the Precambrian–Cambrian boundary. Abundant geochemical evidence suggests that oceanic basins were fully oxygenated by the late Ediacaran, while other studies provide seemingly conflicting evidence for anoxic deep waters, with ferruginous conditions [Fe(II)-enriched] persisting into the Cambrian. Here, two early Cambrian sedimentary platform and shelf-slope sections in South China were investigated to trace early Cambrian ocean chemistry from Mo isotopes. The results reveal that early Cambrian sediments deposited under oxic to anoxic/euxinic conditions have δ98/95Mo values ranging from −0.28‰ to 2.29‰, which suggests that early Cambrian seawater may have had δ98/95Mo values of at least 2.29‰, similar to modern oceans. The heaviest and relatively homogeneous δ98/95Mo values were recorded in siltstone samples formed under completely oxic conditions, which is considered that Mn oxide-free shuttling was responsible for such heavy δ98/95Mo value. Further, combined with Fe species data and the accumulation extent of Mo and U, the variation of δ98/95Mo values in the two studied sections demonstrate a redox-stratified ocean with completely oxic shallow water and predominantly anoxic (even euxinic) deeper water having developed early on, which eventually became completely oxygenated. This suggests that oceanic circulation at the time became reorganized, and such changes in oceanic chemistry may have been responsible for triggering the “Cambrian Explosion” of biological diversity.

The geology of the northern tip of the Arabian–Nubian Shield

Recently, a detailed (1:50,000) geological map of the Elat area, southern Israel was published. Attached to this map is a stratigraphic table of the Neoproterozoic metamorphic–magmatic complex of the study area. The Neoproterozoic basement in the Elat area encapsulates the Arabian Nubian Shield (ANS) geologic evolution. Uranium–Lead and Lead–Lead zircon ages, included in previous studies and referred to in this paper, reveal that these rocks were formed during more than 300 million years of Neoproterozoic time. The major process controlling the formation of the ANS as part of the East African Orogen is the closure of the Mozambique Ocean. The first orogenic phase in the Elat area, represented by the metamorphic rocks, includes the development of an island arc, erosion of the islands and deposition, and metamorphism. This event took place between ∼950Ma and 780–790Ma. Elat Schist, the oldest metamorphic rock in the area, was deformed and then intruded by quartz dioritic and granitic plutons that were later deformed and metamorphosed. The amphibolite metamorphic rock facies indicate metamorphic conditions of up to 650°C and between 4 and 5kbar. The peak of the metamorphic event was most probably before 750Ma. A gradual change from compressional to extensional stress regime is evidenced by emplacement andesitic magnesium-rich dykes dated to 705Ma that were later metamorphosed to schistose dykes at a greenschist metamorphic facies. The second orogenic phase (terrane amalgamation, main shaping of crust) was associated with the emplacement of large volumes (>50% of area) of calc-alkaline intrusions in a post-collision setting. These very last stages of metamorphism and deformation are characterized by intrusion of ∼630Ma granitoids exhibiting some foliation. Pluton emplacement continued also after the end of deformation. Exhumation and transition to an extensional regime is recorded by the intrusion of shallow alkaline granites in ∼608Ma which were accompanied in ∼609Ma by rhyolite, andesite and composite dykes. The last magmatic event in the Elat area is represented by the volcano-conglomeratic series comprising rhyolites, basalts, andesites, hypabyssal intrusions of monzonite and syenite and conglomerates. The conglomerates, dated to about 590Ma, are the products of a major erosion phase in which about 12,000m of the section were removed. These conglomerates were intruded by 585Ma rhyolite, andesite and composite dykes. The Neoproterozoic basement is truncated by a peneplain whose age, post 532Ma, is constrained by the age of the youngest eroded dolerite dykes. This Early Cambrian peneplain was associated with erosion of 2000m of the section and by chemical weathering. Three major breaks in Neoproterozoic magmatic activity are recognized: the first, occurred in Cryogenian time, lasted ∼60 million years after the amphibolite facies metamorphism and before emplacement of the calc alkaline plutons, separating the first and the second orogenic phases; the second break between the orogenic and the extensional phases occurred in early Ediacaran time, encompassed ∼20 million years between the emplacement of the calc-alkaline and alkaline plutonic rocks and rhyolite, andesite and the composite dykes; and the third, ∼50Ma break, occurred between the emplacement of the last felsic intrusions at ∼585Ma and intrusion of the dolerite dykes in 532Ma, before the Early Cambrian peneplain developed.The great lateral extension of the Cambrian to Eocene sedimentary rocks and their slow facies and thickness changes suggest a stable flat platform area at the northern tip of the ANS. Early Cambrian sedimentation began with fluviatile subarkoses of the Amudei Shlomo Formation. It was overlain by an Early to Middle Cambrian transgressive–regressive lagoonal cycle of dolostones, sandstones, and siltstones of the Timna Formation. Then Middle Cambrian subarkoses and siltstones of the Shehoret Formation and the quartz arenite of the Netafim Formation were deposited in a coastal, intertidal environment representing the southern transgression of a Cambrian ocean.

A suspension-feeding anomalocarid from the Early Cambrian

Large, actively swimming suspension feeders evolved several times in Earth's history, arising independently from groups as diverse as sharks, rays and stem teleost fishes, and in mysticete whales. However, animals occupying this niche have not been identified from the early Palaeozoic era. Anomalocarids, a group of stem arthropods that were the largest nektonic animals of the Cambrian and Ordovician periods, are generally thought to have been apex predators. Here we describe new material from Tamisiocaris borealis, an anomalocarid from the Early Cambrian (Series 2) Sirius Passet Fauna of North Greenland, and propose that its frontal appendage is specialized for suspension feeding. The appendage bears long, slender and equally spaced ventral spines furnished with dense rows of long and fine auxiliary spines. This suggests that T. borealis was a microphagous suspension feeder, using its appendages for sweep-net capture of food items down to 0.5 mm, within the size range of mesozooplankton such as copepods. Our observations demonstrate that large, nektonic suspension feeders first evolved during the Cambrian explosion, as part of an adaptive radiation of anomalocarids. The presence of nektonic suspension feeders in the Early Cambrian, together with evidence for a diverse pelagic community containing phytoplankton and mesozooplankton, indicate the existence of a complex pelagic ecosystem supported by high primary productivity and nutrient flux. Cambrian pelagic ecosystems seem to have been more modern than previously believed.

Origin and evolution of Avalonia: evidence from U–Pb and Lu–Hf isotopes in zircon from the Mira terrane, Canada, and the Stavelot–Venn Massif, Belgium

Laser ablation inductively coupled plasma mass spectrometry U–Pb and Lu–Hf isotope analyses of detrital zircon from Neoproterozoic–Cambrian clastic sedimentary rocks in the Mira terrane (Cape Breton Island, Nova Scotia, Canada; West Avalonia) and the Stavelot–Venn Massif (East Belgium; East Avalonia) support deposition on an originally coherent microcontinent. Crustal evolution trends defined by ϵHf (t) values varying with age reflect juvenile magma production in the source continent at 1.2–2.2 and 2.4–3.1 Ga. Mixing of juvenile and recycled crust in continental magmatic arcs is recognized at 0.5–0.72, 1.4–1.7, 1.8–2.2 and 2.4–2.7 Ga. These results concur with the crustal evolution in Amazonia, the likely parent craton. Crustal evolution in Avalonia is recorded in detrital and magmatic zircon from Neoproterozoic arcs (680–550 Ma). Positive ϵHf (t) values suggest juvenile input and mixing with recycled crust. Most negative ϵHf (t) values represent recycling of predominantly Mesoproterozoic underlying crust. Avalonian arc magmatism was followed by late Neoproterozoic–early Cambrian sedimentation in various belts in West Avalonia. These belts were juxtaposed by strike-slip during late early Cambrian deposition in a rift basin. The youngest detrital zircon population ( c . 517 Ma) probably represents synrift magmatism before break-up of Avalonia. Migmatization at 406 ± 2 Ma in a xenolith from the East Avalonian crust reflects post-collisional heating. Supplementary materials: Details of sample locations and analytical results are available at www.geolsoc.org.uk/SUP18641 .

Occurrence of helically coiled microfossil Obruchevella in the Owk Shale of the Kurnool Group and its significance

The present study reports occurrence of helically coiled microfossil Obruchevella Reitlinger from the Owk Shale of the Kurnool Group from the peninsular India. The age of the Kurnool Group is poorly constrained due to the absence of direct radiometric dating and meager palaeobiological data. Occurrence of Obruchevella is considered as a typical Vendian marker genus recorded mostly from close to the Precambrian–Cambrian boundary successions. Hence, the present assemblage is important to ascertain the age of the basin. In the Owk Shale, four species of Obruchevella, viz., O. delicata, O. parva, O. minor and O. valdaica are recorded as organic walled microfossils. Among them O. valdaica is the largest in terms of size parameters. On the global scale, the recovered species occur in the Late Neoproterozoic to Early Cambrian sediments. Therefore, the occurrence of microfossil Obruchevella in the Owk Shale and known burrow structures in the Narji Limestone suggest Ediacaran age close to the Cambrian for the Kurnool Basin and challenges the recently assigned Mesoproterozoic age of the basin.

Basin geometry and salt diapirs in the Flinders Ranges, South Australia: Insights gained from geologically-constrained modelling of potential field data

The Adelaide Basin in Australia is a complex of late Neoproterozoic to Early Cambrian rift and sag basins which was inverted during the Cambro–Ordovician Delamerian Orogeny. The deposition of evaporitic sediments during the earliest stage of basin development in the late Neoproterozoic (Willouran age) played a major role in the subsequent tectonic evolution of the basin. Previous studies have shown that early mobilization, vertical transport and withdrawal of the evaporites influenced the sedimentation during the late Neoproterozoic and Early Cambrian. The evaporites also influenced deformation during the inversion of the basin and the development of the Delamerian fold and thrust belt. However, the control exerted by basement structures in the deposition of the evaporitic beds and the role of these tectonic structures in the later inversion of the basin have been poorly constrained. In this work, we use a combination of published and original geological observations along with the interpretation of potential field datasets (total magnetic intensity and Bouguer anomaly data) to better constrain the geology of the basin at depth. We construct two and a half dimensional forward models of the potential field data along selected profiles across the Adelaide Basin. These models are constrained by the geology at the surface, drill hole data and measured petrophysical properties (specific gravity and magnetic susceptibility). We achieved the best fit between observed and modelled potential fields with a model favouring thick-skinned deformation, where the diapirs are not randomly distributed, but located directly above basement-penetrating normal faults. Furthermore, these normal faults were probably active during the sedimentation of the late Neoproterozoic and Early Cambrian sediments, and underwent partial or total inversion during the Cambro–Ordovician Delamerian Orogeny. Mobilisation and withdrawal of the evaporites was therefore initiated and facilitated by the extension coeval with the opening of the basin, and continued during the subsequent Delamerian Orogeny.

Late Proterozoic to Early Cambrian sedimentation and magmatism at the western Gondwana margin: metasedimentary rocks in the Sierras Norte de Cordoba (Argentina)

Late Proterozoic to Early Cambrian sedimentation and magmatism at the western Gondwana margin: metasedimentary rocks in the Sierras Norte de Cordoba (Argentina)

Testing long‐term patterns of basin sedimentation by detrital zircon geochronology, Centralian Superbasin, Australia

ABSTRACTDetrital zircon geochronology of Neoproterozoic to Devonian sedimentary rocks from the Georgina and Amadeus basins has been used to track changes in provenance that reflect the development and inversion of the former Australian Superbasin. Through much of the Neoproterozoic, sediments appear to have been predominantly derived from local sources in the Arunta and Musgrave inliers. Close similarities between the detrital age signatures of late Neoproterozoic sedimentary rocks in the two basins suggests that they were contiguous at this time. A dominant population of 1.2–1.0 Ga zircon in Early Cambrian sediments of the Amadeus Basin reflects the uplift of the Musgrave Inlier during the Petermann Orogeny between 560 and 520 Ma, which shed a large volume of detritus northwards into the Amadeus Basin. Early Cambrian sedimentary rocks in the Georgina Basin have a much smaller proportion of 1.2–1.0 Ga detritus, possibly due to the formation of sub‐basins along the northern margin of the Amadeus Basin which might have acted as a barrier to sediment transfer. An influx of 0.6–0.5 Ga zircon towards the end of the Cambrian coincides with the transgression of the Larapintine Sea across central Australia, possibly as a result of intracratonic rifting. Detrital zircon age spectra of sedimentary rocks deposited within this epicontinental sea are very similar to those of coeval sedimentary rocks from the Pacific Gondwana margin, implying that sediment was transported into central Australia from the eastern continental margin. The remarkably consistent ‘Pacific Gondwana’ signature of Cambro‐Ordovician sediments in central and eastern Australia reflects a distal source, possibly from east Antarctica or the East African Orogen. The peak of the marine incursion into central Australia in the early to mid Ordovician coincides with granulite‐facies metamorphism at mid‐crustal depths between the Amadeus and Georgina basins (the Larapinta Event). The presence of the epicontinental sea, the relative lack of a local basement zircon component in Cambro‐Ordovician sedimentary rocks and their maturity suggest that metamorphism was not accompanied by mountain building, consistent with an extensional or transtensional setting for this tectonism. Sediments deposited at ∼435–405 and ∼365 Ma during the Alice Springs Orogeny have detrital age signatures similar to those of Cambro‐Ordovician sedimentary rocks, reflecting uplift and reworking of the older succession into narrow foreland basins adjacent to the orogen.

Time constraints on the Famatinian and Achalian structural evolution of the basement of the Sierra de San Luis (Eastern Sierras Pampeanas, Argentina)

Geochronological data pertaining to the structural evolution of the Sierra de San Luis provide important insights into the geodynamic history along the southwestern margin of Gondwana. In the Pringles metamorphic complex, metamorphic fabrics (S 1) were affected by two folding events (D 2 and D 3) related to the Ordovician approach of the Cuyania terrane. Contemporary formations of high-temperature shear zones record a prominent east-side-up displacement. Resumption of compression due to the Achalian collision with the Chilenia terrane was accommodated by the reactivation of the Famatinian high-temperature shear zones in greenschist facies conditions. K–Ar Ms ages point to their activity up to the Early Carboniferous. The post-Pampean structural evolution of the Pringles metamorphic complex is supported by new Sm–Nd and 207Pb/ 206Pb data, which agree with previously proposed early Cambrian sedimentation of the psammopelitic precursors. A Sm–Nd mineral isochron, together with published SHRIMP U–Pb zircon ages, bracket the emplacement of mafic and ultramafic intrusions that control the granulite facies metamorphism between 506 and 478 Ma. A late Cambrian emplacement of the crustal-derived Paso del Rey pluton is suggested by a 207Pb/ 206Pb zircon age at 491 ± 19 Ma. The syn-D 2 emplacement of these granitoids indicates that the D 1 to D 2 structural evolution predates the generally assumed Middle Ordovician accretion of the Precordillera/Cuyania terrane. K–Ar Hbl, Ms, and Bt ages and some Rb–Sr mica data record the cooling after the Famatinian metamorphic peak. Ms ages from large Ms booklets suggest a common cooling of the basement of the sierra at approximately 445 Ma, whereas normal-sized muscovites from gneissic rocks (K–Ar ages of ∼380 Ma) indicate slow cooling of the Pringles metamorphic complex with respect to the other basement domains. K–Ar Bt ages between 360 and 340 Ma capture cooling below approximately 300 °C of the basement. Differential cooling is interpreted to reflect the Achalian tectonic cycle as an event separate from the Famatinian process.

Inherited arc signature in Ediacaran and Early Cambrian basins of the Ossa-Morena Zone (Iberian Massif, Portugal): Paleogeographic link with European and North African Cadomian correlatives

Geochemical data from clastic rocks of the Ossa-Morena Zone (Iberian Massif) show that the main source for the Ediacaran and the Early Cambrian sediments was a recycled Cadomian magmatic arc along the northern Gondwana margin. The geodynamic scenario for this segment of the Avalonian-Cadomian active margin is considered in terms of three main stages: (1) The 570–540 Ma evolution of an active continental margin evolving oblique collision with accretion of oceanic crust, a continental magmatic arc and the development of related marginal basins; (2) the Ediacaran–Early Cambrian transition (540–520 Ma) coeval with important orogenic magmatism and the formation of transtensional basins with detritus derived from remnants of the magmatic arc; and (3) Gondwana fragmentation with the formation of Early Cambrian (520–510 Ma) shallow-water platforms in transtensional grabens accompanied by rift-related magmatism. These processes are comparable to similar Cadomian successions in other regions of Gondwanan Europe and Northwest Africa. Ediacaran and Early Cambrian basins preserved in the Ossa-Morena Zone (Portugal and Spain), the North Armorican Cadomian Belt (France), the Saxo-Thuringian Zone (Germany), the Western Meseta and the Western High-Atlas (Morocco) share a similar geotectonic evolution, probably situated in the same paleogeographic West African peri-Gondwanan region of the Avalonian-Cadomian active margin.

Granite production in the Delamerian Orogen, South Australia

In the South Australian sector of the Cambro-Ordovician Ross–Delamerian Orogen, granites range in age from Mid-Cambrian to Early Ordovician. Their occurrence is largely confined to deep, Early Cambrian, sediment-filled basins where they are associated with mafic rocks. The syntectonic suites have compositions forming a continuum between I- and S-type granites. After the cessation of convergent deformation at c . 490 Ma an abrupt transition to a bimodal magmatic association of mafic intrusions and felsic granites and volcanic rocks of S- and A-type affinities occurred. As exposed on the south coast of Kangaroo Island, S-type granite originated as in situ partial melts of the Early Cambrian sediments locally intruded by either mafic magmas or I–S granite magmas. These migmatite complexes were mingled with intrusions from the magmas that provided the underlying heat sources. Also on Kangaroo Island, composite S-type rhyodacite–dolerite dykes indicate that crustal melting involved mantle-derived melts. Field observations, major and trace element data and Nd–Sr isotopic data indicate that granite magmas in this fold belt result from mixing of crustal and mantle source components, and from fractional crystallization (AFC-type processes). Whereas the Nd–Sr compositions of granite suites from the Delamerian Orogen form a continuous geochemical trend between the crust and the mantle melts, the A- and I-types cluster towards the mantle endmember and the S-types towards the crustal endmember. This dichotomy reflects three granite magma production situations: (1) lower-crustal mafic magma chambers that are contaminated by, and mingled with, melts of the local metasediments producing I-type magmas; (2) crustal melts formed in the heated zones above upwelling mantle or close to mafic or I-type granite intrusions producing S-type magmas; (3) upper-crustal mafic intrusions where closed-system fractionation dominates to produce A-type granite. The extent of fractionation and crustal assimilation varied progressively through the c . 30 Ma deformation history (514–485 Ma) of this orogen. Importantly in this sector of the Ross–Delamerian Orogen, the crustal endmember is represented only by the Cambrian basin sedimentary fill (Kanmantoo Group) and expressly excludes the older Precambrian crust.

Palaeomagnetic study of Vendian and Early Cambrian rocks of South Siberia and Central Mongolia: was the Siberian platform assembled at this time?

A palaeomagnetic study of Vendian and Early Cambrian sediments from the Angara block of the Siberian platform: Shaman (52.08°N, 108.83°E) and Minya (58.0°N, 110.0°E) Formations, and the Tuva-Mongolian block: Tsagan-Olom and Bayan-Gol Formations (46.76°N, 96.37°E) isolated three different components of magnetization through thermal demagnetization. The stable high-temperature characteristic remanence directions show both normal and reverse polarities. The mean palaeopoles computed after these high-temperature components are: 32.0°S/71.1°E (dp/dm=6.9°/13.8°) for the Vendian Shaman Formation (10 sites, 80 samples), 33.7°S/37.2°E (dp/dm=8.6°/14.7°) for the Vendian Minya Formation (12 samples), 22.8°S/28.4°E (dp/dm=10.8°/21.6°) for the Vendian Tsagan-Olom Formation (4 sites, 25 samples) and 21.4°S/167.1°E (dp/dm=9.6°/19.1°) for the Early Cambrian Bayan-Gol Formation (6 sites, 49 samples). From a compilation of Vendian and Early Cambrian palaeopoles from the Anabar, Angara and Aldan blocks of the Siberian platform and Tuva-Mongolia block, we propose a model where these blocks were situated in an equatorial to low south palaeolatitude position, with their present-day southern boundaries facing the north pole. From the analysis of the scatter of these poles, we conclude that the Siberian platform might not have fully amalgamated by this time, and that significant rotations occurred after the Early Cambrian. Our new palaeopoles for the Tuva-Mongolia block, together with previously published ones, show that this block was already adjacent to Siberia by the Vendian and Early Cambrian. We propose that the large counterclockwise rotation of the Tuva-Mongolia block with respect to Angara block could mark the end of the closure of the part of the Palaeo-Asian ocean separating these two blocks, and could account for the occurrence of Vendian-Early Cambrian ophiolites in the region.

True polar wander, a supercontinental legacy : Evans D.A., Earth and Planetary Science Letters, 1998, 157/1–2 (1–8)

A palaeomagnetic study is reported of reddened facies (Fengtai Formation) of Neoproterozoic glacial rocks which underlie Early Cambrian rocks with disconformity in the Huabei (North China/Sino-Korean) Block. The diamictite (preferred age 620-600 Ma) carries a dual polarity remanence residing in hematite of the red matrix. The mean direction derived from 62 samples is DI = 205.9− 32.4° (α95 = 3.9°) yielding a pole position at 233°E, 62°N. Tests on the matrix deformed beneath dropstones suggest that remanence was fixed before full compaction, although clasts near the base of the formation are largely overprinted. Overlying Early Cambrian sediments of the Houjiashan and Yutaishan formations have a similar remanence also of dual polarity (DI = 205.5− 32.1°, α95 = 3.9°, 32 samples). The magnetisation in the diamictite is therefore interpreted to have been acquired during loading by the ice sheet and/or the overlying Cambrian succession. Red shales from the Liulaobei Formation (∼890-840 Ma) near the base of the Neoproterozoic succession in the Huabei Block yield a contrasting remanence of DI = 59.475.3° (α95 = 7.1°, 19 samples) equivalent to a pole position at 150°E, 43°N. Pole positions from this study accord with Lower-Middle Cambrian poles from the Australian and South China Blocks with North China sited adjacent to northeastern Australia in accordance with recent biogeographic and palaeogeographic models. Although the palaeolatitude derived from the Fengtai diamictite (17°) is Cambrian in age and probably later than the glaciation, the correlation with Australia implies that glaciation in North China took place in low palaeolatitudes (∼20°) and reinforces the view that late Neoproterozoic glaciation, at least at this perimeter of Gondwana, occurred at low latitudes. Neoproterozoic-Cambrian poles from North China, South China and Australia fail to conform to the popular Rodinia reconstruction with the latter blocks adjacent to western North America and also fail to support the view that Gondwana formed by the fusion of widely separated eastern and western segments during Pan African orogeny. Instead they accord to poles from Africa and South America in a precursor of Gondwana (Protogondwana). The subsequent Palaeozoic derivation of this supercontinent was probably achieved by intracontinental strike-slip motion during Pan African deformation following extinction of the Afro-Arabian arc.

An isotopic biogeochemical study of Neoproterozoic and Early Cambrian sediments from the Centralian Superbasin, Australia

Organic matter from Neoproterozoic and Early Cambrian sediments of the Amadeus and Officer basins of the Centralian Superbasin, Australia, has been studied for biomarker distributions and the carbon isotopic compositions of kerogen and individual hydrocarbons. These sediments represent both shallow and deep water marine facies in the older sections and marine and saline lacustrine carbonate deposits in the Cambrian. Hydrocarbon biomarker patterns were found to be quite consistent with the known sedimentary environments and provide valuable insights into the biogeochemical changes which accompanied the transition from a microbially-dominated ocean to the early stages of metazoan radiation. In particular, carbon isotopic data for n-alkyl and isoprenoid lipids presented here, and in earlier studies, showed a reversal in carbon isotopic ordering between the Proterozoic and Phanerozoic. By comparison with the δ 13C of kerogen, n-alkyl lipids from deep-water Proterozoic sediments were enriched in 13C and appear to be derived mainly from heterotrophs whilst open marine Phanerozoic counterparts are 13C depleted and evidently derived mainly from autotrophs. Data from the samples studied here are consistent with a model invoking a change in the redox structure of the ocean, possibly aided by the innovation of faecal pellets.