Early Solar System Research Articles

Slow cooling during crystallisation of barred olivine chondrules

Barred olivine (BO) chondrules are small ferromagnesian silicate igneous droplets with unique dendritic textures that are considered to have formed in the early solar system during one or more brief high-temperature episodes, followed by rapid cooling in a gas. Rapid cooling rates of 100–7200 °C/h during chondrule formation have been proposed based on experiments attempting to reproduce BO crystal textures. However, the BO texture has never truly been reproduced under such rapid cooling conditions. Here, we experimentally show that true BO textures can be produced either after rapid cooling (>50 °C/h) following by reheating step or by cooling rates slower than 10 °C/h. Regardless of the thermal history considered, the chemical compositions of glass inclusions trapped within olivines of BO chondrules imply a final slow cooling rate one to two orders of magnitude below previous estimates. Such slow cooling rates are consistent with those estimated for plagioclase-bearing porphyritic chondrules and magmatic type-B Ca-Al-rich inclusions, suggesting that slow cooling rates are common to all similar chondritic objects.

Recent Advances in our Understanding of Water and Aqueous Activity in Chondrites

Water played a critical role in the evolution of rocky material and planetesimals in the early Solar System. Many primitive asteroids (the sources of chondrites) accreted a significant amount of water ice and were affected by aqueous alteration and/or fluid-assisted metamorphism. These secondary parent body processes have strongly modified the primary mineralogy of chondrites in favor of a wide diversity of secondary phases that formed by interaction with water. The mineralogical and isotopic characterization of these secondary phases in chondrites and returned samples from hydrous asteroids Ryugu and Bennu can help us reconstruct the dynamical evolution of water in the early Solar System and understand the timing and mechanisms of aqueous alteration on hydrous asteroids.

Comets in Context: Comparing Comet Compositions with Protosolar Nebula Models

Comets provide a valuable window into the chemical and physical conditions at the time of their formation in the young solar system. We seek insights into where and when these objects formed by comparing the range of abundances observed for nine molecules and their average values across a sample of 29 comets to the predicted midplane ice abundances from models of the protosolar nebula. Our fiducial model, where ices are inherited from the interstellar medium, can account for the observed mixing ratio ranges of each molecule considered, but no single location or time reproduces the abundances of all molecules simultaneously. This suggests that each comet consists of material processed under a range of conditions. In contrast, a model where the initial composition of disk material is “reset,” wiping out any previous chemical history, cannot account for the complete range of abundances observed in comets. Using toy models that combine material processed under different thermal conditions, we find that a combination of warm (CO-poor) and cold (CO-rich) material is required to account for both the average properties of the Jupiter-family and Oort cloud comets, and the individual comets we consider. This could occur by the transport (either radial or vertical) of ice-coated dust grains in the early solar system. Comparison of the models to the average Jupiter-family and Oort cloud comet compositions suggests the two families formed in overlapping regions of the disk, in agreement with the findings of A’Hearn et al. and with the predictions of the Nice model.

ESA's Cometary Mission Rosetta-Re-Characterization of the COSAC Mass Spectrometry Results.

The most pristine material of the Solar System is assumed to be preserved in comets in the form of dust and ice as refractory matter. ESA's mission Rosetta and its lander Philae had been developed to investigate the nucleus of comet 67P/Churyumov–Gerasimenko in situ. Twenty‐five minutes after the initial touchdown of Philae on the surface of comet 67P in November 2014, a mass spectrum was recorded by the time‐of‐flight mass spectrometer COSAC onboard Philae. The new characterization of this mass spectrum through non‐negative least squares fitting and Monte Carlo simulations reveals the chemical composition of comet 67P. A suite of 12 organic molecules, 9 of which also found in the original analysis of this data, exhibit high statistical probability to be present in the grains sampled from the cometary nucleus. These volatile molecules are among the most abundant in the comet's chemical composition and represent an inventory of the first raw materials present in the early Solar System.

3D porosity structure of the earliest solar system material

Carbonaceous chondrites (CCs) contain the earliest preserved Solar System material, and objects containing this material are targets of numerous sample return missions. Both laboratory and remote sensing data have shown that this material can be highly porous, but the origin and nature of this porosity is currently not well understood. Because the majority of porosity within CCs is submicron to micron in size, previous lab efforts have been restricted by the limited observational scale required to examine this porosity with currently available techniques. Here we present results from a newly developed technique that allows submicron porosity to be examined in 3D within a 12 mm3 volume of CM Murchison. We use X-ray computed tomography combined with the highly attenuating noble gas xenon to characterize porosity well below the spatial resolution of the data (3.01 µm/voxel). This method not only allows examination of submicron porosity within a significantly larger volume than previously possible but also reveals the full three-dimensional porosity structure and pore connectivity. Our data reveal that some fine-grained rims (FGRs) surrounding chondrules have a complex 3D porosity structure, suggesting formation of the FGRs via dust aggregates or variable secondary processing around the rim after accretion.

A Review of Research on Grove Mountains CM-Type Chondrites

CM chondrite is the most important carbonaceous chondrite containing abundant Ca, Al-rich inclusions (CAIs) and other interesting objects, which probably experienced early condensation processes in the Solar Nebula environment and later alteration in parent body surroundings. Thus, it is a vital raw material to explore in the formation and evolution of the early Solar System. Grove Mountains (GRV) CM chondrites have been collected from Antarctica by Chinese Antarctic Research Expedition (CARE) for nearly 20 years. In this paper, we review the study of GRV CM chondrites. In total, there are eight CM chondrites named Grove Mountains officially approved by the Meteoritical Society. Petrology and mineral, matrix, CAIs, metal and sulfide in GRV CM chondrites are carefully reviewed. All the meteorites have similar characteristics with a dominant component of matrix. Phyllosilicate minerals generally developed in the matrix. The different altered mineral assemblages, contents and chemical compositions show that these chondrites underwent varying degrees of aqueous alteration, of which GRV 020005 is the most heavily altered CM chondrite. GRV 020025 is the second heaviest of the CM samples with the most extensive studies among these chondrites. It contains abundant CAIs and amoeboid olivine aggregates (AOAs). The modal content is about 1.0 vol% for CAIs. The findings of some new types of CAIs (such as hibonite-rich and spinel-pyroxene inclusions with forsterite-rich accretionary rims), AOAs and a complex, fine-grained P-bearing sulfide phase enrich the study of GRV 020025.

Asteroids accretion, differentiation, and break-up in the Vesta source region: Evidence from cosmochemistry of mesosiderites

The cosmochemistry of meteorites provides unique clues on asteroids accretion, differentiation, collisional break-up and reassembly - processes of critical importance for understanding planet formation in the early solar system. Mesosiderites are a complex group of achondrites whose nearly 50:50 metal-silicate composition is interpreted in the literature as resulting from the mixing of core and crustal materials derived from differentiated asteroids. Because of their complex nature and contrasting geochemical, isotopic, and spectroscopic data, the formation mechanism of mesosiderites is still poorly understood and is open to a large variety of planetary differentiation scenarios and collisional histories. In this study, based on new petrographic and geochemical data of 16 mesosiderites, we investigate in detail the proposal that mesosiderites are related to the howardite-eucrite-diogenite (HED) meteorite group, whose parent body is widely considered to be asteroid 4 Vesta (∼500 km diameter), the target of the recent NASA’s Dawn mission. We present the first high precision oxygen isotope analyses on the matrix of a set of mesosiderite samples, coupled with new chemical and petrographic analyses of mesosiderites Um Hadid, Estherville, and Mount Padbury. Concordant Δ17O values between mesosiderites (–0.241 ± 0.015 (2σ)) and howardite-eucrite-diogenites (−0.241 ± 0.017‰ (2σ)) indicate that they derived from the same oxygen isotope reservoir, but petrological evidence, in particular the distinctly lower Fe/Mn ratios and the larger lithological diversity in mesosiderites, indicates that they formed within different parent bodies. This suggests that mesosiderites and howardite-eucrite-diogenites originated in distinct parent bodies that accreted in the 4 Vesta source region but experienced different geologic evolution in terms of crustal differentiation and impact history, which were more complex and catastrophic in the mesosiderite parent body.

Prolonged early migration of dust from the inner Solar System to the comet-forming region

The most abundant group of meteorites currently falling to Earth, ordinary chondrites, originate from S-type (Si-rich) asteroids and are thought to have originated in the inner Solar System. These asteroids typically underwent only minor aqueous alteration but experienced varying degrees of thermal metamorphism that altered their primary compositions and textures. However, some rare members remain unaltered and retain the pristine compositions they obtained in the protoplanetary disk prior to accretion of their parent asteroids. In contrast, comets formed in the icy reaches of the outer Solar System. Here we report on silicate minerals in pristine ordinary chondrites that are compositionally distinct from those in all other known chondrites but show similarities to those found in comet samples returned from Comet Wild 2 by NASA's Stardust mission and those sourced from an unknown number of comets represented by interplanetary dusty particles. The identification of this material suggests that comets may have formed from diverse far-flung Solar System materials, including grains that migrated from the inner Solar System to the comet-forming region between ∼1 Myr and potentially ⪆3 Myr after the first Solar System solids formed. This finding suggests that migration from the inner to the outer Solar System lasted for millions of years and that comets are composed of residual materials from the entire early Solar System.

The Timing of Potential Last Nucleosynthetic Injections into the Protosolar Molecular Cloud Inferred from 41Ca–26Al Systematics of Bulk CAIs

Short-lived radionuclides (SLRs) provide important information about the chronology of the early solar system. Among them, 41Ca, due to its decay to 41K with a half-life of only 0.1 Ma, is particularly valuable in constraining the timescales and origins of both SLRs and the formation of the oldest solar system materials, the Ca–Al-rich inclusions (CAIs). The initial abundance of 41Ca in the solar system, expressed as the (41Ca/40Ca)I ratio, is the key to unveiling the origin of this nuclide. Here, we report a new solar system (41Ca/40Ca)I ratio of 2.0 × 10−8 derived from the K isotope compositions of two CAIs. This new ratio is about four times higher than the previous value inferred from a mineral isochron. Such a high (41Ca/40Ca)I ratio in the CAIs exceeds that expected for the protosolar molecular cloud by ∼1000×, implying very late injection of the 41Ca (and possibly other SLRs) into the protosolar molecular cloud. The correlated enrichments of 41Ca and 26Al in the bulk CAI samples hint at a common stellar origin of both SLRs. The injection time estimated from our new data depends on the stellar source—it ranges from 0.6 Ma for a Wolf–Rayet wind to 1.0 Ma for a TP-AGB star ejecta.

Atomic-scale characterization of the oxidation state of Ti in meteoritic hibonite: Implications for early solar system thermodynamics

Abstract Calcium-aluminum-rich inclusions (CAIs) in chondritic meteorites are composed of refractory minerals thought to be the first solids to have formed in the solar nebula. Among them, hibonite, nominally CaAl12O19, holds particular interest because it can incorporate significant amounts of Ti into its crystal structure in both Ti3+ and Ti4+ oxidation states. The relative amounts of these cations that are incorporated reflect the redox conditions under which the grain formed or last equilibrated and their measurement can provide insight into the thermodynamic landscape of the early solar nebula. Here we develop a new method for the quantification of Ti oxidation states using electron energy-loss spectroscopy (EELS) in an aberration-corrected scanning transmission electron microscope (STEM) to apply it to hibonite. Using a series of Ti-bearing oxides, we find that the onset intensity of the Ti L2,3 edge decreases with increasing Ti-oxidation state, which is corroborated by simulated Ti-oxide spectra using first-principles density-functional theory. We test the relationship on a set of synthetic hibonite grains with known Ti4+/ΣTi values and apply the developed method on a hibonite grain from a compact type A inclusion in the Northwest Africa (NWA) 5028 CR2 carbonaceous chondrite. The STEM-EELS data show that the chondritic hibonite grain is zoned with a Ti4+/ΣTi ratio ranging from 0.78 ± 0.04 to 0.93 ± 0.04 over a scale of 100 nm between the core and edge of the grain, respectively. The Ti substitution sites are characterized by experimental and calculated high-angle annular-dark-field (HAADF) images and atomic-level EEL spectrum imaging. Simulated HAADF images reveal that Ti is distributed between the M2 and M4 sites while Mg sits on the M3 site. Quantitative energy-dispersive X-ray spectroscopy shows that this grain is also zoned in Al and Ti. The Mg distribution is not well correlated with that of Ti and Ti4+/ΣTi at the nanoscale. The spatial decoupling of the element composition and Ti-oxidation states suggests a multistage evolution for this hibonite grain. We hypothesize that Ti and Mg were incorporated into the structure during condensation at high temperature through multiple reactions. Transient heating, presumably in the solar nebula, adds complexity to the crystal chemistry and potentially redistributed Ti and Mg. Concurrently, the formation of oxygen vacancies as a result of a reducing gas, led to the reduction of Ti4+ to Ti3+. The multiple defect reactions occurring in this single hibonite crystal preclude a simple relationship between the Ti4+/ΣTi and the fO2 of formation. However, moving forward, these measurements are fundamental inputs for modeling of the thermodynamic conditions under which hibonite formed in the early solar nebula.

Early Solar System instability triggered by dispersal of the gaseous disk.

The Solar System's orbital structure is thought to have been sculpted by an episode of dynamical instability among the giant planets1-4. However, the instability trigger and timing have not been clearly established5-9. Hydrodynamical modelling has shown that while the Sun's gaseous protoplanetary disk was present the giant planets migrated into a compact orbital configuration in a chain of resonances2,10. Here we use dynamical simulations to show that the giant planets' instability was probably triggered by the dispersal of the gaseous disk. As the disk evaporated from the inside out, its inner edge swept successively across and dynamically perturbed each planet's orbit in turn. The associated orbital shift caused a dynamical compression of the exterior part of the system, ultimately triggering instability. The final orbits of our simulated systems match those of the Solar System for a viable range of astrophysical parameters. The giant planet instability therefore took place as the gaseous disk dissipated, constrained by astronomical observations to be a few to ten million years after the birth of the Solar System11. Terrestrial planet formation would not complete until after such an early giant planet instability12,13; the growing terrestrial planets may even have been sculpted by its perturbations, explaining the small mass of Mars relative to Earth14.

原始太陽系の謎を明かす鉱物科学

原始太陽系の謎を明かす鉱物科学

Formation of fused aggregates under long‐term microgravity conditions aboard the ISS with implications for early solar system particle aggregation

AbstractIn order to gain further insights into early solar system aggregation processes, we carried out an experiment on board the International Space Station, which allowed us to study the behavior of dust particles exposed to electric arc discharges under long‐term microgravity. The experiment led to the formation of robust, elongated, fluffy aggregates, which were studied by scanning electron microscopy, electron backscatter diffraction, and synchrotron micro‐computed tomography. The morphologies of these aggregates strongly resemble the typical shapes of fractal fluffy‐type calcium‐aluminum‐rich inclusions (CAIs). We conclude that a small amount of melting could have supplied the required stability for such fractal structures to have survived transportation and aggregation to and compaction within planetesimals. Other aggregates produced in our experiment have a massy morphology and contain relict grains, likely resulting from the collision of grains with different degrees of melting, also observed in some natural CAIs. Some particles are surrounded by igneous rims, which remind in thickness and crystal orientation of Wark–Lovering rims; another aggregate shows similarities to disk‐shaped CAIs. These results imply that a (flash‐)heating event with subsequent aggregation could have been involved in the formation of different morphological CAI characteristics.

Cometary science with CUBES

The proposed CUBES spectrograph for ESO’s Very Large Telescope will be an exceptionally powerful instrument for the study of comets. The gas coma of a comet contains a large number of emission features in the near-UV range covered by CUBES (305-400 nm), which are diagnostic of the composition of the ices in its nucleus and the chemistry in the coma. Production rates and relative ratios between different species reveal how much ice is present and inform models of the conditions in the early solar system. In particular, CUBES will lead to advances in detection of water from very faint comets, revealing how much ice may be hidden in the main asteroid belt, and in measuring isotopic and molecular composition ratios in a much wider range of comets than currently possible, provide constraints on their formation temperatures. CUBES will also be sensitive to emissions from gaseous metals (e.g., FeI and NiI), which have recently been identified in comets and offer an entirely new area of investigation to understand these enigmatic objects.

Iron-60 in the Early Solar System Revisited: Insights from In Situ Isotope Analysis of Chondritic Troilite

We measured the nickel isotope composition of troilites from chondritic meteorites using the NanoSIMS to put constraints on the abundance of iron-60 in the early solar system. The troilites were selected from petrologic type 3 ordinary and carbonaceous chondrites. Based on petrographic observations and mineral chemistry, the troilites targeted for isotope analysis crystallized from melts, most likely in a nebular setting. Our isotope analyses did not reveal any significant correlation between nickel-60 enrichments and Fe/Ni ratios, either in the entire set of troilite grains or in individual troilites. The average inferred initial 60Fe/56Fe ratio of the studied troilites (i.e., the 60Fe/56Fe ratio calculated for the entire troilite population) is 1.05 (±1.48) ×10−8. This value is very similar to those estimated in the past for Semarkona chondrules, angrites, as well as diogenites and eucrites, based on the isotope analyses of bulk samples (109–108), but about two orders of magnitude smaller than the average initial 60Fe/56Fe ratios inferred previously for Semarkona troilites and many chondrules from ordinary and carbonaceous chondrites (107–106) using in situ analysis techniques. Based on petrographic evidence, and the generally unequilibrated nature of our samples, as well as on the timing of chondrule formation and planetary evolution, the lack of discernible signs of in situ iron-60 decay in the studied troilites is probably unrelated to metamorphic re-equilibration, and it is also not the result of a late formation of the troilites. We suggest that the highest inferred initial 60Fe/56Fe ratios reported in the literature are probably inaccurate.

Pluto near the edge of chaos

Many of the unusual properties of Pluto’s orbit are widely accepted as evidence for the orbital migration of the giant planets in early solar system history. However, some properties remain an enigma. Pluto’s long-term orbital stability is supported by two special properties of its orbit that limit the location of its perihelion in azimuth and in latitude. We revisit Pluto’s orbital dynamics with a view to elucidating the individual and collective gravitational effects of the giant planets on constraining its perihelion location. While the resonant perturbations from Neptune account for the azimuthal constraint on Pluto’s perihelion location, we demonstrate that the long-term and steady persistence of the latitudinal constraint is possible only in a narrow range of additional secular forcing which arises fortuitously from the particular orbital architecture of the other giant planets. Our investigations also find that Jupiter has a largely stabilizing influence whereas Uranus has a largely destabilizing influence on Pluto’s orbit. Overall, Pluto’s orbit is rather surprisingly close to a zone of strong chaos.

Mothership-Cubesat Radioscience for Phobos Geodesy and Autonomous Navigation

The knowledge of the interior structure (e.g., homogeneous, porous, or fractured) of Martian moons will lead to a better understanding of their formation as well as the early solar system. One approach to inferring the interior structure is via geodetic characteristics, such as gravity field and libration. Geodetic parameters can be derived from radiometric tracking measurements. A feasible mothership-CubeSat mission is proposed in this study with following purposes, (1) performing inter-sat Doppler measurements, (2) improving the understanding of Phobos as well as the dynamic model, (3) securing the mothership as well as the primary mission, and (4) supporting autonomous navigation, given the long distance between the Earth and Mars. This study analyzes budgets of volume, mass, power, deployment Δv, and link, and the Doppler measurement noise of the system, and gives a feasible design for the CubeSat. The accuracy of orbit determination and geodesy is revealed via the Monte-Carlo simulation of estimation considering all uncertainties. Under an ephemeris error of the Mars-Phobos system ranging from 0 to 2 km, the autonomous orbit determination delivers an accuracy ranging from 0.2 m to 21 m and 0.05 mm/s to 0.4 cm/s. The geodesy can return 2nd-degree gravity coefficients at an accuracy of 1‰, even in the presence of an ephemeris error of 2 km. The achieved covariance of gravity coefficients and libration amplitude indicates an excellent possibility to distinguish families of interior structures.

In-situ O-isotope analysis of relict spinel and forsterite in small (

We report high-precision secondary ion mass spectrometer triple oxygen isotope systematics (95 individual analyses) from 37 micrometeorites (MMs) collected from South Pole Water Well (SPWW), Antarctica. The study population focuses on unmelted coarse-grained (Cg) MMs (n = 23) with both multiple (n = 14) and single-mineral (n = 9) varieties investigated. We also analysed relict minerals in porphyritic cosmic spherules (n = 13) and the relict matrix in a single scoriaceous fine-grained (Fg) MM. The target minerals investigated are primarily olivine (Fo ∼ 43–99%) and spinel. Textural, chemical and isotopic data confirm that both olivine and spinel grains have retained their pre-atmospheric O-isotope compositions, allowing inferences to be drawn about their formation and parent body affinities. We separate the study population into three groups: spinel-free particles (consisting of the CgMMs and PO cosmic spherules), spinel-bearing MMs and the single FgMM.Olivine grains in spinel-free MMs vary between δ17O: −12.6‰ and +3.5‰, δ18O: −9.6‰ and +7.5‰, and Δ17O: −9.5‰ and +1.3‰ and define a slope-1 profile in δ18O–δ17O isotope space. They are most likely fragmented chondrules, with both type I and type II varieties represented. Their observed Mg#-Δ17O distribution is best explained by a mixture of CM chondrules and either CR chondrules, Tagish Lake chondrules or WILD2 cometary silicates. One of these chondrule-like MMs has an isotopically heterogeneous composition, characterised by a single olivine grain with a markedly 16O-rich composition (Δ17O: −16.3‰), suggesting it is a relict silicate fragment of AOA material that was incorporated into the chondrule precursor.We analysed 11 spinel grains in five spinel-bearing MMs. In all instances spinels are nearly pure MgAl2O4 with isotopically light (16O-rich) compositions (ranging from δ17O: −34.4‰ to −0.9‰, δ18O: −30.8‰ to +11.0‰, and Δ17O: −18.3‰ to −4.4‰). They are therefore 16O-poor relative to spinel found in unaltered CAIs, indicating a different origin. Grains with high Cr2O3 contents (>0.5 wt.%) are interpreted originating from Al-rich chondrule precursors, while low Cr2O3 spinels (<0.5 wt.%) are interpreted as CAI-derived material affected by parent body aqueous alteration.Finally, we report a single FgMM with a 16O-poor composition (Δ17O > 0‰ and δ18O > +15.0‰). This particle adds to our growing inventory of water-rich C-type asteroid samples united by their formation history which is characterised by accretion of abundant heavy water.Our work strongly supports findings from earlier in-situ O-isotope studies, concluding that small MMs overwhelmingly sample material from CC parent bodies and that CgMMs largely sample chondrules and, to a lesser extent, CAI material. The analysis of CgMMs therefore provides insights into the primitive O-isotope reservoirs that were present in the early solar system and how they interacted.

Cosmogenic records and noble gases in Mukundpura CM2.0 carbonaceous chondrite

The Mukundpura carbonaceous chondrite represents the negligible thermally affected with modest aqueous altered chondrite, providing a new unique opportunity to investigate the composition of the early solar system materials. We investigated cosmogenic records using radioactive and stable isotopes in Mukundpura. The cosmic ray exposure (CRE) age of Mukundpura is estimated to be 6.54 ​± ​1.34 ​Ma based on cosmogenic 21Ne by considering trapped noble gas as Q-gas. The exposure age determined from combination of radioactive isotope and neon yields a range between 5.9 and 6.5 ​Ma. The CRE age lies at the higher end of the CRE age distribution of the CM chondrite group, which is dominated by ages of 0.1–10 ​Ma. Noble gas isotope signature confirms the presence of multiple components, chondritic phase Q, HL from presolar grains and solar wind.

Direct search for primordial 244Pu in Bayan Obo bastnaesite

The abundances of heavy elements produced in r-process nucleosynthesis in the early solar system need experimental verification. 244Pu could be the heaviest primordial nuclide produced before the formation of the Earth still being detectable today. As recent attempts failed to confirm the discovery of 244Pu signals at a concentration of 1.0 × 10−18 g/g in bastnaesite reported by Hoffman et al. in this study, the total primordial 244Pu in 450 g bastnaesite sample from Bayan Obo ore (China) was measured using ultra-sensitive compact accelerator mass spectrometry (AMS). As no 244Pu signal was detected, an upper limit for the 244Pu in our bastnaesite sample was estimated to be 2.1 × 10−20 g/g at 99% confidence level.