Early Eclogite Facies Metamorphism Research Articles

Metamorphic Evolution and Tectonic Implications of the Granulitized Eclogites from the Luliangshan Terrane in the North Qaidam Ultrahigh Pressure Metamorphic Belt, NW China: New Constraints from Phase Equilibrium Modeling

The granulitized eclogites from the Luliangshan terrane of the North Qaidam UHP metamorphic belt occur as lenses within pelitic gneisses and orthogneisses. Combined petrologic data and phase equilibrium modeling indicate a multi-stage metamorphic history of the granulitized eclogites: (1) an earlier eclogite facies metamorphism (P>18.5 kbar, T> 830 °C) is deduced from omphacite relics in the matrix and rare omphacite inclusions within garnet. The possible assemblage is garnet+omphacite+rutile+ quartz; (2) the early stage of high pressure granulite facies assemblages (garnet+clinopyroxene+ plagioclase+rutile+quartz+liquid) developed in the early decompression process has a P-T regime of 17.5 kbar and 852–858 °C, constrained by plagioclase and clinopyroxene inclusions in garnet. The late stage of high pressure granulite assemblages (garnet+clinopyroxene+amphibole+plagioclase+rutile+quartz+liquid) records an isothermal decompression process with the pressure successively declining from 17.5 to 14.7 kbar and to 11.3 kbar at 858 °C; (3) the later medium pressure granulite facies assemblage (garnet+ orthopyroxene+ clinopyroxene+amphibole+plagioclase+ilmenite+liquid+quartz) indicates a drop in pressure and rise in temperature at P-T conditions of 7.6–7.7 kbar and 878–883 °C; (4) retrogressive amphibolite facies stage, which is represented by amphibole+plagioclase kelyphitic rims around garnet, formed under conditions of <5 kbar and <650 °C. The preservation of medium pressure granulite facies assemblage and the garnet composition feature constrain a following isobaric cooling path during late exhumation. This process suggests a clockwise P-T path and indicates that the granulitized eclogites record a high grade “Barrovian” metamorphic overprint at the middle-lower crust during exhumation. The present data show that the Luliangshan terrane is a “hot” HP-UHP terrane.

Bauxite to eclogite: Evidence for late Permian supracontinental subduction at the Red River shear zone, northern Vietnam

We have investigated the geological processes recorded in aluminous granulites from the Red River shear zone in northern Vietnam using mineral and whole-rock chemistries, fluid inclusions, metamorphic pressure–temperature paths, and geochronology. The granulites are extremely rich in Al2O3 (36.3–50.9wt%), TiO2, and total Fe2O3, and poor in SiO2 (7.9–24.1wt%), MgO, CaO, Na2O, and K2O. The granulites are enriched in high-field-strength elements and rare earth elements, and severely depleted in large-ion lithophile elements. These features strongly suggest the protolith was lateritic bauxite. Moreover, the other elemental concentrations and the Zr/Ti ratios point to basaltic rock as the precursor of the bauxite. Some of the aluminous granulites contain high-pressure mineral inclusions of kyanite, staurolite, siderite, and rutile, none of which are observed in the matrix. Abundant primary carbonic fluid inclusions are observed in garnet, corundum, and staurolite, but are rare in quartz and zircon. The average densities of fluid inclusions in garnet, corundum, staurolite, quartz, and zircon are 1.00±0.06, 1.07±0.04, 1.09±0.03, 0.29±0.07, and 1.15±0.05g/cm3, respectively. The mineral features not only in the matrix and but also in garnet from all rock types, isochemical phase diagrams obtained for each bulk rock composition, and Zr-in-rutile thermometry indicate an early eclogite-facies metamorphism (~2.5GPa at 650°C) and a subsequent nearly isothermal decompression. Zircons yield a wide range of U–Pb ages from 265 to 36Ma, whereas the dark luminescent cores of the zircons, which contain high-density CO2 inclusions, yield a concordia age of 257±8Ma. These observations suggest that the dark luminescent zircon cores were formed at the same time as the garnet, corundum, and staurolite that contain high-density CO2 fluid inclusions. Based on the carbonic fluid inclusion isochore and the densities as well as calculated phase diagram, the concordia age can be regarded as recording a prograde stage of metamorphism under conditions lower than 600°C and 0.7GPa. Our new data provide the following geological and tectonic constraints: 1) the eruption of basalt occurred before the Permian, possibly related to subduction of the Paleo-Tethys Plate beneath the Indochina craton near the paleo-equator in the Devonian–Carboniferous; 2) strong weathering transformed the basalt to bauxite before the late Permian; 3) the uppermost continental crust, including the bauxites, was subducted in the late Permian due to the collision of the Indochina and South China cratons, leading to eclogite-facies metamorphism; 4) the rocks were then exhumed; and 5) shearing-related thermal events took place until the Paleogene.

Felsic granulite with layers of eclogite facies rocks in the Bohemian Massif; did they share a common metamorphic history?

High pressure granulite and granulite gneiss from the Rychleby Mountains in the East Sudetes form an approximately 7km long and 0.8km wide body, which is enclosed by amphibolite facies orthogneiss with a steep foliation. Well preserved felsic granulite is located in the central part of the body, where several small bodies of mafic granulite are also present. In comparison to other high pressure granulites in the Bohemian Massif, which show strong mineral and textural re-equilibration under granulite facies conditions, the mafic granulite samples preserve eclogite facies minerals (garnet, omphacite, kyanite, rutile and phengite) and their field and textural relations indicate that both mafic and felsic granulites shared common metamorphic history during prograde eclogite facies and subsequent granulite facies events. Garnet from both granulite varieties shows prograde compositional zoning and contains inclusions of phengite. Yttrium and REEs in garnet show typical bell-shaped distributions with no annular peaks near the grain rims. Investigation of major and trace elements zoning, including REEs distribution in garnet, was combined with thermodynamic modelling to constrain the early eclogite facies metamorphism and to estimate pressure-temperature conditions of the subsequent granulite facies overprint. The first (U)HP metamorphism occurred along a low geothermal gradient in a subduction-related environment from its initial stage at 0.8GPa/460°C and reached pressures up to 2.5GPa at 550°C. The subsequent granulite facies overprint (1.6–1.8GPa/800–880°C) affected the rocks only partially; by replacement of omphacite into diopside+plagioclase symplectite and by compositional modification of garnet rims. The mineral textures and the preservation of the eclogite facies prograde compositional zoning in garnet cores confirm that the granulite facies overprint was either too short or too faint to cause recrystallisation and homogenisation of the eclogite facies mineral assemblage. The results of this study are compared with other granulite massifs in the Moldanubian Zone. In addition, a possible scenario for the Variscan eclogite and subsequent granulite facies metamorphism in the Bohemian Massif is discussed.

U–Pb geochronology of paragneisses and metabasite in the Xitieshan area, north Qaidam Mountains, western China: Constraints on the exhumation of HP/UHP metamorphic rocks

The Xitieshan HP/UHP metamorphic unit is a polyphase paragneiss–orthogneiss–metabasite complex preserving relics of an early eclogite facies metamorphism (as deduced from the presence of clinopyroxene + plagioclase symplectite after omphacite in metabasite) followed by decompression through the granulite and amphibolite facies. Paragneisses contain garnet, kyanite (partially replaced by sillimanite), feldspar, quartz and biotite, with minor rutile and zircon. The metabasite consists of garnet, amphibole and plagioclase with relict clinopyroxene + plagioclase symplectite. Two main high-temperature metamorphic stages are distinguished: (1) a high-pressure granulite stage, characterized by the assemblage garnet–kyanite–K-feldspar–plagioclase–quartz–rutile in the paragneisses and garnet–clinopyroxene–plagioclase–quartz in the metabasite; (2) a medium–low pressure granulite to upper amphibolite facies stage, leading to the formation of sillimanite in the paragneisses and overgrowth of amphibole on Cpx–Pl symplectite in the metabasite. SHRIMP U–Pb analyses of metamorphic zircons, in conjunction with LA-ICPMS REE data and rare mineral inclusions in zircons, show that the high-pressure granulite metamorphism recorded by these rocks occurred between 451 and 461 Ma and the medium–low pressure granulite–upper amphibolite facies metamorphic overprint between 423 and 427 Ma, suggesting about 30 Ma residence time in medium–lower crustal levels after an earlier eclogite facies metamorphism (ca. 480 Ma). Based on comparison with other HP/UHP metamorphic units in the North Qaidam Mountains (NQD), these results suggest diachronous subduction and exhumation in the different units of the NQD.

Pan-African Tectonism in the Western Maud Belt: P–T–t Path for High-grade Gneisses in the H.U. Sverdrupfjella, East Antarctica

Extensive high-grade polydeformed metamorphic provinces surrounding Archaean cratonic nuclei in the East Antarctic Shield record two tectono-thermal episodes in late Mesoproterozoic and late Neoproterozoic–Cambrian times. In Western Dronning Maud Land, the high-grade Mesoproterozoic Maud Belt is juxtaposed against the Archaean Grunehogna Province and has traditionally been interpreted as a Grenvillian mobile belt that was thermally overprinted during the Early Palaeozoic. Integration of new U–Pb sensitive high-resolution ion microprobe and conventional single zircon and monazite age data, and Ar–Ar data on hornblende and biotite, with thermobarometric calculations on rocks from the H.U. Sverdrupfjella, northern Maud Belt, resulted in a more complex P–T–t evolution than previously assumed. A c. 540Ma monazite, hosted by an upper ampibolite-facies mineral assemblage defining a regionally dominant top-to-NW shear fabric, provides strong evidence for the penetrative deformation in the area being of PanAfrican age and not of Grenvillian age as previously reported. Relics of an eclogite-facies garnet–omphacite assemblage within strainprotected mafic boudins indicate that the peak metamorphic conditions recorded by most rocks in the area (T ¼ 687–758 � C, P ¼ 9� 4–11� 3kbar) were attained subsequent to decompression from P >12� 9kbar. By analogy with limited U–Pb single zircon age data and on circumstantial textural grounds, this earlier eclogitefacies metamorphism is ascribed to subduction and accretion around 565Ma. Post-peak metamorphic K-metasomatism under amphibolite-facies conditions is ascribed to the intrusion of postorogenic granite at c. 480Ma. The recognition of extensive PanAfrican tectonism in the Maud Belt casts doubts on previous Rodinia reconstructions, in which this belt takes a pivotal position between East Antarctica, the Kalahari Craton and Laurentia. Evidence of late Mesoproterozoic high-grade metamorphism during the formation of the Maud Belt exists in the form of c. 1035Ma zircon overgrowths that are probably related to relics of granulite-facies metamorphism recorded from other parts of the Maud Belt. The polymetamorphic rocks are largely derived from a c. 1140Ma volcanic arc and 1072 � 10Ma granite.

The high-pressure granulites of the Bacariza Formation: an earlier stage in the exhumation of other eclogites in the Cabo Ortegal Complex (Hecynian belt, NW Spain)

This paper deals with the metamorphic evolution of the Bacariza Fm that outcrops in the two uppermost structural units of the Cabo Ortegal Complex (NW Iberian Massif). This formation includes ultramafic and mafic granulites, garnet amphibolites and garnet trondhjemitic gneisses. Although mineral associations characteristic of high pressure granulites predominate in the least retrogressed of these rocks, the presence of relic kyanite along with the fact that plagioclase only appears in symplectitic textures resulting from de-jadeitization of pyroxenes point to an earlier eclogite facies metamorphism. Thermobarometric estimations indicate higher P-T conditions for the rocks in the uppermost structural unit.