Dynamic Flux Chamber Research Articles

Surface-air exchanges of H2S and SO2 in an urban wetland in eastern China

Wetlands are widely recognized as hot spots for the emission or deposition of biogenic sulfur gases, including hydrogen sulfur (H2S) and sulfur dioxide (SO2), which significantly affect air quality and climate change. With the expansion of urban wetlands, it is critical to know the roles that urban wetlands played in atmospheric H2S and SO2 budget. In this study, the surface-air exchange fluxes of H2S and SO2 were measured by the Dynamic Flux Chamber (DFC) method in a typical urban wetland in eastern China from Sep 2022 to July 2023. It was found that the urban wetland did not have the expected high H2S emission, might be caused by the relatively high pH value and low sulfate concentration in the soil. Although H2S showed emission in the daytime of spring and summer, an overall H2S flux of −0.04 kg S ha−1 yr−1 was observed throughout the year. Meanwhile, the urban wetland presented a net sink of SO2, with a deposition flux of 0.14 kg S ha−1 yr−1. The negative peaks of SO2 flux corresponded to the suddenly elevated SO2 concentration in the ambient air especially in spring and winter. Through linear fitting of SO2 flux and concentration, the concept of SO2 “compensation point” was proposed. The compensation point is the concentration level at which the observed SO2 flux equals zero. The “compensation point” changed with the season and was related to temperature and humidity. The “compensation point” in summer and autumn were larger, being 2.37 ppb and 1.40 ppb, respectively, while they were 1.07 ppb and 0.86 ppb in spring and winter respectively. Our results suggest that the urban wetland expansion may have little risk of increasing air H2S but could act as a significant sink of SO2 with high SO2 concentration in the urban region.

Carbon dioxide fluxes in Alpine grasslands at the Nivolet Plain, Gran Paradiso National Park, Italy 2017–2023

We introduce a georeferenced dataset of Net Ecosystem Exchange (NEE), Ecosystem Respiration (ER) and meteo-climatic variables (air and soil temperature, air relative humidity, soil volumetric water content, pressure, and solar irradiance) collected at the Nivolet Plain in Gran Paradiso National Park (GPNP), western Italian Alps, from 2017 to 2023. NEE and ER are derived by measuring the temporal variation of CO2 concentration obtained by the enclosed chamber method. We used a customised portable non-steady-state dynamic flux chamber, paired with an InfraRed Gas Analyser (IRGA) and a portable weather station, measuring CO2 fluxes at a number of points (around 20 per site and per day) within five different sites during the snow-free season (June to October). Sites are located within the same hydrological basin and have different geological substrates: carbonate rocks (site CARB), gneiss (GNE), glacial deposits (GLA, EC), alluvial sediments (AL). This dataset provides relevant and often missing information on high-altitude mountain ecosystems and enables new comparisons with other similar sites, modelling developments and validation of remote sensing data.

Effects of Acacia mearnsii added to silages differing in nutrient composition and condensed tannins on ruminal and manure-derived methane emissions of dairy cows

This study investigated the effects of acacia (extract of Acacia mearnsii) and sainfoin (Onobrychis viciifolia) as condensed tannin (CT)-rich sources on ruminal and manure methane (CH4) emissions in comparison with non-CT silages characterized by different contents of the cell wall and water-soluble carbohydrates. In a 3 × 6 incomplete Latin square design, 30 Holstein cows (63 ± 23 d in milk; mean ± SD; 33.8 ± 7.6 kg of milk per day, body weight 642 ± 81 kg) were provided with ad libitum access to 1 of 6 total mixed rations comprising 790 g of silage and 210 g of concentrate per kilogram of dry matter (DM). The silages were either rich in sainfoin [neutral detergent fiber (NDF): 349 g/kg of DM], perennial ryegrass (NDF: 420 g/kg of DM), or red clover (NDF: 357 g/kg of DM). Each silage was supplemented with 20 g/kg (of total diet DM) of acacia or straw meal. Feed intake and milk yield were recorded daily. Milk composition and ruminal fluid characteristics and microbiota were analyzed. The individual ruminal CH4 production was determined using the GreenFeed system, and CH4 emissions from the manure of cows fed the same diets were measured in a parallel experiment over 30 d at 25°C using a dynamic flux chamber. The CT sources did not reduce CH4 yield or emission intensity. Acacia reduced milk production (from 26.3 to 23.2 kg/d) and DM intake (from 19.7 to 16.7 kg/d) when supplemented with ryegrass, and both CT sources reduced the milk protein content and yield. Acacia supplementation and ryegrass silage reduced the ruminal acetate:propionate ratio. Furthermore, during acacia treatment, the abundance of Methanobrevibacter archaea tended to be lower and that of Thermoplasmata was higher. Acacia reduced the CH4 emissions from manure for the ryegrass group by 17% but not for the sainfoin and clover groups. Feeding sainfoin silage resulted in the lowest manure-derived CH4 emissions (-47% compared with ryegrass). In conclusion, acacia reduced ruminal CH4 production by 10%, but not emission intensity, and the mitigation effect of sainfoin depended on the silage to which it was compared. Because mitigation was partially associated with animal productivity losses, careful evaluation is required before the implementation of tanniferous feeds in farm practice.

Efficacy of a vermifilter at mitigating greenhouse gases and ammonia emissions from dairy wastewater.

Dairy effluent is a potential source of gaseous pollutants associated with global warming and soil acidification. Mitigating such emissions during handling and storage requires substantial financial and labor input. This study evaluated a low-cost technology for mitigating gaseous emissions from dairy wastewater. For 9 mo, a pilot-scale vermifilter system installed on a commercial dairy farm was studied. Bimonthly samples of the dairy wastewater influent and effluent from the vermifilter system were collected. These samples' potential gas emissions (ammonia [NH3 ], methane [CH4 ], carbon dioxide [CO2 ], and nitrous oxide [N2 O]) were measured using a closed-loop dynamic flux chamber method. Results indicated the following reductions in emissions of these gases by the vermifilter system: 84-100% for NH3 , 58-82% for CO2 , and 95-100% for CH4 . Nitrous oxide emissions were mainly below our instrument detection limits and were thus not reported. The vermifilter showed the potential of reducing the global warming potential from the dairy wastewater by up to 100%. This study further indicated that higher ambient temperatures led to higher emissions of CH4 (R2 =.56) and NH3 (R2 =.53) from untreated dairy wastewater. Overall, the vermifilter system has potential to mitigate gaseous emissions from dairy wastewater.

Assessing nitrous oxide (N2O) isotopic analyzer performance for in-field use

Analysis of N2O isotope ratios is a way to apportion N2O production in soils among source pathways and develop mitigation strategies. Measurement systems employing a field-deployable LAS instrument coupled with automatic and dynamic soil flux chambers, where the soil emitted gas continuously circulates between the analyzer and the chamber can provide direct in situ N2O flux and N2O isotope ratio measurements with high temporal resolution. Reliable use of these measurements, however, requires quantification of measurement accuracy at high analyzer sampling rates - 2 seconds. We evaluated the variability of the measurements of an LAS isotope N2O analyzer – the OA-ICOS (Isotopic N2O Analyzer model 914–0027, Los Gatos Research Inc, Los Gatos, CA), over N2O concentrations observed in field experiments. We calculated the uncertainty of isotope ratios estimated using the Keeling plot method for representative soil N2O fluxes and chamber closure times. The variability of OA-ICOS isotopic ratio measurements is inversely related to N2O concentration leading to high uncertainty in soil emitted N2O isotope ratios estimated using the Keeling plot method in which low concentration measurements have the largest influence. Instrument precision evaluated using reference gasses was propagated through Monte Carlo simulation to predict system performance under a range of conditions. Model predictions of in situ measurement accuracy were evaluated with soil flux simulations using soil emitted gasses. Isotope ratios derived using OA-ICOS measurements during soil flux simulations deviated markedly from IRMS measurements. System performance was limited by the concentration dependence of N2O isotope ratio measurements and the suspected presence of interferents in soil emitted gasses. These characteristics of the OA-ICOS isotopic analyzer make it poorly suited for in situ source partitioning of soil emitted N2O. Until we overcome these limitations in situ N2O isotopic ratio measurements by OA-ICOS and automatic flux chambers are best used qualitatively.

Field Quantification of Ammonia Emission following Fertilization of Golf Course Turfgrass in Sub/Urban Areas

Low cost and favorable handling characteristics make urea (46-0-0) a leading nitrogen source for frequent, foliar N fertilization of golf course putting greens in season. Yet few field investigations of resulting NH3 volatilization from putting greens have been directed. Meanwhile, NH3 emissions degrade air and surface water quality. Our objective was to quantify NH3 volatilization following practical, low-N rate, and foliar application of commercial urea-N fertilizers. Over the 2019 and 2020 growing seasons in University Park, PA, USA, an industrial vacuum pump, H3BO3 scrubbing flasks, and sixteen dynamic flux chambers were employed in four unique experiments to measure NH3 volatilization from creeping bentgrass putting greens (Agrostis stolonifera L. ‘Penn G2’) in the 24 h period ensuing foliar application of urea based-N at a 7.32 or 9.76 kg/ha rate. Simultaneous and replicated flux chamber trapping efficiency trials showing 35% mean NH3 recovery were used to adjust NH3 volatilization rates from treated plots. Under the duration and conditions described, 3.1 to 8.0% of conventional urea N volatilized from the putting greens as NH3. Conversely, 0.7 to 1.1% of methylol urea liquid fertilizer (60% short-chain methylene urea) or 0.7 to 2.2% of urea complimented with dicyandiamide (DCD) and N-(n-butyl) thiophosphoric triamide (NBPT) volatilized as NH3.

New Estimation of the NOx Snow‐Source on the Antarctic Plateau

AbstractTo fully decipher the role of nitrate photolysis on the atmospheric oxidative capacity in snow‐covered regions, NOx flux must be determined with more precision than existing estimates. Here, we introduce a method based on dynamic flux chamber measurements for evaluating the NOx production by photolysis of snowpack nitrate in Antarctica. Flux chamber experiments were conducted for the first time in Antarctica, at the French‐Italian station Concordia, Dome C (75°06'S, 123°20’E, 3233 m a.s.l) during the 2019–2020 summer campaign. Measurements were gathered with several snow samples of different ages ranging from newly formed drifted snow to 6‐year‐old firn. Contrary to existing literature expectations, the daily average photolysis rate coefficient, , did not significantly vary between differently aged snow samples, suggesting that the photolabile nitrate in snow behaves as a single‐family source with common photochemical properties, where a = (2.37 0.35) × 10−8 s−1 (1) has been calculated from December 10th 2019 to January 7th 2020. At Dome C summer daily average NOx flux, , based on measured NOx production rates was estimated to be (4.3 1.2) × 108 molecules cm−2 s−1, which is 1.5–7 times less than the net NOx flux observed previously above snow at Dome C using the gradient flux method. Using these results, we extrapolated an annual continental snow sourced NOx budget of 0.017 0.003 TgN y−1, 2 times the nitrogen budget, (N‐budget), of the stratospheric denitrification previously estimated for Antarctica. These quantifications of nitrate photolysis using flux chamber experiments provide a road‐map toward a new parameterization of the product that can improve future global and regional models of atmospheric chemistry.

CFD modeling of different mass transfer coefficients on hydrogen sulfide emission in a flux chamber.

Hydrogen sulfide (H2S) is commonly used as an indicator for odorous gas emission monitoring in wastewater treatment plants. The H2S emission estimations can be performed using algebraic mathematical models or carrying out measurements at the source, with the dynamic flux chamber, for example. This work brings together these two methodologies in a computational fluid dynamics analysis. Fifteen liquid-phase mass transfer coefficient ([Formula: see text]) models were initially evaluated in establishing, at the liquid-gas interface in a flux chamber, an H2S emission flux based on the friction velocity field from three different inlet flows (2, 5, and 10 L min-1). Ten [Formula: see text] models were fully simulated, and the numerical results were compared with available experimental data. The higher the inlet flow, the higher the friction velocity at the interface, and the higher the H2S emission. The H2S emission was also strongly dependent on the constant coefficients of the existing [Formula: see text] models. Small variability on those coefficients generates considerable changes in emissions at the interface. Few and different models performed well in describing the available concentration data at the outlet sampling probe for different inlet flows, which shows there is still no single model capable of representing all simulated friction velocity ranges (0.005 to 0.017ms-1).

Gaseous Elemental Mercury Exchange Fluxes over Air-Soil Interfaces in the Degraded Grasslands of Northeastern China.

Simple SummaryThis study investigated the gaseous elemental mercury exchange fluxes over Artemisia anethifolia coverage and removal and bare soil using a dynamic flux chamber attached to the LumexR RA915+ Hg analyzer during the growing season from May to September of 2018, in which the interactive effects of plant coverage and meteorological conditions were highlighted. The results showed that the net emissions from the soil to the atmosphere, which varied diurnally, with releases occurring during the daytime hours and depositions occurring during the nighttime hours. Significant differences were observed in the fluxes between the vegetation coverage and removal during the growing months. In addition, it was determined that the mercury fluxes were positively correlated with the solar radiation and air/soil temperature levels and negatively correlated with the air humidity and soil moisture. The grassland soil served as both a source and a sink for atmospheric mercury, depending on the season and meteorological factors. The plants played an important inhibiting role in the mercury exchanges between the soil and the atmosphere. This research will potentially assist in the development of more accurate local and regional estimates of mercury emissions from degraded grassland areas and the terrestrial environment as a whole.Mercury (Hg) is a global pollutant that may potentially have serious impacts on human health and ecologies. The gaseous elemental mercury (GEM) exchanges between terrestrial surfaces and the atmosphere play important roles in the global Hg cycle. This study investigated GEM exchange fluxes over two land cover types (including Artemisia anethifolia coverage and removal and bare soil) using a dynamic flux chamber attached to the LumexR RA915+ Hg analyzer during the growing season from May to September of 2018, in which the interactive effects of plant coverage and meteorological conditions were highlighted. The daily mean ambient levels of GEM and the total mercury concentrations of the soil (TSM) were determined to be 12.4 ± 3.6 to 16.4 ± 5.6 ng·m−3 and 32.8 to 36.2 ng·g−1, respectively, for all the measurements from May to September. The GEM exchange fluxes (ng·m−2·h−1) during the five-month period for the three treatments included the net emissions from the soil to the atmosphere (mean 5.4 to 7.1; range of −27.0 to 47.3), which varied diurnally, with releases occurring during the daytime hours and depositions occurring during the nighttime hours. Significant differences were observed in the fluxes between the vegetation coverage and removal during the growing months (p < 0.05). In addition, it was determined that the Hg fluxes were positively correlated with the solar radiation and air/soil temperature levels and negatively correlated with the air relative humidity and soil moisture under all the conditions (p < 0.05). Overall, the results obtained in this study demonstrated that the grassland soil served as both a source and a sink for atmospheric Hg, depending on the season and meteorological factors. Furthermore, the plants played an important inhibiting role in the Hg exchanges between the soil and the atmosphere.

Characterizing ammonia emissions from water bodies using dynamic floating chambers

Ammonia (NH3) is the most important alkaline gas in the atmosphere and plays a central role in atmospheric pollution and the global N cycle. Water bodies receive increasing nitrogen inputs from effluents and atmospheric deposition due to anthropogenic activities and are regarded as the major natural NH3 and NH4+ sinks. In this work, floating dynamic flux chambers were deployed at four types of freshwater (rivers, large reservoirs, medium-sized reservoirs and ponds) systems and a coastal seawater system to estimate the water-air NH3 emission fluxes. The NH3 emission fluxes of rivers (26.4 μg NH3 m−2 h−1) were significantly higher than those of other types of freshwater systems, and the NH3 flux of offshore water was unexpectedly high (3.9 μg NH3 m−2 h−1). The ammonium content and water temperature were the most important factors driving NH3 emissions from water bodies. The global NH3 emissions from water bodies reached 8.88 TgN a−1, and this value will increase persistently with global warming and water quality deterioration. Water bodies that are relatively eutrophic and directly affected by anthropogenic activities should be considered reservoirs of inputted N instead of permanent sinks.

Surface-air mercury fluxes and a watershed mass balance in forested and harvested catchments.

Forest soils are among the world's largest repositories for long-term accumulation of atmospherically deposited mercury (Hg), and understanding the potential for remobilization through gaseous emissions, aqueous dissolution and runoff, or erosive particulate transport to down-gradient aquatic ecosystems is critically important for projecting ecosystem recovery. Forestry operations, especially clear-cut logging where most of the vegetaiton is removed, can influence Hg mobility/fluxes, foodweb dynamics, and bioaccumulation processes. This paper measured surface-air Hg fluxes from catchments in the Pacific Northwest, USA, to determine if there is a difference between forested and logged catchments. These measurements were conducted as part of a larger project on the impact of forestry operations on Hg cycling which include measurements of water fluxes as well as impacts on biota. Surface-air Hg fluxes were measured using a commonly applied dynamic flux chamber (DFC) method that incorporated diel and seasonal variability in elemental Hg (Hg0) fluxes at multiple forested and harvested catchments. The results showed that the forested ecosystem had depositional Hg0 fluxes throughout most of the year (annual mean:-0.26ng/m2/h). In contrast, the harvested catchments showed mostly emission of Hg0 (annual mean: 0.63ng/m2/h). Differences in solar radiation reaching the soil was the primary driver resulting in a shift from net deposition to emission in harvested catchments. The surface-air Hg fluxes were larger than the fluxes to water as runoff and accounted for 97% of the differences in Hg sequestered in forested versus harvested catchments.

Part B: Advances in gas emission control techniques for anaerobic-based STPs Technical Note 8 – Emission and mathematical models of dispersion of odorants gases generated in the STPs

Companies related to environmental sanitation, such as sewage treatment plants (STP), especially those based on anaerobic effluent treatment, are faced with the need to evaluate their odorous gaseous emissions, aiming to reduce any impacts on the environment and on the surrounding community, since odorant gases emission has a real impact on people and their well-being, in addition to being one of the main reasons related to complaints and nuisance around the STP. In this context, this Technical Note discusses: (i) the application of the dynamic flux chamber for the direct measurement of volatile gas in units that have quiescent liquid surfaces (low degree of agitation); (ii) the use of algebraic mathematical models to estimate the emission rate of odorants gases in the units of a STP; and (iii) the use of dispersion models as tools to evaluate the concentration of pollutants after their emission. The required input data from each model is highlighted as well as the limitations of each process.

Soil–atmosphere exchange flux of total gaseous mercury (TGM) at subtropical and temperate forest catchments

Abstract. Evasion from soil is the largest source of mercury (Hg) to the atmosphere from terrestrial ecosystems. To improve our understanding of controls and in estimates of forest soil–atmosphere fluxes of total gaseous Hg (TGM), measurements were made using dynamic flux chambers (DFCs) over 130 and 96 d for each of five plots at a subtropical forest and a temperate forest, respectively. At the subtropical forest, the highest net soil Hg emissions were observed for an open field (24 ± 33 ng m−2 h−1), followed by two coniferous forest plots (2.8 ± 3.9 and 3.5 ± 4.2 ng m−2 h−1), a broad-leaved forest plot (0.18 ± 4.3 ng m−2 h−1) and the remaining wetland site showing net deposition (−0.80 ± 5.1 ng m−2 h−1). At the temperate forest, the highest fluxes and net soil Hg emissions were observed for a wetland (3.81 ± 0.52 ng m−2 h−1) and an open field (1.82 ± 0.79 ng m−2 h−1), with lesser emission rates in the deciduous broad-leaved forest (0.68 ± 1.01 ng m−2 h−1) and deciduous needle-leaved forest (0.32 ± 0.96 ng m−2 h−1) plots, and net deposition at an evergreen pine forest (−0.04 ± 0.81 ng m−2 h−1). High solar radiation and temperature during summer resulted in the high Hg emissions in the subtropical forest and the open field and evergreen pine forest at the temperate forest. At the temperate deciduous plots, the highest Hg emission occurred in spring during the leaf-off period due to direct solar radiation exposure to soils. Fluxes showed strong positive relationships with solar radiation and soil temperature and negative correlations with ambient air TGM concentration in both the subtropical and temperate forests, with area-weighted compensation points of 6.82 and 3.42 ng m−3, respectively. The values of the compensation points suggest that the atmospheric TGM concentration can play a critical role in limiting TGM emissions from the forest floor. Climate change and land use disturbance may increase the compensation points in both temperate and subtropical forests. Future research should focus on the role of legacy soil Hg in reemissions to the atmosphere as decreases in primary emissions drive decreases in TGM concentrations and disturbances of climate change and land use.

Soil-atmosphere exchange of gaseous elemental mercury in three subtropical forests with different substrate Hg concentrations

The subtropical forest soil in southern China has accumulated a large amount of historically deposited mercury (Hg), which may result in Hg re-emission to the atmosphere and contribute to the global Hg cycle. In this study, the soil-atmosphere exchange of gaseous elemental mercury (Hg0) was monitored using a dynamic flux chamber (DFC) method at three forest sites, with different levels of soil Hg content and atmospheric Hg0 concentration. Specifically, the background testing site, located in Qianyanzhou, showed a net annual soil Hg0 emission (2.12 ng m−2 h−1 during the day and 2.23 ng m−2 h−1 at night), with significant diurnal and seasonal variations. In contrast, the moderately polluted site, which was in Tieshanping (suburb of Chongqing city), showed a much lower annual soil Hg0 emission (0.74 ng m−2 h−1 during the day) and even negative values in spring and winter. The last site, located in Zhuzhou (near a zinc smelter) with heavy Hg contamination, showed an extremely high soil emission all through the year (37.1 ng m−2 h−1 during the day), but relatively lower value in summer (1.37 ng m−2 h−1 during the day). Overall, these results clearly indicated the stimulate effect of high soil Hg content and the suppression effect of high atmospheric Hg0 concentration on soil Hg0 emission. By considering the results, we would suggest that the future Hg emission abatement from anthropogenic sources should enhance the re-emission of historically deposited Hg from subtropical forests, thus delay the decrease in atmospheric Hg0 concentration.

Key Factors in Measuring Ammonia Emissions with Dynamic Flux Chamber in Barns

In this study, measurement methods for estimating the NH3 emissions in barns and the development of different emission factors were reviewed, and the factors to be considered when applying a dynamic flux chamber approach were analyzed. First, one of the factors to be considered when applying the dynamic flux chamber was determined as the stabilization time in the chamber. As a result of the experiment, it was confirmed that the concentration in the chamber stabilized after 45 min. This is considered to take longer than the stabilization time of 20 min suggested in the previous study. The second is the choice of the measurement method. This method includes real-time measurement and the indophenol method. As a result of the experiment in both methods, the ammonia flux showed a difference of about 10%, so both methods are considered to be considered. Therefore, it is judged that the methodology should be selected according to the situation, such as weather or electric power secured at the barn site. In the future, if studies on whether the stabilization time in the chamber can be changed according to seasonal factors and ambient temperature, and based on a sufficiently large sample size, the results will contribute to improving the reliability of the estimated ammonia(NH3) emissions and the development of an emissions factor for use in the livestock sector in Korea.

Determination of ammonia and hydrogen sulfide emissions from a commercial dairy farm with an exercise yard and the health-related impact for residents

Airborne emissions from concentrated animal feeding operations (CAFOs) have the potential to pose a risk to human health and the environment. Here, we present an assessment of the emission, dispersion, and health-related impact of ammonia and hydrogen sulfide emitted from a 300-head, full-scale dairy farm with an exercise yard in Beijing, China. By monitoring the referred gas emissions with a dynamic flux chamber for seven consecutive days, we examined their emission rates. An annual hourly emission time series was constructed on the basis of the measured emission rates and a release modification model. The health risk of ammonia and hydrogen sulfide emissions around the dairy farm was then determined using atmospheric dispersion modeling and exposure risk assessment. The body mass-related mean emission factors of ammonia and hydrogen sulfide were 2.13 kg a−1 AU−1 and 24.9 g a−1 AU−1, respectively (one animal unit (AU) is equivalent to 500 kg body mass). A log-normal distribution fitted well to ammonia emission rates. Contour lines of predicted hourly mean concentrations of ammonia and hydrogen sulfide were mainly driven by the meteorological conditions. The concentrations of ammonia and hydrogen sulfide at the fence line were below 10 μg m−3 and 0.04 μg m−3, respectively, and were 2–3 orders of magnitude lower than the current Chinese air quality standards for such pollutants. Moreover, the cumulative non-carcinogenic risks (HI) of ammonia and hydrogen sulfide were 4 orders of magnitudes lower than the acceptable risk levels (HI = 1). Considering a health risk criterion of 1E-4, the maximum distance from the farm fence line to meet this criterion was nearly 1000 m towards north-northeast. The encompassed area of the contour lines of the ambient concentration of ammonia is much larger than that of hydrogen sulfide. However, the contour lines of the ammonia health risk are analogous to those of hydrogen sulfide. In general, the ammonia and hydrogen sulfide emissions from the dairy farm are unlikely to cause any health risks for the population living in the neighborhood.

Methane oxidation of residual landfill gas in a full-scale biofilter: human health risk assessment of volatile and malodours compound emissions.

A human health risk assessment was performed to evaluate if a biofilter for the biological methane oxidation reduces the risk from exposure to landfill gas emissions and improves the air quality mitigating odour emissions from an aftercare landfill. Accordingly, three different scenarios of landfill gas management were defined, 9 volatile organic compounds (VOCs) (cyclohexane, n-hexane, 2-methylpentane, 3-methylpentane, benzene, xylenes, toluene, dichlorodifluoromethane, vinyl chloride) were identified and using the CALPUFF dispersion model; the pollutant concentration at eleven sensitive receptors was determined. Consequently, the risk (for cancer and non-cancer compounds) was assessed applying the methodology proposed by USEPA 2009. From one hand, to determine concentration and emission rates of VOCs and hydrogen sulphide, a sample of raw landfill gas and three air samples from the biofilter surface were collected with dynamic flux chamber method and analysed in accordance with US EPA, 1986 and USEPA TO-15, 1999. To the other hand, odour emissions were assessed based both on chemical and dynamic olfactometric measurements (EN 13725:2003). The field surveys results showed a reduction of the cancer risk on average by 79% and of the hazard quotient on average by 92%. In contrast, the results of olfactometry measurements showed a lower efficiency on odour reduction than the target value of 70%. Nonetheless, the odour concentration was always far below 300uoEm-3 at the biofilter surface and odour concentration never exceed 1uoEm-3 at the sensitive receptors.

Comparison of mass transfer parameters inside a USEPA flux hood for two VOCs.

Odorous emissions from area sources at wastewater treatment plants have become an environmental issue due to negative impacts on neighboring communities causing annoyance. Enclosure devices (such as dynamic flux chambers) have been used as direct methods to estimate area source emission rates from liquid-gas surfaces. Previously, model compounds have provided information about the internal mass transfer behavior of these sampling devices and the parameters estimated for certain model compounds that can be adapted for other compounds with similar liquid-gas partitioning properties. Acetic acid and butyric acid (both gas-phase-controlled compounds) were compared in order to assess the validity of adapting results from one compound to another. Mass transfer parameters for acetic acid and butyric acid were determined for a USEPA flux hood using a sweep air flow rate of 5 L/min. Mass transfer rates estimated for butyric acid, using the mass transfer parameters of acetic acid, were of the same order of magnitude as the experimental butyric acid mass transfer rates.

Recent advances in understanding and measurement of Hg in the environment: Surface-atmosphere exchange of gaseous elemental mercury (Hg0)

The atmosphere is the major transport pathway for distribution of mercury (Hg) globally. Gaseous elemental mercury (GEM, hereafter Hg0) is the predominant form in both anthropogenic and natural emissions. Evaluation of the efficacy of reductions in emissions set by the UN's Minamata Convention (UN-MC) is critically dependent on the knowledge of the dynamics of the global Hg cycle. Of these dynamics including e.g. red-ox reactions, methylation-demethylation and dry-wet deposition, poorly constrained atmosphere–surface Hg0 fluxes especially limit predictability of the timescales of its global biogeochemical cycle. This review focuses on Hg0 flux field observational studies, namely the theory, applications, strengths, and limitations of the various experimental methodologies applied to gauge the exchange flux and decipher active sub-processes. We present an in-depth review, a comprehensive literature synthesis, and methodological and instrumentation advances for terrestrial and marine Hg0 flux studies in recent years. In particular, we outline the theory of a wide range of measurement techniques and detail the operational protocols. Today, the most frequently used measurement techniques to determine the net Hg0 flux (>95% of the published flux data) are dynamic flux chambers for small-scale and micrometeorological approaches for large-scale measurements. Furthermore, top-down approaches based on Hg0 concentration measurements have been applied as tools to better constrain Hg emissions as an independent way to e.g. challenge emission inventories. This review is an up-dated, thoroughly revised edition of Sommar et al. 2013 (DOI: 10.1080/10643389.2012.671733). To the tabulation of >100 cited flux studies 1988–2009 given in the former publication, we have here listed corresponding studies published during the last decade with a few exceptions (2008–2019). During that decade, Hg stable isotope ratios of samples involved in atmosphere-terrestrial interaction is at hand and provide in combination with concentration and/or flux measurements novel constraints to quantitatively and qualitatively assess the bi-directional Hg0 flux. Recent efforts in the development of relaxed eddy accumulation and eddy covariance Hg0 flux methods bear the potential to facilitate long-term, ecosystem-scale flux measurements to reduce the prevailing large uncertainties in Hg0 flux estimates. Standardization of methods for Hg0 flux measurements is crucial to investigate how land-use change and how climate warming impact ecosystem-specific Hg0 sink-source characteristics and to validate frequently applied model parameterizations describing the regional and global scale Hg cycle.

Soil-air exchange of mercury from agricultural fields in Zhejiang, East China: Seasonal variations, influence factors, and models of fluxes

Mercury exchange between soil and air is an important processe governing the biogeochemical cycling of Hg. This study investigated the in situ soil-air Hg fluxes in agricultural soils of Quzhou, Zhejiang Province, China, using a dynamic flux chamber coupled with a Hg vapor analyzer. Soil-air Hg exchange fluxes were overall emission for all seasons, indicating that agricultural soil was a Hg source for the atmosphere. Seasonal variations in soil-air Hg flux were observed, with low values in winter, elevated values in spring, peak values in summer, and a decline in autumn. Mercury emissions from soils showed a clear diurnal pattern where Hg released into the atmosphere reached a maximum at 11 a.m. and declined to a minimum at 2:00 and 20:00 in spring and summer, respectively. Meanwhile, soil-air Hg flux peaked at 1 p.m. and declined to a minimum at 6:00 and 23:00 in autumn and winter, respectively. The impact of each factor on the Hg exchange between soil and air varied in different seasons. Soil temperature was the major variable controlling the Hg flux in winter and spring; soil temperature and total gaseous Hg evidently affected the Hg flux in summer, and ozone (O3) played a dominant role in influencing the Hg flux in autumn. Models for estimating the Hg evasive flux from soils were developed, and the atmospheric O3 concentration was used for the first time as a parameter in these models. The measured and modeled Hg fluxes showed significant linear correlations (R2 = 0.61; P < 0.001).