Two DGAs are called topologically equivalent if the corresponding Eilenberg-Mac Lane ring spectra are weakly equivalent as ring spectra. Quasi-isomorphic DGAs are topologically equivalent but the converse is not necessarily true. As a counter-example, Dugger and Shipley showed that there are DGAs that are non-trivially topologically equivalent, i.e. topologically equivalent but not quasi-isomorphic. In this work, we define $E_\infty$ topological equivalences and utilize the obstruction theories developed by Goerss, Hopkins and Miller to construct first examples of non-trivially $E_\infty$ topologically equivalent $E_\infty$ DGAs. Also, we show using these obstruction theories that for co-connective $E_\infty$ DGAs, $E_\infty$ topological equivalences and quasi-isomorphisms agree. For $E_\infty$ $\mathbb{F}_p$-DGAs with trivial first homology, we show that an $E_\infty$ topological equivalence induces an isomorphism in homology that preserves the Dyer-Lashof operations and therefore induces an $H_\infty $ $\mathbb{F}_p$-equivalence.