Dust Front Research Articles

On Saharan Air Layer Stability and Suppression of Convection over the Northern Tropical Atlantic: Case Study Analysis of a 2007 Dust Outflow Event

A prominent Saharan Air Layer (SAL) was detected over the Northern Atlantic from the West African Coast to the Caribbean Sea in 2007. Data was collected from the Aerosols and Ocean Science Expedition (AEROSE), which encountered a major dust outflow on 13 and 14 May 2007. These observational measurements came from onboard instrumentation and radiosondes that captured the dust-front event from 13 to 14 May 2007. Aerosol backscatter was confined within the Marine Boundary Layer (MBL), with layers detected up to 3 km. Aerosol Optical Depth (AOD) increased by one order of magnitude during the dust front, from 0.1 to 1. Downward solar radiation was also attenuated by 200 W/m2 and 100 W/m2 on the first and second days, respectively. A weaker gradient at and above 500 m from potential temperature profiles indicates a less-defined MBL, and an ambient air temperature of 26 °C on 14 May and 28 °C on 15 May were observed above 500 m, reinforcing the temperature inversion and static stability of the SAL. Subsequent days, clear and boundary-layer cloudy days were observed after the dust front. From 14 to 18 May, a Convective Inhibition (CIN) layer started to form at the top of the MBL, developing into a negative buoyancy from 17 to 23 May, and reinforcing the large-scale anticyclonic atmospheric conditions. These results show that the SAL acts as positive feedback on suppressing deep convection over the tropical Atlantic during this dust outflow and several days after its passage.

CFD modeling of particle dispersion behavior in the MIKE 3 apparatus

A simulation investigation on the flow domain and particle movement pattern in the dispersion stage of dust explosion experiment were conducted using CFD simulation based on Euler–Lagrange approach. A new solver that couples two phases was developed based on the default solver rhoPimpleFoam from the OpenFOAM tool kit. Three sizes of particles 25 μm, 125 μm and 250 μm were simulated and studied. The simulation results of dust front propagation were evaluated by the experiment data. Particles with smaller diameters tended to move slower. Due to the high turbulence, flow vortices in the lower part of the dispersion domain were identified. These vortices gradually became larger with time and the decrease of inflow velocity. Uneven distribution of particles along with the equipment and high concentration of particles between the discharge electrodes were found in the simulation. Furthermore, particles with higher velocity favored the middle position in the tube. These facts suggested that the ignition delay time for particles larger than 125 μm should be higher than 60 ms.

Atmospheric Dynamics of a Saharan Dust Outbreak Over Mindelo, Cape Verde Islands, Preceded by Rossby Wave Breaking: Multiscale Observational Analyses and Simulations

AbstractWe investigate the synoptic precursors to the Harmattan wind and dust frontogenesis during the high impact Saharan dust outbreak over the Cape Verde Islands on 13 November 2017. We employ multiscale observations and the Weather Research and Forecasting model Coupled with Chemistry simulations. The analyses indicate that the dust storm was initiated on the lee side of the Saharan Atlas Mountains (SAM) in Algeria on 10 November 2017. This dust storm was associated with a double Rossby wave break linked through nonlinear wave reflection. Two successive Rossby wave breaks contributed to the wave amplification over the Eastern North Atlantic Ocean which transported large magnitude potential vorticity air into the North African continent. The resulting coupled pressure surge was associated with cold air advected equatorward over the SAM which organized the strong near‐surface wind that ablated the dust. The simulation results indicate that the dust front was initially related to a density current‐like cold front which formed due to the downslope transport of cold airflow over the SAM and then triggered undular bores on the lee side. Each bore perturbed the dust loading and then the subsequent diurnal heating generated differential planetary boundary layer turbulence kinetic energy strengthening the dust frontogenesis. Dust became confined behind the cold surge and interacted with the daytime Saharan planetary boundary layer leading to increased dust loading, while the dust front propagated equatorward. Two distinct dust plumes arrived successively at low levels at Mindelo, Cape Verde Islands: (1) from the coasts of Mauritania and Senegal and (2) from the SAM southern flank.

Three‐dimensional pathways of dust over the Sahara during summer 2011 as revealed by new Infrared Atmospheric Sounding Interferometer observations

AbstractWe present a new characterisation of the three‐dimensional (3D) distribution of dust over the Sahara during summer, exemplified for June 2011. Our approach, called AEROIASI, is based on the innovative retrieval of vertical profiles of the dust extinction coefficient from daily cloud‐free hyperspectral Infrared Atmospheric Sounder Interferometer (IASI) satellite observations. AEROIASI observations clearly agree with other widely used measurements (from lidar and radiometers). The 3D characterisation is focused on the dust maximum in June 2011, located in the central Sahara (17–23°N, 1–7°E) and linked to the major atmospheric dynamical drivers associated with the West African Monsoon (WAM) system. AEROIASI shows the near‐surface dust load to be dominated by five major emission events occurring every 3–4 days. These all occur when the study region is under the influence of northward bursts of the WAM and convection‐related cold pools, likely associated with orographic forcing by the Aïr Mountains. During the earliest (June 10) and the dustiest (June 17) cases, northward advection of moisture over the hotspot is favoured by the superposition of cyclonic circulations related to an extratropical disturbance northwest of the Sahara and to the Saharan heat low over Mauritania, respectively. Convection over the hotspot also triggers wave‐like disturbances that travel westwards. The three dustiest events are characterised by elongated dust fronts moving northwards, with a leading edge spanning 200–300 km horizontally and extending from the surface up to 2 km of altitude. Further south, the dust layer progressively elevates to 3.5 km along the slanted isentropes at the interface of the monsoon and the harmattan, increasingly losing contact with the ground. When northerlies blow over the study region, elevated dust layers at 3–5 km are observed, which are transported southwards within the Saharan air layer and westwards along the northern edge of the African easterly jet (after June 13).

Dust tides and rapid meridional motions in the Martian atmosphere during major dust storms

The atmosphere of Mars is strongly affected by the spatial and temporal variability of airborne dust. However, global dust variability within a sol (Martian day) is still poorly understood. Although short-term dynamic processes are crucial, detailed comparisons of simulated diurnal variations are limited by relatively sparse observations. Here, we report the discovery of ubiquitous, strong diurnal tides of dust in the Southern Hemisphere of Mars. Driven by the westward-propagating migrating diurnal thermal tide, zonally distributed dust fronts slosh back and forth in a wide latitudinal range of up to 40° within one sol during major dust storms. Dust tides—tidal transport of dust in this way—rapidly transport heat and constituents meridionally, allowing moist air near the summer pole to be rapidly transported to lower latitudes during the night, where it then can be lifted by daytime deep convection and contribute to hydrogen escape from Mars during global dust storms.

Disentangling Planets from Photoelectric Instability in Gas-rich Optically Thin Dusty Disks

Abstract Structures in circumstellar disks such as gaps and rings are often attributed to planets. This connection has been difficult to show unequivocally, as other processes may also produce these features. In particular, a photoelectric instability (PEI) has been proposed, operating in gas-rich optically thin disks, that generates structures predicted by planet–disk interactions. We examine the question of how to disentangle the planetary effects on disk structure from the effects of the PEI. We use the Pencil Code to perform 2D global hydrodynamical models of the dynamics of gas and dust in a thin disk with and without planetary perturbers. Photoelectric heating is modeled with an equation of state where pressure is proportional to dust surface density. The drag force on grains and its backreaction on the gas are included. Analyzing the situation without PEI, we find that gas–dust interactions alter the shape of the planetary gap from the dust-free case when the local dust-to-gas ratio ε approaches unity. This result also applies to primordial disks, because dust drifting inward accumulates at the edge of the planetary gap, and any initial dust-to-gas ratio eventually achieves ε = 1 if the dust reservoir is sufficient. We find a result particular to high dust-to-gas ratio disks as well: as dust drifts inward, the dust front becomes a sharp transition, and the backreaction triggers the Rossby wave instability. When PEI is included, we find that it obscures structures induced by planets unless the planet’s mass is sufficiently large to carve a noticeable gap. Specifically, the instability generates arcs and rings of regular spacing: a planet is discernible when it carves a dust gap wider than the wavelength of the PEI.

Extreme dust storm over the eastern Mediterranean in September 2015: satellite, lidar, and surface observations in the Cyprus region

Abstract. A record-breaking dust storm originating from desert regions in northern Syria and Iraq occurred over the eastern Mediterranean in September 2015. In this contribution of a series of two articles (part 1, observations; part 2, atmospheric modeling), we provide a comprehensive overview of the aerosol conditions during this extreme dust outbreak in the Cyprus region. These observations are based on satellite observations (MODIS, moderate resolution imaging spectroradiometer) of aerosol optical thickness (AOT) and Ångström exponent, surface particle mass (PM10) concentrations measured at four sites in Cyprus, visibility observations at three airports in southern Cyprus and corresponding conversion products (particle extinction coefficient, dust mass concentrations), EARLINET (European Aerosol Research Lidar Network) lidar observations of dust vertical layering over Limassol, particle optical properties (backscatter, extinction, lidar ratio, linear depolarization ratio), and derived profiles of dust mass concentrations. Maximum 550 nm AOT exceeded values of 5.0, according to MODIS, and the mass loads were correspondingly > 10 g m−2 over Larnaca and Limassol during the passage of an extremely dense dust front on 8 September 2015. Hourly mean PM10 values were close to 8000 µg m−3 and the observed meteorological optical range (visibility) was reduced to 300–750 m at Larnaca and Limassol. The visibility observations suggest peak values of the near-surface total suspended particle (TSP) extinction coefficients of 6000 Mm−1 and thus TSP mass concentrations of 10 000 µg m−3. The Raman polarization lidar observations mainly indicated a double layer structure of the dust plumes (reaching to about 4 km height), pointing to at least two different dust source regions. Dust particle extinction coefficients (532 nm) already exceeded 1000 Mm−1 and the mass concentrations reached 2000 µg m−3 in the elevated dust layers on 7 September, more than 12 h before the peak dust front on 8 September reached the Limassol lidar station around local noon. Typical Middle Eastern dust lidar ratios around 40 sr were observed in the dense dust plumes. The particle depolarization ratio decreased from around 0.3 in the lofted dense dust layers to 0.2 at the end of the dust period (11 September), indicating an increasing impact of anthropogenic haze.

High-resolution dust modelling over complex terrains in West Asia

The present work demonstrates the impact of model resolution in dust propagation in a complex terrain region such as West Asia. For this purpose, two simulations using the NMMB/BSC-Dust model are performed and analysed, one with a high horizontal resolution (at 0.03° × 0.03°) and one with a lower horizontal resolution (at 0.33° × 0.33°). Both model experiments cover two intense dust storms that occurred on 17–20 March 2012 as a consequence of strong northwesterly Shamal winds that spanned over thousands of kilometres in West Asia. The comparison with ground-based (surface weather stations and sunphotometers) and satellite aerosol observations (Aqua/MODIS and MSG/SEVIRI) shows that despite differences in the magnitude of the simulated dust concentrations, the model is able to reproduce these two dust outbreaks. Differences between both simulations on the dust spread rise on regional dust transport areas in south-western Saudi Arabia, Yemen and Oman. The complex orography in south-western Saudi Arabia, Yemen and Oman (with peaks higher than 3000 m) has an impact on the transported dust concentration fields over mountain regions. Differences between both model configurations are mainly associated to the channelization of the dust flow through valleys and the differences in the modelled altitude of the mountains that alters the meteorology and blocks the dust fronts limiting the dust transport. These results demonstrate how the dust prediction in the vicinity of complex terrains improves using high-horizontal resolution simulations.

Aerosol data assimilation using data from Himawari‐8, a next‐generation geostationary meteorological satellite

AbstractHimawari‐8, a next‐generation geostationary meteorological satellite, was launched on 7 October 2014 and became operational on 7 July 2015. The advanced imager on board Himawari‐8 is equipped with 16 observational bands (including three visible and three near‐infrared bands) that enable retrieval of full‐disk aerosol optical properties at 10 min intervals from geostationary (GEO) orbit. Here we show the first application of aerosol optical properties (AOPs) derived from Himawari‐8 data to aerosol data assimilation. Validation of the assimilation experiment by comparison with independent observations demonstrated successful modeling of continental pollution that was not predicted by simulation without assimilation and reduced overestimates of dust front concentrations. These promising results suggest that AOPs derived from Himawari‐8/9 and other planned GEO satellites will considerably improve forecasts of air quality, inverse modeling of emissions, and aerosol reanalysis through assimilation techniques.

HUBBLE SPACE TELESCOPEAND HI IMAGING OF STRONG RAM PRESSURE STRIPPING IN THE COMA SPIRAL NGC 4921: DENSE CLOUD DECOUPLING AND EVIDENCE FOR MAGNETIC BINDING IN THE ISM

Remarkable dust extinction features in the deep HST V and I images of the face-on Coma cluster spiral galaxy NGC 4921 show in unprecedented ways how ram pressure strips the ISM from the disk of a spiral galaxy. New VLA HI maps show a truncated and highly asymmetric HI disk with a compressed HI distribution in the NW, providing evidence for ram pressure acting from the NW. Where the HI distribution is truncated in the NW region, HST images show a well-defined, continuous front of dust that extends over 90 degrees and 20 kpc. This dust front separates the dusty from dust-free regions of the galaxy, and we interpret it as galaxy ISM swept up near the leading side of the ICM-ISM interaction. We identify and characterize 100 pc-1 kpc scale substructure within this dust front caused by ram pressure, including head-tail filaments, C-shaped filaments, and long smooth dust fronts. The morphology of these features strongly suggests that dense gas clouds partially decouple from surrounding lower density gas during stripping, but decoupling is inhibited, possibly by magnetic fields which link and bind distant parts of the ISM.

Lagrangian dust model simulations for a case of moist convective dust emission and transport in the western Sahara region during Fennec/LADUNEX

AbstractDue to the harshness and inaccessibility of desert regions, the uncertainties concerning the processes of dust mobilization at the surface, airborne transport, and sedimentation are still considerable, limiting the ability to perform model simulations. In June 2011, a comprehensive data set of ground‐based and airborne in situ measurements and remote sensing observations was acquired within the Fennec/Lagrangian Dust Source Inversion Experiment (LADUNEX) field campaign in the western Sahara region. Here we evaluate the ability of the state‐of‐the‐art Lagrangian particle dispersion model FLEXPART, newly fitted with a dust mobilization capability, to simulate dust transport in this region. We investigate a case where a large mesoscale convective system (MCS) triggered dust emissions in central Mali, which subsequently moved as a large cold pool dust front toward northern Mauritania. Specifying dust mobilization for this case is shown to be an important obstacle to simulating dust transport during this event, since neither the MCS nor the associated cold pool‐causing dust emission is represented in the meteorological analysis. Obtaining a realistic dust transport simulation for this case therefore requires an inversion approach using a manual specification of the dust sources supported by satellite imagery. When compared to in situ and remote sensing data from two aircraft, the Lagrangian dust transport simulations represent the overall shape and evolution of the dust plume well. While accumulation and coarse mode dust are well represented in the simulation, giant mode particles are considerably underestimated. Our results re‐emphasize that dust emission associated with deep moist convection remains a key issue for reliable dust model simulations in northern Africa.

THE PARSEC-SCALE ENVIRONMENT AND THE EVOLUTIONARY STATUS OF MWC 349A

We report on a study of the ~10' (~5 pc in projection) environs of the peculiar, high-luminosity emission-line star MWC 349A in the IR, radio, and visible domains. Besides the recently discovered X-shaped, arcmin-scale IR nebula centered on MWC 349A (X nebula), with the kinematic age of ~104 yr, we identify several young objects pointing toward an ongoing process of active star formation in this region and estimate some physical parameters of the newly discovered objects. The radiation of the X nebula is due to a geometrically and optically thin dust front heated to Td 60-70 K by the radiation of the central star. The bipolar dust front probably results from the interaction of a powerful stellar wind with the circumstellar disk. One of the related objects is an elongated, cold molecular cloud, ~1 pc in size, adjacent to MWC 349A in projection and having the same radial velocity (V LSR +9 km s–1). The proximity of the molecular cloud may indicate that MWC 349A was born locally rather than being a runaway object ejected from the core of Cyg OB2 several Myr ago. If it is still associated with its natal cloud, MWC 349A may be a rare example of the observable pre-main-sequence stage of a ~30 M ☉ star. If the association with the molecular cloud is an effect of projection, however, MWC 349A may already be an evolved star, even if it was born locally. We discuss future observations that may shed more light on the evolutionary status of this unique object.

Observed Chemical Characteristics of Long-Range Transported Particles at a Marine Background Site in Korea

ABSTRACT Deokjeok Island is located off the west coast of the Korean Peninsula and is a suitable place to monitor the long-range transport of air pollutants from the Asian continent. In addition to pollutants, Asian dust particles are also transported to the island during long-range transport events. Episodic transport of dust and secondary particles was observed during intensive measurements in the spring (March 31–April 11) and fall (October 13–26) of 2009. In this study, the chemical characteristics of long-range-transported particles were investigated based on highly time-resolved ionic measurements with a particle-into-liquid system coupled with an online ion chromatograph (PILS-IC) that simultaneously measures concentrations of cations (Li+, Na+, NH4 +, K+, Ca2+, Mg2+) and anions (F−, Cl−, NO3 −, SO4 2−). The aerosol optical thickness (AOT) distribution retrieved by the modified Bremen Aerosol Retrieval (M-BAER) algorithm from moderate resolution imaging spectroradiometer (MODIS) satellite data confirmed the presence of a thick aerosol plume coming from the Asian continent towards the Korean peninsula. Seven distinctive events involving the long-range transport (LRT) of aerosols were identified and studied, the chemical components of which were strongly related to sector sources. Enrichment of acidic secondary aerosols on mineral dust particles, and even of sea-salt components, during transport was observed in this study. Backward trajectory, chemical analyses, and satellite aerosol retrievals identified two distinct events: a distinctively high [Ca2++Mg2+]/[Na+] ratio (>2.0), which was indicative of a preprocessed mineral dust transport event, and a low [Ca2++Mg2+]/[Na+] ratio (<2.0), which was indicative of severe aging of sea-salt components on the processed dust particles. Particulate Cl− was depleted by up to 85% in spring and 50% in the fall. A consistent fraction of carbonate replacement (FCR) averaged 0.53 in spring and 0.55 in the fall. Supporting evidences of Cl− enrichment on the marine boundary layer prior to a dust front were also found. Supplemental materials are available for this article. Go to the publisher's online edition of the Journal of the Air & Waste Management Association for sector and air mass classifications of clean and LRT cases. IMPLICATIONS The chemical characteristics of aerosol particles evolve as they undergo long-range transport (LRT) in the atmosphere from the source region. Aside from meteorological conditions, the signature of the source region influences the loading and chemical characteristics of LRT aerosols.

Phoenix and MRO coordinated atmospheric measurements

The Phoenix and Mars Reconnaissance Orbiter (MRO) missions collaborated in an unprecedented campaign to observe the northern polar region summer atmosphere throughout the Phoenix mission (25 May to 2 November 2008; Ls = 76°–150°) and slightly beyond (∼Ls = 158°). Five atmospherically related campaigns were defined a priori and were executed on 37 separate Martian days (sols). Phoenix and MRO observed the atmosphere nearly simultaneously. We describe the observation strategy and history, the participating experiments, and some initial results. We find that there is general agreement between measurements from different instruments and platforms and that complementary measurements provide a consistent picture of the atmosphere. Seasonal water abundance behavior matches with historical measurements. Winds aloft, as measured by cloud motions, showed the same seasonally consistent, diurnal rotation as the winds measured at the lander, during the first part of the mission (Ls = 76°–118°). A diurnal cycle recorded from Ls ∼ 108.3°–109.1°, in which a dust front was approaching the Phoenix Lander, is examined in detail. Cloud heights measured on subsequent orbits showed that in areas of active lifting, dust can be lofted quite high in the atmosphere, doubling in height over 2 h. The combination of experiments also revealed that there were discrete vertical layers of water ice and dust. Water vapor column abundances compared to near‐surface water vapor pressure indicate that water is not well mixed from the surface to a cloud condensation height and that the depth of the layer that exchanges diurnally with the surface is 0.5–1 km.

African dust outbreaks: A satellite perspective of temporal and spatial variability over the tropical Atlantic Ocean

We describe the temporal evolution and spatial structure of extreme African dust outbreaks and their associated meteorological fields over West Africa and the tropical Atlantic using A‐Train data and a global reanalysis product. We used Aqua–Moderate Resolution Imaging Spectroradiometer daily aerosol optical depth (AOD) to identify major dust outbreaks, defined as AOD events one standard deviation above the background along the African coast. Dry air outbreaks were defined using water vapor data of the Aqua Atmospheric Infrared Sounder. Dry air outbreaks do not always coincide with dust outbreaks. Most boreal summer outbreaks reached the West Indies between 10°N and 20°N, some traveling on to the southeastern United States; winter outbreaks moved to South America between 0° and 10°N. Outbreaks travel westward at an average speed of 1000 km d−1, reaching the Caribbean or South America in a week's time. The advance of a dust front is associated with decreases in water vapor (up to −1.0 g kg−1) and increases in temperature (up to 1.0 K) and, behind the fronts, an anticyclonic circulation. We used Cloud‐Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) data to characterize dust altitude distributions. The vertical distribution of warm dry air is similar to that of dust observed in CALIPSO. The dust layer altitude decreases during transport across the Atlantic and is significantly lower in boreal winter than summer. The study highlights the temporal and spatial variability of African dust outbreaks, which are important to improving our understanding of climate impacts of African dust and Atlantic climate variability in general.

Meteorological processes forcing Saharan dust emission inferred from MSG‐SEVIRI observations of subdaily dust source activation and numerical models

Fifteen‐minute Meteosat Second Generation (MSG) Spinning Enhanced Visible and Infrared Imager (SEVIRI) infrared dust index images are used to identify dust source areas. The observations of dust source activation (DSA) are compiled in a 1° × 1° map for the Sahara and Sahel, including temporal information at 3‐hourly resolution. Here we use this data set to identify the most active dust source areas and the time of day when dust source activation occurs most frequently. In the Sahara desert 65% of DSA (March 2006 to February 2008) occurs during 0600–0900 UTC, pointing toward an important role of the breakdown of the nocturnal low‐level jet (LLJ) for dust mobilization. Other meteorological mechanisms may lead to dust mobilization including density currents initiated by deep convective systems which mobilize dust fronts (haboobs) occurring preferentially in the afternoon hours and cyclonic activities. The role of the nocturnal LLJ for dust mobilization in the Sahara is corroborated by regional model studies and analysis of meteorological station data.

Characterization of three atmospheric aerosol episodes at a coastal site in China: Implications for regional transport of air pollution

Size-selective atmospheric aerosol samples, collected between March 28 and April 8 2002 in Changdao, a small island in eastern China, were characterized by analysis of elements, ions, organic and elemental carbon, lead isotopes, and single particles. On the basis of compositional differences and remote sensing information, three distinct aerosol pollution episodes were identified. The first was dominated by fine particles with a substantial contribution from biomass burning emissions and industrial lead-containing particles from inland China at least 800 kilometers away. The second was characterized by coarse and aged secondary calcium sulfate particles and primary calcium sulfate particles from local industrial sources as well as windblown mineral dust. The third was a typical Asian Dust event with a source region on the border between China and Mongolia at a distance of around 1000 kilometers. Abundant sulfate particles found at the beginning of the Asian Dust event were predominantly ammonium sulfates in the fine fraction and calcium and ammonium sulfates in the coarse fraction. The major portion of the pollutants and the dust front of the event arrived in separate air masses. Although the three events occurred in quick succession they were quite different in terms of size distribution, chemical composition, sulfate speciation, source types, and source geographic locations. Biomass burning, industrial emission, coal combustion, and mineral dusts were identified as sources of the Asian continental outflow.

Mineral dust is a sink for chlorine in the marine boundary layer

Dust particles affect the budgets of important traces gases by providing a surface on which heterogeneous reactions can occur. The uptake of soluble species on dust alters the physical, chemical, and optical properties and the overall ability of dust to act as cloud condensation and ice nuclei. It is commonly assumed that all measured chloride in particulate filter samples is associated with sea-salt particles and any chloride in dust occurs as the result of internal mixtures of sea-salt and dust particles, formed by cloud processing. Here we show high temporal resolution data demonstrating the direct uptake of chlorine by dust via heterogeneous reaction with HCl(g). This reaction added significant amounts of chlorine to the dust particles during a major dust storm, representing 4–9% of the individual dust particle mass. Up to 65±4% of the dust particles contained chlorine due to this heterogeneous reaction during the dust front. Ignoring this process leads to an overestimation of sea-salt concentrations from bulk measurements, and an underestimation of the degree of sea-salt aging. The uptake of chloride will change the pH and hygroscopic properties of the dust and thus can influence the budgets of other reactive gases. Including this heterogeneous process in atmospheric measurements and chemical transport models will improve our ability to predict the atmosphere's composition and radiation budget with greater accuracy.

Direct observations of the atmospheric processing of Asian mineral dust

Abstract. The accumulation of secondary acids and ammonium on individual mineral dust particles during ACE-Asia has been measured with an online single-particle mass spectrometer, the ATOFMS. Changes in the amounts of sulphate, nitrate, and chloride mixed with dust particles correlate with air masses from different source regions. The uptake of secondary acids depended on the individual dust particle mineralogy; high amounts of nitrate accumulated on calcium-rich dust while high amounts of sulphate accumulated on aluminosilicate-rich dust. Oxidation of S(IV) to S(VI) by iron in the aluminosilicate dust is a possible explanation for this enrichment of sulphate, which has important consequences for the fertilization of remote oceans by soluble iron. This study shows the segregation of sulphate from nitrate and chloride in individual aged dust particles for the first time. A transport and aging timeline provides an explanation for the observed segregation. Our data suggests that sulphate became mixed with the dust first. This implies that the transport pathway is more important than the reaction kinetics in determining which species accumulate on mineral dust. Early in the study, dust particles in volcanically influenced air masses were mixed predominately with sulphate. Dust mixed with chloride then dominated over sulphate and nitrate when a major dust front reached the R. V. Ronald Brown. We hypothesize that the rapid increase in chloride on dust was due to mixing with HCl(g) released from acidified sea salt particles induced by heterogeneous reaction with volcanic SO2(g), prior to the arrival of the dust front. The amount of ammonium mixed with dust correlated strongly with the total amount of secondary acid reaction products in the dust. Submicron dust and ammonium sulphate were internally mixed, contrary to frequent reports that they exist as external mixtures. The size distribution of the mixing state of dust with these secondary species validates previous mechanisms of the atmospheric processing of dust and generally agrees with simulated aerosol chemistry from the STEM-2K3 model. This series of novel results has important implications for improving the treatment of dust in global chemistry models and highlights a number of key processes that merit further investigation through laboratory and field studies.

COAMPS Real-Time Dust Storm Forecasting during Operation Iraqi Freedom

Abstract Dust storms are a significant weather phenomenon in the Iraq region in winter and spring. Real-time dust forecasting using the U.S. Navy’s Coupled Ocean–Atmospheric Mesoscale Prediction System (COAMPS) with an in-line dust aerosol model was conducted for Operation Iraqi Freedom (OIF) in March and April 2003. Daily forecasts of dust mass concentration, visibility, and optical depth were produced out to 72 h on nested grids of 9-, 27-, and 81-km resolution in two-way nest interaction. In this paper, the model is described, as are examples of its application during OIF. The model performance is evaluated using ground weather reports, visibility observations, and enhanced satellite retrievals. The comparison of the model forecasts with observations for the severe dust storms of OIF shows that COAMPS predicted the arrival and retreat of the major dust events within 2 h. In most cases, COAMPS predicted the intensity (reduction in visibility) of storms with an error of less than 1 km. The forecasts of the spatial distribution of dust fronts and dust plumes were consistent with those seen in the satellite images and the corresponding cold front observations. A statistical analysis of dust-related visibility for the OIF period reveals that COAMPS generates higher bias, rms, and relative errors at the stations having high frequencies of dust storms and near the source areas. The calculation of forecast accuracy shows that COAMPS achieved a probability of dust detection of 50%–90% and a threat score of 0.3–0.55 at the stations with frequent dust storms. Overall, the model predicted more than 85% of the observed dust and nondust weather events at the stations used in the verification for the OIF period. Comparisons of the forecast rates and statistical errors for the forecasts of different lengths (12–72 h) for both dust and dynamics fields during the strong dust storm of 26 March revealed little dependence of model accuracy on forecast length, implying that the successive COAMPS forecasts were consistent for the severest OIF dust event.