Ductile Deformation Research Articles

Recycled PET Packaging Materials of Improved Toughness— Importance of Devitrification of the Rigid Amorphous Fraction

AbstractDegradation, a common problem faced during the processing of recycled poly(ethylene terephthalate) (PET), leads to significant embrittlement of the products, as a result of which the material loses its applicability. Increased crystallization rate of the short chains of recycled PET and obstructed mobility of the amorphous phase are the main causes of enhanced brittleness. In this research, a straightforward method is proposed for improving the toughness of recycled PET products, namely the devitrification of the rigid amorphous phase by thermal annealing, which results in enhanced molecular mobility in the amorphous fraction, thereby promoting ductile deformation. The effects of thermal annealing conditions are comprehensively evaluated on the microstructure and macroscopic properties, i.e., impact resistance, of recycled PET films. The perforation energy value of the recycled PET film is found to increase to its threefold, reaching a value higher than 18 J mm−1, as a result of 10 s thermal treatment at 120 °C. Differential scanning calorimetry, dynamic mechanical analyses, and thermally stimulated depolarization current measurements provide evidence for the devitrification of the rigid amorphous fraction under these conditions, which is the key to efficient enhancement in toughness.

A pluton-dike system as an incomplete assembled pluton: field geology, petrography and geochemistry of the Rodríguez dike swarm and the Kranck pluton, Fuegian Andes

Dikes extending into the host-rock are a common feature at pluton roofs. Typically, the dikes are considered offshoots from differentiated magma reservoirs within the pluton, i.e. late-stage intrusions of the successive discrete magma pulses that built the pluton. We evaluate this hypothesis on a dike swarm and associated pluton, the Kranck-Rodríguez pluton-dike system, by analyzing its field geology, petrography and geochemistry (whole-rock and mineral). This system was emplaced in the shallow crust (∼1.7 kbar) within the fold-and-thrust belt of the Fuegian Andes. The Kranck pluton is a small (∼4.4 km2), composite body composed of a diverse range of lithologies, from mafic to felsic. Internal contacts are mainly sharp and subvertical, suggesting diking as a mode of assembly. The Rodríguez dike swarm extends up to 6 km from the pluton, mainly exposed adjacent to it. This swarm also displays a wide variety of lithotypes, encompassing a set of dikes affected by ductile deformation, and a younger set without it. Geochemical and petrographic analyses, along with thermobarometry, suggest that the Rodríguez dikes and lithotypes within the pluton were fed from different, deeper magma reservoirs, in an inferred trans-crustal plumbing system. We propose that the dikes represent discrete increments of the growing pluton, in a protracted process of successive injections. This ultimately led to the assembly of the pluton in the sector of the system with greater magma flux. The system developed in two major episodes, pre- and post-ductile deformation, each characterized by multiple, discrete magma injections. We consider this system as an embryonic stage of a broader model that would evolve from sheets separated by host-rock, to bodies with sheeted margins containing host-rock rafts, and eventually to relatively inclusion-free plutons, potentially forming larger bodies if provided with a greater magma supply and/or higher accretion rates.

Fluid inclusion characteristics and mechanisms of tin mineralisation in the Jialong tin polymetallic deposits, Jiuwandashan–Yuanbaoshan, northern Guangxi, China

The Jiuwandashan–Yuanbaoshan area, which is located in the western Jiangnan orogenic belt, has experienced frequent tectonic and magmatic events, and contains extensive Neoproterozoic Sn–polymetallic deposits. The Jialong Sn–polymetallic deposit is located in the northeastern part of the Neoproterozoic Yuanbaoshan granite and superimposed Sirong ductile shear zone and represents the first Caledonian Sn–polymetallic deposit discovered in this area. In this study, we investigated the mechanisms of Caledonian Sn mineralisation using the numerous types of fluid inclusions that formed during the main mineralisation stage. Liquid-rich inclusions (Wa-type) have a wide range of homogenisation temperatures (180–302 °C) and a bimodal distribution of salinities (8–10 and 21–22 wt% NaClequiv). Gas-rich inclusions (Wb-type) have homogenisation temperatures of 379–383 °C and salinities of 4.34–4.49 wt% NaClequiv. The homogenisation temperatures of CO2-rich liquid inclusions (Ca-type) are 222–248 °C, and the salinities are 11.32–13.45 wt% NaClequiv, indicating the fluid underwent significant boiling. δ18Owater values vary from 1.1 to 5.3‰ VSMOW, with δD = −65 to −35‰ VSMOW. The ore-forming fluid has the characteristics of a typical metamorphic hydrothermal fluid. There is a significant difference in δ34S values between the mafic–ultramafic and granitic rocks in the study area, indicate the ore-forming materials were derived mainly from metamorphosed sedimentary rocks of the Sibao Group. The Jialong Sn–polymetallic deposit is a typical example of Caledonian Sn mineralisation, but there was no coeval magmatism, although the Sirong ductile shear zone was active during the period of Sn mineralisation. During the Caledonian activity of the Sirong ductile shear zone, ductile shear deformation resulted in the generation of metamorphic fluids from distal Neoproterozoic strata. This fluid migrated to the northwest under the influence of a pressure gradient, underwent decompression-driven boiling and precipitated Sn and other elements.

Unraveling the genetic type and metallogenetic mechanism of the oldest uranium deposit associated with granitoid, South China: A comprehensive analysis of whole-rock geochemistry, and elemental and U-Pb isotopic signatures of uranium minerals

The Daliang deposit in the Motianling area of South China is unique for its synchronous uranium mineralization with regional metamorphism. To elucidate its genetic mechanism, whole-rock geochemistry from the Daliang deposit was undertaken, along with analyses of the chemical and isotopic signatures of minerals. The Motianling granitoids exhibit strongly peraluminous S-type affinities with low Th/U ratios, representing a uranium source for mineralization. Altered mineralogical and geochemical signatures of altered and ore samples indicate a multi-stage history after granitic emplacement: (1) Late magmatic-hydrothermal alteration characterized by greisenization, K-feldspathization, and propylitization; and (2) brittle-ductile deformation with uranium mineralization. Notably, ore-stage alteration mineral contains chlorite + quartz + sericite, which is consistent with the mineral assemblage of low-greenschist facies metamorphism. EMPA and LA-ICPMS dating on pitchblende yielded ages of 378 and 380 Ma, coinciding with the timing of regional ductile deformation. The pitchblende exhibits weak fractionation between LREEs and HREEs and negative Eu anomalies, mirroring characteristics observed in syn-metamorphic uranium deposits. Therefore, we suggest that uranium mineralization within the Daliang was related to crustal metamorphism, and the Daliang deposit belongs to syn-metamorphic deposit. Fluids likely have been liberated from the acidic brines-bearing Sibao Group that underwent low-greenschist facies metamorphism. Paleozoic intracontinental orogeny in South China resulted in brittle-ductile deformation in the Motianling pluton. These zones provided favorable pathways for the migration of ore-forming fluids and subsequent uranium mineralization. Late Devonian retro-metamorphism facilitated the percolation of oxidizing metamorphic fluids into the Motianling granitoids, circulating along the pre-existing brittle-ductile zones. This study presents the first evidence for syn-metamorphic uranium deposits within the granite of South China. This finding suggests potentially distinct mineralization mechanisms compared to traditional granite-related uranium deposits in the region, warranting further investigation.

Low-temperature preparation of C/C-W-Cu composites with enhanced particle impact and ablation resistance

Herein, C/C-W-Cu composites were innovatively developed by a molten salt assisted reactive infiltration method, with the preparation temperature of only 1300 ℃, far lower than the traditional infiltration temperatures. The as-prepared C/C-W-Cu composites exhibited better particle erosion and high-temperature ablation resistance than C/C composites, with a linear variation rate decrease of 99.5 % and 80.3 % under particle impact (70 m/s, 10 s) and oxyacetylene ablation (2.4 MW/m2, 120 s) conditions, respectively. The improved protection performance can be attributed to the synergistic effects of ductile deformation of the surface W-Cu metal layer and transpiration cooling of the filled Cu phase, which prevents serious carbon fiber damage and ensures a low response of surface ablation temperature (∼1400 ℃).

Internal shear damage evolution of CFRP laminates ranging from −100 °C to 100 °C using in-situ X-ray computed tomography

Carbon Fiber Reinforced Polymer (CFRP) composites have been widely used in aerospace due to their high specific stiffness, strength, and fatigue properties. However, the ambient temperature significantly influences CFRP's mechanical properties and damage evolution, deriving from the temperature effect on the microstructural behavior and the mesoscopic damage evolution. In this study, the temperature-dependent in-plane shear failure behavior of CFRP composites was investigated. In-situ X-ray Computed tomography (CT) tensile experiments of laminates ([45°/-45°]2s) at RT, −100 °C, and 100 °C were carried out to study the in-plane shear failure mechanisms. The 3D fracture morphology was extracted with internal damage evolution process estimated and quantified. The in-situ 3D deformation fields of critical regions were acquired using the Digital Volume Correlation (DVC) method. The effect of temperature on strain field and the correlation between the high-strain region and the fracture location were analyzed. The results revealed the temperature correlations and failure mechanisms of CFRP's mechanical characteristics and internal damage evolution process. Compared to room temperature (RT), the delamination damage area of the sample increased by 80 % at 100 °C. Meanwhile, the shear modulus of CFRP decreases by 78.4 % from −100 °C to 100 °C, and the fracture strain increases by 95 % from RT to 100 °C. The DVC results indicated a dispersion of high-strain regions at −100 °C, reflecting the brittle damage characteristics, while an extensive ductile deformation region was captured at 100 °C. Fiber-matrix debonding is the dominant failure mode of composites under shear loading, whereas significant matrix cracking was observed at −100 °C and partial fiber pullout occurred at 100 °C.

The Magino Gold Deposit, Ontario, Canada: An Overprinted Archean Intrusion-Related Gold Deposit

Abstract The Magino gold deposit, located within the Michipicoten greenstone belt of the Wawa subprovince (Ontario, Canada), is a past-producing underground mine which has recently begun production as an open-pit gold mine with 4.5 Moz of Au in resources. Gold is primarily hosted within the ca. 2724 Ma Webb Lake stock, a steeply dipping, tabular, multiphase tonalitic intrusion oriented parallel to the penetrative regional S2 foliation along the Goudreau Lake deformation zone. The Magino deposit underwent two gold mineralization events (Au1, Au2) and three ductile deformation events (D2, D3, D4). The main gold event (Au1) is expressed by pervasive biotitic/phengitic alteration of the stock and the emplacement of auriferous sugary quartz veins. The veins have a molybdenite Re-Os age of 2731 ± 6.9 Ma, which is indistinguishable from that of the host Webb Lake stock. Quartz-feldspar porphyry dikes cogenetic with the Webb Lake stock cut across the veins and are transposed, stretched, and folded parallel to the S2 foliation within high-strain corridors in the stock, supporting a pre-D2 timing for the Au1 event. These D2 high-strain corridors formed during localization of deformation along Au1 hydrothermally altered zones. The Au2 event occurred during the D2 event and is associated with the emplacement of N-trending quartz-tourmaline-carbonate veins with albitic alteration selvages, which were later deformed during D3 dextral reactivation of the high-strain corridors. Later D4 vertical loading produced a subhorizontal crenulation cleavage, which is overprinted by chloritoid porphyroblasts that grew during late upper greenschist facies peak metamorphism. The Magino deposit is an example of an Archean intrusion-related gold system, which was structurally modified and overprinted by a syndeformation epigenetic gold mineralization event and late metamorphism.

A synthesis of the REE-Fe-polymetallic mineral system of the REE-line, Bergslagen, Sweden: New mineralogical and textural-paragenetic constraints

Rare earth elements (REE) have gained increasing significance for numerous technologies, particularly in today’s rapidly expanding “green transition” applications such as wind generators and electric vehicle traction engines. Among the more well-known REE mineralisation types in Sweden, together with alkaline intrusions and apatite-iron oxide ores, is the classic yet enigmatic REE-Fe-polymetallic mineral system of Bastnäs-type. The mineralisation type is regional in context and occurs in a discontinuous SW-NE-striking belt (the REE-line) in the west-central part of the Palaeoproterozoic Bergslagen ore province, Sweden. This contribution is aimed at integrating and synthesising existing geological mineralogical, and textural features with new observations from both well-known and several lesser-known, underexplored or previously unrecognised REE-enriched occurrences within this belt, and to discuss key features within the context of mineral systems modelling. A considerable diversity in both the style and abundance of REE mineralisation as well as in discrete REE mineralogy is evident both regionally across the entire REE-line and locally within different ore districts or mine fields. These variations also extend laterally within or across different stratigraphic levels, and within different host rocks, primarily skarn-altered metacarbonates but also variably altered felsic metavolcanic rocks. Many of the mineralisations share similar textural features, which record a protracted evolution with multiple stages of formation or replacement of REE-minerals. The earliest recognised REE assemblages feature fine-grained cerite-(CeCa) with minor bastnäsite-(Ce) – bastnäsite-(La) or fluorbritholite-(Ce) – fluorbritholite-(Y) or locally britholite-(Ce) – britholite-(Y) minerals. Such assemblages typically display anhedral-granoblastic textures appearing in folded assemblages, all suggesting recrystallisation and ductile deformation during regional metamorphism of REE-minerals that had formed during an early stage of the Svecokarelian orogeny. Overprinting overgrowths and cross-cutting vein-like features of allanite-group minerals likely represent different stage(s) of REE mineralisation and (re)-mobilisation during this orogenic evolution. Several of the REE-enriched occurrences contain variably abundant and diverse polymetallic Cu-Mo-Bi-(Co) sulphide mineralisation that typically occur in late paragenetic positions and show a prevalence to REE-rich assemblages, often dominated by different allanite-group minerals. Sulphide and REE mineralisation are locally strongly associated with metamorphic minerals formed during metamorphism of variably Mg-(Fe)-altered metavolcanic rocks. The diversity in style and intensity of the REE mineralisations, along with variations in textures and specific mineralogy, suggest slight differences in the ore-forming conditions or environment at the time of mineralisation. Additionally, these differences may also reflect variations in the preservation or modification processes that operated later in the evolution of the Svecokarelian orogeny, also featuring remobilisation of REEs and sulphidic minerals. The insights gained from all available evidence synthesised herein, from micro-scale to province-scale, help define key proxies for prospectivity mapping. The combined evidence supports that the primary ore-forming stages in the mineral system coincided with felsic volcanism and associated sub-volcanic to plutonic processes at around 1.9 Ga.

3D geometry of the Dugald River Shear Zone, Mount Isa Inlier, Australia

The Dugald River Shear Zone is a structurally complex, anastomosing shear zone that hosts high-grade Zn mineralisation within the Dugald River Slate. The Dugald River Zn–Pb–Ag mine is situated within the Mount Isa Inlier, Australia and developed through two phases of mineralisation with high-grade Zn mineralisation intimately associated with the development of the brittle–ductile Dugald River Shear Zone. The first phase of mineralisation occurred during the regionally extensive, D2 ductile fold and axial planar cleavage forming event and resulted in the development of a sulfide horizon. This horizon was a preferential site for strain partitioning during early D4 ductile deformation, which resulted in transposition-related concentration and thickening of a sulfide horizon marking the second phase of mineralisation. The Dugald River Shear Zone developed during D4 wherein strain rate incompatibilities between a ductile-deforming sulfide horizon and the brittle-deforming Dugald River Slate resulted in the development of a Riedel shear zone. A high-resolution 3D model of the shear zone was constructed from robust drilling and mapping datasets in which releasing and restraining bends highlight the thickening and thinning of ore lenses, respectively. The 3D model with detailed structural analysis and observations allows for predictive modelling of dilational zones within throughgoing Y-shears, which are prospective sites for remobilisation of high-grade Zn sulfides as the ore body developed coevally with progressive shearing.

Microstructural Insights and Composition Analysis of a Fractured Brass Alloy of Unknown Composition Using Advanced Characterization Techniques

This study aims to investigate the microstructural and compositional characteristics of a fractured brass alloy using energy-dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), and X-ray diffraction (XRD). The brass alloy, initially of unknown composition, was determined to consist of 63.65 at% Cu, and 36.35 at% Zn through EDS analysis. Microstructural analysis via SEM revealed a typical ductile fracture pattern with necking and dimple formation, indicative of significant plastic deformation prior to failure. The alloy exhibited a grain size ranging from 10 µm to 80 µm and displayed both α-phase (FCC structure) and possible traces of β-phase, though XRD detected only the α-phase due to the low concentration of β-phase (<5%). A comparison between EDS and XRD results for analyzing chemical composition showed that good assumptions could be made from the lattice parameters of the binary alloy following Nelson-Relay function to predict an approximate composition in binary alloy systems, which was found to be 34 at% Zn in our analysis. Furthermore, the sample’s crystal structure was confirmed as FCC, which supported its observed ductility and plastic deformation prior to fracture. The SEM analysis also confirmed that the material went through an annealing process. The fracture morphology further showed that the FCC structure and the annealing process both contributed to the material’s increased ductility. The analysis further confirms that EDS is more reliable for chemical composition determination in an alloy system. Evidence of annealing twinning in the SEM images suggests the sample underwent an annealing process, contributing to its enhanced ductility.

Sulfur and metal mobilization during the life cycle of an oceanic core complex: Implications for seafloor massive sulfide deposits formation at slow and ultra-slow spreading ridges

Seafloor massive sulfide (SMS) deposits at slow and ultra-slow spreading ridges are often spatially related to, or hosted in oceanic core complexes (OCCs). The specific oceanic crust architecture, magmatism, hydrothermal fluid circulation and lithologies at OCCs, however, imply different S and metal (e.g. Cu, Zn, Co, Ni) fluxes relative to well-structured oceanic crust at-fast spreading ridges and which are not yet fully constrained. The study of S and metal distribution in the ODP Hole 735B deep drill core from the Atlantis bank allows to understand these fluxes along detachment faults and to better constrain the source zone of S and metals for OCC-related SMS deposits. Significant depletion of S, Cu, Zn and Ni are observed within the upper 250 m of the drill core where intense deformation and hydrothermal fluid circulation occurred. During the complex tectono-magmatic-hydrothermal evolution of the Atlantis Bank, four important stages are recognized for S and metal mobilization: 1) magmatic stratification leading to a higher proportion of sulfide-rich and S, Cu, Zn and Co fertile oxide gabbros in the root zone of the Atlantis Bank detachment, 2) high temperature ductile deformation leading to magmatic sulfide reworking and onset of sulfide leaching with limited metal mobilization, 3) extensive sulfide leaching and metal mobilization during amphibolite to greenschist facies metasomatism and, 4) late stage secondary sulfide precipitation and S enrichment during low temperature fluid circulation. Mass balance calculations from the source zones of the Atlantis Bank detachment highlights that metal mobilization during hydrothermal alteration of gabbroic rocks along detachment faults can fully account for the formation of OCC-related SMS deposits at slow and ultraslow spreading ridges. The Atlantis Bank detachment system, however, is gabbroic-dominated and represent the magmatic end-member of OCCs and further work is necessary for understanding metal fluxes in ultramafic-dominated detachment systems.

An innovative strategy for improving ductility of seawater sea-sand engineered cementitious composites beam reinforced with GFRP bar

Seawater sea-sand engineered cementitious composites (SS-ECC) members with glass fiber reinforced polymer (GFRP) bars have inferior ductility due to the brittle nature of GFRP bars. In the current research, an enlarged head anchorage system (EHAS) was recommended to improve the ductility of GFRP bars reinforced SS-ECC beams. To explore the bond characteristics between SS-ECC and GFRP bars with EHAS, a total of 39 specimens were tested by pull-out loading. The influences of enlarged head shape, stirrup spacing and SS-ECC's strength grade on the bond characteristics were experimentally investigated. GFRP longitudinal bars in specimens with EHAS presented rupture failure rather than anchorage failure. EHAS could effectively realize the slip hardening of GFRP bars in low strength SS-ECC, and ensure the reliable bond of GFRP bars in high strength SS-ECC. Additionally, the failure mechanism of specimens under pull-out loading was explored by finite element analysis (FEA). The pull-out resistance was mainly provided by EHAS in force transition stage and slip hardening stage. The influences of fiber reinforced polymer (FRP) bar type on the bond performance were investigated by FEA. EHAS could realize the slip-hardening behaviors of aramid, basalt and carbon FRP bars in normal strength SS-ECC. More importantly, to verify the effectiveness of the proposed ductility enhancement strategy, SS-ECC beams reinforced with GFRP bars were tested by four-point bending. These beams with different enlarged head shapes possessed excellent ductility and strong ultimate deformation capacity. It was recommended that low strength SS-ECC and GFRP bars with EHAS were jointly utilized to enhance the ductile performance of the beams.

Experimental and numerical studies on seismic performance of a novel lead viscoelastic coupling beam

Replaceable coupling beams (RCBs) with different types of dampers have gained significant attention in coupled shear walls for enhancing seismic performances in high-rise buildings, showing superior advantages to conventional reinforced concrete coupling beams (RCCBs). Recently, the authors proposed the hybrid lead viscoelastic damper (HLVD), and its basic mechanical behaviors were experimentally studied. This paper used the HLVD as a replaceable fuse and installed it in the coupling beam to form a new RCB, i.e., lead viscoelastic coupling beam (LVCB). To examine the seismic performance of the LVCB, experimental and numerical studies were carried out in the present study. Quasi-static tests were conducted to comparatively investigate the seismic performances of the RCCB and LVCB. The experimental findings revealed that the RCCB experienced shear failure with severe pinching behaviors under cyclic loadings, while the LVCB exhibited a resilient behavior, showing favorable energy dissipation capacity with a ductile deformation capacity exceeding a rotation angle of 0.04 rad. The LVCB also demonstrated excellent recoverability in repeatability tests, proving its merit for maintaining post-earthquake functionality. Numerical simulations indicated that adjusting the lead rods of the LVCB could conveniently enhance the load-carrying capacity and energy dissipation capacity of the LVCB. The isolated floor slab was recommended as a low-damage control solution for the LVCB to facilitate post-earthquake replacement.

Structural Analysis for Qazzaz Metamorphic Core Complex, Northwestern Arabian Shield, Saudi Arabia

AbstractIdentifying deformational mechanisms and associated structures at various scales, ranging from regional‐scale structures to microscopic fabric, is crucial for the assessment of tectonic development. Thirty‐three samples were taken from the Qazzaz metamorphic core complex to estimate the finite strain for felsic and mafic minerals. These samples included gneisses rocks, monzogranite, and metavolcano–sedimentary rocks for both the Thalbah and Bayda groups. Using the Rf/j and Fry methods, the axial ratios (XZ) range about 2.20 to 7.10 and 1.90 to 9.10, respectively. For various rock units, the strain measurements show moderate to highly deformation. Most of the observed samples show shallow WNW dipping along a N to WNW trend of finite strain (X). The short axes (Z) based to be subvertical foliation related with a subhorizontal foliation. The results demonstrate that contacts generated at semi‐brittle to ductile deformation and that the strain of magnitude has the same value for different lithologic units. It concluded that nappe generation in orogens results from pure shear deformation.

Metallogenic model of the Lykling ophiolite-hosted lode Au deposit, Scandinavian Caledonides: Insight from fluid inclusions, mineral chemistry and stable isotope geochemistry

The Lykling lode Au deposit represents a unique example of gold mineralization in the Upper Allochthone of the Scandinavian Caledonides. The mineralization is hosted by the Early Ordovician Lykling Ophiolite Complex and the intruding trondhjemite unit and spatially associated with two generations of mafic dykes that crosscut both the ophiolitic complex and trondhjemite. Field observations indicate that the mafic dykes did not play an active role in the emplacement of Au at Lykling, however their contacts with the immediate host rocks (i.e., gabbro and trondhjemite) may have focused ore-forming fluids.Three main stages in the evolution of the hydrothermal system in the Lykling area are documented by two generations of auriferous quartz veins: 1) older quartz-carbonate veins hosted by moderately angled brittle-ductile shear zones and 2) younger quartz-sulfide veins that fill steeply dipping brittle faults. Stage 1 resulted in deposition of barren quartz and gold-free pyrite from moderately saline NaCl-CaCl2-H2O ± CO2 fluids at temperatures between ∼310–330 °C and pressures in the range from 2.7 to 3.5 kbars. Under the given physicochemical conditions Au was mobile in the form of its chloride complexes. Stage 2 is associated with multiple episodes of ductile deformation punctuated by concomitant brecciation reflecting brittle-ductile transition processes. Fluid inclusion data reveals a decrease in temperature and pressure that may result in the formation of stable Au-bisulfide complexes and making the hydrothermal mobility of Au sensitive to changes in pressure. Consequently, the fluctuation in pressure controlled by the development of brittle-ductile structures likely resulted in the precipitation of native gold in quartz veins. Stage 3 represents a pure brittle event which is accompanied by a significant decrease in the fCO2/fS2 ratio. Mixing of higher-temperature and moderate-salinity fluids with cooler fluids has been recognized as the principal trigger for deposition of sulfides and a paragenetically late phase of native gold in the Lykling hydrothermal system.The Lykling ophiolite-hosted lode Au deposit shows numerous similarities with orogenic gold deposits elsewhere, including structural controls during mineralizing events, deposition from moderately to low salinity CO2-bearing aqueous solutions, deposition from a focused fluid flow along trans-crustal fault zones with a mixed brittle-ductile character and the spatial association with regionally metamorphosed terranes. In contrast to the great majority of the known orogenic gold deposits, the Lykling ophiolite-hosted lode Au deposit records a magmatic origin of volatiles. Therefore, taking into consideration field relationships and the regional setting of the Lykling deposit, we argue that its formation is concomitant with emplacement of the Sunnhordland Batholith during post-collisional thinning of the crust and associated localized uplift within the Lykling Ophiolite Complex.

Mountain building process of the Taiwan orogeny.

The Taiwan orogeny, an example of arc-continental collision, exhibits complex geological structures and rapid exhumation. Many models have tried and failed to fully capture the dynamics of these processes. We developed a comprehensive thermomechanical model that considers the transition from brittle to ductile behavior with depth, lithology-dependent erosion and observed decollement and backstop geometries. This model successfully reproduces the intricate structures observed within the Taiwan orogeny, aligns with structural complexities, metamorphic temperature profiles, thermochronological records, strain distributions, and the rates of exhumation and cooling and elucidates the roles of ductile deformation and ramp structures in forming the Hsuehshan Range and the Western fold and thrust belt. The insights from this model offer potential applicability to other orogenic wedges worldwide.

Experimental Investigation on the Seismic Performance of Novel Prefabricated Composite RC Shear Walls with Concrete-Filled Steel Tube Frame

The present study proposed novel prefabricated composite RC shear walls with a concrete-filled steel tube frame (CCRCSW-CFST) because of the superior seismic performance of shear walls incorporating CFSTs as boundary-restrained members. One cast-in-place reinforced concrete shear wall (RCSW) and seven CRCSW-CFSTs, each varying in axial compression ratios, concrete strengths, and shear span ratios, were designed for experimental analysis. Cyclic loading tests were performed on these specimens, yielding the following results: (1) Compared to reinforced concrete shear walls, CCRCSW-CFSTs demonstrated superior seismic performance, with 14.2% increased ductility and 47.5% greater energy dissipation capacity. (2) Elevating the axial compression ratio in CCRCSW-CFSTs resulted in increased yield strength, peak strength, and stiffness. Conversely, this adjustment also expedited the degradation of stiffness with displacement and decreased both ductility and ultimate deformation. (3) The peak displacement and ultimate displacement of CCRCSW-CFSTs were both increased with an increase in concrete strength. Increasing the axial compression ratio enhanced the initial stiffness of CCRCSW-CFSTs and mitigated the rate at which stiffness deteriorated with increasing displacement. (4) The stiffness, peak and ultimate displacements, peak and ultimate loads, and shear span ratio of CCRCSW-CFSTs were significantly reduced as the shear span ratio was increased. (5) The minor slip between the reinforced concrete panel of the precast slab and the encasing C-shaped steel contributed to an increase in early-stage energy dissipation of the CCRCSW-CFSTs.

Two-stage mineralization of the Jinkeng Sn-Cu deposit in Eastern Guangdong, Southeast China: Response to magmatic activities and tectonic transformation

The Jinkeng Sn-Cu polymetallic deposit in South China consists of two different types of orebodies: 1) NE-striking skarn- and vein-type Cu-Pb-Zn-Sn orebodies in volcanic rocks suffering subsequent ductile shear deformation, and 2) NW-striking quartz-cassiterite-sulfide veins filled in the faults at the porphyritic granodiorite outward from the fine-grained granite which does not exhibit deformation. The relationships among Sn-Cu polymetallic mineralization, regional magmatism, and deformation metamorphism are still controversial. To address it, the geochronological, whole-rock and mineral geochemical research along with the detailed field investigation were conducted in this study. Our zircon U-Pb dating results show that the volcanic rocks formed at 158–162 Ma, earlier than the porphyritic granodiorite which yields the emplacement age of 146–147 Ma. In-situ LA-ICP-MS U-Pb dating of cassiterite from the deformed skarn ores indicates the early-stage mineralization occurred at 146 ∼ 148 Ma, which is similar to the emplacement age of the porphyritic granodiorite, but earlier than the formation of quartz-cassiterite-sulfide veins and the fine-grained granite (141∼144 Ma). Further, the whole-rock and biotite geochemistry, and zircon Hf isotope compositions suggest that the porphyritic granodiorite exhibits a lower degree of magma differentiation, higher oxygen fugacity, higher Cl and lower F contents than the fine-grained granite. The porphyritic granodiorite might provide the most Cu-Pb-Zn budget accompanied by minor Sn for early-stage mineralization. Overall, our study suggests that the Jinkeng Sn-Cu polymetallic deposit formed in two scenarios where the early dominated Cu-Pb-Zn and minor Sn mineralization related to the emplacement of the porphyritic granodiorite is superimposed by the late vein-type Sn-dominated mineralization related to the emplacement of the fine-grained granite. The two isolated mineralizing events (∼147 Ma and ∼141 Ma, respectively) in Jinkeng were probably responded to the regional magmatic activities triggered by the tectonic transformation where two extensional tectonic events were separated by a short contractional event (147–144 Ma).

Late Mesozoic ductile deformation and exhumation along the Shangdan suture zone in the Qinling Orogenic Belt, China

The Qinling Orogenic Belt (QOB) is a multi‐stage orogenic belt recording subduction and collision processes. The ductile shearing deformation with different properties and ages is developed on the boundary of the different litho‐tectonic units, which can be used to decipher the tectonic evolution of the QOB. Previous studies mainly concentrated on the pre‐Late Mesozoic shearing deformation, while the Late Mesozoic shearing deformation received less attention. It restricts the understanding of the Late Mesozoic tectonic evolution of the QOB. Hence, we conducted detailed field structural analysis and laboratory analysis of the Shagou shear zone (SGSZ) in the middle part of the Shangdan suture zone (SDSZ). The SGSZ, developed in the southern margin of the Baliping pluton, is an S–SSW‐dipping sinistral strike‐slip ductile shear zone with a top‐to‐the‐ESE shear sense. The mylonite protoliths are voluminous Late Triassic granites (200–215 Ma) and a small amount of Neoproterozoic granites (759 Ma) and Early Cretaceous granites (145 Ma). Microstructures and geothermobarometer results suggest that the ductile shearing deformation occurred under high greenschist–low amphibolite‐facies conditions (400–650°C) at middle crustal depths (13–21 km). Zircon U–Pb and amphibole‐biotite 40Ar/39Ar dating results constrain the timing of shearing deformation to 135–145 Ma and the rapid exhumation of the SGSZ to 115–135 Ma. Combining with the regional data, we consider that the sinistral strike‐slip shearing deformation in the SGSZ controls and accommodates the south‐eastward extrusion of the East SQB under the intracontinental compression. Subsequently, the intracontinental extension led to the rapid exhumation of the SGSZ.

Cyclic tensile response and crack closure performance of novel superelastic Ni-Ti SMA cable grid-reinforced engineered cementitious composites

To further improve the tensile and self-healing properties of engineered cementitious composites (ECCs) for their special uses such as harsh environments, plastic hinge regions, and old members strengthening, an innovative high-performance superelastic Ni-Ti shape memory alloy (SMA) cable grid-reinforced ECC (SMACG-ECC) was first proposed and tested in this study. The effects of water-binder ratio, cable grid material, and reinforcement ratio on the cyclic tensile properties and crack closure performance of the proposed SMACG-ECC were systematically examined. Test results revealed that the tensile strength, initial crack strength, ultimate tensile strain, dense crack, crack closure, and self-healing properties of the traditional ECC were obviously improved by being reinforced with the SMACG. Compared with the ordinary steel cable grid-reinforced ECC (SCG-ECC), the proposed SMACG-ECC exhibited approximately 50 % lower first crack strength, similar tensile strength and deformation ductility, but a 53.7 %-75.1 % greater energy dissipation, 75.8 %-80.2 % lower residual strain, and 80.4 %-83.4 % smaller maximum residual crack width. The tensile properties, cracking performance, and self-healing ability improved with the incorporation of SMACG as well as the increase in reinforcement ratio. Notably, most specimens showed satisfactory composite operation with no cable ends slipping during the entire cyclic loading process, with a maximum tensile strain amplitude of 8 %.